Abstract: Compositions and methods useful for oxygen sorption and other uses are presented, the compositions A composite material comprising components (A) and (B), wherein component (A) is selected from crystalline ceramic materials capable of forming a stable, reversible perovskite crystal phase at elevated temperatures (T>500° C.), and combinations thereof, and component (B) comprises a metal selected from rhodium (Rh), platinum (Pt), palladium (Pd), nickel (Ni) and silver (Ag), and combinations and alloys of these metals.

Abstract: This invention is to a process for removing dimethyl ether from an olefin stream. The process includes contacting the olefin stream with a molecular sieve that has improved capacity to adsorb the dimethyl ether from the olefin stream. The molecular sieve used to remove the dimethyl ether has low or no activity in converting the olefin in the olefin stream to other products.

Abstract: When a shutoff signal is entered to shut off a fuel gas manufacturing apparatus, it is determined whether a PSA mechanism is in a prescribed shutoff state or not. If the PSA mechanism is judged as not being in the prescribed shutoff state, the fuel gas manufacturing apparatus is continuously operated until the PSA mechanism is brought into the prescribed shutoff state. Then, if the PSA mechanism reaches the prescribed shutoff state, the fuel gas manufacturing apparatus is shut off.

Abstract: Pressure swing adsorption process for the separation of a feed gas mixture comprising (a) providing a pressure swing adsorption system comprising one or more composite beds, each composite bed comprising adsorbent material disposed in two or more vessels in parallel flow configuration, each vessel having a feed end and a product end; (b) performing cyclic sequential steps comprising adsorption/make product, withdrawing gas at decreasing pressure from the composite bed, purging the composite bed, and introducing gas into the composite bed at increasing pressure; and (c) for any of the sequential steps, setting a flow rate or flow rates of one or more gases selected from the group consisting of gas introduced into or withdrawn from the feed end or ends of any of the two or more vessels and gas introduced into or withdrawn from the product end or ends of any of the two or more vessels.

Abstract: Novel polybed VPSA process and system to achieve enhanced O2 recovery are disclosed. The VPSA process comprises using three or more adsorber beds; providing a continuous feed supply gas using a single feed blower to one bed, wherein at any instant during the process, two beds are in an evacuation step and only one bed is in a feed mode; and purging the adsorber beds using two purge gases of different purity. The VPSA cycle may further comprise utilizing a storage device (e.g., a packed or empty equalization tank) to capture void gases during co-current depressurization step of the VPSA cycle, which is used at a later stage for purging and repressurization of the bed. In addition, the VPSA process employs a single feed compressor and two vacuum pumps at 100% utilization. Furthermore, the use of the storage device minimizes the use of product quality gas for purging. About 10-20% improvement in O2 productivity is realized in the new VPSA process.

Abstract: The present invention relates to cryogenic air separation processes and systems that employ a pressure swing adsorption (PSA) prepurification process. It is advantageous to operate the PSA process at a pressure comparable to or below the operating pressure of the highest pressure column in the cryogenic separation unit. Following PSA prepurification, the air can be split into at least two fractions, with at least a portion of the air being directed to the cryogenic separation unit and at least a portion of the remaining air being further pressurized in at least one stage of compression.

Abstract: A process for the removal of inert gases, such as nitrogen and carbon dioxide, from methane-containing gases, such as natural gas, including a first stage removal which lowers the total combined inert content to about less than 30% and a second stage removal utilizing a pressure swing adsorption process comprising one or more adsorbent beds comprising contracted titanosilicate-1 adsorbent, wherein the purified methane-containing gas contains less than about 6% total combined inerts.

Abstract: A gas separator works on a pressure swing principle. The separator includes multiple sieve beds, preferably five arranged in pentagonal fashion about a centerline, and a control valve. The control valve includes a rotor and a stator. The rotor is mounted for rotation relative to the stator. One part of the rotor allows pressurized gas to flow to the stator and thereon to one or more, and preferably two, of the sieve beds for separation. Another part of the rotor blocks flow of gas through the stator to or from one or more of the sieve beds, and yet another part of the rotor allows waste gas to flow from one or more of the sieve beds back through the stator to an exhaust. The separator may be used as part of a system. In a method of use, sieve beds are cycled between adsorption, de-pressurization, purging, and pre-pressurization phases.

