Abstract: The process comprises contacting a hydrocarbon feedstock containing a substantial amount of organic nitrogen-containing compounds in a first reaction zone under hydrocracking conditions and in the presence of hydrogen with a first catalyst comprising nickel and molybdenum or nickel and tungsten, their oxides, and/or their sulfides on a co-catalytic acidic cracking support comprising ultrastable, large-pore crystalline alumino-silicate material and a silica-alumina matrix to produce a first hydrocracked effluent and contacting said first hydrocracked effluent in a second reaction zone under hydrocracking conditions and in the presence of hydrogen with a second catalyst comprising cobalt and molybdenum, their oxides, and/or their sulfides on a co-catalytic acidic cracking support comprising ultrastable, large-pore crystalline aluminosilicate material and a silica-alumina matrix to produce a second hydrocracked effluent.
Abstract: Lubricant compositions containing polymer alkylated aromatic amino acids as antioxidants and a process for the preparation of these amino acids comprising hydrolysis of cyclic keto amides formed from an intramolecular acylation of an imide of an aromatic amine.
Abstract: Over-based oil-soluble magnesium sulfonate compositions are formed by one-step carbonation of a reactant mixture containing magnesium hydroxide formed in situ.
Type:
Grant
Filed:
October 24, 1975
Date of Patent:
May 6, 1980
Assignee:
Standard Oil Company (Indiana)
Inventors:
Albert R. Sabol, Dennis G. Petrille, Edward W. Heffern
Abstract: This invention relates to the intramolecular oxidation and reduction of aromatic hydrocarbons containing at least one methyl group and a nitro group ortho to the methyl group. Further, it relates to preparing methyl o-amino arylcarboxylates and aromatic amines. The process comprises reacting aromatic hydrocarbons having at least one methyl group and a nitro group ortho to the methyl group in a solvent at a temperature of about 450.degree. to 750.degree. C. When the solvent is methanol, methyl o-amino arylcarboxylates useful in anesthetics, printing inks for polyethylene, and useful in the manufacture of azo dyes are produced. Novel substituted methyl anthranilates have been produced which have the foregoing uses. When no solvent is used or the solvent is benzene, cyclohexane, toluene, hexafluorobenzene or any other non-reactive solvent, the compounds are demethylated and aromatic amines are produced.
Abstract: High molecular weight alkylated phenols, in which the alkyl substituent has an average molecular weight of from about 300 to about 100,000 are nitrosated with nitrous acid anhydride gas, in the presence of an acid catalyst, and the nitrosated product reacted with an amine compound having at least one HN< group to obtain oil-soluble amine derivatives of such nitrosated alkylated phenols suitable as lubricating oil additives having dispersancy properties.
Abstract: Whole single-cell protein cells possessing improved functional properties are obtained by heat treating said cells at a temperature of from about 215.degree. to about 300.degree. F. for from about 30 seconds to about 25 minutes to inactivate invertase.
Type:
Grant
Filed:
April 29, 1977
Date of Patent:
March 11, 1980
Assignee:
Standard Oil Company (Indiana)
Inventors:
Shingo Kajinami, Elmer J. Saunders, Philip G. Schnell
Abstract: A heavy hydrocarbon stream containing metals, asphaltenes, nitrogen compounds, and sulfur compounds is (a) contacted with hydrogen and a hydrotreating catalyst containing molybdenum and chromium, either as metals, as oxides, as sulfides, or mixtures thereof, deposed on a large-pore, catalytically active alumina to reduce the metals content in said stream, to convert the asphaltenes, nitrogen compounds, and sulphur compounds in said stream, the catalyst has a pore volume within the range of about 0.4 cc/gm to about 0.8 cc/gm, a surface area within the range of about 150 m.sup.2 /gm to about 300 m.sup.2 /gm, and an average pore diameter within the range of about 100 A (10 nm) to about 200 A (20 nm); and (b) at least a portion of the hydrotreated stream is cracked with a cracking catalyst to produce gasoline and distillates in improved yields. The catalyst in step (a) may also contain cobalt.
Type:
Grant
Filed:
December 7, 1978
Date of Patent:
March 4, 1980
Assignee:
Standard Oil Company (Indiana)
Inventors:
Leonard M. Quick, Albert L. Hensley, Jr.
Abstract: Growth of pseudomycelial yeasts and removal of bacterial contamination in conventional fermentation processes are accomplished by withdrawing product as a foam from the fermentor.
Type:
Grant
Filed:
June 22, 1978
Date of Patent:
February 19, 1980
Assignee:
Standard Oil Company (Indiana)
Inventors:
Constance R. Corbett, John A. Ridgway, Jr., Helen D. Haller
Abstract: In an alpha-olefin polymerization process using a transition metal halide-aluminum alkyl catalyst system, addition of minor, effective amounts of aromatic amines or amine N-oxides substituted with electron withdrawing groups decreases the amount of low molecular weight or amorphous polymer produced.
