Patents Represented by Attorney Dean A. Sandford
  • Patent number: 4601754
    Abstract: Compositions for the production of rare earth-ferromagnetic metal permanent magnets comprise mixtures of rare earth-ferromagnetic metal alloy powder and a lesser amount of a powdered second-phase sintering aid, wherein there is added up to about 2 percent by weight of a particulate refractory oxide, carbide, or nitride additive. Permanent magnets are prepared by mixing the components, aligning the mixture in a magnetic field, pressing and sintering. The refractory material inhibits grain growth in the second phase during sintering, improving the magnetic properties of the major phase.
    Type: Grant
    Filed: March 30, 1984
    Date of Patent: July 22, 1986
    Assignee: Union Oil Company of California
    Inventor: Mohammad H. Ghandehari
  • Patent number: 4600498
    Abstract: A catalyst containing hydrogenation metals supported on a base having (1) a crystalline aluminosilicate zeolite having activity for cracking and (2) a dispersion of silica-alumina in an alumina matrix is employed to mildly hydrocrack a hydrocarbon oil.
    Type: Grant
    Filed: March 22, 1985
    Date of Patent: July 15, 1986
    Assignee: Union Oil Company of California
    Inventor: John W. Ward
  • Patent number: 4600408
    Abstract: A fuel composition containing an alkyl phenyl carbonate as an anti-knock additive.
    Type: Grant
    Filed: April 29, 1985
    Date of Patent: July 15, 1986
    Assignee: Union Oil Company of California
    Inventors: Peter J. Jessup, Stephen G. Brass, Michael C. Croudace
  • Patent number: 4600497
    Abstract: Waxy shale oil feeds containing organonitrogen and/or organosulfur components are contacted with a catalyst comprising a Group VIB metal component on a support containing a crystalline aluminosilicate zeolite of the ZSM-5 type and a porous refractory oxide under conditions of elevated temperature and pressure and in the presence of hydrogen so as to simultaneously reduce its pour point and its organosulfur and/or organonitrogen content.
    Type: Grant
    Filed: May 8, 1981
    Date of Patent: July 15, 1986
    Assignee: Union Oil Company of California
    Inventors: John W. Ward, Timothy L. Carlson
  • Patent number: 4599477
    Abstract: Oxidative dehydrogenation catalysts suitable for converting C.sub.4 to C.sub.8 mono-olefins to conjugated dienes comprise vanadium, phosphorus, and alkali metal components, and preferably also a tin component, in combination with a microporous crystalline silica or a crystalline zeolite having a silica-to-alumina ratio of at least 6.0. In one embodiment, the catalyst has a surface area between 30 M.sup.2 /g to 450 M.sup.2 /g and the vanadium has an average valence in the range of from 3.50 to 4.95.
    Type: Grant
    Filed: October 30, 1985
    Date of Patent: July 8, 1986
    Assignee: Union Oil Company of California
    Inventors: Paul R. Robinson, Eric L. Moorehead
  • Patent number: 4597954
    Abstract: A process for removing SO.sub.x pollutants from a stack gas by (1) absorbing the SO.sub.x pollutants into an aqueous absorbent containing a formate compound and (2) regenerating the spent absorbent containing dissolved SO.sub.x compounds by contact, in the presence of added formate anion, with a water-insoluble, solid substance containing one or more tertiary amine functional groups. Nitrogen monoxide is removed by providing in the aqueous absorbent an iron(II) chelate, such as a chelate of ferrous ion with ethylenediaminetetraacetic acid. Regeneration of the spent absorbent containing absorbed NO is accomplished under the same conditions as for spent absorbents containing absorbed SO.sub.x compounds. SO.sub.x and NO pollutants dissolved in the absorbent are, during regeneration, converted to hydrogen sulfide and nitrogen, respectively.
    Type: Grant
    Filed: September 29, 1982
    Date of Patent: July 1, 1986
    Assignee: Union Oil Company of California
    Inventor: Robert H. Hass
  • Patent number: 4595350
    Abstract: A process and apparatus for preparing a porous, particulate sulfur by combining a coherent molten sulfur stream with a coherent water stream to provide an aqueous slurry of a porous, particulate sulfur having a uniform particle size distribution. In the process of this invention, a molten sulfur stream is passed through a substantially downwardly oriented, rectangular slot to provide a sheet of molten sulfur, and said sheet of molten sulfur is sheared by directing at least one sheet of water thereat, at a velocity and flow rate sufficient to disrupt said sheet of molten sulfur and provide solid sulfur particles having a substantially uniform size. The solid sulfur particles are recovered, as an aqueous slurry thereof, and separated from said slurry by substantially removing the water therefrom.
