Patents Represented by Attorney Frederick D. Hunter
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Patent number: 5000034Abstract: A short-term test procedure for comparing the engine sludge performance of different engine oils to a reference oil. The test procedure involves establishing a base line by operating one or more engines on the reference oil while maintaining a substantially constant volume of the reference oil in the engines without changing the oil until a Coordinating Research Council (CRC) sludge rating within a preferred range of 8.5 to 9.0 is achieved. In like manner, a series of engine tests are performed on one or more test oils using engines substantially identical to the reference oil engines for substantially the same number of miles as the average test miles of all of the reference oil engines under substantially the same test conditions as the reference oil engines while maintaining substantially the same volume of the test oil in the engines as the reference oil without changing the test oil in the engines throughout the tests.Type: GrantFiled: May 15, 1990Date of Patent: March 19, 1991Assignee: The Lubrizol CorporationInventors: Scot E. Jaynes, Kirk E. Davis
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Patent number: 4997969Abstract: Compounds which improve extreme pressure and anti-wear properties of lubricating compositions are described. The compounds include the compounds of the following formula as well as statistical mixtures of those compounds: ##STR1## wherein R.sub.1 is hydrogen or hydrocarbyl; R.sub.2 is hydrocarbyl having at least 4 carbon atoms or together with R.sub.1 forms a heterocyclic radical,wherein R.sub.3, R.sub.4, R.sub.7 and R.sub.8 are each independently hydrogen or alkyl;wherein a is 0 or 1;wherein n is 1, 2 or 3;wherein X is oxygen or sulfur;wherein R.sub.5 is hydrogen or hydrocarbyl; andwhen n is 1, R.sub.6 is selected from the group consisting of ##STR2## and when n is 2, R.sub.6 is selected from the group consisting of ##STR3## and when n is 3, R.sub.6 is ##STR4## wherein R is independently an alkyl moiety, alkylene or alkylidene moiety containing 1 to 12 carbon atoms, R' is hydrogen or alkyl moiety, alkylene, alkylidene or carboxyl containing 1 to 60 carbon atoms, and R" is aryl or substituted aryl.Type: GrantFiled: December 12, 1988Date of Patent: March 5, 1991Assignee: The Lubrizol CorporationInventor: Carmen V. Luciani
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Patent number: 4997594Abstract: Succinimide derivatives represented by the formula: ##STR1## wherein X is selected from the group consisting of M, ##STR2## wherein R is a hydrocarbon-based group containing from about 8 up to about 35 carbon atoms, R.sub.1 and R.sub.2 are each independently hydrogen or an alkyl group containing up to 8 carbon atoms; R.sub.4 is a hydrocarbon-based group containing up to about 28 carbon atoms; R.sub.4 and R.sub.5 are each independently hydrogen or a hydrocarbon-based group containing up to about 25 carbon atoms; and M is a metal cation.Type: GrantFiled: January 23, 1990Date of Patent: March 5, 1991Assignee: The Lubrizol CorporationInventor: Reed H. Walsh
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Patent number: 4997968Abstract: A method of preparing an oil-soluble composition is disclosed. The method comprises preparing a dihydrocarbyl monothiophosphoric acid characterized by the formula ##STR1## wherein R.sub.1 and R.sub.2 are each independently hydrocarbyl groups of from 1 to about 30 carbon atoms and X is oxygen or sulfur, with the proviso that one X is sulfur comprising reacting(A) a phosphite ester of the structure ##STR2## with (B) a sulfur source, in the presence of(C) a catalytic amount of an amide of the structure R.sub.3 CONR.sub.4 R.sub.5 wherein R.sub.3, R.sub.4 and R.sub.5 are each independently hydrogen or a hydrocarbyl group containing from 1 to about 30 carbon atoms or an ethoxylated amide of the structure ##STR3## wherein the sum of x and y is from 1 to about 50; and isolating the reaction product obtained.Type: GrantFiled: September 28, 1989Date of Patent: March 5, 1991Assignee: The Lubrizol CorporationInventors: Louis Burjes, Alan C. Clark
