Abstract: This invention provides an optical medium which consists of a composite of a homogeneous inorganic oxide glass monolith with a microporous structure containing a liquid crystalline polymer component.In one embodient this invention provides a sol-gel process for producing a composite of a transparent homogeneous microporous inorganic oxide glass monolith and a liquid crystalline polymer.
Type:
Grant
Filed:
September 19, 1988
Date of Patent:
June 12, 1990
Assignee:
Hoechst Celanese Corp.
Inventors:
Alan Buckley, Tessie M. Che, Thomas M. Leslie, James B. Stamatoff, Dagobert E. Stuetz, Donald R. Ulrich
Abstract: Titanium-containing preceramic fibers are provided with a high loading of titanium by impregnating a polymeric fiber with a liquid comprising a titanium alkoxide where the alkoxide contains at least 2 carbon atoms and precipitating the titanium alkoxide in the fiber as titanium dioxide. Useful titanium alkoxides include titanium tetraethoxide, titanium tetrabutoxide and titanium isopropoxide.
Abstract: A process for producing boron-containing ceramics such as boron carbide and boron nitride comprises pyrolyzing a blend of a precarbonaceous polymer such as polyacrylonitrile and a boron-containing polymer such as that formed by the reaction of a borane with a Lewis base. Pyrolyzation in an inert atmosphere yields boron carbide while pyrolyzation in a reactive gas burns away the precarbonaceous polymer and yields a ceramic comprising the reaction product of boron and the pyrolyzation gas. Boron nitride ceramics are formed by pyrolyzing the preceramic blend in ammonia.
Abstract: This invention provides novel bisacrylate monomers and thermoset polymers which exhibit nonlinear optical response. The polymers have utility as a transparent nonlinear optical component in optical light switch and light modulator devices.
Type:
Grant
Filed:
November 13, 1989
Date of Patent:
May 29, 1990
Assignee:
Hoechst Celanese Corp.
Inventors:
Ronald N. DeMartino, Anthony J. East, Gordon W. Calundann
Abstract: This invention provides novel bisacrylate monomers and thermoset polymers which exhibit nonlinear optical response. The polymers have utility as a transparent nonlinear optical component in optical light switch and light modulator devices.
Type:
Grant
Filed:
December 21, 1987
Date of Patent:
May 1, 1990
Assignee:
Hoechst Celanese Corp.
Inventors:
Ronald N. DeMartino, Anthony J. East, Gordon W. Calundann
Abstract: This invention provides novel acrylic copolymers which exhibit nonlinear optical response, and which have utility as a transparent optical component in optical light switch and light modulator devices.
Type:
Grant
Filed:
October 3, 1986
Date of Patent:
April 10, 1990
Assignee:
Hoechst Celanese Corporation
Inventors:
Ronald N. DeMartino, Hyun-Nam Yoon, James B. Stamatoff
Abstract: This invention provides novel side chain liquid crystalline polymers. An invention polymer exhibits nonlinear optical response, and has utility as a transparent nonlinear optical component in optical light switch and light modulator devices.
Abstract: In one embodiment this invention provides injection moldable polyimides, as exemplified by the condensation and imidization product of a aromatic dianhydride such as 2,2-bis(3,4-dicarboxyphenyl)propane dianhydride with a novel aromatic diamine such as 2,2-bis[p,p'-(m-aminophenoxy)phenylsulfonyl(p-phenyleneoxy)phenyl]propane.
Abstract: In one embodiment this invention provides an nonlinear optical medium which is a composite of a polymer matrix which exhibits nonlinear optic response, and a silver colloid which is dispersed in the polymer matrix.
Type:
Grant
Filed:
January 10, 1989
Date of Patent:
April 3, 1990
Assignee:
Hoechst Celanese Corp.
Inventors:
Gunilla E. Gillberg-LaForce, Garo Khanarian
Abstract: This invention provides novel isotropic acrylic polymers and copolymers which exhibit nonlinear optical response, and which have utility as a transparent optical component in optical light switch and light modulator devices.
