Abstract: The present invention relates to a fixed bed hypersorber having moving ports for injecting and withdrawing fluids which can be used for fractionation of gaseous mixtures in a fixed bed filled with absorbents/adsorbents, where separation is brought about by contacting gaseous mixture in a counter-current fashion. The moving ports may take the form of pistons or pairs of tubes arranged concentrically, where one of the tubes has a straight slot and the other tube has a helical slot. Rotation of the tubes with respect to each other produces the moving port.

Abstract: The present invention relates to a method of reducing or elimination pressure pulsations and noise created by blowers in a gas separation plant. The method employs two identical and 180° out of phase blowers synchronized together to provide both a large flow of air and active noise cancellation to eliminate pressure pulsations. The two blowers are synchronized in such a way that pressure pulses created by one blower will actively be cancelled by the pulses generated by the other blower. At the same time, both blowers will work together to force a large quantity of gas flow in or out of the plant. The twin set of blowers can be used for feed or vacuum applications in the plant. This way large tonnage plant capital costs can be reduced by eliminating the need for an expensive silencer and a single large custom-made blower.

Abstract: A method of providing concentrated oxygen product gas to a patient. The method comprises producing product gas by a vacuum swing adsorption (VSA) process with an oxygen concentrator comprising a plurality of separation columns connected to a vacuum source driven by a motor. Separated product gas is then pumped to a product reservoir. The pressure of the reservoir is monitored and used to adjust the speed of the motor based on the reservoir pressure. The separated gas is then delivered to the patient.

Abstract: Methods and systems are provided where a production gas stream including natural gas and carbon dioxide is separated downhole using dual reflux pressure swing adsorption with the natural gas being produced and the carbon dioxide being directed for downhole storage (sequestration).

Abstract: Embodiments of a rapid cycle PSA apparatus are described that are useful for producing a hydrogen enriched product gas comprising not more than about 50 ppm carbon monoxide by volume and with a hydrogen gas recovery of at least about 70% by adsorptive separation from a syngas feed gas mixture comprising at least about 50 percent hydrogen and at least about 1 percent carbon monoxide by volume. One disclosed embodiment of a rapid cycle PSA apparatus comprised at least 3 adsorber elements each having at least one thin adsorbent sheet material which comprises at least one adsorbent material therein, and a bed size factor less than about 4.0 seconds. Embodiments of a rapid cycle PSA process also are described that utilize disclosed embodiments of the rapid-cycle PSA device.

Abstract: The present invention relates to an apparatus and process for oxygen concentration that makes possible the production of highly purified concentrated oxygen by modifying the structure of the adsorption bed and with various valves coupled thereto, and which can increase purity of the oxygen produced and reduce mechanical energy and consumption of electricity of the air compressor.

Abstract: A pressure swing adsorption method for separating gas components includes pressurizing an adsorption bed to an adsorption pressure using a first gas component of a feed gas, the adsorption bed including an adsorbent for substantially adsorbing a second gas component of a feed gas; introducing the feed gas to the pressurized adsorption bed, wherein the first gas component of the feed gas substantially passes through the pressurized adsorption bed and the second gas component of the feed gas substantially adsorbs onto the adsorbent; and depressurizing the pressurized adsorption bed to recover at least a portion of the second gas component of the feed gas in the pressurized adsorption bed.

Abstract: The invention relates to a method of adjusting a unit that is used to control an installation for the adsorption treatment of a gas, comprising: at least a first member and a second member (2, 5, R0, . . . , R9) which receive a gas; a connection conduit (3, 4, 6, 7) which connects the first and second members to one another; and a valve on the connection conduit, which is closed and opened selectively in accordance with a variable valve-opening parameter. The control unit controls the opening of the valve according to the opening parameter on the basis of: an earlier opening parameter for the valve, a provisional valve opening parameter and at least one correction parameter. The inventive method comprises a step (a) in which the correction parameter is adjusted as a function of the installation and flow parameters.

Abstract: A method for concentrating a single gas component from a gas mixture is disclosed. The method utilizes concentration units and recovery units to concentrate the single gas component which is often at very low concentrations in the gas mixture. This method allows for the recovery of a valuable gas depending upon application such as oxygen and Ar-40.

