Patents Represented by Attorney Charles W. Stewart
  • Patent number: 7897550
    Abstract: Urea grease composition for constant velocity joints is provided containing base oil, one or more urea thickener compounds, (A) one or more molybdenum sulphurized dialkyldithiocarbamates represented by general formula (I) wherein R1 and R2 are independently chosen from alkyl groups of from 1 to 24 carbons, m+n=4, m is from 0 to 3 and n is from 4 to 1, (B) triphenylphosphorothionate represented by formula (II) and (C) one or more stearic acid metal salts.
    Type: Grant
    Filed: June 17, 2004
    Date of Patent: March 1, 2011
    Assignee: Shell Oil Company
    Inventors: Yasushi Kawamura, Takumi Matsumoto, Kazuhiro Miyajima, Tetsuo Nimura, Kazushige Ohmura, Noriaki Shinoda, Keiji Tanaka, Takeo Yamamoto
  • Patent number: 7871513
    Abstract: Described is a catalyst useful in the hydroprocessing of a heavy hydrocarbon feedstock wherein the catalyst comprises a calcined mixture made by calcining a formed particle of a mixture comprising molybdenum trioxide, a nickel compound, and an inorganic oxide material. The catalyst may be made by mixing an inorganic oxide material, molybdenum trioxide, and a nickel compound to form a mixture that is formed into a particle and calcined to provide a calcined mixture. The process involves the hydrodesulfurization and hydroconversion of a heavy hydrocarbon feedstock which process may include the conversion of a portion of the pitch content of the heavy hydrocarbon feedstock and the yielding of a treated product having an enhanced stability as reflected by its P-value.
    Type: Grant
    Filed: September 9, 2010
    Date of Patent: January 18, 2011
    Assignee: Shell Oil Company
    Inventor: Opinder Kishan Bhan
  • Patent number: 7867956
    Abstract: A urea-based lubricating grease composition comprising (a) as a thickener, a diurea compound which is an alkyldiurea compound having an average molecular weight in the range of from 600 to 700, wherein in the range of from 25 to 60 mole % of the total alkyl groups is an unsaturated component, and the total amine value of the primary amine constituting the raw material is in the range of from 250 to 350, (b) a base oil having as its main component one or more synthetic hydrocarbon oil(s) having a pour point of ?40° C. or below, wherein the kinematic viscosity of the base oil is 6000 mm2/sec or less at ?40° C., and (c) as additives, a mixture comprising an oil-soluble organic molybdenum complex, an oil-soluble organic zinc compound of dithiocarbamic acid, an oil-soluble organic zinc compound of dithiophosphoric acid and an inorganic sulphur compound; and a roller bearing and electric power steering device wherein the said lubricating grease composition is used as the lubricant.
    Type: Grant
    Filed: December 23, 2005
    Date of Patent: January 11, 2011
    Assignee: Shell Oil Company
    Inventors: Toshihiro Asakura, Yasushi Kawamura, Hirofumi Kuwabara, Takahiro Ozaki, Shigeyuki Sugimori, Keiji Tanaka
  • Patent number: 7841585
    Abstract: A separation tray, suitable for mounting in a vertical column, for separating liquid/gas mixtures. The separation tray has horizontal upper and lower walls and a plurality of primary separation devices for separating a fluid into a primary gas and a liquid-enriched secondary gas. The invention is characterized by a secondary separation zone located in the inner free space between the upper and lower walls and the primary separation devices. Liquid-enriched secondary gas is removed through outlets in the primary separation devices and guided downwardly by return skirts into the inner free space, whereupon the entrained liquid in the liquid-enriched secondary gas is substantially removed from the secondary gas.
    Type: Grant
    Filed: February 17, 2004
    Date of Patent: November 30, 2010
    Assignee: Shell Oil Company
    Inventor: Gerrit Konijn
  • Patent number: 7833341
    Abstract: The invention provides modified sulphur comprising sulphur and a polysulphide-containing organosilane in an amount of in the range of from 0.3 to 25 wt % based on the weight of sulphur, in which modified sulphur the combined amount of sulphur and polysulphide-containing organosilane make up in the range of from 90 to 100 wt % of the obtained modified sulphur and wherein the polysulphide-containing organosilane is of the general molecular formula (1): (X3Si)mH(2n+1?m)Cn-Sa-Cn?H(2n?+1?m?)(SiX?3)m?; wherein a is an integer in the range of from 2 to 8, X and X? each are, independently, a hydrolysable group, n and n? each are, independently, an integer in the range of from 1 to 4, and m and m? each are, independently, an integer in the range of from 1 to (2n+1). The invention further provides a process for preparing such modified sulphur, a sulphur cement product comprising the modified sulphur and a process for preparing such.
