Patents Represented by Attorney, Agent or Law Firm Henry E. Millson, Jr.
  • Patent number: 5783534
    Abstract: A process for the production of a solid esterquat free from solvents comprising the steps ofA) forming a mixture comprising(i) at least one fatty acid triethanolamine ester corresponding to formula (I) ##STR1## in which R.sup.1 CO is a saturated and/or unsaturated acyl radical containing 6 to 22 carbon atoms, R.sup.2 and R.sup.3 independently of one another represent hydrogen or have the same meaning as R.sup.1 CO, and n, m and p together stand for O or for a number of from 1 to 10;(ii) at least one fatty alcohol polyglycol ether, and(iii) at least one fatty acid partial glyceride; andB) adding an alkylating agent to the above mixture to form said solid esterquat.
    Type: Grant
    Filed: July 15, 1996
    Date of Patent: July 21, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Bernd Wahle, Joaquim Bigorra Llosas, Rafael Pi, Antoni Soler Codina, Emili Brau Balague, Yvonne Reichert, Peter Waltenberger
  • Patent number: 5777183
    Abstract: The invention relates to a process for the production of Guerbet alcohols by condensation of aliphatic alcohols in the presence of alkali metal or alkaline earth metal hydroxides as catalyst using the Guerbet reaction, in which the initial pressure in the reactor corresponds to the vapor pressure of the alcohol components used and, during the reaction, the pressure is continually reduced to the vapor pressure of the reaction mixture at the particular temperature.
    Type: Grant
    Filed: July 5, 1996
    Date of Patent: July 7, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Gerd Mueller, Bernhardt Gutsche, Lutz Jeromin, Udo Steinberner, Reinhold Sedelies, Ralf Bohlander, Richard Ridinger, Dirk Springer, Franz Buettgen, Frank Bartschik
  • Patent number: 5773636
    Abstract: A process for the production of fatty acid lower alkyl esters comprising the steps of:A) treating at least one fatty acid ester of glycerol with from about 0.3 to about 3% by weight, based on the weight of ester, of an acid at an elevated temperature;B) removing said acid from the treated fatty acid ester; andC) reacting the treated fatty acid ester with at least one lower aliphatic alcohol to transesterify the fatty acid ester.
    Type: Grant
    Filed: August 5, 1996
    Date of Patent: June 30, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Guenther Demmering, Christian Pelzer, Lothar Friesenhagen
  • Patent number: 5770662
    Abstract: A composition of matter comprising a resin obtained by a process comprising reacting at an elevated temperature an epoxidized ester of an unsaturated fatty acid with an aliphatic alcohol with a resin acid is provided. The equivalent ratio of epoxy groups of said epoxidized ester to carboxyl groups of said resin acid is in the range from 1.5:1 to 0.01:1. The resin is useful as a tackifier for adhesives and has a reduced tendency to crystallize.
    Type: Grant
    Filed: September 18, 1996
    Date of Patent: June 23, 1998
    Assignee: Henkel Kommanditgesellschaft Auf Aktien (Henkel KGaA)
    Inventors: Ulrich Eicken, Manfred Gorzinski, Paul Birnbrich, Thomas Tamcke
  • Patent number: 5759974
    Abstract: Block-form cleaners for flush toilets which consist of at least two masses of different composition, one of the masses being at least partly surrounded by the other mass(es) and the surrounded mass containing an active substance in a concentration at least 1.3 times higher than in the surrounding mass. This distribution ensures that the active substance is more uniformly released over the useful life of the cleaning block.
    Type: Grant
    Filed: July 30, 1996
    Date of Patent: June 2, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Ronald Menke, Alexander Ditze, Gerd Praus
  • Patent number: 5759979
    Abstract: Detergent mixtures containing a) alkyl and/or alkenyl oligoglycosides corresponding to formula (I)R.sup.1 O--?G!.sub.p (I)in which R.sup.1 is an alkyl or alkenyl radical containing 8 to 22 carbon atoms, G is a sugar unit containing 5 or 6 carbon atoms and p is a number of 1 to 10; b) fatty alcohol polyglycol ethers corresponding to formula (II) ##STR1## in which R.sup.2 represents alkyl radicals containing 6 to 14 carbon atoms, n is a number of 0.5 to 2 and m is a number of 2 to 10 and, optionally, c) amphoteric or zwitterionic surfactants and water, have synergistic effects in regard to their washing, dishwashing, foaming and cleaning performance and in regard to their skin-cosmetic compatibility. Accordingly, they are suitable for the production of a number of surface-active preparations, particularly manual dishwashing detergents.
    Type: Grant
    Filed: October 4, 1995
    Date of Patent: June 2, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Karl Schmid, Brigitte Giesen, Karin Koren
  • Patent number: 5756624
    Abstract: A method of tackifying an adhesive is provided, the improvement comprising the use of a copolymer consisting of monomer units derived monomers consisting of:(A) 10 to 50% by weight of a terpene with no conjugated double bonds,(B) 20 to 50% by weight of a member selected from the group consisting of olefinically unsaturated monocarboxylic acids containing 3 to 5 carbon atoms and anhydrides thereof, and olefinically unsaturated dicarboxylic acids containing 3 to 5 carbon atoms and anhydrides thereof, and(C) 40 to 50% by weight of an ester selected from the group consisting of esters and semiesters of olefinically unsaturated monocarboxylic containing 3 to 5 carbon atoms and esters and semiesters of olefinically unsaturated dicarboxylic acids containing 3 to 5 carbon atoms, with the proviso that the sum total of said monomers is 100% by weight.