Abstract: Stranded natural gas, when contaminated by difficult to remove constituents such as Nitrogen and Oxygen, has long been considered uneconomical to process into pipeline quality gas and is abandoned or utilized in other energy applications where economically viable. Landfill Gas (LFG) is often considered a stranded gas although in many instances it is available at reasonable distances to natural gas pipelines, and has only rarely been processed for injection into natural gas pipelines. Other stranded contaminated gases, such as gases vented from remote oil wells or coal beds where access to transportation pipelines is not feasible are also candidates for collection. In many instances, billions of cubic feet of methane rich LFG has been vented or flared into the atmosphere.

Abstract: A system for recycling vented atmosphere gas discharged from a heat treatment chamber utilizing a protective atmosphere gas therein. The system includes an atmosphere recycling apparatus configured to receive the vented atmosphere gas. The atmosphere recycling apparatus includes a gas separator configured to separate the vented atmosphere gas into a purified atmosphere gas stream and an impure stream. The atmosphere recycling apparatus is configured to feed the purified atmosphere gas stream to the heat treatment chamber. A storage vessel can be provided to receive the purified atmosphere gas stream from the atmosphere recycling apparatus, and configured to supplement an atmosphere gas supply to the heat treatment chamber with the purified atmosphere gas stream.

Abstract: The present invention relates to mixtures comprising, in each case based on the total weight of the mixture, a) from 2 to 60% by weight of a latent heat storage component A and b) from 40 to 98% by weight of a framework component B, wherein the component A comprises at least one microencapsulated latent heat storage material and the component B comprises at least one porous metal organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion. The present invention further relates to the use of such mixtures, in particular in processes for separating substances from a mixture of substances.

Abstract: A method of determining the purity of oxygen present in an oxygen-enriched gas produced from an oxygen delivery system is disclosed. The oxygen delivery system includes at least one sieve bed having a nitrogen-adsorbing material disposed therein and configured to adsorb nitrogen from a feed gas introduced into the at least two sieve beds via a pressure-swing adsorption cycle. The method includes determining a quantity of nitrogen adsorbed by the nitrogen-adsorbing material by inferring an effective volume of the at least one sieve bed based on a pressure change of the at least one sieve bed.

Abstract: The subject of the invention is method and envelope structure for handling gas diffusion of airships and other balloons to significantly decrease, respectively fully eliminate envelope diffusion of gases through envelopes of airships and other balloons. During the method according to the invention the gases diffused through the envelope (8, 9) of airships and other balloons are collected into a separator space (2). These gases are separated from the mixture of this separator space by physical and/or chemical action and forwarded back to their sources. The invention is further an envelope structure for handling gas diffusion of airships and other balloons for applying methods according to the invention.

Abstract: The present invention relates to the use of expensive and highly selective adsorbents and catalysts for trace contaminant gas removal to generate products of high and ultra-high purity. Mixing such highly selective materials with other less expensive, less selective materials results in the ability to achieve higher purity, higher capacity and/or lower cost without adding additional expensive selective material.

Abstract: Component gas is separated from a gas mixture. Component gas flow rate, or demand, is determined. One or more gas separator operating parameters is changed based on the component gas flow rate. For example, gas flow rate can be approximated by measuring a rate of pressure decay of a product tank during a time period in which the tank is not being replenished by the separating system. When it is determined that the flow rate is relatively low, operating parameters of the separating system are changed to improve system performance with the lower demand. For example, a target product tank pressure at which sieve beds are switched can be lowered when demand is lower.

Abstract: An adsorption system with a sorbent bed that includes at least two distinct layer with two different sorbent materials, one of the sorbents being a natural zeolite such as clinoptilolite. The clinoptilolite is particularly suited to be positioned at the outlet end of the bed.

Abstract: PSA process for oxygen production comprising (a) providing an adsorber having a first layer of adsorbent selective for water and a second layer of adsorbent selective for nitrogen, wherein the heat of adsorption of water on the adsorbent in the first layer is ?about 14 kcal/mole at water loadings ?about 0.05 to about 3 mmol per gram; (b) passing a feed gas comprising at least oxygen, nitrogen, and water successively through the first and second layers, adsorbing water in the first layer of adsorbent, and adsorbing nitrogen in the second layer of adsorbent, wherein the mass transfer coefficient of water in the first layer is in the range of about 125 to about 400 sec?1 and the superficial contact time of the feed gas in the first layer is between about 0.08 and about 0.50 sec; and (c) withdrawing a product enriched in oxygen from the adsorber.