    Type: Grant
    Filed: June 4, 2008
    Date of Patent: November 16, 2010
    Assignee: Shell Oil Company
    Inventors: Jany Birgitta Maria Antens, Denka Georgieva Hristova, Cornelis Hamelink, Guy Lode Magda Maria Verbist
  • Patent number: 7824541
    Abstract: Described is a catalyst and process useful in the hydrodesulfurization of a distillate feedstock to manufacture a low-sulfur distillate product. The catalyst comprises a calcined mixture of inorganic oxide material, a high concentration of a molybdenum component, and a high concentration of a Group VIII metal component. The mixture that is calcined to form the calcined mixture comprises molybdenum trioxide, a Group VIII metal compound, and an inorganic oxide material. The catalyst is made by mixing the aforementioned starting materials and forming therefrom an agglomerate that is calcined to yield the calcined mixture that may be used as the catalyst or catalyst precursor.
    Type: Grant
    Filed: August 1, 2007
    Date of Patent: November 2, 2010
    Assignee: Shell Oil Company
    Inventor: Opinder Kishan Bhan
  • Patent number: 7820036
    Abstract: Described is a catalyst useful in the hydroprocessing of a heavy hydrocarbon feedstock wherein the catalyst comprises a calcined mixture made by calcining a formed particle of a mixture comprising molybdenum trioxide, a nickel compound, and an inorganic oxide material. The catalyst may be made by mixing an inorganic oxide material, molybdenum trioxide, and a nickel compound to form a mixture that is formed into a particle and calcined to provide a calcined mixture. The process involves the hydrodesulfurization and hydroconversion of a heavy hydrocarbon feedstock which process may include the conversion of a portion of the pitch content of the heavy hydrocarbon feedstock and the yielding of a treated product having an enhanced stability as reflected by its P-value.
    Type: Grant
    Filed: August 1, 2007
    Date of Patent: October 26, 2010
    Assignee: Shell Oil Company
    Inventor: Opinder Kishan Bhan
  • Patent number: 7820579
    Abstract: A method of restoring catalytic activity to a spent hydroprocessing catalyst that has a first carbon concentration. The concentration of carbon on the spent hydroprocessing catalyst is reduced to provide a carbon-reduced catalyst having a second carbon concentration that is less than the first carbon concentration. The carbon-reduced catalyst is exposed to a solution, comprising a chelating agent and a solvent, for an aging time period sufficient to provide for a restored catalytic activity thereby resulting in an aged catalyst having incorporated therein the chelating agent and the solvent. The aged catalyst is exposed to conditions, including a drying temperature, so as to remove from the aged catalyst a portion of the solvent without removing a significant portion of the chelating agent from the aged catalyst thereby resulting in a dried aged catalyst. The dried aged catalyst is then sulfur treated to thereby provide a restored catalyst.
    Type: Grant
    Filed: January 19, 2005
    Date of Patent: October 26, 2010
    Assignee: Shell Oil Company
    Inventors: Josiane Marie-Rose Ginestra, James Dallas Seamans, Kenneth Scott Lee
  • Patent number: 7811372
    Abstract: A rejuvenating agent having a viscosity of from 200 to 60000 cSt at 60° C. and comprising 10-90 weight % palm oil and 90-10 weight % bitumen, where the percentages are based upon the total weight of the composition, is disclosed. The rejuvenating agent is suitable for use in hot in-place and hot in-plant recycling processes.
    Type: Grant
    Filed: January 4, 2008
    Date of Patent: October 12, 2010
    Assignee: Shell Oil Company
    Inventors: Sophie Nigen-Chaidron, Laurent Porot
  • Patent number: 7803339
    Abstract: The invention provides a method for disposal of di-sulphide compounds having the general formula of R—S—S—R, wherein R is an alkyl group, the method comprising the steps of: (a) combusting said di-sulphide compounds in the presence of an oxygen-containing gas in a sulphur dioxide generation zone, whereby at least part of the di-sulphide compounds is converted to sulphur dioxide to obtain a gas stream comprising sulphur dioxide; (b) reacting the gas stream comprising sulphur dioxide with hydrogen sulphide to obtain elemental sulphur.
