Abstract: In chemical light devices comprising a chemi-luminescent mixture with a first fluorescer contained in a transparent or translucent container, a second fluorescer is incorporated in the walls of the container to shift at least part of the emissions from the device from the shorter wavelength emission of the first fluorescer to a longer wavelength emission of the second fluorescer. The second fluorescer has an absorption spectrum substantially overlapping the emission spectrum of the first fluorescer. The shift is usually about 20 to 100 nanometers and may be as much as 200 nanometers.
Abstract: A urethane-modified ester of rosin and a primary polyhydric alcohol has negligible hydroxyl content and is particularly useful as a polar tackifier in an adhesive composition made with a polar elastomer. The modified ester is prepared by reacting a rosin ester, for example, a rosin-pentaerythritol ester which contains some residual hydroxyl groups with a suitable isocyanate or diisocyanate.
Abstract: Electrochromic devices are described having a layer of electrochromic material, e.g. WO.sub.3, in contact with a layer of organic electrolyte resin, with electrode means for changing electrochromic properties of the device by electric field means. The electrolyte resin layer comprises a hydrophilic layer of homopolymer of poly(2-acrylamido-2-methylpropanesulfonic acid) with an organic humectant and in some preferred embodiments may further comprise a thinner layer of less hydrophilic electrolyte resin between the homopolymer and electrochromic layers.
Abstract: There is provided a new compound: d-N-(2-amino-2-phenethyl-2-methoxyethylamine useful in the direct synthesis of levamisole. The compound is prepared by slurrying the racemic N-(2-amino-2-phenethyl)-2-methoxyethylamine with dibenzoyl-d-tartaric acid as the resolving agent in an aqueous acidic menstruum containing ammonium chloride, heating the resultant mixture, preferably under reflux, cooling and filtering the resultant mixture to recover crystals rich in the desired d-amine compound, hereinabove noted.
Abstract: Water-soluble sulfonated rubrenes are used as fluorescer components in water-soluble chemiluminescent mixtures and particularly in combination with a water-soluble amide of oxalic acid which reacts with hydrogen peroxide to produce chemiluminescence.
Abstract: In electrochromic devices having a layer of electrochromic material, e.g. tungsten oxide, in contact with a polymeric electrolyte layer, the stability and speed of the device are improved by using a copolymer of 2-acrylamido-2-methylpropanesulfonic acid and vinyl sulfonic acid as the polymeric electrolyte.
Abstract: An electrochromic device having an electrochromic layer of persistent electrochromic material such as tungsten oxide, and an electrolyte layer and a counter electrode which comprises an oxidizing agent which has oxidizing electrode potential more negative than the electrochromic layer to provide a stored charge for erasing color from the electrochromic layer, and to increase the emf of the charge used for the erase function. Examples of suitable oxidizing agents are manganese dioxide and chromic oxide.
Abstract: There is provided a process for racemizing an undesirable, optically active compound for conversion to levamisole, namely, l-N-(2-amino-2-phenethyl)-2-methoxyethylamine, by converting the latter to optically active l-(2-methoxyethyl)-4-phenyl-2-imidazolidone, which is next converted to the corresponding optically inactive imidazolidone derivative, which derivative is hydrolyzed to the optically inactive racemate, dl-N-(2-amino-2-phenethyl)-2-methoxyethylamine. The latter can be resolved to obtain the d and l components of the racemate, the d component being utilized directly in levamisole synthesis and the l component being again subjected to the above procedure.
Abstract: Quaternary salts of N,N'-bis(morpholinoalkyl)-N,N'-bis(trifluoromethylsulfonyl)oxamides and of N,N'-bis(pyridylalkyl)-N,N'-bis(trifluoromethylsulfonyl)oxamides are useful for generation of chemiluminescence by reaction with hydrogen peroxide in aqueous solvent.
Abstract: Additives to tall oil pitch react to cause crosslinking which improves hardness, viscosity, tackiness, etc., properties of the modified pitch. Additives include for example maleic anhydride, wood flour, formylated melamine, phenol and other resins, diisocyanates, alcohols and the like. The modified pitch has properties improved for use as binders for briquetting adhesives, etc.
Abstract: Electrochromic devices are described having a layer of electrochromic material, e.g. WO.sub.3, in contact with a layer of organic electrolyte resin, with electrode means for changing electrochromic properties of the device by electric field means. The electrolyte resin layer comprises a hydrophilic layer of homopolymer of poly(2-acrylamido-2-methylpropane sulfonic acid) and in some preferred embodiments may further comprise a thinner layer of less hydrophilic electrolyte resin between the homopolymer and electrochromic layers.
Abstract: Electrophotographic element typically comprising in sandwiched arrangement a transition metal oxide layer and a photoconductive layer. When an electric field is applied across the element, preferably after inserting the element between a pair of electrode layers, and an optical image is projected onto the photoconductive layer, the resulting conductivity pattern in the photoconductive layer causes corresponding coloration in the transition metal oxide layer, thereby visibly recording the optical image.
Abstract: An improved single-pot process for synthesis of 3,5,6-trichlorosalicylic acid and esters thereof is described. Salicylic acid is chlorinated first in concentrated sulfuric acid and then with iodine catalyst to make the trichlorosalicylic acid which is extracted and then reacted with an alcohol to make the ester.
Type:
Grant
Filed:
July 11, 1980
Date of Patent:
December 29, 1981
Assignee:
American Cyanamid Company
Inventors:
Robert J. Manfre, Arthur G. Mohan, Michael M. Rauhut
Abstract: Apparatus for activation of a chemical lightstick by downward sag of a mine roof is described. Through a spool and collar at the mine roof, two wires are extended from an anchor set in a stable formation above the roof, and are tied to a lightstick below the collar and spool. Pathways for passage of the two wires through the spool are provided so the wires are outside a center opening in the spool but are inside the outermost diameter of the neck of the spool. A spring-loaded embodiment permits the apparatus to tolerate a measured sag without activating the lightstick.
Type:
Grant
Filed:
November 21, 1979
Date of Patent:
November 10, 1981
Assignee:
American Cyanamid Company
Inventors:
William R. Heffernan, Mary-Louise Vega, Joel A. Gingras, Sr.
Abstract: For making low density alumina or silica-alumina beads as catalyst support particles for auto-exhaust catalysts, hollow glass spheres of very small diameter are incorporated in the alumina powder mix before it is formed into beads and calcined. The beads may be finished with a surface coat of alumina without the microspheres to improve resistance to abrasion. Preferred beads are made with rehydratable alumina powder.
Abstract: For settling suspended solids in phosphoric acid product solutions, a copolymer of 95 mole percent ammonium acrylate monomer, 5% acrylamide monomer is shown to remove more solids than prior art flocculants when used in equivalent dosage, and to remove equivalent solids at much less dosage.
Abstract: There is provided a process for preparing amides which comprises reacting an amine, or an amide, and an acid halide, or anhydride, in suitable molecular proportions, in an inert organic diluent, in the presence of an effective amount of a molecular sieve, until the reaction is completed, separating the molecular sieve, and recovering the amide from the organic mother liquor.
Abstract: Quaternary salts of N,N'-bis(morpholinoalkyl)-N,N'-bis(trifluoromethylsulfonyl)oxamides and of N,N'-bis(pyridylalkyl)-N,N'-bis(trifluoromethylsulfonyl)oxamides are useful for generation of chemiluminescence by reaction with hydrogen peroxide in aqueous solvent.
Abstract: An electrochromic data display and imaging device which may be formed by sandwich arrangement of the imaging area and the counter-electrode area, with a suitable self-supporting ion-conductive layer between.