Abstract: Alkali metal salt of meso-2,3-bis(benzylamino)succinic acid, phosgene, and alkali metal hydroxide are reacted under alkaline conditions and in the presence of water and anisole in a multi-phase system to form a multi-phase mixture comprising: (1) a liquid aqueous phase having a pH of at least about 7.5 and comprising an aqueous solution of alkali metal salt of 2-oxo-1,3-dibenzyl-4,5-cis-imidazolidinedicarboxylic acid, and (2) a liquid organic phase. The aqueous solution is acidified to precipitate 2-oxo-1,3-dibenzyl-4,5-cis-imidazolidinedicarboxylic acid.
Abstract: Benzene or a chlorinated benzene feedstock compound represented by the formula C.sub.6 H.sub.6-x Cl.sub.x is chlorinated in the rectifying zone of a catalytic distillation reactor to produce a chlorinated benzene product compound represented by the formula C.sub.6 H.sub.5-x Cl.sub.x+1, where x is an integer in the range of from 0 to 5.
Abstract: Disclosed is a process for preparing surface modified silica sorption agent suitable for purifying contaminated aqueous liquid, the sorption agent comprising amorphous, precipitated, silica having surface deposited thereon an organic quaternary ammonium compound.
Type:
Grant
Filed:
May 9, 1991
Date of Patent:
August 11, 1992
Assignee:
PPG Industries, Inc.
Inventors:
Frederick F. Guzik, Suresh B. Damle, William W. Carlin
Abstract: The water resistance of intumescent compositions is improved if the composition comprises at least one organotin derivative of a polyol. Organotin derivatives of polyols can be produced by reacting polyol with dialkyltin oxide or with dialkyltin dialkoxide.
Type:
Grant
Filed:
November 7, 1991
Date of Patent:
July 14, 1992
Assignee:
PPG Industries, Inc.
Inventors:
Seetha Eswarakrishnan, Carol L. Knox, Suresh B. Damle
Abstract: An abrasive article comprises abrasive particles bonded to microporous material wherein the microporous material comprises (a) a matrix consisting essentially of thermoplastic organic polymer, (b) a large proportion of finely divided water-insoluble siliceous filler, and (c) a large void volume.
Type:
Grant
Filed:
October 29, 1990
Date of Patent:
May 19, 1992
Assignee:
PPG Industries, Inc.
Inventors:
Dennis D. Leatherman, James J. McGinley, Daniel E. Adams, George A. Brons
Abstract: The water leaching of ammonium polyphosphate from compositions comprising organic polymer and particles of ammonium polyphosphate is reduced if the ammonium polyphosphate is surface-modified with copolymer of vinylpyrrolidone and comonomer selected from the group consisting of .alpha.-olefin containing from about 4 to about 50 carbon atoms, styrene, styrene substituted on the ring with at least one alkyl group containing from 1 to about 12 carbon atoms, and mixtures thereof.
Type:
Grant
Filed:
June 15, 1990
Date of Patent:
April 28, 1992
Assignee:
PPG Industries, Inc.
Inventors:
Paritosh M. Chakrabarti, Kenneth J. Sienkowski
Abstract: Diethanolamine and triglyceride are reacted to produce a reaction mixture comprising diethanol amide of monocarboxylic acid and hydroxy-functional glyceride. The reaction mixture is useful as an antistatic composition for formulating with polymers, especially polyolefins.
Type:
Grant
Filed:
March 23, 1990
Date of Patent:
March 24, 1992
Assignee:
PPG Industries, Inc.
Inventors:
Kenneth J. Sienkowski, Paritosh M. Chakrabarti
Abstract: Reinforced precipitated silica having, on a coating-free and impregnant-free basis, a surface area of from about 220 to about 340 square meters per gram, a pore diameter at the maximum of the volume pore size distribution function of from about 9 to about 20 nanometers, and a total intruded volume of from about 2.6 to about 4.4 cubic centimeters per gram, is produced by a process wherein precipitated silica is heavily reinforced using a multiplicity of precipitation and aging steps.
Type:
Grant
Filed:
June 21, 1990
Date of Patent:
March 10, 1992
Assignee:
PPG Industries, Inc.
Inventors:
Thomas G. Krivak, Timothy A. Okel, Melvin P. Wagner
Abstract: As zeolite L is used as catalyst for the chlorination of benzene, chlorobenzene, ortho-dichlorobenzene, and/or meta-dichlorobenzene, its catalytic activity diminishes. Zeolite L which has been used for such chlorinations may be reactivated by contact with steam.
Abstract: The water leaching of ammonium polyphosphate from compositions comprising organic polymer and particles of ammonium polyphosphate is reduced if the ammonium polyphosphate is surface-modified with quaternary ammonium salt cationic surfactant.
Type:
Grant
Filed:
October 30, 1990
Date of Patent:
December 10, 1991
Assignee:
PPG Industries, Inc.