Abstract: The present invention relates to a process for purifying a syngas of the CO/H2 or N2/H2 type, which consists in removing CO2 and possibly other gaseous impurities (water, etc.) before the gas undergoes a cryogenic process. These impurities are adsorbed by the gas stream to be purified passing over an NaLSX-type zeolite and then desorbed during a regeneration step which may be performed by raising the temperature (TSA) and/or reducing the pressure (PSA or VSA).

Abstract: Process step in a pressure swing adsorption process using multiple parallel adsorbent beds operating in cyclic process steps to recover a less strongly adsorbable component from a feed gas mixture containing at least one less strongly adsorbable component and at least one more strongly adsorbable component, wherein each adsorbent bed has a feed end and a product end, wherein each bed is subjected to at least a feed/product step, one or more depressurization steps, a purge step in which a purge gas enriched in the less strongly adsorbable component is introduced into the product end of the bed and a purge effluent gas is withdrawn from the feed end of the bed, and one or more repressurization steps. The process step comprises introducing at least a portion of the purge effluent gas from a first bed into the feed end of a second adsorbent bed at any time other than during the feed/product step in the second adsorbent bed.

Abstract: A first aspect of a process of recovering xenon from feed gas includes: providing an adsorption vessel containing adsorbent having a Xe/N2 selectivity ratio <75; feeding into the adsorption vessel feed gas having an initial nitrogen concentration >50% and an initial xenon concentration ?0.5%; evacuating the adsorption vessel; and purging the adsorption vessel at a purge-to-feed ratio ?10. The final xenon concentration is ?15× the initial xenon concentration. A second aspect of the process includes providing an adsorption vessel containing adsorbent having a Xe Henry's law Constant ?50 mmole/g/atm; feeding into the adsorption vessel feed gas having an initial nitrogen concentration >50% and an initial xenon concentration ?0.5%; heating and purging the adsorption vessel to recover xenon having a final concentration ?15× its initial concentration. Apparatus for performing the process are also described.

Abstract: The present invention relates to a PSA system using an indexing rotary dual valve regulating a stepping mode of operation that controls a variable bed inlet feed flow rate, controllable pressure between feed lines in different beds of the PSA system and varied output flow rate of product gas such as high purity hydrogen gas.

Abstract: Oxygen generation system having a portable oxygen generator unit including a portable air separation device for the generation of an oxygen-rich gas, a primary gas pump including means to supply air to the portable air separation device, a primary motor to drive the gas pump, a rechargeable power supply to drive the motor, connector means adapted to deliver power to the rechargeable power supply, flow coupling means to transfer the oxygen-rich gas from the portable oxygen generator unit, and a first oxygen-rich gas product discharge port. The system also includes a stationary base unit adapted to couple with the portable oxygen generator unit, wherein the stationary base unit has a stationary power supply system including connector means adapted to recharge the rechargeable power supply in the portable oxygen generator unit, flow coupling means to receive the oxygen-rich gas from the portable oxygen generator unit, and an optional second oxygen-rich gas product discharge port.

Abstract: For PSA or TSA prepurifiers, the temperature rise on adsorption is particularly troublesome when the temperature rise reaches the end of the bed at the end of the adsorption step. This results in an increase in the CO2 and N2O concentration at the end of the cycle. Addition of a regenerator in the middle of the adsorption layer will reduce the temperature rise at the end of the bed and thus enhance the performance of the bed.

Abstract: The invention concerns a treatment method which consists in using a pressure swing adsorption treatment unit (16) and causing said treatment unit (16) to follow a nominal operating cycle, based on nominal operating conditions and in order to ensure minimal performances of the feed gas treatment. It further consists in providing at least a pre-programmed auxiliary operating cycle, different from the nominal cycle, and, when the operating conditions differ from the nominal conditions to the extent that the treatment unit (16) no longer achieves its minimal performances, in imposing to the treatment unit (16) to follow the or one of the auxiliary cycles.