Abstract: The present invention relates generally to adsorbents for use in pressure swing adsorption (PSA) prepurification processes. The invention more particularly relates to the design of adsorbent zones to be used in PSA prepurification processes that are expected to provide for extensions in PSA cycle time, thereby reducing blowdown loss and operating costs associated with the process. One particular embodiment of the present invention includes a first adsorption zone containing activated alumina and a second adsorption zone of an alumina-zeolite mixture or composite adsorbent in which the volume of the first zone does not exceed 50% of the total volume of the first and second zone.

Abstract: A method and apparatus for extracting CO2 from air comprising an anion exchange material formed in a matrix exposed to a flow of the air, and for delivering that extracted CO2 to controlled environments. The present invention contemplates the extraction of CO2 from air using conventional extraction methods or by using one of the extraction methods disclosed; e.g., humidity swing or electro dialysis. The present invention also provides delivery of the CO2 to greenhouses where increased levels of CO2 will improve conditions for growth. Alternatively, the CO2 is fed to an algae culture.

Abstract: The concentrator separates one gas (i.e. oxygen) from a gas mixture (i.e. air) through the process of vacuum swing adsorption (VSA). An adsorber material is located within an adsorber bed. The adsorber bed has an inlet and an outlet. A valve is located downstream of the outlet. A pump, such as a blower, is provided upstream of the adsorber bed to drive a mixed gas into the adsorber bed. The adsorber material selectively adsorbs an undesirable gas (i.e. nitrogen) leaving a desirable gas (i.e. oxygen) from the mixture to pass through the outlet and through the valve. The pump is reversible. When the adsorber material becomes saturated, the pump is reversed and a vacuum is drawn on the adsorber bed. The valve is closed while the pump is operating in this reverse direction. After the adsorber material has desorbed the undesirable gas, the pump again reverses and the cycle is repeated.

Abstract: Methods and systems for producing hydrogen are provided. In one embodiment, a method of producing hydrogen comprises reacting a feed source with steam to produce a gas mixture containing hydrogen and a residue gas; introducing the gas mixture into a purification unit; adsorbing the residue gas; and discharging at least a portion of the hydrogen. The method further comprises depressurizing the purification unit; discharging at least a portion of the residue gas during the depressurization; recycling the residue gas to the feed source; and discharging the residue gas remaining in the purification unit. In another embodiment, the method includes discharging a portion of the residue gas during the depressurization such that the residue gas discharged has a higher hydrocarbon content than the secondary product remaining in the purification unit.

Abstract: An electronic controller (16) controls the operation of an electrochemical oxygen generating system (14) producing a desired gas. The product gas is fed to a storage unit (12) or a regulator (28) and pulsing valve (28) controlling the gas flow to a user. A two-stage system (180) combines a low pressure 100 and a high pressure (150) gas generating subsystems. The low pressure subsystem (100) uses IMAT's (106) to pump oxygen from ambient air to generate a low-pressure. The high pressure subsystem (150) uses IMAT's (160) to pump oxygen to high-pressure oxygen storage devices (194).

Abstract: Hydrogen production is provided via integrated closed-loop processing of landfill gas (LFG) and solid biomass feedstocks such as various agricultural wastes with minimal environmental impact. LFG is purified of harmful contaminants over a bed of activated charcoal (AC) and is catalytically reformed to synthesis gas, which is further processed to pure hydrogen via CO-shift and pressure-swing adsorption stages. Biomass is gasified in the presence of steam with production of a producer gas and AC. The producer gas is mixed with LFG and is processed to hydrogen as described above. High-surface area AC produced in the gasifier is used for the purification of both LFG and producer gas. An integrated processing of LFG and biomass offers a number of advantages such as a high overall energy efficiency, feedstock flexibility, substantial reduction in greenhouse gas emissions and production of value-added product-biocarbon that can be used as a soil enhancer.