    Type: Grant
    Filed: November 4, 1996
    Date of Patent: May 26, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Arno Behr, Wolfgang Ritter, Hans-Peter Handwerk, Oliver Pietsch
  • Patent number: 5756442
    Abstract: Pourable, liquid, aqueous cleaning concentrates comprisinga) at least about 10% by weight of at least one water soluble abrasive; andb) from about 2 to about 30% by weight of a mixture of narrow-range alkyl polyglycol ethers, amphoteric surfactants and soap, the ratio by weight of amphoteric surfactants to narrow-range alkyl polyglycol ethers being 1:10 to 3:1, the ratio by weight of amphoteric surfactants to soap being 15:1 to 1:3 and the ratio by weight of narrow-range alkyl polyglycol ethers to soap being 25:1 and 1:1.
    Type: Grant
    Filed: December 11, 1995
    Date of Patent: May 26, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Rainer Jeschke, Eva Kiewert, Katica Bocarac, Rainer Hofmann
  • Patent number: 5756694
    Abstract: Light-colored alkyl and/or alkenyl oligoglycosides corresponding to formula (I)R.sup.1 O--?G!.sub.p (I)which R.sup.1 is an alkyl and/or alkenyl radical containing 4 to 22 carbon atoms, G is a sugar unit containing 5 or 6 carbon atoms and p is a number of 1 to 10, can be produced by a process in which sugars are subjected to acid-catalyzed acetalization with a large excess of primary alcohols, the reaction mixture is neutralized in the presence of reducing agents and is then bleached in known manner. At the same time, the quality of the excess fatty alcohol to be separated off is considerably improved.
    Type: Grant
    Filed: November 20, 1995
    Date of Patent: May 26, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventor: Manfred Weuthen
  • Patent number: 5753606
    Abstract: A water-containing detergent or cleaning composition comprisingA) at least one alkyl polyglycosides corresponding to the formula R.sup.1 --O--(Z).sub.x (I), where R.sup.1 is a linear or branched, saturated or unsaturated alkyl group containing 8 to 18 carbon atoms, Z is a sugar unit, and x is an integer of 1 to 10; andB) at least one fatty acid alkyl ester alkoxylate of the formula R.sup.2 CO.sub.2 --(AO).sub.y --R.sup.3 (II), where R.sup.2 is a branched or linear, saturated or unsaturated alkyl group containing 5 to 21 carbon atoms, AO is a C.sub.2-4 alkylene oxide unit, y is a number of 1 to 30 and R.sup.3 is a linear or branched alkyl group containing 1 to 6 carbon atoms; and methods for using the above composition.
    Type: Grant
    Filed: March 4, 1996
    Date of Patent: May 19, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Udo Hees, Eva Kiewert, Ansgar Behler, Astrid Haferkamp, Kerstin Link, Amerigo Pastura, Nada Volf, Guenther Vogt
  • Patent number: 5746777
    Abstract: A scatterable dry cleaning formulation for textiles containing cellulose powder, colloidal silicon dioxide, and water.
    Type: Grant
    Filed: January 28, 1997
    Date of Patent: May 5, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Theo Fleckenstein, Alexander Ditze, Thomas Hahn
  • Patent number: 5723538
    Abstract: A process is provided for preparing a dispersion of a polyamide in water, said process comprising:dissolving a polyamide having an amine value of greater than about 2 in an organic solvent to form a solution of said polyamide in said solvent, said polyamide and said solvent being at a temperature below the softening point of said polyamide during said dissolving, said solution further comprising a surfactant and an inorganic alkaline material,adding sufficient water containing an acid to said solution with mixing to form an oil-in-water dispersion, the temperature of said solution and said water being below the softening point of said polyamide during said adding, the amount of said acid being sufficient to neutralize a portion of said inorganic alkaline material, but insufficient to coagulate said polyamide from the resulting oil-in-water dispersion, andremoving at least a major amount of said organic solvent from said oil-in-water dispersion.
    Type: Grant
    Filed: October 25, 1996
    Date of Patent: March 3, 1998
    Assignee: Henkel Corporation
    Inventors: Stephen A. Fischer, David I. Devore, Kartar S. Arora, Reimar Heucher, Michael S. Wiggins, Chase J. Boudreaux
  • Patent number: 5718891
    Abstract: Solid esterquats with improved dispersibility in water are obtained by quaternizing fatty acid triethanolamine esters with alkylating agents in known manner in the presence ofa) dispersants selected from the group consisting of fatty alcohols, fatty acid monoglycerides and dialkyl ethers and optionallyb) emulsifiers selected from the group consisting of fatty alcohol polyglycol ethers, fatty acid monoglyceride polyglycol ethers, fatty acid oligoglyceride polyglycol ethers, polysorbates and alkyl oligoglucosides.The products are suitable, for example, for the production of hair-care preparations.