    Type: Grant
    Filed: February 20, 2007
    Date of Patent: September 28, 2010
    Assignee: Shell Oil Company
    Inventor: Anders Carlsson
  • Patent number: 7790652
    Abstract: A method of hydroprocessing a heavy hydrocarbon feedstock using a hydroprocessing catalyst having specific properties making it effective in the hydroconversion of at least a portion of the heavy hydrocarbon feedstock to lighter hydrocarbons. The hydroprocessing catalyst comprises a Group VIB metal component (e.g., Cr, Mo, and W), a Group VIII metal component (e.g., Ni and Co) and, optionally, a potassium metal component that are supported on a support material comprising alumina. The alumina has novel physical properties that, in combination with the catalytic components, provide for the hydroprocessing catalyst. The hydroprocessing catalyst is particularly effective in the conversion of the heavy hydrocarbon feedstock. The alumina is characterized as having a high pore volume and a high surface area with a large proportion of the pore volume being present in the pores within a narrow pore diameter distribution about a narrowly defined range of median pore diameters.
    Type: Grant
    Filed: September 15, 2004
    Date of Patent: September 7, 2010
    Assignee: Shell Oil Company
    Inventors: Russell Craig Ackerman, Josiane Marie-Rose Ginestra, Christian Gabriel Michel
  • Patent number: 7776300
    Abstract: Disclosed is a process for removing sulfur from a fuel gas stream that comprises an organic sulfur compound and a light olefin. The process includes introducing a fuel gas stream into an elongated hydrotreating reactor vessel in which it is contacted with a hydrodesulfurization catalyst under hydrodesulfurization process conditions. A quench gas stream is also introduced into the elongated hydrotreating reactor vessel at a location below the point of introduction of the fuel gas stream. A reactor effluent is yielded that contains hydrogen sulfide and a significantly reduced organic sulfur concentration that is below the organic sulfur concentration of the fuel gas stream.
    Type: Grant
    Filed: May 23, 2008
    Date of Patent: August 17, 2010
    Assignee: Shell Oil Company
    Inventor: Gary Lee Ripperger
  • Patent number: 7758673
    Abstract: The present invention relates to a process for removing carbon dioxide and optionally hydrogen sulphide and/or COS from a gas stream containing these compounds by washing the gas with an aqueous washing solution containing water, sulfolane and a secondary or tertiary amine derived from ethanolamine. More particularly the invention relates to the process described above, the process being carried out in the presence of a primary or secondary amine compound in an amount between 0.5 and 15 wt. % based on water, sulfolane and amine. The invention further relates to an absorbent liquid to be used in the above process.
    Type: Grant
    Filed: January 14, 2003
    Date of Patent: July 20, 2010
    Assignee: Shell Oil Company
    Inventors: Theodorus Johannes Brok, Rudolf Johannes Mathilda Groenen, Jeanine Marie Klinkenbijl, Mariette Catharina Knaap
  • Patent number: 7758679
    Abstract: A treating unit that comprises an absorber unit for contacting a regenerated solvent with a gas stream loaded with contaminants to yield a treated gas stream and a loaded solvent stream; a regenerator unit for stripping the loaded solvent stream to yield a loaded gas stream and the regenerated solvent; and a device for smoothing contaminant peak concentrations in the loaded solvent stream and for receiving the loaded solvent stream. The device comprises a first hold-up tank having a first inlet and a first outlet, a second hold-up tank having a second inlet and a second outlet, and an inlet distributor that is operatively connected to the first inlet and to the second inlet and that provides for directing flow of the loaded solvent stream to either the first hold-up tank or the second hold-up tank.
    Type: Grant
    Filed: August 13, 2009
    Date of Patent: July 20, 2010
    Assignee: Shell Oil Company
    Inventors: Anders Carlsson, Gijsbert Jan Van Heeringen, Thijme Last
  • Patent number: 7754471
    Abstract: A process for the recovery of sulfur from an acid gas stream is disclosed. The process includes a Claus sulfur recovery step in combination with a direct reduction step and a biological sulfur recovery step to provide a sweet gas stream having a very low concentration of hydrogen sulfide and sulfur dioxide. The process includes reacting an acid gas steam with oxygen under such oxidation conditions to yield a combustion gas comprising hydrogen sulfide and sulfur dioxide. The combustion gas is reacted under Claus reaction conditions to yield a reaction gas comprising sulfur. Sulfur is recovered from the reaction gas to yield a Claus tail gas comprising hydrogen sulfide and sulfur dioxide. The Claus tail gas is reacted under direct reduction reaction conditions to yield a direct reduction gas comprising sulfur. Sulfur is recovered from the direct reduction reaction gas to yield a tail gas comprising a concentration of hydrogen sulfide.