Abstract: A chemical reaction is performed with separation of the product(s) and reactant(s) by pressure swing adsorption (PSA), using an apparatus having a plurality of adsorbers cooperating with first and second valve assemblies in a PSA module. The PSA cycle is characterized by multiple intermediate pressure levels between higher and lower pressures of the PSA cycle. Gas flows enter or exit the PSA module at the intermediate pressure levels as well as the higher and lower pressure levels, entering from compressor stage(s) or exiting into exhauster or expander stages, under substantially steady conditions of flow and pressure. The PSA module comprises a rotor containing the adsorbers and rotating within a stator, with ported valve faces between the rotor and stator to control the timing of the flows entering or exiting the adsorbers in the rotor. The reaction may be performed within a portion of the rotor containing a catalyst.

Abstract: A process for gas purification or separation intended to produce a gas mixture containing mainly hydrogen and, to a minor extent CO, it being imperative for the CO content to remain below a set value is presented. This invention particularly relates to adsorption processes and even more particularly to processes of the PSA (“Pressure Swing Adsorption”) type.

Abstract: A pressure swing adsorption system including a plurality of vessels having one or more layers of adsorbent material therein, a feed gas channel, a waste channel, and a product channel. The system also includes at least one parallel channel connected to each of the vessels via a respective conduit with a valve. At least one pressure measuring device i configured to measure a pressure within the parallel channel. And, a controller is provided that is configured to monitor the at least one pressure measured by the at least one pressure measuring device during a PSA cycle performed within the PSA system, in order to determine the performance of the cycle and monitor proper operation of the system.

Abstract: It is an object of the present invention to provide an industrially viable PSA process that requires small volumes of molecular sieve carbon and feed air. In order to achieve the above object, the PSA process uses the molecular sieve carbon satisfying the following relationships (I) and (II). (1)ln C?0.325+5.14×ln {(0.64+0.098)×Q/(P+0.098)}??(I) (2)ln U?2.124?0.135×ln C??(II) where C indicates an oxygen level (ppm) in the nitrogen gas product; Q indicates a volume of nitrogen gas produced per minute per unit effective volume of a single adsorption column; P indicates an adsorption pressure (MPa); and U indicates a ratio of the volume of the feed air to the volume of the nitrogen gas produced.

Abstract: Methods, devices, and systems, and devices for carrying out sorption (adsorption and absorption) for separating and/or purifying fluid mixtures are disclosed. Medical oxygen generators, dehumidifying units, sorptive heat pumps, ozone generators and Peltier devices are also disclosed. The sorption methods involve pressure swing operation of at least two sorption units. Energy from the desorbing and decompressing fluid is substantially recovered and used within the system.

Abstract: A thermocyclic process having a short cycle time, typically a cycle time of less 30 minutes, especially a PSA (Pressure Swing Adsorption) process, using agglomerates that contain phase change materials (PCMs), so as to reduce the thermal effects that said thermocyclic process is subjected to during each cycle is provide.

Abstract: The present invention provides a method for improving the air quality in the limited space and the equipment using thereof. The said method is that the air suctioned from the limited space is transferred to the outside of the limited space and acts as an air source for making oxygen. The oxygen is extracted from the said air source and the waste gas generated thereby is directly discharged to the outside of the limited space. The oxygen extracted is transferred into the limited space and offered the said space by means of the oxygen-supply controller. In addition, the atmosphere is supplemented into the limited space when the air inside is suctioned out. The equipment for the said method includes an indoor machine positioned in the limited space, an outdoor machine and an atmosphere supplement equipment.

Abstract: Process step in a pressure swing adsorption process using multiple parallel adsorbent beds operating in cyclic process steps to recover a less strongly adsorbable component from a feed gas mixture containing at least one less strongly adsorbable component and at least one more strongly adsorbable component, wherein each adsorbent bed has a feed end and a product end, wherein each bed is subjected to at least a feed/product step, one or more depressurization steps, a purge step in which a purge gas enriched in the less strongly adsorbable component is introduced into the product end of the bed and a purge effluent gas is withdrawn from the feed end of the bed, and one or more repressurization steps. The process step comprises introducing at least a portion of the purge effluent gas from a first bed into the feed end of a second adsorbent bed at any time other than during the feed/product step in the second adsorbent bed.

