Patents Represented by Attorney Ernest G. Szoke
  • Patent number: 5958862
    Abstract: Transport- and storage-stable paste-form detergents based on sodium hydroxide that are easily processed and handled are obtained by thickening concentrated aqueous sodium hydroxide preparations with glycols, glycol derivatives, alkanolamines, or alkanolamine derivatives. The detergents also can contain builders and other typical detergent composition ingredients.
    Type: Grant
    Filed: October 6, 1997
    Date of Patent: September 28, 1999
    Assignee: Henkel-Ecolab GmbH & Co. OHG
    Inventors: Dieter Hemm, Guenter Hellmann, Klaus Wilbert, Horst Pruehs
  • Patent number: 5958511
    Abstract: Defects in an initial protective coating, particularly a conversion coating, on a metal substrate can be touched up so as to at least equal the original coating in corrosion protection by use of a dry-in-place aqueous acidic liquid comprising:(A) fluorometallate anions;(B) divalent or tetravalent cations of elements selected from the group consisting of cobalt, magnesium, manganese, zinc, nickel, tin, copper, zirconium, iron, and strontium;(C) a component selected from the group consisting of phosphorus-containing inorganic oxyanions and phosphonate anions; and(D) a component of water-soluble and/or -dispersible organic polymers and/or polymer-forming resins.
    Type: Grant
    Filed: April 18, 1997
    Date of Patent: September 28, 1999
    Assignee: Henkel Corporation
    Inventor: Shawn E. Dolan
  • Patent number: 5955567
    Abstract: Cross-linked cationic polymers are prepared by alkylating a polyaminoalide with 5 to 30 mole percent, relative to the amount of nitrogen available for alkylation, of a quaternary ammonium alkylating agent and cross-linking the resulting alkylated polyaninoamide with a molar amount of epichlorohydrin corresponding to the non-quaternized nitrogen content. The cross-linked cationic polymers are suitable for use as wet-strength resins in the treatment of paper.
    Type: Grant
    Filed: January 8, 1998
    Date of Patent: September 21, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Joaquim Bigorra Llosas, Rafael Pi Subirana
  • Patent number: 5954024
    Abstract: This invention relates to a method applied in combustion engines having two spark plugs in each combustion chamber for controlling ignition and ionization current measurements, one of the spark plugs acting as a sensor for the ionization current measurements. The ignition voltage supplied to each of the spark plugs in a chamber is controlled such that the spark duration of the spark plug acting as the sensor is less than 50% of the other spark plug in the chamber.
    Type: Grant
    Filed: February 19, 1998
    Date of Patent: September 21, 1999
    Assignee: Henkel Corporation
    Inventors: Joel Duhr, Anders J Goras
  • Patent number: 5955587
    Abstract: A process for producing alkyl oligoglucosides having a high degree of polymerization involving: (a) providing a fatty alcohol; (b) providing a glucose component; (c) mixing the fatty alcohol and glucose component; (d) acetylizing the reaction mixture by adding an acid catalyst to the mixture; (e) continuously distilling off water from the reaction mixture during acetylization; (f) neutralizing the acid catalyst upon completion of acetylization; (g) removing unreacted fatty alcohol from the reaction mixture; (h) post-polymerizing the reaction mixture to form a final alkyl oligoglucoside product; and (i) neutralizing any remaining acid catalyst and removing any unreacted fatty alcohol from the reaction mixture.
    Type: Grant
    Filed: November 20, 1997
    Date of Patent: September 21, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventor: Manfred Weuthen
  • Patent number: 5952287
    Abstract: A terpene-free hard surface cleaning composition containing: (a) a nonionic surfactant; (b) an anionic surfactant; (c) a primary solvent consisting of a C.sub.6 -C.sub.14 methyl ester; (d) a short-chain cosurfactant; and (e) water, all weights being based on the total weight of the composition.
    Type: Grant
    Filed: October 20, 1997
    Date of Patent: September 14, 1999
    Assignee: Henkel Corporation
    Inventors: Stephen F. Gross, Martin J. Barabash, J. Frederick Hessel
  • Patent number: 5952279
    Abstract: Surfactant mixtures providing improved dermal compatibility and foam stability contain(a) monoglyceride sulfates or monoglyceride ether sulfates, and(b) sugar surfactants selected from(b1) sucrose esters,(b2) sorbitan esters, and(b3) polysorbates, with the proviso that the ratio by weight of component (a) to component (b) is 75:25 to 50:50.
    Type: Grant
    Filed: March 7, 1997
    Date of Patent: September 14, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Bernd Fabry, Ansgar Behler
  • Patent number: 5948880
    Abstract: A process is provided for preparing a dispersion of a polyamide in water, said process comprising:forming a solution of a polyamide having an acid value of greater than about 2 in an organic solvent to form a solution of said polyamide in said solvent, said polyamide and said solvent being at a temperature below the softening point of said polyamide during said dissolving, said solution further comprising a surfactant, wherein at least a portion of the acid value of said polyamide is neutralized,adding sufficient water to said solution with mixing to form an oil-in-water dispersion, the temperature of said solution and said water being below the softening point of said polyamide during said adding, andremoving at least a major amount of said organic solvent from said oil-in-water dispersion. The resulting dispersion is useful in preparing a coating of the polyamide, which coating is useful as an adhesive.
