With Specified Chirality And/or Electrical Conductivity (e.g., Chirality Of (5,4), (5,5), (10,5), Etc.) Patents (Class 977/751)
  • Patent number: 8747799
    Abstract: The present invention relates to a method of forming single-walled carbon nanotubes. The method comprises contacting a gaseous carbon source with mesoporous TUD-1 silicate at suitable conditions. The mesoporous TUD-1 silicate comprises a metal of groups 3-13 of the Periodic Table of the Elements.
    Type: Grant
    Filed: July 5, 2010
    Date of Patent: June 10, 2014
    Assignee: Nanyang Technological University
    Inventors: Yuan Chen, Yanhui Yang
  • Patent number: 8715608
    Abstract: A method for synthesizing carbon nanotubes having a narrow distribution of diameter and/or chirality is presented. The method comprises providing catalyst particles to a reactor for synthesizing the carbon nanotubes, wherein the catalyst particles are characterized by a narrow distribution of catalyst-particle diameters and a narrow distribution of catalyst-particle compositions. Preferably, the catalyst particles are characterized by a mean catalyst-particle diameter of 2.6 nm or less and a composition of NixFe1-x, wherein x is less than or equal to 0.5.
    Type: Grant
    Filed: November 29, 2010
    Date of Patent: May 6, 2014
    Assignee: Case Western Reserve University
    Inventors: R. Mohan Sankaran, Wei-Hung Chiang
  • Patent number: 8703092
    Abstract: The subject invention provides a two-phase liquid-liquid extraction process that enables sorting and separation of single-walled carbon nanotubes based on (n, m) type and/or diameter. The two-phase liquid extraction method of the invention is based upon the selective reaction of certain types of nanotubes with electron withdrawing functional groups as well as the interaction between a phase transfer agent and ionic moieties on the functionalized nanotubes when combined in a two-phase liquid solution. Preferably, the subject invention enables efficient, bulk separation of metallic/semi-metallic nanotubes from semi-conducting nanotubes. More preferably, the subject invention enables efficient, bulk separation of specific (n, m) types of nanotubes.
    Type: Grant
    Filed: September 15, 2006
    Date of Patent: April 22, 2014
    Assignee: University of Florida Research Foundation, Inc.
    Inventor: Kirk Jeremy Ziegler
  • Patent number: 8591858
    Abstract: Methods and processes for synthesizing high quality carbon single-walled nanotubes (SWNTs) are provided. The method provides the means for optimization of amount of carbon precursor and transport gas per unit weight of catalyst. In certain aspects, methods are provided wherein a supported metal catalyst is contacted with a carbon precursor gas at about one atmosphere pressure, wherein SWNTs are synthesized at a growth rate of about 0.002 ?m/sec to about 0.003 ?m/sec and the SWNTs have a ratio of G-band to D-band in Raman spectra (IG:ID) of greater than about 4. Efficiencies of about 20% can be achieved when contacting the catalyst deposited on a support with a carbon precursor gas with a flow rates of about 4.2×10?3 mol CH4/sec·g (Fe) at 780° C. Hydrocarbon flow rates of about 1.7 10?2 mol CH4/sec·g (Fe) and higher result in faster carbon SWNTs growth with improved quality. Slower rates of carbon atoms supply (˜4.5×1020 C atoms/s·g Fe or 6.
    Type: Grant
    Filed: May 1, 2008
    Date of Patent: November 26, 2013
    Assignee: Honda Motor Co., Ltd.
    Inventors: Avetik R. Harutyunyan, Elena Mora
  • Patent number: 8518870
    Abstract: The present invention is a method for detecting and destroying cancer tumors. The method is based on the concept of associating a linking protein or linking peptide such as, but not limited to, annexin V or other annexins to carbon nanotubes such as single-walled carbon nanotubes (SWNTs) to form a protein-CNT complex. Said linking protein or peptide can selectively bind to cancerous cells, especially tumor vasculature endothelial cells, rather than to healthy ones by binding to cancer-specific external receptors such as anionic phospholipids including phosphatidylserine expressed on the outer surfaces of cancer cells only. Irradiation of bound CNTs with one or more specific electromagnetic wavelengths is then used to detect and destroy those cells to which the CNTs are bound via the linking protein or peptide thereby destroying the tumor or cancer cells and preferably an immunostimulant is provided to the patient to enhance the immune response against antigens released from the tumor or cancer cells.
    Type: Grant
    Filed: November 13, 2009
    Date of Patent: August 27, 2013
    Assignee: The Board of Regents of the University of Oklahoma
    Inventors: Roger G. Harrison, Jr., Daniel E. Resasco, Luis Filipe Ferreira Neves
  • Publication number: 20130183439
    Abstract: A method includes the steps of receiving a conductor element formed from a plurality of carbon nanotubes; and exposing the conductor element to a controlled amount of a dopant so as to increase the conductance of the conductor element to a desired value, wherein the dopant is one of bromine, iodine, chloroauric acid, hydrochloric acid, hydroiodic acid, nitric acid, and potassium tetrabromoaurate. A method includes the steps of receiving a conductor element formed from a plurality of carbon nanotubes; and exposing the conductor element to a controlled amount of a dopant solution comprising one of chloroauric acid, hydrochloric acid, nitric acid, and potassium tetrabromoaurate, so as to increase the conductance of the conductor element to a desired value.
