Patents Represented by Attorney, Agent or Law Firm Henry E. Millson, Jr.
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Patent number: 6261526Abstract: A process for the recovery of nickel from a nickel containing ore in which the ore, particularly a laterite ore, is initially leached with an aqueous acid solution, after which the nickel is precipitated as nickel hydroxide by adding a hydroxide to the aqueous acid leach solution containing the nickel, followed by a re-leaching of the nickel with an aqueous ammoniacal solution and recovery of the nickel by a solvent extraction of the nickel from the aqueous ammoniacal solution with an organic phase of a water insoluble oxime extractant comprising a ketoxime containing less than 10% phenols dissolved in a water-immiscible hydrocarbon solvent and the nickel recovered by electrowinning the nickel from the aqueous acid stripping solution employed to strip the nickel from the organic phase.Type: GrantFiled: August 12, 1999Date of Patent: July 17, 2001Assignee: Henkel CorporationInventors: Michael J. Virnig, George Wolfe
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Patent number: 6251958Abstract: A process for preparing a defoamer composition by providing a high-shear, in-line mixer having a rotor-stator assembly with at least one concentric set of shearing teeth which rotate at a tip speed of up to about 25 meters per second and feeding to said mixer a melt of a hydrophobic defoaming agent along with a functional carrier liquid at a controlled mass flow rate and temperature. After mixing, the mixture is cooled and discharged into a receiving vessel.Type: GrantFiled: April 8, 1999Date of Patent: June 26, 2001Assignee: Henkel CorporationInventors: Puvin Pichai, Kenneth Breindel
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Patent number: 6245727Abstract: The invention relates firstly to a discontinuous process for conducting a heterogeneously catalyzed reaction taking place at elevated temperature, in which heat-sensitive products are formed, a heat transfer unit (4) different from the reactor (1) being used for heating and a fixed-bed catalyst (3) being used as the catalyst and the reaction mixture being continuously circulated in succession through the catalyst (3) and then through the heat transfer unit (4). The problem to be solved in this process is to avoid losses of catalyst and product and to shorten the batch time and, optionally, the reaction time in accordance with German patent applications P 38 13 612.0 and P 38 26 320.3.Type: GrantFiled: June 14, 1994Date of Patent: June 12, 2001Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Bernhard Gutsche, Lutz Jeromin, Eberhard Peukert, Levent Yueksel, Kurt Adrian, Heinz Bollweg
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Patent number: 6242625Abstract: In an acid leach copper extraction circuit for leaching copper values from copper ores using a water-immiscible organic solvent solution containing a copper extractant and an acid strip solution, the improvement wherein the stripped organic solvent solution is contacted with copper-free fresh aqueous acid to remove additional copper values therefrom, and then the resulting super stripped organic and the copper-containing aqueous acid are sent to the copper extraction circuit.Type: GrantFiled: September 30, 1999Date of Patent: June 5, 2001Assignee: Henkel CorporationInventor: Gary A. Kordosky
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Patent number: 6232433Abstract: A composition comprising the reaction product of: a) a polycarboxylic member selected from the group consisting of polycarboxylic acids comprised of a diacid having more than about 12 carbon atoms and reactive derivatives thereof (e.g. alkyl esters thereof wherein the alkyl group has from 1 to 4 carbon atoms), b) an ethylenically unsaturated member selected from the group consisting of ethylenically unsaturated mono-carboxylic acids and reactive derivatives thereof, (e.g. alkyl esters thereof wherein the alkyl group thereof has from 1 to 4 carbon atoms), and c) an ethoxylated alkanetriol having an average degree of ethoxylation per hydroxyl of less than about 2 and comprised predominantly of ethoxylated alkanetriol species having one ethoxylate group per hydroxyl. This composition is useful as a polymerizable component, particularly for UV curable coatings and inks.Type: GrantFiled: October 27, 1997Date of Patent: May 15, 2001Assignee: Henkel CorporationInventor: Ramesh Narayan