Abstract: A method of hydrogen recovery in refineries and petrochemical operations in which some or all of the feed streams for separate PSA units are combined and utilized as feed for a single PSA unit, and in which some or all of steam reformer product and refinery offgas streams being used as feed streams for separate PSA units are combined and utilized as feed for a single PSA unit. Total hydrogen recovery is increased by maximizing hydrogen recovery from refinery offgases. The load on the steam reformer is reduced by lowering the reformer feed stream. Refinery fuel gas consumption is reduced in the steam reformer furnace. The amount of a PSA feed stream being burned as fuel or sent to flare is reduced. The load on the PSA unit receiving feed from refinery offgases is reduced. The hydrocarbon content and heating value of the tail gas from the PSA unit fed by the steam reformer product stream is enriched.

Abstract: Gas separation by pressure swing adsorption (PSA) and vacuum pressure swing adsorption (VPSA), to obtain a purified product gas of the less strongly adsorbed fraction of the feed gas mixture, is performed with an apparatus having a plurality of adsorbers. The adsorbers cooperate with first and second valves in a rotary PSA module, with the PSA cycle characterized by multiple intermediate pressure levels between the higher and lower pressures of the PSA cycle. Gas flows enter or exit the PSA module at the intermediate pressure levels as well as the higher and lower pressure levels, under substantially steady conditions of flow and pressure. The PSA module may comprise a rotor containing laminated sheet adsorbers and rotating within a stator, with ported valve faces between the rotor and stator to control the timing of the flows entering or exiting the adsorbers in the rotor.

Abstract: An exhaust gas aftertreatment filter system for an internal combustion engine includes an aftertreatment filter disposed in-line with an exhaust gas conduit coupled to an internal combustion engine, a mounting bracket defining a mounting surface and at least one leg extending from the mounting bracket, the at least one leg defining a mounting foot at a distal end thereof with the mounting foot of the at least one leg and the mounting surface of the mounting bracket defining a first air gap therebetween, the mounting foot of the at least one leg secured to the aftertreatment filter, and at least one electrical component secured to the mounting surface of the mounting bracket.

Abstract: This invention relates to gas separation processes using a Li-rho zeolite, in particular to an air separation process where the Li-rho zeolite is an oxygen selective adsorbent.

Abstract: The present invention relates to a gas recycling system that includes a) a source of gas having a predetermined purity; b) an application system that uses the gas and adds contaminants to the gas; c) an adsorption system for removing the contaminants from the gas to produce a purified gas and a waste gas; d) a gas purity analyzer for measuring the amount of the contaminants in the waste gas; and e) conduits connecting the gas source to the application system, and the application system to the adsorption system.

Abstract: An on-board adsorber and method for delivering oxygen on an aircraft that has a squat and compact configuration with a mass of adsorbent with a height to diameter ratio ranging from 0.8 and 2, and the ratio of the cross-sectional area S of the mass of adsorbent to the cross-sectional area S of the central duct ranges from 80 to 110.

Abstract: Process for purifying or separating a gas or gas mixture using a monolithic adsorbent for the separation or purification of gases or gas mixtures, having a cellular structure with open porosity in the form of a solid foam permeable to the gas molecules. The gas phase of the adsorbent possesses an essentially convex structure and the solid phase an essentially concave structure. The solid foam has a density of greater than or equal to 500 kg/m3 and an open porosity of between 20 and 60%. The gas is air or an H2/CO mixture. The process is of the VSA, PSA or TSA type. This process can be used in particular in OBOGS-type systems to supply passengers of the vehicle or a device participating in the traction of the vehicle and/or in its electrical supply, in particular a fuel cell. This process can also be used in medical oxygen concentrators.

Abstract: The present invention is a pressure adsorber vessel that employs a radial adsorbent bed with a variable perforated flow distributor to provide an effective uniform fluid flow though the adsorbent bed.

Abstract: Method and apparatus for providing clean air to an environment. Incoming air, which may be contaminated with chemical, nuclear or biological contamination is initially cooled and water is removed from the cooled air by a first cooler, a first water separator, a second cooler and a second water separator. The cooled air is passed through a regenerative pressure swing absorption system which removes the contaminants. The resulting, cleaned, air is expanded by an expander. The expanded, cleaned air is provided to the environment, after being used in the second cooler to clean the incoming air.

Abstract: A vehicle air system has an air dryer which is periodically regenerated by reverse flow of dry air. The regeneration threshold is variable, and determined according to the operating state of the vehicle. The operating state is in turn determined from easily measurable vehicle status parameters, preferably in the form of on/off or in/out signals.