    Type: Application
    Filed: January 17, 2012
    Publication date: July 18, 2013
    Inventors: John A. Starkovich, Edward M. Silverman, Hsiao-Hu Peng
  • Patent number: 8475661
    Abstract: This invention relates to heterogenous pore polymer nanotube membranes useful in filtration, such as reverse osmosis desalination, nanofiltration, ultrafiltration and gas separation.
    Type: Grant
    Filed: April 27, 2012
    Date of Patent: July 2, 2013
    Assignee: Nagare Membranes, LLC
    Inventors: Timothy V. Ratto, Jason K. Holt, Alan W. Szmodis
  • Patent number: 8350391
    Abstract: The sheet structure includes a plurality of linear structure bundles including a plurality of linear structures of carbon atoms arranged at a first gap, and arranged at a second gap larger than the first gap, a graphite layer formed in a region between the plurality of linear structure bundles and connected to the plurality of linear structure bundles, and a filling layer filled in the first gap and the second gap and retaining the plurality of linear structure bundles and the graphite layer.
    Type: Grant
    Filed: July 31, 2012
    Date of Patent: January 8, 2013
    Assignee: Fujitsu Limited
    Inventors: Daiyu Kondo, Taisuke Iwai, Yoshitaka Yamaguchi, Ikuo Soga
  • Patent number: 8317978
    Abstract: A method of fabricating a non-brittle, carbon nanopaper from single wall, multiwall, and combination thereof, from carbon nanotubes, using a vacuum deposition, high temperature annealing, and polystyrene polymer rinse process; which nanopaper can be nitrided by either a plasma-enhanced chemical vapor deposition (PECVD) process, or an by an electrochemical method, to obtain a useful chemically functionalized substrate, a substrate containing metastable N4, N8, and longer chain polymeric nitrogen clusters. Such nitrided carbon nanopaper can be used to enhance the ballistic performance of gun propellants, while reducing gun barrel wear and erosion thereof.
    Type: Grant
    Filed: April 6, 2011
    Date of Patent: November 27, 2012
    Inventors: Thelma G. Manning, Zafar Iqbal
  • Publication number: 20120292578
    Abstract: The invention relates to a method for producing composite materials based on at least one polymer and carbon nanotubes (CNTs), and to composite materials obtained in this manner and the use thereof.
    Type: Application
    Filed: February 8, 2010
    Publication date: November 22, 2012
    Inventors: Alexander Bacher, Michael Berkei, Eva Potyra, Jan Diemer, Susanne Lüssenheide, Jörg Metzge, Helmut Meyer, Irma Mikonsaari, Thomas Sawitowski, Boris Schunke, Janin Tecklenburg, Nadine Willing, Adrian Zanki
  • Publication number: 20120182666
    Abstract: The invention is directed, in an embodiment, to an inherently conductive polymer comprising a conductive polymer, carbon nanotubes, and dinonylnaphthalene sulfonic acid. The conductive polymer may comprise polyaniline. The invention is also directed to polymeric films and supercapacitors comprising the inherently conductive polymer.
    Type: Application
    Filed: September 30, 2011
    Publication date: July 19, 2012
    Applicant: LUMIMOVE, INC. D/B/A CROSSLINK
    Inventors: Patrick J. Kinlen, June-Ho Jung, Young-Gi Kim, Joseph Mbugua, Eve F. Fabrizio
  • Patent number: 8216364
    Abstract: Direct resistive heating is used to grow nanotubes out of carbon and other materials. A growth-initiated array of nanotubes is provided using a CVD or ion implantation process. These processes use indirect heating to heat the catalysts to initiate growth. Once growth is initiated, an electrical source is connected between the substrate and a plate above the nanotubes to source electrical current through and resistively heat the nanotubes and their catalysts. A material source supplies the heated catalysts with carbon or another material to continue growth of the array of nanotubes. Once direct heating has commenced, the source of indirect heating can be removed or at least reduced. Because direct resistive heating is more efficient than indirect heating the total power consumption is reduced significantly.
    Type: Grant
    Filed: April 14, 2008
    Date of Patent: July 10, 2012
    Assignee: Raytheon Company
    Inventors: Delmar L. Barker, Mead M. Jordan, William R. Owens
  • Patent number: 8196756
    Abstract: This invention relates to heterogenous pore polymer nanotube membranes useful in filtration, such as reverse osmosis desalination, nanofiltration, ultrafiltration and gas separation.