    Type: Grant
    Filed: February 14, 1985
    Date of Patent: June 17, 1986
    Assignee: Union Oil Company of California
    Inventors: Bruce Harbolt, James T. Saake
  • Patent number: 4595514
    Abstract: A boron-containing heterocyclic compound prepared by reacting a primary amine or ammonia with an alkylene oxide or epoxide and then reacting concurrently or subsequently this reaction intermediate with a boric acid. This boron-containing heterocyclic compound may further be reacted with a metal, metaloid or other metal compound and even further contain sulfur, such as a sulfide group.The boron-containing heterocyclic compound provides extreme pressure anti-wear properties when provided in a lubricating composition. The lubricating composition may also comprise anti-oxidants, copper corrosion inhibitors, and lead corrosion inhibitors. The anti-wear properties of a lubricating composition can be enhanced using the borates of the present invention in conjuction with a copper compound.
    Type: Grant
    Filed: January 29, 1985
    Date of Patent: June 17, 1986
    Assignee: Union Oil Company of California
    Inventors: Richard A. Holstedt, Michael C. Croudace
  • Patent number: 4594287
    Abstract: A liquid impregnant containing furfural, an acid catalyst and a pore-forming agent comprising a surfactant, e.g. a polyalkylene oxide adduct, is impregnated into fine grained, isotropic graphite bodies and then polymerized and pyrolyzed. An increase in the density of the impregnated body and an improved surface finish is obtained by means of the liquid impregnant and method of this invention.
    Type: Grant
    Filed: July 29, 1985
    Date of Patent: June 10, 1986
    Assignee: Union Oil Company of California
    Inventor: Edward E. Hucke
  • Patent number: 4592807
    Abstract: A photoelectrode, containing a highly conductive coating material having a band gap greater than 0 to about 3.0 e.V. on a substrate containing a semiconductor material, is utilized in photovoltaic cells, photoelectrosynthesis and photoelectrocatalysis.
    Type: Grant
    Filed: March 13, 1985
    Date of Patent: June 3, 1986
    Assignee: Union Oil Company of California
    Inventor: Jay A. Switzer
  • Patent number: 4589925
    Abstract: Acid-reactive organic and inorganic matter, such as stains and/or deposits, is removed from substrates by contacting such matter with a composition containing urea and sulfuric acid in which the urea/sulfuric acid molar ratio is less than 2. The urea-sulfuric acid compositions may optionally contain other components such as water, surfactants, and/or non-aqueous polar solvents which accentuate the activity of the compositions toward hydrophobic materials. The water-containing compositions which have H.sub.2 O/(urea+H.sub.2 SO.sub.4) molar ratios below about 2.5 are particularly useful for removing hydrolyzable matter by partial or complete hydroylsis.
    Type: Grant
    Filed: December 7, 1984
    Date of Patent: May 20, 1986
    Assignee: Union Oil Company of California
    Inventor: Donald C. Young
  • Patent number: 4588496
    Abstract: Hydrocarbon feedstocks containing relatively high levels of metal contaminants, such as nickel and vanadium, are converted via catalytic cracking into products of lower average molecular weight by contacting the feedstock with a catalyst comprising a (1) porous, inorganic refractory oxide component and (2) a dealuminated Y zeolite having a silica-to-alumina mole ratio above about 6.0. The dealuminated Y zeolite is preferably prepared by contacting an ammonium-exchanged Y zeolite having a silica-to-alumina mole ratio below about 6.0 with an aqueous solution of ammonium hexafluorosilicate. The refractory oxide component will preferably contain alumina and a clay such as kaolin. The catalyst may also contain a nondealuminated Y zeolite, preferably one that has been ion exchanged with rare earth cations. Typically, the hydrocarbon feedstock will contain contaminant metals in sufficient quantities such that their concentration exceeds about 4.0 ppmw Nickel Equivalents.
    Type: Grant
    Filed: January 3, 1985
    Date of Patent: May 13, 1986
    Assignee: Union Oil Company of California
    Inventor: Julius Scherzer
  • Patent number: 4586376
    Abstract: A method and apparatus for determining the effect of the flow of a fluid through a permeable particulate medium wherein a sample of the fluid is maintained as nearly as possible in the same physical and chemical condition as when it is sampled and is uniformly aged before being passed through a permeable particulate test medium. Some property of the sample, or of the permeable particulate test medium, such as a flow characteristic, is measured to determine the effect of passing the fluid through the permeable medium.
