Abstract: A liquid monomer composition comprising of at least one poly(allyl carbonate)-functional monomer is contacted with molecular oxygen to produce a liquid intermediate composition which is then heated to produce a polymerizable, liquid substantially gel-free composition which contains poly(allyl carbonate)-funtional prepolymer which has an allylic utilization of at least about 12 percent.
Abstract: When a solution of liquid allylic-functional material and bromoxylenol blue is polymerized using a thermally decomposable polymerization initiator, the color imparted by the bromoxylenol blue is brilliant yellow.
Abstract: Polyhalophthalimidoalkyl-functional carbonates may be employed as fire retardant additives to polymers. Examples of such carbonates are 2-(tetrabromophthalimido)ethyl 2,4,6-tribromophenyl carbonate, 2-(tetrabromophthalimido)ethyl pentabromophenyl carbonate and bis[2-(tetrabromophthalimido)ethyl] carbonate.Polyhalophthalimidoalkyl haloformates, N-(hydroxyalkyl)-polyhalophthalimides, and 2-(hydroxyalkylcarbamyl)-polyhalobenzoic acids are useful as intermediates in the preparation of the carbonates.
Abstract: Olefins containing at least 7 carbon atoms are used to remove molecular chlorine form compositions comprising 1,2-dichloroethane and a contaminating amount of molecular chlorine.
Abstract: Chloral is removed from aqueous hydrochloric acid containing chloral in a stripping zone at superatmospheric pressure and concentrated in a rectifying zone at superatmospheric pressure. The method is particularly suited for the treatment of feed compositions originating from the oxychlorination of ethylene.
Abstract: Alkylidene bromo-substituted arylene acetal and/or ketal polymers are useful for imparting fire resistance to compositions containing flammable polymers.
Abstract: Pourable, polymerizable compositions comprising aromatic-containing poly(allyl carbonate)-functional material, styrenic material, and monomer having three or more allyl, methallyl, acrylyl and/or methacrylyl groups is free radically polymerized to produce polymerizates having high refractive index, high hardness, and low yellowness. The polymerizates are especially useful in the form of ophthalmic lenses.
Type:
Grant
Filed:
June 27, 1985
Date of Patent:
November 11, 1986
Assignee:
PPG Industries, Inc.
Inventors:
Michael S. Misura, Richard A. Schwarz, Stephanie J. Oates
Abstract: Amino acid ester hydrohalide is produced by reacting amino acid, alcohol, and halocarbonyl compound represented by the formula: ##STR1## in the presence of an excess of the alcohol and under substantially anhydrous conditions, wherein X.sub.1 and X.sub.2 are each independently fluoro, chloro, bromo, trichloromethoxy or tribromomethoxy.
Abstract: Fire retardant compositions comprising organic polymer, organic fire retardant compound and particles of antimony oxide surface-modified with poly(dialkylsiloxane) or condensation residue thereof, often exhibit enhanced physical properties as compared with similar compositions employing untreated antimony oxide particles.
Type:
Grant
Filed:
April 24, 1985
Date of Patent:
October 7, 1986
Assignee:
PPG Industries, Inc.
Inventors:
Ralph B. Thompson, Kenneth J. Sienkowski
Abstract: N,N-Bis(polybromophenyl)organoamines are useful flame retardants which may be admixed with polymers to impart flame retardancy to the resulting compositions. Examples of such flame retardants include N,N-bis(2,4,6-tribromophenyl)methylamine, N,N-bis(2,4,6-tribromophenyl)ethylamine, N,N-bis(2,4,6-tribromophenyl)-allylamine, and N,N-bis(2,4,6-tribromophenyl)benzylamine.
Type:
Grant
Filed:
December 29, 1983
Date of Patent:
July 22, 1986
Assignee:
PPG Industries, Inc.
Inventors:
Kenneth J. Sienkowski, Ralph B. Thompson
Abstract: Esters of carbamic acids containing at least one hydrogen atom attached to the carbamic nitrogen atom are reacted with organic carbonates to produce esters of carbamic acids having a greater degree of organic substitution on the carbamic nitrogen atom than the reactant esters. Preferably, the reactant esters are alkylated using dialkyl carbonates.
Abstract: 1,2-Dichloroethane is pyrolyzed in a pyrolysis furnace to produce a stream comprising vinyl chloride and 1,2-dichloroethane. The stream is removed from the furnace and introduced to essentially unheated conduit means to establish a stream flowing in the conduit means. Pyrolysis promoter is introduced to the stream in the conduit means and sensible heat of the stream is utilized in the conduit means to pyrolyze further amounts of 1,2-dichloroethane and to increase the yield of vinyl chloride.
Abstract: Compound represented by the formula ##STR1## wherein each X is independently chloro or bromo is employed as a pyrolysis promoter in the pyrolysis of 1,2-dichloroethane to vinyl chloride.
Abstract: When a solution of liquid allylic-functional material and dye comprising molybdenum dioxydichloride and molybdenum hexacarbonyl in combination is polymerized using a thermally decomposable polymerization initiator, the color imparted by the combination of the two molybdenum compounds remains essentially stable during the polymerization.
Abstract: Polyhalophthalimidoalkyl-functional carbonates may be employed as fire retardant additives to polymers. Examples of such carbonates are 2-(tetrabromophthalimido)ethyl 2,4,6-tribromophenyl carbonate, 2-(tetrabromophthalimido)ethyl pentabromophenyl carbonate and bis[2-(tetrabromophthalimido)ethyl]carbonate.Polyhalophthalimidoalkyl haloformates, N-(hydroxyalkyl)-polyhalophthalimides, and 2-(hydroxyalkylcarbamyl)-polyhalobenzoic acids are useful as intermediates in the preparation of the carbonates.
Abstract: Ester is produced by reacting highly hindered carboxylic acid or salt thereof represented by the formula ##STR1## wherein a. R.sub.3, R.sub.4, and R.sub.5 are each independently a monovalent organo group, andb. M is hydrogen, monovalent metal, or the monovalent fractional part of a polyvalent metal,with organic carbonate represented by the formula ##STR2## wherein R.sub.1 and R.sub.2 are each independently monovalent organic groups which may be the same or different, and wherein the alpha carbon of at least one of R.sub.1 and R.sub.2 is substantially sterically unhindered.
Abstract: Poly(oxyalkylene) glycols and polymer-supported poly(oxyalkylene) alcohols are employed as phase-transfer reagents in blocking primary amino functionality of alkali metal salts of amino acids with a benzyloxycarbonyl group.
Abstract: Carbonate polymer contains both divalent aromatic groups substituted by at least two bromo groups and at least one divalent aliphatic group. The presence of the divalent aliphatic group or groups reduces the melting range of the carbonate polymer. The carbonate polymer is fire resistant and may be admixed with flammable polymer to provide a composition having greater fire resistance than that of the flammable polymer.