    Type: Grant
    Filed: April 2, 2010
    Date of Patent: June 12, 2012
    Assignee: NanOasis
    Inventors: Timothy V. Ratto, Jason K. Holt, Alan W. Szmodis
  • Patent number: 8193430
    Abstract: Disclosed herein too is a method that includes dispersing nanotubes in media that comprises flavin moieties substituted with solubilizing side chains, and/or non-flavin containing molecular species; self-assembling the flavin moieties and other non-flavin containing molecular species in a pattern that is orderly wrapped around the nanotubes to form a composite; introducing desired amounts of an optional reagent that competes with self-assembly in order to disturb the wrapping around nanotubes with moderate order; and centrifuging the mass of the nanotubes and the composites to extract the composite from other nanotubes that are not in composite form.
    Type: Grant
    Filed: January 5, 2009
    Date of Patent: June 5, 2012
    Assignee: The University of Connecticut
    Inventors: Fotios Papadimitrakopoulos, Sang-Yong Ju
  • Publication number: 20120107594
    Abstract: Disclosed is a single wall carbon nanotube (SWCNT) film electrode (FE), all-organic electroactive device systems fabricated with the SWNT-FE, and methods for making same. The SWCNT can be replaced by other types of nanotubes. The SWCNT film can be obtained by filtering SWCNT solution onto the surface of an anodized alumina membrane. A freestanding flexible SWCNT film can be collected by breaking up this brittle membrane. The conductivity of this SWCNT film can advantageously be higher than 280 S/cm. An electroactive polymer (EAP) actuator layered with the SWNT-FE shows a higher electric field-induced strain than an EAP layered with metal electrodes because the flexible SWNT-FE relieves the restraint of the displacement of the polymeric active layer as compared to the metal electrode. In addition, if thin enough, the SWNT-FE is transparent in the visible light range, thus making it suitable for use in actuators used in optical devices.
    Type: Application
    Filed: October 28, 2011
    Publication date: May 3, 2012
    Applicant: U.S.A. as represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: Jin Ho Kang, Cheol Park, Joycelyn S. Harrison
  • Patent number: 8119719
    Abstract: Disclosed are an intermediate transfer belt for use in a laser printer, a fax machine and a copier, and a production method thereof. Specifically, an intermediate transfer belt including silicone modified polyimide resin and a production method thereof are provided, thereby realizing a monolayer intermediate transfer belt having excellent electrical properties, water repellency and heat dissipation properties and good mechanical strength. Further, even without the additional use of an adhesive layer for adhesion to a fluorine resin layer and fluorine resin, the intermediate transfer belt can exhibit satisfactory properties, and process efficiency can be maximized.
    Type: Grant
    Filed: January 3, 2007
    Date of Patent: February 21, 2012
    Assignee: Kolon Industries, Inc.
    Inventors: Hyo Jun Park, Chae Hyun Lim, Chung Seock Kang, Sang Min Song
  • Patent number: 8097141
    Abstract: According to some embodiments, a method for separating a first fraction of a single wall carbon nanotubes and a second fraction of single wall carbon nanotubes includes, but is not limited to: flowing a solution comprising the nanotubes into a dielectrophoresis chamber; applying a DC voltage, in combination with an AC voltage, to the dielectrophoresis chamber; and collecting a first eluent from the dielectrophoresis chamber, wherein the first eluent comprises the first fraction and is depleted of the second fraction, wherein the first and second fractions differ by at least one of conductivity, diameter, length, and combinations thereof.
    Type: Grant
    Filed: March 2, 2007
    Date of Patent: January 17, 2012
    Assignee: William Marsh Rice University
    Inventors: Howard K. Schmidt, Haiqing Peng, Manuel Joao Mendes, Matteo Pasquali
  • Patent number: 8093174
    Abstract: A carbon nanohorn (CNH) is oxidized to make an opening in the side of the CNH. A substance to be included, e.g., a metal, is introduced through the opening. The inclusion substance is moved to a tip part of the carbon nanohorn through heat treatment in vacuum or an inert gas. The CNH is further heat treated in an atmosphere containing oxygen in a low concentration to remove the carbon layer in the tip through catalysis of the inclusion substance. This exposes the inclusion substance. If the inclusion substance is a metal which is not moved to a tip part by the heat treatment in vacuum or an inert gas, the carbon part surrounding the fine catalyst particle is specifically burned by a heat treatment in an low oxygen concentration atmosphere, while utilizing the catalysis. Thus, the fine catalyst particle is fixed to the tip part of the CNH.
    Type: Grant
    Filed: January 16, 2008
    Date of Patent: January 10, 2012
    Assignee: NEC Corporation
    Inventors: Ryota Yuge, Masako Yudasaka, Sumio Iijima
  • Patent number: 8064203
    Abstract: A free standing film includes: i. a matrix layer having opposing surfaces, and ii. an array of nanorods, where the nanorods are oriented to pass through the matrix layer and protrude an average distance of at least 1 micrometer through one or both surfaces of the matrix layer. A method for preparing the free standing film includes (a) providing an array of nanorods on a substrate, optionally (b) infiltrating the array with a sacrificial layer, (c) infiltrating the array with a matrix layer, thereby producing an infiltrated array, optionally (d) removing the sacrificial layer without removing the matrix layer, when step (b) is present, and (e) removing the infiltrated array from the substrate to form the free standing film. The free standing film is useful as an optical filter, ACF, or TIM, depending on the type and density of nanorods selected.