    Type: Grant
    Filed: May 8, 1997
    Date of Patent: September 7, 1999
    Assignee: Henkel Corporation
    Inventors: Stephen A. Fischer, Chase J. Boudreaux, Michael S. Wiggins
  • Patent number: 5948747
    Abstract: A spray-dried particulate detergent composition containinga) 3% to 20% by weight of anionic surfactant,b) 0 to 2% by weight of nonionic surfactant,c) 20% to 65% by weight of inorganic builders, based on water-free active substance, selected from carbonates, hydrogen carbonates and silicate-based builders, andd) 0 to 25% by weight of neutral salts, based on the weight of the spray-dried composition, wherein the spray-dried composition has been aftertreated with nonionic surfactant. The composition has favorable dispensing and solubility properties.
    Type: Grant
    Filed: August 11, 1997
    Date of Patent: September 7, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Fred Schambil, Wolfram Linke, Hubert Freese
  • Patent number: 5944908
    Abstract: Residue that accumulates on metallic molding surfaces during repeated molding of plastics such as PVC can be removed by cleaning with an aqueous solution of a glycol or oligo-glycol monoether, an amine, and a chelating agent. The cleaner is sufficiently effective to replace mechanical blasting that was previously required.
    Type: Grant
    Filed: October 10, 1996
    Date of Patent: August 31, 1999
    Assignee: Henkel Corporation
    Inventors: Chester P. Jarema, Michael A. Stuart
  • Patent number: 5945299
    Abstract: Wheat protein hydrolyzates are produced by hydrolyzing a wheat protein-containing starting material, preferably a wheat protein isolate having a protein content of 70 to 90%, with a proteinase such as a serine protease at a pH of 2 to 5, then with a proteinase at a pH of 8 to 10 and finally with a peptidase at a pH of 6 to 7. The hydrolysis steps are preferably at a temperature below the gelatinization temperature of carbohydrate present in the protein. Each hydrolysis may be carried out for 1 to 24 hours at a temperature of 40 to 70.degree. C. To reduce traces of unwanted color formers, an adsorbent such as silica gel, aluminum oxide or activated carbon may be present during the hydrolysis steps. Aqueous wheat protein hydrolyzate solutions are obtained and, if required, may be concentrated, for example using falling film evaporators. The hydrolyzates have an average molecular weight in the range of 100 to 30,000, preferably 2,000 to 5,000, and a solids content of around 5 to 50%.
    Type: Grant
    Filed: October 6, 1997
    Date of Patent: August 31, 1999
    Assignee: Henkel Kommanditgesellschaft Auf Aktien (KGaA)
    Inventors: Edith von Kries, Andrea Heilemann, Andreas Sander
  • Patent number: 5939372
    Abstract: Detergent mixtures containing fatty alcohol sulfates, fatty alcohol ether sulfates, alkyl and/or alkenyl oligoglycosides and/or fatty acid N-alkyl polyhydroxyalkyl amides are eminently suitable in solid form for the production of toilet blocks.
    Type: Grant
    Filed: May 28, 1996
    Date of Patent: August 17, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Karl Schmid, Andreas Syldath, Ditmar Kischkel, Volker Bauer, Wolfgang Schmidt, Anke Grosser
  • Patent number: 5935656
    Abstract: A process for sealing anodized metal surfaces is characterized by bringing the anodized metal into contact with an aqueous solution at a temperature from 75.degree. C. to the boiling point of the solution for a time equal to from 0.5 to 2 minutes per micrometer of anodized layer thickness. The solution contains: a) from 0.0001 to 5 g/l of one or more alkali metal and/or alkaline earth metal ions and b) from 0.0005 to 0.5 g/l of one or more organic acids selected from: polycarboxylic acids with from 3 to 6 carboxyl groups; phosphonic acids; and/or polyphosphinocarboxylic acids, the solution containing a greater amount of metal ions of group a) than is needed to insure complete neutralization of the acids of group b).
    Type: Grant
    Filed: April 20, 1998
    Date of Patent: August 10, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Torsten Koerner, Josef Kresse, Wolf-Achim Roland, Juergen Lindener
  • Patent number: 5935920
    Abstract: Powdered, paste, or liquid media for cleaning and/or degreasing hard surfaces, especially surfaces of organic polymers (PVC) contain active ingredients of amino acids, carboxylic acids, and nonionic surfactants, possibly supplemented by action-reinforcing auxiliaries and/or demulsifying additives. Processes using these media are also claimed.