    Type: Grant
    Filed: March 2, 2005
    Date of Patent: July 13, 2010
    Assignee: Shell Oil Company
    Inventors: Jen Kai Chen, Michael Arthur Huffmaster
  • Patent number: 7749937
    Abstract: An unsupported catalyst composition which comprises one or more Group VIb metals, one or more Group VIII metals, and a refractory oxide material which comprises 50 wt % or more titania, on oxide basis, which is prepared by precipitation techniques, finds use in the hydroprocessing of hydrocarbonaceous feedstocks.
    Type: Grant
    Filed: June 2, 2009
    Date of Patent: July 6, 2010
    Assignee: Shell Oil Company
    Inventors: Laszlo Domokos, Hermanus Jongkind, Willem Hartman Jurriaan Stork, Johanna Maria Helena Van Den Tol-Kershof
  • Patent number: 7744675
    Abstract: A gas separation membrane and a method of manufacturing such gas separation membrane that comprises a porous substrate treated with a layer of metal-coated inorganic oxide particles and with the layer of such metal-coated inorganic oxide particles being coated with an overlayer of a gas-selective material.
    Type: Grant
    Filed: October 31, 2007
    Date of Patent: June 29, 2010
    Assignee: Shell Oil Company
    Inventors: John Charles Saukaitis, Alan Anthony Del Paggio
  • Patent number: 7737074
    Abstract: An aromatics hydrogenation catalyst composition which comprises a noble metal component and a support comprising zirconia, silica, and, optionally, alumina. The catalyst composition is manufactured by co-mulling silica, a zirconium compound, and, optionally, alumina to form a mixture that is formed into a shape, such as by extrusion to form an extrudate, with the shape being calcined and noble metal being incorporated into the shape. The catalyst composition may be used in the saturation of aromatic compounds.
    Type: Grant
    Filed: June 18, 2007
    Date of Patent: June 15, 2010
    Assignee: Shell Oil Company
    Inventors: John Anthony Smegal, Johannes Anthonius Robert Van Veen
  • Patent number: 7731921
    Abstract: A process for sequestration of carbon dioxide comprising the following steps: (a) dispersing solid waste material comprising calcium oxide and a calcium-comprising mixed oxide in water to dissolve at least part of the calcium oxide and to form calcium oxide-depleted solid waste material in a calcium hydroxide solution; (b) separating the calcium hydroxide solution from the calcium oxide-depleted solid waste material; (c) converting the calcium hydroxide in the separated calcium hydroxide solution in precipitated calcium carbonate; and (d) contacting an aqueous slurry of the calcium oxide-depleted solid waste material with carbon dioxide for mineral carbonation of the carbon dioxide to form carbonated solid waste material.
    Type: Grant
    Filed: December 18, 2006
    Date of Patent: June 8, 2010
    Assignee: Shell Oil Company
    Inventors: Jacobus Johannes Cornelis Geerlings, Gerardus Antonius Franciscus Van Mossel, Bernardus Cornelis Maria In' T Veen
  • Patent number: 7727379
    Abstract: Process to prepare simultaneously two or more base oil grades and middle distillates from a mineral crude derived feed, in particular a de-asphalted oil or a vacuum distillate feed or their mixtures, by performing the following steps: (a) hydrocracking the mineral crude derived feed, thereby obtaining an effluent; (b) distillation of the effluent as obtained in step (a) into one or more middle distillates and a full range residue boiling substantially above 340° C., (c) catalytically dewaxing the full range residue by contacting the residue with a dewaxing catalyst comprising a zeolite of the MTW type and a Group VIII metal, thereby obtaining a dewaxed oil; (d) isolating by means of distillation two or more base oil grades from the dewaxed oil obtained in step (c); and (e) isolating a dewaxed gas oil from the dewaxed-oil obtained in step (c); wherein the dewaxed oil as obtained in step (c) comprises between 10 and 40 wt % of a dewaxed heavy gas oil boiling for more than 70 wt % between 370 and 400° C.
    Type: Grant
    Filed: March 1, 2005
    Date of Patent: June 1, 2010
    Assignee: Shell Oil Company
    Inventors: Nicholas James Adams, Harmannus Julius Hegge, Laurent Georges Huve, Kevin John Anthony Polder, Wiecher Derk Evert Steenge