    Type: Grant
    Filed: January 25, 2008
    Date of Patent: November 22, 2011
    Assignee: Dow Corning Corporation
    Inventors: Carl Fairbank, Mark Fisher
  • Publication number: 20110262729
    Abstract: This disclosure provides articles that include functionalized nanoscale fibers and methods for functionalizing nanoscale fibers. The functionalized nanoscale fibers may be made by oxidizing a network of nanoscale fibers, grafting one or more molecules or polymers to the oxidized nanoscale fibers, and cross-linking at least a portion of the molecules or polymers grafted to the oxidized nanoscale fibers. The functionalized nanoscale fibers may be used to make articles.
    Type: Application
    Filed: March 10, 2011
    Publication date: October 27, 2011
    Applicant: Florida State University Research Foundation
    Inventors: I-Wen Chen, Zhiyong Liang, Ben Wang, Chun Zhang
  • Patent number: 8038795
    Abstract: A precursor chiral nanotube with a specified chirality is grown using an epitaxial process and then cloned. A substrate is provided of crystal material having sheet lattice properties complementary to the lattice properties of the selected material for the nanotube. A cylindrical surface(s) having a diameter of 1 to 100 nanometers are formed as a void in the substrate or as crystal material projecting from the substrate with an orientation with respect to the axes of the crystal substrate corresponding to the selected chirality. A monocrystalline film of the selected material is epitaxially grown on the cylindrical surface that takes on the sheet lattice properties and orientation of the crystal substrate to form a precursor chiral nanotube. A catalytic particle is placed on the precursor chiral nanotube and atoms of the selected material are dissolved into the catalytic particle to clone a chiral nanotube from the precursor chiral nanotube.
    Type: Grant
    Filed: July 16, 2008
    Date of Patent: October 18, 2011
    Assignee: Raytheon Company
    Inventors: Delmar L. Barker, William R. Owens
  • Patent number: 8038887
    Abstract: Nanoporous membranes comprising single walled, double walled, and multiwalled carbon nanotubes embedded in a matrix material were fabricated for fluid mechanics and mass transfer studies on the nanometer scale and commercial applications. Average pore size can be 2 nm to 20 nm, or seven nm or less, or two nanometers or less. The membrane can be free of large voids spanning the membrane such that transport of material such as gas or liquid occurs exclusively through the tubes. Fast fluid, vapor, and liquid transport are observed. Versatile micromachining methods can be used for membrane fabrication. A single chip can comprise multiple membranes. These membranes are a robust platform for the study of confined molecular transport, with applications in liquid and gas separations and chemical sensing including desalination, dialysis, and fabric formation.
    Type: Grant
    Filed: August 23, 2006
    Date of Patent: October 18, 2011
    Assignee: Lawrence Livermore National Security, LLC
    Inventors: Olgica Bakajin, Jason Holt, Aleksandr Noy, Hyung Gyu Park
  • Patent number: 8017934
    Abstract: Gate electrodes are formed on a semiconducting carbon nanotube, followed by deposition and patterning of a hole-inducing material layer and an electron inducing material layer on the carbon nanotube according to the pattern of a one dimensional circuit layout. Electrical isolation may be provided by cutting a portion of the carbon nanotube, forming a reverse biased junction of a hole-induced region and an electron-induced region of the carbon nanotube, or electrically biasing a region through a dielectric layer between two device regions of the carbon nanotube. The carbon nanotubes may be arranged such that hole-inducing material layer and electron-inducing material layer may be assigned to each carbon nanotube to form periodic structures such as a static random access memory (SRAM) array.
    Type: Grant
    Filed: August 4, 2010
    Date of Patent: September 13, 2011
    Assignee: International Business Machines Corporation
    Inventors: Joerg Appenzeller, AJ Kleinosowski, Edward J. Nowak, Richard Q. Williams
  • Publication number: 20110198559
    Abstract: A method is provided for growth of carbon nanotube (CNT) synthesis at a low temperature. The method includes preparing a catalyst by placing the catalyst between two metal layers of high chemical potential on a substrate, depositing such placed catalyst on a surface of a wafer, and reactivating the catalyst in a high vacuum at a room temperature in a catalyst preparation chamber to prevent a deactivation of the catalyst. The method also includes growing carbon nanotubes on the substrate in the high vacuum in a CNT growth chamber after preparing the catalyst.
    Type: Application
    Filed: April 25, 2011
    Publication date: August 18, 2011
    Applicant: STMICROELECTRONICS ASIA PACIFIC PTE LTD
    Inventors: Shanzhong Wang, Mui Hoon Nai, Zhonglin Miao
  • Publication number: 20110177493
    Abstract: A molecular sensor is provided that contains at least one carbon nanotube suspended on a suitable support structure. In one aspect, at least one receptor is attached to a surface of the suspended carbon nanotube. Also provided are methods of detecting an analyte in a sample by contacting a sample suspected of containing the analyte with the molecular sensor of this invention under suitable conditions that favor binding of the analyte to the receptor and detecting any analyte bound to the receptor, if present.