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Patent number: 6228806Abstract: Fertilizer compositions comprising: A) an effective quantity of an inorganic or organic fertilizer; and B) a quantity of beneficial microorganisms sufficient to further enhance plant growth when the fertilizer composition is applied to soil and/or control pathogens in the soil, and methods for their use.Type: GrantFiled: October 6, 1998Date of Patent: May 8, 2001Assignee: Organica Inc.Inventor: Raj J. Mehta
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Patent number: 6221370Abstract: An emulsifier mixture for use in the production of phase inversion temperature (PIT) emulsions is provided. The emulsifier mixture comprises fatty acid ethoxylates and partial glycerides which enable PIT emulsions to be produced at a given phase inversion temperature irrespective of the polarity of the oils, allowing for the emulsifying of a broad range of oils irrespective of their character, under the same conditions.Type: GrantFiled: February 26, 1999Date of Patent: April 24, 2001Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Armin Wadle, Achim Ansmann, Holger Tesmann, Karl-Heinz Gantke, Ansgar Behler, Bernhard Guckenbiehl
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Patent number: 6211119Abstract: The invention relates to multiphase lubricant concentrates with improved properties for use in aqueous fluids for geological exploration by drilling which contain organic lubricating components which are solid and/or liquid at room temperature (O phase) together with emulsifiers finely dispersed in a continuous aqueous phase (W phase). These concentrates are characterized in that the system of O phase/W phase and emulsifiers has a phase inversion temperature (PIT) above room temperature and has been produced by heating the multiphase system to temperatures equal to or above the PIT and subsequent cooling to temperatures below the PIT. The present invention also relates to the use of the multiphase lubricant concentrates as an additive in water-based fluids for use in geological exploration by drilling and for the subsequent treatment of the resulting boreholes.Type: GrantFiled: June 1, 1999Date of Patent: April 3, 2001Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Claus-Peter Herold, Heinz Mueller, Thomas Foerster, Stephan Von Tapavicza, Marcus Claas
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Patent number: 6197879Abstract: A polymer useful as an inorganic pigment dispersant is provided. The polymer is derived from monomers consisting essentially of an ethylenically unsaturated aromatic monomer, an ethylenically unsaturated dicarboxylic acid monomer, and an ethylenically unsaturated monocarboxylic acid monomer. The total amount of said ethylenically unsaturated acid monomers is sufficient to permit said polymer to associate with an inorganic pigment in an aqueous medium in a manner which disperses said inorganic pigment in said aqueous medium to form a stable aqueous dispersion of said inorganic pigment, and the amount of said ethylenically unsaturated aromatic monomer is sufficient to reduce the water sensitivity of a dried coating of a latex paint comprised of said stable aqueous dispersion of said inorganic pigment. A process of preparing a polymer useful as an inorganic pigment dispersant and a method of preparing an inorganic pigment dispersion useful in the preparation of latex paints are also provided.Type: GrantFiled: September 13, 1996Date of Patent: March 6, 2001Assignee: Henkel CorporationInventors: Stephen A. Fischer, Michael S. Wiggins, Bruce Matta, Eric Nowicki
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Patent number: 6191097Abstract: A process for producing solid detergent granular materials is presented involving (a) forming an aqueous surfactant paste of an anionic surfactant, an amphoteric surfactant or mixtures thereof, and (b) drying and granulating the aqueous paste in a horizontal thin-layer evaporator or dryer having rotating fittings, wherein the drying is carried out at a temperature of 120° C. to 130° C. The process produces granules having a bulk density greater than 600 grams/liter and a uniform particle size distribution.Type: GrantFiled: August 25, 1999Date of Patent: February 20, 2001Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Thomas Lueder, Konstantinos Scholinakis, Bernhard Gutsche, Christoph Breucker, Norbert Wrede