    Type: Grant
    Filed: December 19, 1994
    Date of Patent: February 17, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Esther Prat, Joaquim Bigorra
  • Patent number: 5716418
    Abstract: A composition and process for coloring keratin-containing fibers wherein the composition comprises: (a) an alkyl glycoside of the formula (I):R.sup.1 --O--(G).sub.x --H (I)wherein R.sup.1 is a linear or branched alkyl or alkenyl radical having from 12 to 16 carbon atoms, (G) is an anhydroglucose unit, and x is a number from about 1 to about 2.5; (b) an oxidation dye precursor; and (c) a water-based carrier.
    Type: Grant
    Filed: March 15, 1996
    Date of Patent: February 10, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Iduna Matzik, Horst Hoeffkes, Detlef Hollenberg, Reinhard Mueller, Manuela Ehlert, Christa Schramm
  • Patent number: 5714154
    Abstract: A process for the production of multiple w/o/w emulsions in whicha) a mixture of an oil and a lipophilic emulsifier I comprising glycerol and/or oligoglycerol or polyglycerol fatty acid esters is initially processed with intensive shearing to form a w/o pre-emulsion A, andb) the w/o pre-emulsion A is then further treated with an aqueous emulsifier II comprising adducts of ethylene oxide with fatty alcohols and/or sterols and, optionally, fatty alcohols, wherein the treatment is accompanied by gentle shearing;and to the resulting multiple w/o/w emulsions and their use in the preparation of cosmetic and pharmaceutical products.
    Type: Grant
    Filed: December 20, 1995
    Date of Patent: February 3, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Catherine Le Hen-Ferrenbach, Isabelle Terrisse, Armelle Magnet, Monique Seiller, Francis Puisieux, Jean-Louis Grossiord
  • Patent number: 5712235
    Abstract: New toilet soaps contain: (a1) 4 to 7% by weight alkyl and/or alkenyl oligoglycosides and/or (a2) 2 to 7% by weight fatty acid N-allcylpolyhydroxyalkylamide; (b) 45 to 95% by weight soap and (c) 0 to 10% by weight anionic surfactants selected from the group of alkyl sulphates, isethionates, taurides, sarcosinates, mono- and dialkylsulfosuccinates, ether carboxylic acids, sulphotriglycerides and alkyloligoglucoside sulphates. These new soaps are characterized among others by an improved creaminess, a high foaming power, remarkable cosmetic compatibility with the skin and mechanical firmness.
    Type: Grant
    Filed: March 15, 1996
    Date of Patent: January 27, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Claus Nieendick, Gerhard Wollmann, Bernd Richter, Karl-Heinz Schmid, Andreas Syldath, Bernd Fabry
  • Patent number: 5705462
    Abstract: A bar soap comprising:A) from about 70 to about 85% by weight of at least one fatty acid salt,B) from about 0.5 to about 10% by weight of at least one fatty acid,C) from about 1 to about 10% by weight of at least one alkyl ether sulfate, andD) from about 0.1 to about 1% by weight of at least one of an alkyl oligoglycoside and an alkenyl oligoglycoside.
    Type: Grant
    Filed: April 26, 1996
    Date of Patent: January 6, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Marlene Hormes, Werner Schneider, Wolfhard Scholz, Udo Hennen
  • Patent number: 5696074
    Abstract: Liquid crystalline aqueous surfactant compositions containing alkyl glycosides, long-chain alcohols, and, optionally, anionic surfactants; and to finished products containing them.
    Type: Grant
    Filed: December 18, 1995
    Date of Patent: December 9, 1997
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Dieter Nickel, Rainer Hofmann, Manfred Weuthen
  • Patent number: 5688976
    Abstract: The invention relates to a process for producing 8.alpha.,12-oxido-13,14,15,16-tetranorlabdane through the cyclizing dehydration of 8.alpha.,12 -dihydroxy-13,14,15,16-tetranorlabdane in the presence of aluminophyllosilicates.
    Type: Grant
    Filed: July 3, 1996
    Date of Patent: November 18, 1997
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Georg Knuebel, Andreas Bomhard, Ulf-Armin Schaper, Theo Stalberg, Thomas Markert
  • Patent number: 5688759
    Abstract: Nitrogen-free anionic conditioning formulations containing sulfated polyol fatty acid esters corresponding to formula (I): ##STR1## in which R.sup.1 CO is a linear or branched, saturated or unsaturated acyl radical containing 6 to 22 carbon atoms, R.sup.2 represents hydrogen, an OCR.sup.1 group or an SO.sub.3 X group, R.sup.3 is hydrogen or an (OCH.sub.2 CH.sub.2).sub.m OR.sup.2 group, n is 0 or a number of 1 to 5, m is 0 or a number of 1 to 10, and X is an alkali metal, alkaline earth metal, ammonium, alkylammonium, alkanolammonium or glucammonium ion.
    Type: Grant
    Filed: March 22, 1996
    Date of Patent: November 18, 1997
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Ansgar Behler, Gunther Uphues, Bernd Wahle