    Type: Grant
    Filed: September 25, 1984
    Date of Patent: May 6, 1986
    Assignee: Union Oil Company of California
    Inventor: H. Donald Outmans
  • Patent number: 4586752
    Abstract: A solution mining process for recovering mineral values from a subterranean mineral-bearing formation, which includes (1) a first injection-and-production phase during which a leaching solution is injected into the formation and a pregnant liquor is simultaneously recovered from the formation, (2) a production-only phase during which injection is suspended and additional pregnant liquor is recovered from the formation, and (3) a second injection-and-production phase.
    Type: Grant
    Filed: February 26, 1979
    Date of Patent: May 6, 1986
    Assignee: Union Oil Company of California
    Inventor: William E. Showalter
  • Patent number: 4584287
    Abstract: Y Zeolites are prepared with rare earth cations and Group VIII metal cations exchanged thereinto, such zeolites being especially useful in hydrocracking catalysts. The zeolites of the invention are prepared by exchanging a sodium Y zeolite with cations of one or more rare earth elements followed by a calcination, an ammonium ion exchange, and a Group VIII metal cation exchange. The resultant zeolite is not only highly active for catalytically promoting hydrocracking reactions but is also, after use in hydrocracking environments resulting in coke deposition, essentially completely regenerable by combustion of the coke.
    Type: Grant
    Filed: April 15, 1985
    Date of Patent: April 22, 1986
    Assignee: Union Oil Company of California
    Inventor: John W. Ward
  • Patent number: 4582819
    Abstract: A novel catalytic absorbent composition is prepared with a synthetic copper or silver carbonate-containing material. The absorbent is useful for removing hydrogen sulfide and mercaptan sulfur from hydrocarbon oils, especially from feedstreams to a reformer.
    Type: Grant
    Filed: December 11, 1984
    Date of Patent: April 15, 1986
    Assignee: Union Oil Company of California
    Inventors: J. Wayne Miller, John W. Ward
  • Patent number: 4582694
    Abstract: A process for producing a thermally shock calcined crystalline silica comprising (A) precalcining a crystalline silica at a relatively low temperature, (B) very rapidly increasing the temperature of the crystalline silica to a relatively high temperature for a short period of time, and (C) rapidly cooling the crystalline silica. The resulting crystalline silica is catalytically active for hydrocarbon conversion reactions and is particularly selective for the production of para-xylene from a reaction mix of toluene and a methylating agent.
    Type: Grant
    Filed: June 21, 1984
    Date of Patent: April 15, 1986
    Assignee: Union Oil Company of California
    Inventor: Dean A. Young
  • Patent number: 4580633
    Abstract: Method for treating a formation, particularly one containing finely divided particulate material, to increase the flow of fluids through the formation wherein there is injected therein an organosilicon compound, preferably in a hydrocarbon carrier liquid, followed by injection of steam containing a compound which contains ammoniacal nitrogen, selected from the group consisting of ammonium hydroxide, ammonium salts of inorganic acids, ammonium salts of carboxylic acids, quaternary ammonium halides, amine or substituted amine hydrochlorides, derivatives of ammonium cyanate, and water-soluble ammonia or ammonium ion precursors selected from the group consisting of amides of carbamic acid and thiocarbamic acid, derivatives of such amides, tertiary carboxylic acid amides and their substituted and alkylated derivatives. A preferred nitrogen-containing compound is urea.
    Type: Grant
    Filed: December 21, 1983
    Date of Patent: April 8, 1986
    Assignee: Union Oil Company of California
    Inventors: David R. Watkins, Leonard J. Kalfayan
  • Patent number: 4581129
    Abstract: Deactivated hydrorefining catalysts are regenerated by incorporation of a phosphorus component followed by combustive coke-removal from the catalyst. The regenerated catalyst is useful for promoting hydrodesulfurization reactions, particularly those involving demetallation of hydrocarbons.
    Type: Grant
    Filed: September 17, 1984
    Date of Patent: April 8, 1986
    Assignee: Union Oil Company of California
    Inventors: Richard B. Miller, Ryden L. Richardson
  • Patent number: 4581214
    Abstract: A process for producing a thermally shock calcined aluminosilicate zeolite comprising (A) precalcining an aluminosilicate zeolite at a relatively low temperature, (B) very rapidly increasing the temperature of the aluminosilicate zeolite to a relatively high temperature for a short period of time, and (C) rapidly cooling the aluminosilicate zeolite. The resulting zeolite is catalytically active for hydrocarbon conversion reactions and is particularly selective for the production of para-xylene from a reaction mix of toluene and a methylating agent.
    Type: Grant
    Filed: January 17, 1984
    Date of Patent: April 8, 1986
    Assignee: Union Oil Company of California
    Inventor: Dean A. Young