Abstract: The disclosure herein relates to a novel process for producing tertiary 2-haloacetamides by reacting primary or secondary 2-haloacetamides with an agent capable of generating an anion of the primary or secondary 2-haloacetamide under base conditions and alkylating the anion of the 2-haloamide with an alkylating agent; said anion is generated, for example, by electrolysis or by metals, metal hydrides, fluorides, oxides, hydroxides, carbonates, phosphates, or alkoxides.
Abstract: This disclousure relates to regulating the growth of corn plants utilizing substituted-3-phenacylidene-phthalides. More particularly the present disclosure is concerned with a method of treating a corn plant with a substituted-3-phenacylidenephthalide or composition containing such a compound in order to effectively alter the development of the reproductive components of the corn plant.
Abstract: The invention relates to the safening of crop plants to the use of herbicides utilizing a substituted-1,2,3-thiadiazole or composition containing such compounds to reduce the herbicidal injury to treated crop plants. The invention is also concerned with novel compositions which comprise an acetanilide herbicide and a substituted-1,2,3-thiadiazole.
Abstract: This disclosure relates to novel ester derivatives of N-arylthio-N-phosphonomethylglycinonitrile which are useful as herbicides. This disclosure further relates to herbicidal compositions containing such N-phosphonomethylglycinonitriles and to herbicidal methods employing such compounds and compositions.
Abstract: 2-Chloro-4-trifluoromethyl-5-thiazolecarboxylic acids and derivatives thereof have been found to reduce herbicidal injury of sorghum plants due to the application thereto of 2-chloro-N-(2-methoxy-1-methylethyl)-6'-ethyl-o-acetotoluidide.
Abstract: A new class of compounds, prepared by reacting a salt of N-phosphonomethylglycine with a cyclic anhydride, have utility as post-emergent herbicides.
Abstract: This disclosure relates to N-(substituted carbonyl) triester derivatives of N-phosphinylmethylglycine wherein a substituted thiocarbonyl, RS(CO)--, a substituted sulfinylcarbonyl, ##STR1## or a substituted sulfonyl carbonyl, ##STR2## group is bonded to the nitrogen atom, to herbicidal compositions containing the same and to the herbicidal use thereof.
Abstract: Certain N-substituted ethylene derivatives of N-phosphonomethylglycine are novel compounds and display useful post-emergent herbicidal activity.
Abstract: This disclosure relates to a process for producing substituted benzoxaphospholes employing a directive metalation technique utilizing an organolithium compound. The substituted benzoxaphospholes produced are useful as herbicides.
Abstract: Compounds of the formula: ##STR1## where X is chloro, bromo, fluoro or iodo, have been found to be effective in reducing herbicidal injury to direct seeded rice plants caused by 2-chloro-2',6'-diethyl-N-(butoxymethyl)acetanilide herbicide.
Abstract: The invention relates to the safening of crop plants to the use of herbicides using a 5-aryl-4-isoxazolecarboxylate or composition containing such compounds to reduce the herbicidal injury to treated crop plants. The invention is also concerned with novel compositions which comprise an acetanilide herbicide and a 5-aryl-4-isoxazolecarboxylate.
Type:
Grant
Filed:
December 26, 1978
Date of Patent:
January 6, 1981
Assignee:
Monsanto Company
Inventors:
Lawrence H. Brannigan, John E. Franz, David E. Schafer
Abstract: The disclosure herein relates to herbicidal compositions containing 2'-carboalkoxy-6'-alkyl-2-haloacetanilides and method of use to selectively control undesired vegetation in agricultural crops, e.g., monocotyledons such as wheat, sorghum and rice and dicotyledons such as sugarbeets and soybeans.
Abstract: The invention relates to 2-(pyridylthio)pyridine-N-oxides and their use in reducing the herbicidal injury to sorghum due to the application thereto of various herbicides.
Abstract: This disclosure relates to ethanimidothioic acid ester hydrochlorides. More particularly, this disclosure relates to novel (.alpha.-diaryloxyphosphinylmethylamino) ethanimidothioic hydrocarbon ester hydrochlorides, herbicidal compositions containing such thioimidate hydrochlorides and the herbicidal use thereof.
Abstract: Derivatives of 2-imino-1,3-dithiolane, 1,3-dithiole, 1,3-dithiane, 1,3-dithietane and 1,3-oxathiole have been found to reduce herbicidal injury to crop plants due to thiocarbamate and acetanilide herbicides.
Abstract: This disclosure relates to N-phosphonomethylglycine derivatives wherein a benzoxycarbonyl group is attached to the nitrogen and alkoxy, alkenylthio, alkylthio, phenylalkylthio, phenylthio or substituted phenylthio groups are attached to the phosphorus atom and alkyl, chloroalkyl, alkoxyalkyl or alkoxyalkoxyalkyl groups are attached to the carboxyl group of the molecule. These compounds are useful as herbicides.
Abstract: A method and compositions for reducing injury to crops, especially wheat and sorghum, by thiolcarbamate herbicides employing compounds having in common the base structure ##STR1## wherein Y and Y' are oxygen or sulfur.
Abstract: 3-Aryl-isoxazol-5-yl benzoic acid and salts thereof are prepared by base treatment of 3'-(Aryl)-spiro[isobenzofuran-1(3H),5'(4'H)-isoxazol]-3-one.