Abstract: In a PSA separation method with compression (C1, C2) of at least one offgas (3), in case of temporary shutdown of one of the compressors (C1, C2), the operating parameters of the PSA unit (S) are changed to increase the outlet pressure of the offgas (3), in order to maintain a production level above 50% with a single compressor (C1).

Abstract: Improved adsorbent sheet based parallel passage adsorbent structures for enhancing the kinetic selectivity of certain kinetic-controlled adsorption processes, such as PSA, TSA and PPSA processes, and combinations thereof, are provided. The enhancements in kinetic selectivity made possible through the implementation of the present inventive improved adsorbent structures may unexpectedly enable significant intensification of selected kinetic adsorption processes relative to attainable performance with conventional adsorbent materials in beaded or extruded form. Such process intensification enabled by the present inventive adsorbent structures may provide for increased adsorption cycle frequencies, and increased gas flow velocities within the adsorbent beds, which may increase the productivity and/or recovery of a kinetic adsorption system incorporating the inventive adsorbent structures.

Abstract: A process for producing oxygen by using of three-stage pressure swing adsorption plants, wherein the process is used to separate nitrogen and oxygen from a feed air stream, the product can be oxygen or nitrogen or both of them. The process utilizes three-stage pressure swing adsorption plants which are serially connected. In the first stage, carbon dioxide, water and part of nitrogen are removed and nitrogen is concentrated. In the second stage, nitrogen is further separated from the effluent intermediate gas from the adsorption step in the adsorption towers of the first stage and oxygen is concentrated to the desired concentration. In the third stage, nitrogen and argon are further separated from the effluent oxygen-enriched mixture gas from the adsorption step in the adsorption towers of the second stage and the concentration of oxygen is raised to 95V % or more.

Abstract: A pressure swing adsorption process including the step of separating a gas mixture by absorbing at least one gas component in an adsorbent mass provided within each vessel of a plurality of vessels. The separating step has a single pressure equalization cycle. The separating step is preferably performed with only four valves per vessel of the plurality of vessels. Additionally, a pressure swing adsorption system of the invention includes a plurality of vessels each containing therein an adsorbent mass configured to separate a gas mixture by absorbing at least one gas component in said adsorbent mass, where the system is configured to separate the gas mixture using a single pressure equalization cycle and includes only four valves per vessel of the plurality of vessels.

Abstract: The invention relates to a composite material, a method for controlling the thermal effects generated in a physicochemical process using said material, and applications of the material and the method. The composite material comprises an active solid and a phase change material. The phase change material takes the form of micronodules having an average size of between 1 micron and 5 millimeters and it is selected from materials with a liquid/solid phase change temperature of between ?150° C. and 900° C. The active solid is selected from solids that can be used in a method involving reversible physicochemical processes that are exothermic in one direction and endothermic in the opposite direction.

Abstract: The present invention relates to cryogenic air separation processes and systems that employ a pressure swing adsorption (PSA) prepurification process. It is advantageous to operate the PSA process at a pressure comparable to or below the operating pressure of the highest pressure column in the cryogenic separation unit. Following PSA prepurification, the air can be split into at least two fractions, with at least a portion of the air being directed to the cryogenic separation unit and at least a portion of the remaining air being further pressurized in at least one stage of compression.

Abstract: A feedstock hydrogen-enriched gas (3) is supplied to a PSA purification unit (1) which delivers pure hydrogen at a production output (4) and a hydrogen-deficient gas at a residual output. Said hydrogen-deficient gas is compressed (9) and injected into a line (10) wherein a gaseous combustible mixture circulates whose part (12) is extracted upstream of the PSA unit (1), compressed (13) and reinjected into said feedstock of the PSA unit (1). Said invention is used, in particular for petrochemical sites.

Abstract: The present invention relates to a process for the separation of gases which comprises putting a mixture of gases in contact with a zeolite of the ESV type to obtain the selective adsorption of at least one of the gases forming the gaseous mixture. The present invention also relates to particular zeolitic compositions suitable as adsorbents.