    Type: Application
    Filed: February 13, 2009
    Publication date: July 21, 2011
    Inventor: Jennifer Lu
  • Publication number: 20110174701
    Abstract: A process for metallizing nanomaterial including subjecting nanomaterial in a metallizing solution to microwave radiation; nanomaterial made by such a process; and density gradient separation of such material. This abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure and is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims, 37 C.F.R. 1.72(b).
    Type: Application
    Filed: January 16, 2010
    Publication date: July 21, 2011
    Inventors: Clayton Gallaway, Dean Hulsey, Michael Searfass, Joshua Falkner
  • Publication number: 20110171531
    Abstract: In one aspect, the present invention provides a method of forming a film of nanocomposites of carbon nanotubes (CNTs) and platinum (Pt) nanoparticles. In one embodiment, the method includes the steps of (a) providing a first solution that contains a plurality of CNTs, (b) providing a second solution that contains a plurality of Pt nanoparticles, (c) combining the first solution and the second solution to form a third solution, and (d) filtering the third solution through a nanoporous membrane using vacuum filtration to obtain a film of nanocomposites of CNTs and Pt nanoparticles.
    Type: Application
    Filed: September 8, 2010
    Publication date: July 14, 2011
    Applicant: NORTHWESTERN UNIVERSITY
    Inventors: Mark C. Hersam, Gordana Ostojic, Yu Teng Liang
  • Publication number: 20110155964
    Abstract: The present teachings provide methods for providing populations of single-walled carbon nanotubes that are substantially monodisperse in terms of diameter, electronic type, and/or chirality. Also provided are single-walled carbon nanotube populations provided thereby and articles of manufacture including such populations.
    Type: Application
    Filed: December 3, 2010
    Publication date: June 30, 2011
    Inventors: Michael S. Arnold, Mark C. Hersam, Samuel I. Stupp
  • Publication number: 20110123735
    Abstract: A structural support includes a cylindrical core, an inner layer within the core and an outer layer. The inner and outer layers include CNT-infused fiber materials in a thermoset matrix. A composite includes a thermoset matrix and a CNT-infused fiber material having CNTs with lengths between about 20 to about 500 microns or about 0.1 to about 15 microns. For the latter range, CNTs are present between about 0.1 to about 5 percent by weight of the composite. A method of making a structural support includes wet winding a first CNT-infused fiber about a cylindrical mandrel in a direction substantially parallel to the mandrel axis, wet winding a baseline layer about the first CNT-infused fiber at an angle substantially non-parallel to the mandrel axis, and wet winding a second CNT-infused fiber about the baseline layer in a direction substantially parallel to the mandrel axis.
    Type: Application
    Filed: November 22, 2010
    Publication date: May 26, 2011
    Applicant: APPLIED NANOSTRUCTURED SOLUTIONS, LLC
    Inventors: Tushar K. SHAH, Harry C. Malecki, Samuel J. Markkula, Mark R. Alberding
  • Patent number: 7947542
    Abstract: A method for making a thin film transistor, the method comprising the steps of: (a) providing a carbon nanotube array and an insulating substrate; (b) pulling out a carbon nanotube film from the carbon nanotube array by using a tool; (c) placing at least one carbon nanotube film on a surface of the insulating substrate, to form a carbon nanotube layer thereon; (d) forming a source electrode and a drain electrode; wherein the source electrode and the drain electrode being spaced therebetween, and electrically connected to the carbon nanotube layer; and (e) covering the carbon nanotube layer with an insulating layer, and a gate electrode being located on the insulating layer.
    Type: Grant
    Filed: April 2, 2009
    Date of Patent: May 24, 2011
    Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.
    Inventors: Kai Liu, Kai-Li Jiang, Shou-Shan Fan
  • Patent number: 7939047
    Abstract: The present invention is directed to methods of separating carbon nanotubes (CNTs) by their electronic type (e.g., metallic, semi-metallic, and semiconducting). Perhaps most generally, in some embodiments, the present invention is directed to methods of separating CNTs by bandgap, wherein such separation is effected by interacting the CNTs with a surface such that the surface interacts differentially with the CNTs on the basis of their bandgap, or lack thereof. In some embodiments, such methods can allow for such separations to be carried out in bulk quantities.
    Type: Grant
    Filed: July 27, 2005
    Date of Patent: May 10, 2011
    Assignee: William Marsh Rice University
    Inventors: James M. Tour, Christopher A. Dyke, Austen K. Flatt
  • Patent number: 7931884
    Abstract: Methods and processes for preparing interconnected carbon single-walled nanotubes (SWNTs) are disclosed. The SWNTs soot, synthesized by any one of the art methods, is heated to less than about 1250° C. in flowing dry air using the electrical field (E) component of microwave energy. The tubes of the SWNTs thus treated become welded and interconnected.
    Type: Grant
    Filed: October 30, 2009
    Date of Patent: April 26, 2011
    Assignee: Honda Motor Co., Ltd.