Inventors:
Paritosh M. Chakrabarti, Kenneth J. Sienkowski
Abstract: An active agent delivery device comprises (a) microporous material comprising a matrix consisting essentially of linear ultrahigh molecular weight polyolefin, a large proportion of finely divided water-insoluble filler of which at least about 50 percent by weight is siliceous, and interconnecting pores; and (b) a releasable active agent or precursor thereof associated with at least a portion of the filler.
Abstract: Disclosed are compositions useful as surface coatings for nonwoven substrates which compositions are reaction products of a melamine formaldehyde compound, long chain saturated alcohols and long chain saturated or unsaturated polyethoxylated alcohols. The invention compositions when used to surface size paper impart oil, water and polar solvent resistance thereto. The compositions may be used alone or as substantial replacements for anionic or non-ionic fluorocarbon based surface sizes that are typically used to impart oil resistance to paper.
Type:
Grant
Filed:
November 14, 1988
Date of Patent:
October 22, 1991
Assignee:
PPG Industries, Inc.
Inventors:
William W. Carlin, Sai H. Hui, John D. Mansell
Abstract: One stereoisomer of 1,2-dichloroethene is isomerized to the other stereoisomer in the liquid phase and in the presence of free radical initiator.
Type:
Grant
Filed:
November 13, 1989
Date of Patent:
September 24, 1991
Assignee:
PPG Industries, Inc.
Inventors:
Earl M. Gorton, John D. Driskill, Randall M. Hall
Abstract: Microporous material comprising (1) a matrix consisting essentially of thermoplastic organic polymer, (2) a large proportion of finely divided water-insoluble siliceous filler, and (3) interconnecting pores is coated with electrically conductive coating and/or printed with electrically conductive printing ink. The resulting products have many uses as electrically conductive articles, including electromagnetic interference shields and printed circuit boards. Three-dimensional printed circuit boards are disclosed.
Type:
Grant
Filed:
September 20, 1989
Date of Patent:
September 10, 1991
Assignee:
PPG Industries, Inc.
Inventors:
Dennis D. Leatherman, Kee V. Sin, James A. Russell
Abstract: An active agent delivery device comprises (a) microporous material comprising a matrix consisting essentially of linear ultrahigh molecular weight polyolefin, a large proportion of finely divided water-insoluble filler of which at least about 50 percent by weight is siliceous, and interconnecting pores; and (b) a releasable active agent or precursor thereof associated with at least a portion of the filler.
Type:
Grant
Filed:
May 10, 1990
Date of Patent:
July 30, 1991
Assignee:
PPG Industries, Inc.
Inventors:
Paritosh M. Chakrabarti, Harlan B. Johnson, Malcolm Korach, Dennis D. Leatherman, Robert R. Simmons
Abstract: A coated article comprises a substantially continuous, moisture vapor permeable coating of hydrophobic polymer joined to one side of a sheet of microporous material comprises a matrix consisting essentially of linear ultrahigh molecular weight polyolefin, a large proportion of finely divided, water-insoluble siliceous filler, and interconnecting pores.
Abstract: Disclosed are cationic aqueous emulsions containing (a) sizing composition comprising the reaction product of melamine formaldehyde compound, long chain saturated alcohol and long chain saturated or unsaturated polyethoxylated alcohol; and (b) cationic surfactant. The emulsions when used to surface size paper impart improved oil, water and polar solvent resistance thereto. The emulsions may be used alone or as substantial replacements for anionic or non-ionic fluorocarbon based emulsions that are typically used to impart oil resistance to paper.
Abstract: Polyol (allyl carbonate), e.g., diethylene glycol bis(allyl carbonate), are polymerized in solution, i.e., in an organic solvent, until from about 20 to 50 percent of the allylic carbon-carbon linkages are consumed. The solvent is then removed yielding a product that is a gel-free, syrupy viscous liquid of unpolymerized monomer and polymer. This liquid polymer can be polymerized to a hard, transparent material with less shrinkage. Also described is the addition of mono- or polyfunctional acrylates to the liquid polymer to product a polymerizable mixture that can be cured quickly with the addition of a free-radical initiator.
Abstract: 1,1,1-Trichloroethane (viz., methylchloroform) is stabilized with from about 2 to about 4 percent by weight 1,3-dioxolane, from about 0.25 to about 0.5 percent by weight butylene oxide, from about 0.25 to about 2 percent by weight nitromethane, from about 0.2 to about 0.75 percent by weight 1-nitropropane, from about 0.75 to about 2 percent by weight secondary butanol, and from 0 to about 100 parts per million by weight acetaldehyde dimethylhydrazone.
Type:
Grant
Filed:
July 24, 1989
Date of Patent:
February 12, 1991
Assignee:
PPG Industries, Inc.
Inventors:
Donald A. Reich, Catherine C. Doyen, Stephanie J. Oates
Abstract: As zeolite L is used as catalyst for the chlorination of benzene, chlorobenzene, ortho-dichlorobenzene, and/or meta-dichlorobenzene, its catalytic activity diminishes. Zeolite L which has been used for such chlorinations may be reactivated by contact with steam.