Abstract: The invention relates to an installation for separating or purifying gases comprising at least one gas treatment vessel, characterized in that the vessel comprises at least one plane structure comprising a matrix and at least one phase change material (PCM).

Abstract: The invention concerns a method for decarbonating gas streams polluted by CO2, which consists in contacting them with an adsorbent consisting of an agglomerate of zeolite X with an Si/Al ratio of 1 to 1.15, highly sodium-exchanged comprising not more than 20% of inert binder, to eliminate at least the carbon dioxide.

Abstract: A removable gas separation cartridge which includes a housing containing three columns, each having an inlet port, an outlet port, and a bed of adsorbent material. The cartridge is removable from an oxygen concentrator which separates oxygen from ambient air by using a vacuum swing absorption process.

Abstract: A gas purification unit includes a gas purification vessel (12) and at least one of inlet conduit means (18, 20, 34) for connecting a feed gas source (16) to the gas purification vessel and outlet conduit means (36, 22, 24) for connecting the gas purification vessel (12) to at least one downstream gas processing unit. Each of said inlet and outlet conduit means includes at least two subsidiary pipes arranged in parallel and a common pipe (34, 36), each subsidiary pipe being in fluid flow communication with the common pipe and having a flow control valve (18, 20, 22, 24) operating in unison with the flow control valve of the or each other subsidiary pipe. The use of at least two valves in unison increases the reliability of the unit. The use of at least two smaller valves in place of a single large valve also increases the reliability.

Abstract: An oxygen separator for separating oxygen from ambient air utilizing a vacuum swing adsorption process has a mass of less than 2.3 kg. A carrier is mountable on a person to support the oxygen separator for ambulatory use.

Abstract: Systems and processes are provided for gas separation using high-speed permanent magnet variable-speed motors to accelerate and decelerate centrifugal compressors suitable for use in pressure swing adsorption (PSA) or vacuum pressure swing adsorption (VPSA) processes.

Abstract: A method of operating a fuel cell system includes providing a fuel inlet stream into a fuel cell stack, operating the fuel cell stack to generate electricity and a hydrogen containing fuel exhaust stream, separating at least a portion of hydrogen contained in the fuel exhaust stream using partial pressure swing adsorption, and providing the hydrogen separated from the fuel exhaust stream into the fuel inlet stream.

Abstract: The present invention is a method for operating a rapid cycling pressure swing adsorption (RCPSA) having a cycle time, T, to separate a feed gas into a non-adsorbed gas and tail gas. The method includes the steps of passing the feed gas having a purity of F % at high pressure into a first end of a bed which selectively adsorbs the tail gas and passes the product gas out a second end of the bed for a time, F. The product gas has a purity, P %, and a rate of recovery of R %. Then the bed is cocurrently depressurized for a time, tCO, followed by countercurrently depressurizing the bed for a time, tCN. The bed is then purged for a time, tP, wherein desorbate (tail gas) is released at the first end of the bed at a pressure greater than 30 psig, Subsequently the bed is repressurized for a duration, tRP. R>80%, P/F?1.1 or R?90%, 0<P/F <1.1.

Abstract: A system for generating oxygen includes a compression means configured to compress a feed gas including at least nitrogen and oxygen, and at least one sieve bed configured to generate an oxygen-enriched gas from the compressed feed gas. The sieve bed(s), having an internal gas pressure ranging from about 1 psi to about 10 psi, include a housing and a nitrogen-adsorption material operatively disposed in the housing. The nitrogen-adsorption material is configured to adsorb at least nitrogen from the compressed feed gas during a pressure swing adsorption process, thereby generating an oxygen-enriched gas for a user.

Abstract: A gas fractionalization apparatus and methods for providing oxygen rich air to patients are disclosed. The apparatus comprises a variable output compressor, a PSA unit, a control system, and one or more pressure sensing devices. Pressure of the oxygen rich gas is maintained within a selected window by adjusting the output of the compressor in response to changes in the pressure of the oxygen rich gas. Methods of feedback control are further provided for calibration of the compressor under factory and in-service conditions, as well as under high-altitude conditions. Methods for providing diagnostic estimates and alarms of time to service are further provided.