    Inventor: Avetik Harutyunyan
  • Patent number: 7884300
    Abstract: A method of realizing selective separation of metallic single-walled carbon nanotubes and semiconducting carbon nanotubes from bundled carbon nanotubes; and obtaining of metallic single-walled carbon nanotubes separated at high purity through the above method. Metallic single-walled carbon nanotubes are dispersed one by one from bundled carbon nanotubes not only by the use of a difference in interaction with amine between metallic single-walled carbon nanotubes and semiconducting carbon nanotubes due to a difference in electrical properties between metallic single-walled carbon nanotubes and semiconducting carbon nanotubes but also by the use of the fact that an amine is an important factor in SWNTs separation. The thus dispersed carbon nanotubes are subjected to centrifugation, thereby attaining separation from non-dispersed semiconducting carbon nanotubes.
    Type: Grant
    Filed: July 29, 2005
    Date of Patent: February 8, 2011
    Assignee: University of Tsukuba
    Inventors: Takeshi Akasaka, Takatsugu Wakahara, Yutaka Maeda
  • Publication number: 20100297449
    Abstract: The present invention is a transparent conductive film characterized in that: a major component of the transparent conductive film is a single-walled carbon nanotube; the single-walled carbon nanotubes are present in a bundle state; and a rope-like shape, which is a state where the bundles are gathered together, can be confirmed by scanning electron microscope observation. The present invention is also a method for producing a liquid crystal alignment film using a transparent electrode substrate, with an electrode layer being the aforementioned transparent conductive film. According to the invention, a transparent electrode substrate with high wettability can be obtained, and further a method for producing an alignment film by which a uniform alignment film can be obtained without deteriorating an electrical characteristic is provided.
    Type: Application
    Filed: October 24, 2007
    Publication date: November 25, 2010
    Applicant: KURARAY CO., LTD.
    Inventors: Takahiro Kitano, Masayasu Ogushi
  • Publication number: 20100272981
    Abstract: An optically transparent and electrically conductive single walled carbon nanotube (SWNT) film comprises a plurality of interpenetrated single walled carbon nanotubes, wherein for a 100 nm film the film has sufficient interpenetration to provide a 25° C. sheet resistance of less than 200 ohm/sq. The film also provides at least 20% optical transmission throughout a wavelength range from 0.4 ?m to 5 ?m.
    Type: Application
    Filed: July 7, 2010
    Publication date: October 28, 2010
    Inventors: ANDREW G. RINZLER, ZHIHONG CHEN
  • Publication number: 20100239491
    Abstract: The present teachings are directed to methods of preparing cylindrical carbon structures, specifically single-walled carbon nanotubes, with a desired chirality. The methods include the steps of providing a catalyst component on a substrate and a carbon component, contacting the catalyst component and the carbon component to produce a cylindrical carbon structure. Then, no longer providing the carbon component and determining the chirality of the cylindrical carbon structure. The catalyst component is then cleaned and the process is repeated until the cylindrical carbon structure fulfills a desired characteristic, such as, length. The chirality of the single-walled carbon nanotube grown, after cleaning of the catalyst component, has the same chirality as the initially produced nanotube.
    Type: Application
    Filed: June 28, 2006
    Publication date: September 23, 2010
    Applicant: Honda Motor Co., Ltd.
    Inventor: Avetik Harutyunyan
  • Patent number: 7786466
    Abstract: Gate electrodes are formed on a semiconducting carbon nanotube, followed by deposition and patterning of a hole-inducing material layer and an electron inducing material layer on the carbon nanotube according to the pattern of a one dimensional circuit layout. Electrical isolation may be provided by cutting a portion of the carbon nanotube, forming a reverse biased junction of a hole-induced region and an electron-induced region of the carbon nanotube, or electrically biasing a region through a dielectric layer between two device regions of the carbon nanotube. The carbon nanotubes may be arranged such that hole-inducing material layer and electron-inducing material layer may be assigned to each carbon nanotube to form periodic structures such as a static random access memory (SRAM) array.
    Type: Grant
    Filed: January 11, 2008
    Date of Patent: August 31, 2010
    Assignee: International Business Machines Corporation
    Inventors: Joerg Appenzeller, AJ Kleinosowski, Edward J. Nowak, Richard Q. Williams
  • Patent number: 7785472
    Abstract: A method of separating, concentrating or purifying uniform carbon nanotubes with desired properties (diameter, chiral vector, etc) in a highly sensitive manner by the use of structure-sensitive properties peculiar to carbon nanotubes; and an apparatus therefor. There is provided a method of separating, concentrating, or purifying carbon nanotubes with the desired properties contained in a sample, comprising the steps of (a) irradiating a sample containing carbon nanotubes with light; and (b) selecting carbon nanotubes with desired properties. In a preferred embodiment, the light irradiation of the step (a) can be carried out in the presence of a metal so as to cause specified carbon nanotubes to selectively induce a photocatalytic reaction, resulting in metal deposition. Further, in a preferred embodiment, a given magnetic filed can be applied in the steps (b) so as to attain accumulation or concentration or carbon nanotubes with metal deposited.