Abstract: A pivoting vane rotary compressor includes a housing having a generally pear-shaped chamber. A rotor mounted within the chamber defines a main and constricted chamber regions. Reversible intake and exhaust ports alternately introduce air into and exhaust air from the chamber. The rotor carries pivotable vanes and a motor drives the rotor alternately in opposing first and second directions to open the vanes and define compartments that transmit the air through the chamber between the ports. Air introduced through one of the ports is compressed and discharged through the other port. A concentrator employs a pair of these compressors as well as associated filters and crossover valves.

Abstract: A method of installing a molecular sieve bed gas enrichment system in a vehicle such as an aircraft. A system controller, a product gas distribution conduit, a high pressure gas supply conduit which extends from a high pressure gas source, and a plurality of molecular sieve beds are installed in the vehicle. Each sieve bed has a first port which delivers product gas through a check valve to an outlet duct. Each sieve bed also includes a second port connected to a valve assembly which is controlled by the system controller to connect the second port either to a gas supply duct during a charging phase or to a venting duct during a venting phase. The outlet duct for each sieve bed is connected to the product gas distribution conduit, and the gas supply duct for each sieve bed is connected to the high pressure gas supply conduit.

Abstract: The present invention relates a method for concentrating a gas by applying a pressure difference to an adsorbent and an apparatus therefor, and particularly, a method for producing an enriched gas in a large amount by introducing a continuous production into every step of the process focusing on productivity rather than concentration of the product gas and an apparatus therefor. The present invention relates to a method incorporating the vacuum swing adsorption method with the pressure swing adsorption method, particularly the rapid pressure swing adsorption method which can continuously produce a desired material in a depressurization step to improve recovery rate of the desired material and productivity and an apparatus therefor. The apparatus according to the present invention is advantageously applied in a small size machine rather than for industrial uses.

Abstract: One embodiment of the present invention provides a system for ionizing airborne particulates. The system includes an insulating substrate and a first electroplated structure on the insulating substrate. This first electroplated structure includes an anchor and a probe structure on the anchor that is separate from the insulating substrate. A second electroplated structure is included on the insulating substrate.

Abstract: The present invention provides for a monolith reactor process for the production of syngas from hydrocarbon and oxygen feeds. The syngas is cooled and separated to produce carbon monoxide and hydrogen, and the purification equipment utilized in this separation process recycles tail gas and fuel gas to the syngas feed gas line and recycles methane from the carbon monoxide separation system for feed back to the monolith reactor. This process results in almost complete carbon to carbon monoxide conversion and very high carbon monoxide and hydrogen recoveries.

Abstract: A portable gas fractionalization apparatus that provides oxygen rich air to patients is provided. The apparatus is compact, lightweight, and low-noise. The components are assembled in a housing that is divided into two compartments. One compartment is maintained at a lower temperature than the other compartment. The lower temperature compartment is configured for mounting components that can be damaged by heat. The higher temperature compartment is configured for mounting heat generating components. An air stream is directed to flow from an ambient air inlet to an air outlet constantly so that there is always a fresh source of cooling air. The apparatus utilizes a PSA unit to produce an oxygen enriched product. The PSA unit incorporates a novel single ended column design in which all flow paths and valves can be co-located on a single integrated manifold. The apparatus also can be used in conjunction with a satellite conserver and a mobility cart.

Abstract: Disclosed embodiments address contaminant management challenges that arise during production of desirably contaminant free product fluid in the operation of PSA equipment, and further address the more serious challenges that arise under intermittent operation of PSA equipment. One disclosed embodiment of a PSA apparatus, intended primarily for normal operating cycle speeds of at least 3 cycles per minute, includes a breather fluidly coupled to a feed end of an adsorber with a contaminant-sensitive adsorbent. The breather can be coupled to the feed end through a shutoff valve closed during production and open during shutdown. Other disclosed embodiments of the PSA apparatus used particular sealing strategies for additional sealing of the apparatus, or at least components thereof, from contaminant ingress.

Abstract: The treatment unit comprises N adsorption units, N being greater than or equal to 1, operating on a parametrized cycle split uniformly into at most N phase times. Further more, use is made of a control unit for controlling the treatment unit, designed to modify at least one parameter of the cycle. Each time there is a predicted change in the composition of the feed gas, the control unit is sent a pre-established signal representing this change. The processing unit then processes the signal to determine the parameters of an exceptional operating cycle of the treatment unit which cycle is suited to the predicted change.