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Patent number: 6187856Abstract: An antistatic composition containing a crosslinked thermosetting resin formed by reacting, in the presence of a water-soluble solvent, (a) a polyaminoamide having unreacted primary and secondary amine groups and (b) a polychlorohydrin derivative.Type: GrantFiled: March 18, 1998Date of Patent: February 13, 2001Assignee: Henkel CorporationInventors: Michael J. Incorvia, Stephen A. Fischer
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Patent number: 6174849Abstract: A water-free surfactant composition is presented having (a) a fatty alcohol sulfate corresponding to the formula R1O—SO3X where R1 is a linear alkyl chain containing 16 or 18 carbon atoms and X is an alkali metal, alkaline earth metal, ammonium, alkylammonium, alkanolammonium or glucammonium and (b) an alcohol sulfate corresponding to the formula R2O—SO3X where R2 is an alkyl chain containing 12 to 15 carbon atoms consisting of a minimum 20 percent by weight branched alkyl chains and a maximum 80 percent by weight unbranched alkyl chains, and X is an alkali metal or alkaline earth metal, ammonium, alkylammonium, alkanolammonium or glucammonium. The surfactant composition has a reduced potential for irritation and good flowability and solubility in cold water. The surfactant composition is useful in laundry detergents, dishwashing detergents and other cleaners.Type: GrantFiled: April 30, 1999Date of Patent: January 16, 2001Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Karl-Heinz Schmid, Ditmar Kischkel, Thomas Krohnen, Andreas Syldath
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Patent number: 6172018Abstract: Aqueous cleaning compositions having high foaming power and minimal effect on the skin which comprise (A) from about 1 to about 50% by weight of one or more anionic surfactants having 1 or 2 lipophilic groups each of which has from 1 to 22 carbon atoms and a polar group selected from the group consisting of a carboxylate, a sulfate, and a sulfonate group; (B) from about 0.5 to about 10% by weight of one or more alkyl glycosides of the formula R(G)x wherein R is a linear, saturate C8-22 alkyl group, (G) is a glycoside or oligoglycoside moiety, and x is a number from 1 to 4; (C) from about 0.1 to about 5% by weight of an anionic polymer; (D) from about 35 to about 98.4% by weight of water; wherein the sum total of components (B) and (C) is no greater man the amount of component (A).Type: GrantFiled: May 2, 1994Date of Patent: January 9, 2001Assignee: Henkel Kommanditgesellschaft Auf AktienInventors: Reinhard Mueller, Kurt Seidel, Detlef Hollenberg, Anja Patten
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Patent number: 6165961Abstract: A water-free surfactant composition containing: (a) a fatty alcohol sulfate corresponding to the formula R.sup.1 O--SO.sub.3 X, where R.sup.1 is a linear alkyl chain, and X is an alkali metal, alkaline earth metal, ammonium, alkyl ammonium, alkanolammonium or glucammonium; and (b) an alkyl benzenesulfonate corresponding to the formula R.sup.2 --Ph--SO.sub.3 X where R.sup.2 is an alkyl chain containing 10 to 14 carbon atoms, Ph is a phenyl group and X is alkali metal, alkaline earth metal, ammonium, alkyl ammonium, alkanolammonium or glucammonium. The fatty alcohol sulfate and alkyl benzenesulfonate are present in the surfactant composition in a weight ratio of 50:50 to 90:10. The water-free surfactant composition provides a reduced potential for irritation, good flow behavior and solubility in cold water. The surfactant composition is useful in laundry detergents, dishwashing detergents and cleaners.Type: GrantFiled: May 20, 1999Date of Patent: December 26, 2000Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Karl-Heinz Schmid, Ditmar Kischkel, Thomas Krohnen, Andreas Syldath