    Type: Grant
    Filed: February 10, 2005
    Date of Patent: August 31, 2010
    Assignee: Japan Science and Technology Agency
    Inventor: Kei Murakoshi
  • Patent number: 7767615
    Abstract: A method for producing aligned carbon nanotubes and/or nanofibres comprises providing finely divided substrate particle having substantially smooth faces with radii of curvature of more than 1 ?m and of length and breadth between 1 ?m and 5 mm and having catalyst material on their surface and a carbon-containing gas at a temperature and pressure at which the carbon-containing gas will react to form carbon when in the presence of the supported catalyst, and forming aligned nanotubes and/or nanofibres by the carbon-forming reaction.
    Type: Grant
    Filed: November 13, 2003
    Date of Patent: August 3, 2010
    Assignee: Cambridge University Technical Services Limited
    Inventors: Ian Kinloch, Charanjeet Singh, Milo Sebastian Peter Shaffer, Krzysztof K. K. Koziol, Alan Windle
  • Publication number: 20100166624
    Abstract: A method of separating at least one carbon nanotube having a desired diameter and/or chirality from a mixture of carbon nanotubes having different diameters and/or chiralities is provided. A calixarene of formula (I): wherein n?4; X is PO3H2, Ra—PO3H, SO3H, or Ra—SO3H; Y is Rb, OH, or ORb; and Ra and Rb are independently selected from the group consisting of optionally substituted alkyl, optionally substituted aryl, optionally substituted arylene alkyl and optionally substituted alkylene aryl is combined with the mixture of carbon nanotubes in an aqueous solvent to produce an aqueous supernatant containing the carbon nanotube(s) having the desired diameter and/or chirality. The aqueous supernatant containing the carbon nanotube(s) is then separated from a residue comprising the remaining carbon nanotubes of the mixture.
    Type: Application
    Filed: October 30, 2009
    Publication date: July 1, 2010
    Applicant: THE UNIVERSITY OF WESTERN AUSTRALIA
    Inventors: Colin Llewellyn RASTON, Lee John Hubble
  • Publication number: 20100166637
    Abstract: The subject invention provides a two-phase liquid-liquid extraction process that enables sorting and separation of single-walled carbon nanotubes based on (n, m) type and/or diameter. The two-phase liquid extraction method of the invention is based upon the selective reaction of certain types of nanotubes with electron withdrawing functional groups as well as the interaction between a phase transfer agent and ionic moieties on the functionalized nanotubes when combined in a two-phase liquid solution. Preferably, the subject invention enables efficient, bulk separation of metallic/semi-metallic nanotubes from semi-conducting nanotubes. More preferably, the subject invention enables efficient, bulk separation of specific (n, m) types of nanotubes.
    Type: Application
    Filed: September 15, 2006
    Publication date: July 1, 2010
    Inventor: Kirk Jeremy Ziegler
  • Patent number: 7727505
    Abstract: A method for separating carbon nanotubes comprises: providing a mixture of carbon nanotubes; introducing an organic molecule having an end group capable of being chelated by a metal ion to the mixture of carbon nanotubes to covalently bond the organic molecule to at least one of the mixture of carbon nanotubes; and introducing a metal salt to the mixture of carbon nanotubes to chelate the end group of the organic molecule with the metal ion of the metal salt; and centrifuging the mixture of carbon nanotubes to cause the separation of the carbon nanotubes based on a density differential of the carbon nanotubes.
    Type: Grant
    Filed: May 21, 2008
    Date of Patent: June 1, 2010
    Assignee: International Business Machines Corporation
    Inventors: Ali Afazali-Ardakani, James B. Hannon, Cherie R. Kagan, George S. Tulevski
  • Publication number: 20100086787
    Abstract: Exemplary embodiments provide coating compositions having pseudo-fluorine surface and methods for processing and using the coating compositions. The coating composition can include, for example, a plurality of fluorine-containing resin fillers and a plurality of nanotubes (e.g., carbon nanotubes (CNTs)) dispersed in a polymer matrix that contains, e.g., one or more cross-linked polymers. The fluorine-containing resin fillers can provide a pseudo-fluorine surface for a low surface energy of the coating composition. The nanotubes can be dispersed in the polymer matrix to provide an improved mechanical robustness of the coating composition. The coating composition can be coated on a member surface, wherein the coated member can be, for example, a fuser member, a fixing member, a pressure roller, or a release agent donor member, used in an electrostatographic printing device or process.