Abstract: A system and a process for recovering high concentrations of methane from crude natural gas and solid waste landfill exhaust gas uses a sequential combination of a pressure swing adsorber unit operation to remove volatile organic compounds from the crude feed gas mixture followed by a membrane separation unit operation. The membrane separation uses a membrane which is selectively gas permeable to reject transmission of methane and thus to produce a permeate depleted in methane relative to the feed mixture. The permeate is also free of volatile organic compounds and is recycled to the pressure swing adsorber unit operation to regenerate saturated adsorbers.

Abstract: A PSA unit for purifying hydrogen in a fuel processor system. The PSA unit employs rotary valves that cycle the pressurization of vessels, including an adsorbent, between a high pressure state and a low pressure state. The purified hydrogen is released from the vessels through a purified gas output port when the vessels are in the high pressure state and the impurities are released through an exhaust port when the vessels are in the low pressure state. The PSA unit also employs a mass flow control device and a pressure sensor in the purified gas output port. A controller receives a pressure signal from the pressure sensor, and controls the flow through the mass flow control device and the speed of the rotary valves so that the proper pressure is maintained at the hydrogen output port.

Abstract: Zeolite adsorbent, and method of production, exchanged with calcium and barium cations, for purifying or separating a gas or gas mixture, in particular air, so as to remove therefrom the impurities found therein, such as hydrocarbons and nitrogen oxides (NxOy). The adsorbent is preferably an X or LSX zeolite and the gas purification process is of the TSA type.

Abstract: A gas generation method and apparatus, capable of use in an aircraft, generates oxygen with at least one On Board Oxygen Generating System (OBOGS) and generates an inert gas with at least one On Board Inert Gas Generating System (OBIGGS) and selectively supplies an auxiliary supply of inert gas utilizing a waste gas output of the at least one OBOGS. The inert gas can include nitrogen. An auxiliary source of oxygen can also be provided. Control valves can be used to selectively supply the waste gas output of the at least one OBOGS to the atmosphere or to either of two locations. The oxygen can be used in a passenger compartment of the aircraft and the inert gas used in either a fuel tank or cargo bay of the aircraft.

Abstract: A process and composition for selectively adsorbing oxygen from a gaseous mixture. The chemisorption is carried out by a porous three-dimensional transition element complex comprised of intermolecularly bound TEC units, said units further comprised of at least one multidentate ligand forming at least one five- or six-membered chelate ring on each unit.

Abstract: The present invention is a separation process for producing a methanol, ethanol and/or dimethyl ether stream from a first stream containing C3+ hydrocarbons. The first stream comprises C3+ hydrocarbons, methanol, ethanol and/or dimethyl ether. The process comprises the step of passing the first stream through an adsorbent bed having a crystalline microporous material that preferentially adsorbs methanol, ethanol and/or dimethyl ether over the C3+ hydrocarbons.

Abstract: Component contained in a gas mixture can be separated based on a PSA method and recovered with high purities at the same time, the system is simple, the system cost is low, and the operation is easy and may be used for separating oxygen and nitrogen from air or for separating noble gases and nitrogen from a gas mixture containing noble gases and nitrogen, and obtaining each gas as a product.

Abstract: Method and system on board an aircraft for the production of an oxygen-enriched gas stream from an oxygen/nitrogen gas mixture, particularly air, comprising at least one adsorber containing at least one adsorbent for adsorbing at least some of the nitrogen molecules contained in the oxygen/nitrogen feed mixture, characterized in that the adsorbent comprises a faujasite-type zeolite, having a Si/Al ratio of 1 to 1.50, exchanged to at least 80% with lithium cations. Aircraft equipped with such a system, in particular an airliner, especially an airliner of the long-range, large-capacity type.

Abstract: Contemplated configurations and methods include a hydrogen pressure swing adsorption unit that receives a feed gas comprising a hydrogen production stream and a non-recycled hydrogen-containing waste stream.

Abstract: A gas separation method and apparatus that recovers efficiently principal gas components from a feed gas that includes a plurality of components, and enables supplying the product gases continuously at a stable flow rate and component concentration. A first separation step using a first adsorption column and a second separation step using a second adsorption column are provided, a circulating feed gas, consisting of the recovered exhaust gases discharged in each of the steps and the feed gas, is used as a gas to be separated. The outflow rate and component concentration of a second gas product are maintained constant by controlling the outflow rate of the first gas product.