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Patent number: 6156280Abstract: Process for removing manganese values from a solution of a water-immiscible hydrocarbon containing manganese values and a water-insoluble oxime extractant capable of extracting nickel values from aqueous ammoniacal solutions comprising the steps ofI) contacting the water-immiscible hydrocarbon solution with a finely divided active metal and an aqueous solution of a strong acid to decrease or complete remove the manganese values from said water-immiscible hydrocarbon solution; andII) separating the stripped hydrocarbon solution from the aqueous solution.The invention also relates to a method for the extraction of nickel from nickel-containing ores in which a content of manganese values is present in which the above process is used.Type: GrantFiled: February 24, 1999Date of Patent: December 5, 2000Assignee: Henkel CorporationInventors: Michael J. Virnig, Stephen M. Olafson, Burrel Boley, III
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Patent number: 6140302Abstract: A process for the production of anionic surfactant granules comprising the steps of:A) Neutralizing an acidic anionic surfactant with a base in a horizontal thin-layer evaporator or thin-layer dryer; andB) Drying the resulting neutralized anionic surfactant in the evaporator or dryer to form surfactant granules; wherein the acidic anionic surfactant and the base taken together have a solids content such that the total quantity of water in the evaporator or dryer at no time exceeds about 15 % by weight and wherein the neutralization and drying are carried out in countercurrent flow with air or an alkaline gas stream at a temperature in the range of from about 120 to about 130.degree. C.Type: GrantFiled: October 29, 1999Date of Patent: October 31, 2000Assignee: Cognis Deutschland GmbHInventors: Thomas Lueder, Bernhard Gutsche, Konstantinos Scholinakis
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Patent number: 6139859Abstract: Methods and compositions for the topical treatment of ectoparasites on animal skin utilizing a water-soluble or water-dispersible, substantially air-impermeable liquid composition.Type: GrantFiled: August 10, 1998Date of Patent: October 31, 2000Assignee: Summers Laboratories, Inc.Inventor: Michael J Precopio
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Patent number: 6130191Abstract: A process for the preparation of a mixture of trimethylolpropane caprylate and trimethylolpropane caprate comprising the steps ofA) purifying a less than pure mixture of methyl caprylate and methyl caprate;B) reacting the purified mixture from step A) with trimethylolpropane to transesterify the purified mixture to produce a reaction mixture containing trimethylolpropane caprylate and trimethylolpropane caprate; andC) removing methanol and unreacted methyl caprylate and methyl caprate from the reaction mixture.Type: GrantFiled: September 10, 1999Date of Patent: October 10, 2000Assignee: Henkel CorporationInventors: Robert P. Ribelin, Stephen W. Turner
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Patent number: 6122860Abstract: The invention relates to a process for intensifying the surface stabilization of soil susceptible to erosion by introduction of water-based adhesion-promoting impregnating compounds based on esters of polyvinyl alcohol with C.sub.1-5 monocarboxylic acids and mixtures thereof with higher monocarboxylic acids (binders) using surface-active and biologiclly compatible wetting agents. The process is characterized in that impregnation of the soil is carried out in several stages and in that an aqueous preparation containing the wetting agents is used at least in the first impregnating stage. Binder is preferably used in a comparatively small quantity in this pre-impregnation stage.Type: GrantFiled: December 22, 1998Date of Patent: September 26, 2000Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Stefan Von Tapavicza, Heinz Mueller, Claus-Peter Herold, Heinz Boettcher, Frank Burbach
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Patent number: 6121227Abstract: A storable, high-viscosity liquid detergent having high washing power and pronounced foaming comprising water, and from about 2% to about 10% by weight of a fatty alcohol sulfate, from about 5% to 25% by weight of an alkyl polyglycoside; from about 0.1% to about 9% by weight of a soap; and from about 3% to 8% by weight of a lower alcohol, wherein said detergent has a viscosity of from about 500 mPa's to about 3000 mPa's.Type: GrantFiled: July 28, 1993Date of Patent: September 19, 2000Assignee: Henkel Kommanditgesellschaft Auf AktienInventors: Georg Meine, Rolf Puchta, Juergen Hoffmeister