    Type: Application
    Filed: October 6, 2008
    Publication date: April 8, 2010
    Applicant: XEROX CORPORATION
    Inventors: Yu QI, Nan-Xing Hu, Qi Zhang, Gordon Sisler, Brian McAneney
  • Publication number: 20100078600
    Abstract: The present invention is directed to the effective dispersion of carbon nanotubes (CNTs) into polymer matrices. The nanocomposites are prepared using polymer matrices and exhibit a unique combination of properties, most notably, high retention of optical transparency in the visible range (i.e., 400-800 nm), electrical conductivity, and high thermal stability. By appropriate selection of the matrix resin, additional properties such as vacuum ultraviolet radiation resistance, atomic oxygen resistance, high glass transition (Tg) temperatures, and excellent toughness can be attained. The resulting nanocomposites can be used to fabricate or formulate a variety of articles such as coatings on a variety of substrates, films, foams, fibers, threads, adhesives and fiber coated prepreg. The properties of the nanocomposites can be adjusted by selection of the polymer matrix and CNT to fabricate articles that possess high optical transparency and antistatic behavior.
    Type: Application
    Filed: August 31, 2009
    Publication date: April 1, 2010
    Applicant: USA as represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: John W. Connell, Joseph G. Smith, Joycelyn S. Harrison, Cheol Park, Kent A. Watson, Zoubeida Ounaies
  • Publication number: 20100081568
    Abstract: Exemplary methods of producing single-walled carbon nanotubes (SWCNTs) are disclosed. A plurality of seed cap molecules having a same diameter and a same chirality are prepared. The plurality of seed cap molecules are attached to a plurality of catalyst particles to form a plurality of catalyst-cap composites. Carbon atoms are provided to the catalyst-cap composites. Carbon nanotubes having the same diameter and the same chirality are grown on the plurality of catalyst-cap composited by exposing the composites to the carbon atoms.
    Type: Application
    Filed: April 13, 2009
    Publication date: April 1, 2010
    Applicant: LOCKHEED MARTIN CORPORATION
    Inventor: Peter V. Bedworth
  • Publication number: 20100072432
    Abstract: Carbon nanotube reinforced polymers include a polymer and carbon nanotubes reinforcing the polymer. The carbon nanotube reinforced polymer exhibits a conductivity percolation threshold of less than 106 ?/cm at a carbon nanotube content of 1.5 wt. % and less. The polymer may be selected from a polyamide or a polystyrene based polymer. In certain embodiments, the carbon nanotube content is between 0.1 to 1.5 wt. %, and the reinforced polymer will have a percolation threshold at a carbon nanotube content of less than 0.5 wt. %.
    Type: Application
    Filed: May 6, 2009
    Publication date: March 25, 2010
    Applicants: STICHTING DUTCH POLYMER INSTITUTE, BEN-GURION UNIVERSITY OF THE NEGEV RESEARCH AND DEVELOPMENT AUTHORITY
    Inventors: Cornelis E. KONING, Oren REGEV, Joachim LOOS
  • Patent number: 7641883
    Abstract: The separation of carbon nanotubes into metallic carbon nanotubes and semiconducting carbon nanotubes is made to be possible simultaneously with the dispersion of the carbon nanotubes by using viologen.
    Type: Grant
    Filed: April 4, 2008
    Date of Patent: January 5, 2010
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Hyeon Jin Shin, Seonmi Yoon, Jaeyoung Choi, Seong Jae Choi, YoungHee Lee, JungJun Bae
  • Patent number: 7611687
    Abstract: Methods and processes for preparing interconnected carbon single-walled nanotubes (SWNTs) are disclosed. The SWNTs soot, synthesized by any one of the art methods, is heated to less than about 1250° C. in flowing dry air using the electrical field (E) component of microwave energy. The tubes of the SWNTs thus treated become welded and interconnected.
    Type: Grant
    Filed: November 17, 2004
    Date of Patent: November 3, 2009
    Assignee: Honda Motor Co., Ltd.
    Inventor: Avetik R. Harutyunyan
  • Publication number: 20090227162
    Abstract: Surface films, paints, or primers can be used in preparing aircraft structural composites that may be exposed to lightning strikes. Methods for making and using these films, paints or primers are also disclosed. The surface film can include a thermoset resin or polymer, e.g., an epoxy resin and/or a thermoplastic polymer, which can be cured, bonded, or painted on the composite structure. Low-density electrically conductive materials are disclosed, such as carbon nanofiber, copper powder, metal coated microspheres, metal-coated carbon nanotubes, single wall carbon nanotubes, graphite nanoplatelets and the like, that can be uniformly dispersed throughout or on the film. Low density conductive materials can include metal screens, optionally in combination with carbon nanofibers.
    Type: Application
    Filed: March 9, 2007
    Publication date: September 10, 2009
    Applicants: Goodrich Corporation, Rohr, Inc.
    Inventors: Teresa M. Kruckenberg, Valerie A. Hill, Anthony Michael Mazany, Eloise Young, Song Chiou
  • Publication number: 20090218549
    Abstract: A nanocarbon film that is produced in such a manner that, after a nanocarbon dispersion containing nanocarbon and a dispersant is used to form a film containing the nanocarbon and the dispersant, an external stimulus is applied to the film to at least partially decompose the dispersant contained in the film. Light irradiation is preferably applied as the external stimulus.
    Type: Application
    Filed: February 24, 2009
    Publication date: September 3, 2009
    Applicant: FUJIFILM CORPORATION
    Inventors: Takashi Kato, Naoyuki Hayashi