Abstract: A pressure swing adsorption (PSA) system including a first group of PSA modules having a plurality of first PSA modules, and a second group of PSA modules having a plurality of second PSA modules. The system includes a feed gas manifold, a product manifold, and a waste manifold connected to the first PSA modules and the second PSA modules. Each first PSA module operates on a first PSA cycle in synchronization with the other first PSA modules, and each second PSA module operates on a second PSA cycle in synchronization with the other second PSA modules. The first PSA cycle is offset from the second PSA cycle. The PSA modules include a plurality of pressurized adsorbent chambers, an inlet manifold, and an outlet manifold. A rigid structure is provided that connects the inlet manifold to the outlet manifold, and structurally joins the inlet and outlet manifolds to the adsorbent chambers.

Abstract: An adsorbent for separating nitrogen from a mixed gas of oxygen and nitrogen is MSC wherein an oxygen and nitrogen separation ratio ? and a ratio (t95/t50) of a time t50 required for adsorbing 50% of the oxygen equilibrium adsorption amount and a time t95 required for adsorbing 95% of the oxygen equilibrium adsorption amount satisfy the inequality (t95/t50)<0.4×(??24)??35. The amount of adsorbent used with respect to a predetermined amount of nitrogen generated can be reduced since a method is carried out which uses this adsorbent to produce nitrogen by separating nitrogen from the mixed gas of oxygen and nitrogen by means of a PSA method. By this method, it is possible to reduce the cost of the apparatus and reduce and miniaturize the scale of the apparatus, and the power consumption amount can be reduced.

Abstract: A method for operating a typical cyclic adsorption unit that is easily implemented in both new and existing treatment plants, wherein fluctuations in the stream compositions due to the adsorption and regeneration phase transitions of the cycles are minimized.

Abstract: A gas separation system for separating a feed gas mixture into a first gas component and a second gas component comprises a stator, and a rotor rotatably coupled to the stator. The stator includes a first stator valve face, a second stator valve surface, and a plurality of function compartments opening into the stator valve surfaces. The rotor includes a first rotor valve surface in communication with the first stator valve surface, and a second rotor valve surface in communication with the second stator valve surface. The rotor also includes a plurality of rotor flow paths for receiving gas adsorbent material therein for preferentially adsorbing the first gas component in response to increasing pressure in the rotor flow paths in comparison to the second gas component. Each rotor flow path includes a pair of opposite ends opening into the rotor valve faces for communication with the function compartments.

Abstract: A gas adsorption composite a high density adsorbent including a high density layer having a first density of at least 0.3 g/cc; and a low density adsorbent having a low density layer having a second density of less than 0.3 g/cc, wherein the high density adsorbent is in substantially contiguous contact with the low density adsorbent and each of the high density adsorbent and the low density adsorbent has an adsorbent surface area of at least 500 m2/g. A pressure swing adsorption process for recovering a product gas from a feed gas, the process including supplying a pressure swing adsorption apparatus including a gas adsorption composite, feeding a feed gas into the pressure swing adsorption apparatus during a feed period not exceeding 100 seconds and recovering the product gas from the pressure swing adsorption apparatus.

Abstract: A method for reducing shock during a flow of fluid between a higher pressure vessel and a lower pressure vessel. The method includes the steps of providing a conduit between the higher pressure vessel and the lower pressure vessel, and minimizing a rate of pressure change within the second vessel caused by the flow of fluid along the conduit from the higher pressure vessel. The minimizing step includes controlling a rate of flow of fluid between the first vessel and the second vessel over a predetermined duration.

Abstract: A method of operating a life support system for an aircraft, the system including a plurality of oxygen supply apparatus, each of which in use is operable to supply product gas, which may be pure oxygen or oxygen enriched gas, to a breathing gas supply apparatus, at least one of the oxygen supply apparatus being a main oxygen supply apparatus and the remainder of the oxygen supply apparatus being auxiliary oxygen supply apparatus, the main oxygen supply apparatus being operable independently of the auxiliary oxygen supply apparatus, characterized in that the method includes operating the main oxygen supply apparatus and supplying product gas to each of the auxiliary oxygen supply apparatus.