Abstract: Method for detecting leakage of semipermeable membranes or hollow fibers, said membranes or fibers exhibiting salt rejection, which comprises contacting one side of the membrane or fiber with an aqueous salt solution so that purified water will pass across non-leaking members to the second side and a salt enriched aqueous solution will pass to the second side of leaking members, and measuring the salt content of the aqueous solution on the second side of the member so that leaking members can be detected.
Abstract: Thermoplastic polymer particles are converted to pellets by depositing the powder onto a moving platform, melting the particles and transferring the melted polymer to a pelletizer.
Type:
Grant
Filed:
December 29, 1977
Date of Patent:
February 19, 1980
Assignee:
Standard Oil Company a corporation of Indiana
Abstract: The process comprises contacting a heavy hydrocarbon stream containing metals and asphaltenes to reduce the contents of nitrogen compounds, sulfur compounds, metals and asphaltenes in the hydrocarbon stream under suitable conditions and in the presence of hydrogen with a catalyst comprising a hydrogenating component consisting essentially of molybdenum and chromium, their oxides, their sulfides, or mixtures thereof on a large-pore, catalytically active alumina. The catalyst has a pore volume within the range of about 0.4 cc/gm to about 0.8 cc/gm, a surface area within the range of about 150 m.sup.2 /gm to about 300 m.sup.2 /gm, and an average pore diameter within the range of about 100 A to about 200 A.
Type:
Grant
Filed:
December 7, 1978
Date of Patent:
February 12, 1980
Assignee:
Standard Oil Company (Indiana)
Inventors:
Leonard M. Quick, Albert L. Hensley, Jr.
Abstract: Compounds having the structures: ##STR1## wherein B is A or a hydrogen and A is R--X; wherein X is ##STR2## M is a Group II metal cation and R is a hydrocarbyl group having about 1 to 100 carbon atoms.
Abstract: Beta-phosphosulfoxy alcohols and preparation thereof by reacting an olefinically unsaturated compound and a poly-thiophosphoric acid with oxygen using actinic radiation as an energy source at a temperature of from -10.degree. to 70.degree. C., preferably in the presence of a dye sensitizer.
Abstract: A decarboxylation process for coupling aromatic compounds wherein cyclic hydrocarbons and heterocyclic compounds having at least one labile ring hydrogen are reacted with the mono silver salts of aromatic carboxylic acids, or mono silver salts of unsaturated compounds such as .alpha.,.beta.-ethylenically unsaturated acid compounds, or silver trifluoroacetate, or the mono silver salts are reacted with themselves, by heating to temperatures of 100.degree. to 500.degree. C. at pressures of 0.1 to 10 atmospheres, or by irradiating the reactants with ultraviolet light of 200 to 400 nanometers at temperatures of -30.degree. to 100.degree. C. The resulting dimers, trimers, polysubstituted polyphenyls, polyheterocyclics and trifluoromethylated aromatics are useful as heat transfer media, as intermediates for high molecular weight polymers, pesticides and petroleum additives, and as scintillation counters.
Abstract: Limiting final conversion of monomer to polymer in a multiple stage, vinyl aromatic-rubber mass polymerization system to about 50 to about 89 percent produces a polymer with increased impact strength and decreases residence time, thereby increasing the production capacity of the system.
Abstract: Novel terpolymers of the amide-imide type are prepared from tricarboxylic-acid-anhydride derivatives, aromatic diamino quinones and two other wholly-aromatic primary diamines. The novel terpolymers are useful for preparing molded articles of superior properties at injection molding temperatures lower than required for molding the amide-imide copolymers disclosed in the prior art.
Abstract: Process for increasing the concentration of normal cis olefins in a hydrocarbon composition with pre-treated molecular sieves which have been heated to a temperature of from 400.degree. to 500.degree. F. for a period of about 1 to 6 hours to reach the water-zeolite equilibrium at said temperature range in the presence of water.
Type:
Grant
Filed:
February 27, 1978
Date of Patent:
January 29, 1980
Assignee:
Standard Oil Company (Indiana)
Inventors:
Chi-Hung Lin, William F. Pansing, deceased
Abstract: Partial esters of polyhydroxy compounds and combinations thereof with organophosphorus compounds have been found to be effective stabilizers for polyolefins made in processes wherein such polymers are not subjected to extensive removal of process produced impurities during or subsequent to the polymerization process. Combinations of polypropylene produced in a solventless polymerization process and such partial esters are particularly suitable and show substantially improved stability in the presence of additional stabilizing compounds.
Type:
Grant
Filed:
May 1, 1978
Date of Patent:
January 22, 1980
Assignee:
Standard Oil Company (Indiana)
Inventors:
Nicholas M. Karayannis, Habet M. Khelghatian, John S. Skryantz