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Patent number: 4992188Abstract: This invention relates to a composition comprising:(A) a major amount of a fluorine-containing hydrocarbon containing one or two carbon atoms; and(B) a minor amount of a soluble tertiary amide represented by the formula ##STR1## wherein a is one or two, provided that when a is one, R is a hydrocarbyl group or a hydrocarbylpolyoxyalkylene group, and when a is two, R is a hydrocarbylene group;each R.sub.2 is independently hydrogen or an alkyl group having from 1 to about 8 carbon atoms;b is one or two;X is oxygen or N--R.sub.3 ;R.sub.3 is a hydrocarbyl group having 1 to about 18 carbon atoms or --C(O)R.sub.4,R.sub.4 is a hydrocarbyl group or a hydrocarbylpolyoxyalkylene alkyl group.The present invention provides compositions which are useful as refrigeration liquids in refrigerators and air-conditioners including auto, home and industrial air-conditioners. The invention provides tertiary amides which are compatible with fluorine-containing hydrocarbons used in refrigerators and air conditioners.Type: GrantFiled: March 30, 1990Date of Patent: February 12, 1991Assignee: The Lubrizol CorporationInventor: Scott T. Jolley
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Patent number: 4981602Abstract: Lubricating oil compositions for internal combustion engines are described which comprise (A) a major amount of oil of lubricating viscosity, and minor amounts of (B) at least one carboxylic derivative composition produced by reacting (B-1) at least one substituted succinic acylating agent with (B-2) from about 0.70 equivalent up to less than one equivalent, per equivalent of acylating agent, of at least one amine compound characterized by the presence within its structure of at least one HN< group, said acylating agents being characterized by the presence within their structure of an average of at least 1.Type: GrantFiled: June 13, 1988Date of Patent: January 1, 1991Assignee: The Lubrizol CorporationInventors: David E. Ripple, Calvin W. Schroeck
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Patent number: 4976881Abstract: Coupled polyamine additives for lubricants, fuels and functional fluids have been discovered. The coupled polyamines are prepared by the cyclization reaction of at least one reactant polyamine reactant with at least one hydrocarbyl polynitrile. This coupled polyamine may be further reacted with a hydrocarbyl carboxylic acid or derivative thereof, a hydrocarbyl phenolic reactant or mixtures thereof to provide an additive having greater oil solubility as well as imparting dispersancy and VI improvement.Type: GrantFiled: August 30, 1989Date of Patent: December 11, 1990Assignee: The Lubrizol CorporationInventor: Paul E. Adams
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Patent number: 4973789Abstract: A process for preparing a lower alkene polymer from a lower alkene feedstream, including the steps of: (A) contacting the lower alkene monomer with a catalyst system comprising boron trifluoride and at least one acid selected from the group consisting of sulfuric acid, sulfurous acid, phosphoric acids and strong acid resins and (B) polymerizing the lower alkene monomer in the presence of the catalyst system at a temperature of about -3.degree. C. to about -30.degree. C. thereby obtaining a lower alkene polymer having a molecular weight of about 250 to about 500.Type: GrantFiled: July 30, 1987Date of Patent: November 27, 1990Assignee: The Lubrizol CorporationInventors: Jack L. Karn, Willis P. Nichols
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Patent number: 4968853Abstract: This invention deals with viscosity improvers which are obtained through the use of a mixed catalyst system comprising a tertiary organo halide and a Lewis acid catalyst. A liquid alpha-olefin polymer composition having a polymodal distribution with peak molecular weight maximum at 2,000 to 5,000 and at 50,000 to 75,000 is useful as a lubricating oil.Type: GrantFiled: December 29, 1987Date of Patent: November 6, 1990Assignee: The Lubrizol CorporationInventor: Curtis R. Scharf