    Type: Grant
    Filed: January 22, 1996
    Date of Patent: August 10, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Juergen Geke, Friedbert Zetzsche
  • Patent number: 5936129
    Abstract: A process for making a sterically-hindered beta-diketone involving: (a) providing a solution comprising: (i) an ester; (ii) a base; and (iii) a solvent; (b) adding a ketone selected from the group consisting of an aromatic ketone and a hindered aliphatic ketone, to the solution, to form a condensation reaction mixture, whereby either the ester or the ketone is hindered; (c) reacting the solution with the ketone to form a sterically-hindered beta-diketone; and (d) recovering the sterically-hindered beta-diketone from the condensation reaction mixture.
    Type: Grant
    Filed: January 22, 1998
    Date of Patent: August 10, 1999
    Assignee: Henkel Corporation
    Inventors: Kevin V. Martin, Phillip L. Mattison, Michael J. Virnig
  • Patent number: 5935348
    Abstract: Aqueous acid treatment solution for the treatment of beverage cans, in particular of aluminum, for producing a corrosion-protective, friction-reducing coating which improves the ability to be enameled, which comprises 0.14 to 2.25 mmol/l of an alkylamine oxide or an alkylammonium salt with an alkyl radical having 8 to 22 C atoms, 0.25-1.5 mmol/l of hydroxycarboxylic acids having 4-7 C atoms, complex fluorides and mineral acids, and preferably tannin.
    Type: Grant
    Filed: May 23, 1997
    Date of Patent: August 10, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventor: Henry Rossmaier
  • Patent number: 5935655
    Abstract: A combination of (A) a nitrogen containing water soluble polymer, (B) a water insoluble film forming polymer, and (C) gas filled, polymer walled microballoons provides a superior thermally releasable coating that (i) can be conveniently and reliably coated from a water based solution and dispersion onto surfaces to be protected against painting, (ii) is reliably stable at ambient temperatures, (iii) even after being coated with many times its own thickness of accumulated paint particles, rapidly disintegrates, along with the accumulated paint coating formed on it, upon contact with hot water, into particles of a size that readily escapes from standard paint booth grate structures, (iv) detackifies any paint particles that escape during distintegration of the combined thermally releasable coating and paint residues accumulated thereon, and (v) disintegrates into particles that float on water, so that they can be readily removed from the grates by immersing the latter in hot water, allowing a few minutes for th
    Type: Grant
    Filed: January 26, 1996
    Date of Patent: August 10, 1999
    Assignee: Henkel Corporation
    Inventor: Scott J. Beleck
  • Patent number: 5932680
    Abstract: The hot-melt adhesive of the invention includesA) at least one polyurethane prepolymer ofa) at least one polyisocyanate, in particular, toluene diisocyanate and/or MDI,b) at least one polyalkylene glycol at a concentration of more than 10% by weight based on total hot-melt adhesive, in particular, polypropylene glycol,c) at least one polyester glycol, preferably of at least two polyester glycols having different glass transition temperature, andB) optional additives such asd) a resin, particularly a hydrocarbon resin, ande) a stabilizer, particularly toluenesulfonyl isocyanate.Preferably, the hot-melt adhesive has a melt viscosity ranging from 10 to 300 Pa.s at 130.degree. C. The PU pre-polymer has only one single Tg in the DSC diagram. The hot-melt adhesive is notable for its high creep resistance with similarly high initial and final strength.
    Type: Grant
    Filed: October 30, 1996
    Date of Patent: August 3, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventor: Roland Heider
  • Patent number: 5932020
    Abstract: An aqueous liquid composition containing dihydrogen phosphate salt, sulfur containing surfactant, and preferably a small amount of phosphoric acid cleans soiled metal surfaces without damaging any plastic parts that come into contact with the composition with the composition and without supporting the growth of bacteria that cause unpleasant odors. The composition is particularly useful for cleaning unpainted aluminum sided rail transport cars that have polycarbonate housings insulating electrical contact points that provide motive electric power to the cars; many conventional aqueous alkaline and acid cleaners promote stress cracking of polycarbonate plastics.
    Type: Grant
    Filed: April 8, 1997
    Date of Patent: August 3, 1999
    Assignee: Henkel Corporation
    Inventor: Donald P. Murphy
  • Patent number: 5932629
    Abstract: An aqueous printing ink composition containing finely dispersed pigments and a synthetic polymer binder, the binder containing: (a) finely dispersed, aqueous-basic insoluble emulsion (co)polymers having a number average molecular weight of from about 10,000 to 1,000,000 and a glass transition temperature of up to 0.degree. C., in intimate admixture with (b) aqueous-basic soluble or dispersible (co) polymers having a number average molecular weight lower than that of the (co)polymers of component (a) and a glass transition temperature of at least 0.degree. C.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: August 3, 1999
    Assignees: Henkel Kommanditgesellschaft auf Aktien, Hartmann Druckfarben, GmbH
    Inventors: Michael Beck, Herbert Fischer, Wolfgang Ritter, Ludwig Schieferstein, Udo Griebsch, Quang-Minh Thai