Abstract: In one embodiment this invention provides a novel polymerizable quaternary ammonium carbonate corresponding to the formula: ##STR1## In another embodiment this invention provides a novel copolymer of the above represented methacrylamidopropyltrimethylammonium methyl carbonate and acrylamide, which exhibits a high level clay flocculation efficiency.
Abstract: Greenbodies are produced by a RIM injection molding process wherein a homogeneous mixture of finely divided ceramic or metallic material and a polymerizable monomeric binder is injected into a mold and held at an elevated temperature for a sufficient time to polymerize the binder and form the greenbody. A preferred monomeric binder includes di- and tri-acrylate or -methacrylate esters of polyols. The low viscosity of the monomeric binder allows a loading of ceramic material of greater than 50 vol. % without adversely affecting the ability to injection mold the mixture.
Abstract: In one embodiment this invention provides a novel class of azomethine compounds which exhibit nonlinear optical response, such as 4-(4-dimethylaminobenzylideneamino)-4'-nitrostilbene: ##STR1##
Type:
Grant
Filed:
March 20, 1989
Date of Patent:
March 6, 1990
Assignee:
Hoechst Celanese Corporation
Inventors:
Ronald N. DeMartino, Hyun-Nam Yoon, James B. Stamatoff
Abstract: Ceramic alloys or solid solutions are formed by dispersing a powdery metal alloy or intimate mixture of two alloying metals in a precarbonaceous polymer such as polyacrylonitrile, forming the mixture into a molded article such as fibers, and heating the molded articles at a temperature and in a pyrolyzation atmosphere sufficient to carbonize the polymer and cause reaction of the metals with carbon and/or the pyrolyzation gas.
Abstract: This invention provides novel 4H-quinolizin-4-one compounds which exhibit a selective inhibitory activity against IgE-antibody formation, and have utility for treatment of diseases associated with IgE formation in mammals, such as allergic bronchial asthma, allergic rhinitis, atopic dermatitis, hypersensitiveness, and the like.
Abstract: Sodium diethyl oxalacetate is prepared in a specific manner by adding sodium ethoxide to a mixture of diethyl oxalate and ethyl acetate to obtain a free flowing sodium salt which is easily separable and purified.
Abstract: A thermoplastic molding composition comprising a polyester blend of polybutylene terephthalate and a copolyester derived from condensing ethylene glycol, cyclohexanedimethanol and terephthalic acid wherein the ethylene glycol units of the copolyester comprises at least 25 mole % based on the total glycol content. The polyester blend can also include an impact modifier. The blend is useful in the formation of molded keycaps.
Type:
Grant
Filed:
February 19, 1988
Date of Patent:
February 13, 1990
Assignee:
Hoechst Celanese Corporation
Inventors:
Arie A. Hochberg, Varkki P. Chacko, Paul DeStio
Abstract: This invention provides an optical medium which consists of an inorganic glass monolith with a microporous structure containing an organic component which exhibits nonlinear optical response.In one embodiment this invention provides a sol-gel process for producing a composite of a transparent homogeneous microporous inorganic oxide glass monolith and an organic compound which exhibits nonlinear optical response.
Type:
Grant
Filed:
October 24, 1988
Date of Patent:
February 6, 1990
Assignee:
Hoechst Celanese Corporation
Inventors:
Tessie M. Che, Dagobert E. Stuetz, Alan Buckley, Donald R. Ulrich
Abstract: This invention provides an optical medium which consists of a composite of a homogeneous inorganic oxide glass monolith with a microporous structure containing a liquid crystalline component. In one embodiment this invention provides a sol-gel process for producing a composite of a transparent homogeneous microporous inorganic oxide glass monolith and a liquid crystalline compound.
Type:
Grant
Filed:
August 24, 1988
Date of Patent:
February 6, 1990
Assignee:
Hoechst Celanese Corporation
Inventors:
Alan Buckley, Tessie M. Che, Thomas M. Leslie, James B. Stamatoff, Dagobert E. Stuetz, Donald R. Ulrich