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Patent number: 4963282Abstract: A liquid composition is described which comprises(A) a major amount of at least one fluorine containing hydrocarbon containing one or two carbon atoms; and(B) a minor amount of at least one soluble organic lubricant comprising at least one organic thiocarbamate characterized by the formulaeR.sub.1 R.sub.2 NC(X)SC(R.sub.3 R.sub.4)[C(H)(R.sub.5)].sub.a Z, or (I)[R.sub.1 R.sub.2 NC(X)SC(R.sub.3 R.sub.4)[C(H)(R.sub.5)].sub.a C(X)A].sub.2 Z' (II)wherein R.sub.1 and R.sub.2 are each independently lower alkyl, aryl, aralkyl or together form a heterocyclic group in which the ring is completed through the nitrogen;X is O or S;A is O, S or NR;R is H or a lower alkyl group;R.sub.3, R.sub.4 and R.sub.5 are each independently H, lower alkyl or aryl groups;a is 0 or 1;Z is --CN, --S(O)R.sub.6, --S(O)OR.sub.6, --S(O).sub.2 R.sub.6, --S(O).sub.2 OR.sub.6, or --C(O)Y;R.sub.6 is H, alkyl or aralkyl;Y is H, --OH, --R.sub.7, --OR.sub.7, --OR.sub.8 OH, or --NR.sub.9 R.sub.10 ;R.sub.7 is an alkyl, aryl or aralkyl group;R.sub.Type: GrantFiled: May 11, 1989Date of Patent: October 16, 1990Assignee: The Lubrizol CorporationInventors: Scott T. Jolley, Betsy J. Butke
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Patent number: 4960761Abstract: Polymers of pyrrole or copolymers of pyrrole are obtained having high surface area and low conductivity. Such polymers and copolymers are useful in forming catalysts.Type: GrantFiled: November 28, 1988Date of Patent: October 2, 1990Assignee: The Lubrizol CorporationInventor: Richard Yodice
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Patent number: 4959168Abstract: Sulfurized mixtures which include (A) at least one partial fatty acid ester of a polyhydric alcohol, and (B) at least one member of the group consisting of(1) at least one fatty acid ester of a polyhydric alcohol, which fatty acid ester is different from the partial ester (A),(2) at least one fatty acid,(3) at least one olefin, and(4) at least one fatty acid ester of a monohydric alcohol. The sulfurized compositions are useful in preparing additive concentrates and lubricating compositions.Type: GrantFiled: January 15, 1988Date of Patent: September 25, 1990Assignee: The Lubrizol CorporationInventor: Calvin W. Schroeck
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Patent number: 4957649Abstract: Lubricating oil compositions for internal combustion engines are described with comprise (A) a major amount of oil of lubricating viscosity, and minor amounts of (B) at least one carboxylic derivative composition produced by reacting (B-1) at least one substituted succinic acylating agent with (B-2) at least one amine compound characterized by the present within its structure of at least one HN< group (C) at least one partial fatty acid ester of a polyhydric alcohol, and (D) at least one metal salt of a dihydrocarbyl dithiosphosphoric acid. The oil compositions also may contain (E) at least one carboxylic ester derivative composition, and/or (F) at least one neutral or basic alkaline earth metal salt of at least one acidic organic compound.Type: GrantFiled: August 1, 1988Date of Patent: September 18, 1990Assignee: The Lubrizol CorporationInventors: David E. Ripple, William B. Chamberlin, III
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Patent number: 4957648Abstract: A spin fiber lubricant composition is disclosed. The composition is essentially comprised of a liquid carrier having therein an ester of the general structural formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are hydrocarbyl groups preferably in the form of alkyl groups containing 1-6 carbon atoms. The composition has been found to be useful in connection with providing materials with lubricating properties which are desirable for the spinning of fibers.Type: GrantFiled: February 7, 1990Date of Patent: September 18, 1990Assignee: The Lubrizol CorporationInventors: Richard Yodice, Gregory A. Lentz
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Patent number: 4957651Abstract: Mixtures of partial fatty acid esters of polyhydric alcohols and sulfurized compositions. Compositions comprising these mixtures are useful as additives for a wide variety of lubricants.Type: GrantFiled: January 15, 1988Date of Patent: September 18, 1990Assignee: The Lubrizol CorporationInventor: James J. Schwind
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Patent number: 4954273Abstract: Oil based compositions including crank case oils and in particular diesel engine crank case oils are disclosed which are comprised of oil having a multi-functional additive component therein. The additive component is present in sufficient amounts so as to provide improved performance characteristics to the composition such as pH stability, water tolerance and antiwear characteristics. The additive is an overbased salt of a compound represented by the general structural formula (I): ##STR1## wherein R is a hydrocarbyl, preferably iso-stearyl, R.sub.1, R.sub.2, and R.sub.3 are independently hydrogen or aklyl, preferably hydrogen and n is 1 to 20, preferably 1 to 5. Statistical mixtures and mixed salts of the additive compound are also disclosed as are fully formulated oils. The additive is an effective pH stabilizer, EP agent, and water tolerance fix in a variety of functional fluids and lubricating compositions such as crank case oils, particularly diesel engine crank case oils.Type: GrantFiled: October 27, 1988Date of Patent: September 4, 1990Assignee: The Lubrizol CorporationInventors: Richard A. Denis, Frederick W. Koch
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Patent number: 4952328Abstract: A lubricating oil formulation is described which is useful in internal combustion engines. More particularly, lubricating oil compositions for internal combustion engines are described with comprises (A) at least about 60% by weight of oil of lubricating viscosity, (B) at least about 2.0% by weight of at least one carboxylic derivative composition produced by reacting (B-1) at least one substituted succinic acylating agent with (B-2) from about 0.70 equivalent up to less than one equivalent, per equivalent of acylating agent, of at least one amine compound characterized by the presence within its structure of at least one HN< group, and wherein said substituted succinic acylating agent consists of substituent groups and succinic groups wherein the substituent groups are derived from a polyalkene, said polyalkene being characterized by an Mn value of abotu 1300 to about 5000 and an Mw/Mn value of about 1.5 to about 4.Type: GrantFiled: June 3, 1988Date of Patent: August 28, 1990Assignee: The Lubrizol CorporationInventors: Kirk E. Davis, Calvin W. Schroeck
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Patent number: 4943303Abstract: A cetane improver for diesel fuels is a sulfur containing compound having at least one electron withdrawing group therein. The electron withdrawing group desirably is a carbonyl group.Type: GrantFiled: November 25, 1985Date of Patent: July 24, 1990Assignee: The Lubrizol CorporationInventor: Joseph W. Pialet
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Patent number: 4941984Abstract: A lubricating oil composition is described which is useful in spark-ignited engines which may be fueled with gasoline, alcohol, or mixtures of both. More particularly, lubricating oil compositions for spark-ignited engines are described which comprise (A) an oil of lubricating viscosity; (B) at least one detergent selected from the group consisting of a basic magnesium salt of an organic acid or a mixture of at least one basic magnesium salt of an organic acid and another alkaline earth metal salt of an organic acid wherein the metal in the mixture is predominantly magnesium; and (C) at least one metal salt of (C-1) a substituted succinic acid acylated polyamine; or (C-2) a hydrocarbon-substituted aromatic carboxylic acid containing at least one hydroxyl group attached to an aromatic ring, provided that the metal of said metal salt (C) is not calcium or magnesium.Type: GrantFiled: July 31, 1989Date of Patent: July 17, 1990Assignee: The Lubrizol CorporationInventors: William B. Chamberlin, III, Frank V. Zalar
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Patent number: 4941986Abstract: A liquid composition is described which comprises(A) a major amount of at least one fluorine containing hydrocarbon containing one or two carbon atoms; and(B) a minor amount of a soluble organic lubricant comprising at least one organic nitro compound characterized by the formulaeR.sub.z N(H).sub.x [CH.sub.2 C(R.sup.1)(R.sup.2)NO.sub.2 ].sub.y (I)andCH.sub.2 [N(R)CH.sub.2 C(R.sup.1)(R.sup.2)NO.sub.2 ].sub.2 (II)whereinR is a hydrocarbyl group, a polyaminoalkyl group, or R.sup.4 XR.sup.5 - wherein R.sup.4 is H, hydrocarbyl, hydroxyalkyl or aminoalkyl, X is O or NR.sup.6, wherein R.sup.6 is H or a nitroalkyl group, and R.sup.5 is an alkylene group, or R.sup.4 X is a morpholinyl group attached to R.sup.5 through the nitrogen atom; andR.sup.1 and R.sup.2 are each independently H or lower aliphatic groups;x is 0 or 1;y is 1 or 2; andz is 1 or 2, provided that the sum of x, y and z is 3.Type: GrantFiled: March 16, 1989Date of Patent: July 17, 1990Assignee: The Lubrizol CorporationInventor: Scott T. Jolly