Patents Represented by Attorney James B. Guffey
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Patent number: 5491195Abstract: High impact polystyrene resins are provided having a surprisingly good combination of toughness and gloss characteristics. Such resins contain small (i.e., 0.1 to 0.4 micron) capsule morphology rubber particles in combination with relatively small (i.e., 0.25 to 1 micron) entanglement morphology rubber particles. It has been found that such resins are capable of providing Izod impact strength values in the range of 2.5 to 3.5 ft-lb/in (133.4 to 186.7 J/m) and higher at an overall volume average rubber size of less than 0.4 micron with corresponding gloss values in excess of 90 percent.Type: GrantFiled: December 21, 1994Date of Patent: February 13, 1996Assignee: The Dow Chemical CompanyInventors: David Schrader, Mark E. Soderquist, Mark D. Heires
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Patent number: 5446103Abstract: Graft copolymerized maleimide-modified, impact resistant monovinylidene aromatic copolymer compositions have substantially improved impact strength and fatigue resistance properties when the swelling index thereof is 12 or greater and when the numerical difference in maleimide monomer content as between the grafted copolymer and matrix copolymer portions thereof differ by no more than 9 percentage points from each other. Such compositions are conveniently prepared by mass, solution or mass/suspension graft copolymerization processes and by deferring the addition of at least about 30 percent of the maleimide monomer ingredient to a point in the process after (and preferably only shortly after) phase inversion of the dissolved impact modifying rubbery polymer ingredient.Type: GrantFiled: November 18, 1994Date of Patent: August 29, 1995Assignee: The Dow Chemical CompanyInventors: Thomas D. Traugott, Shari L. Workentine
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Patent number: 5428106Abstract: High impact polystyrene resins are provided having a surprisingly good combination of toughness and gloss characteristics. Such resins contain small (i.e., 0.1 to 0.4 micron) capsule morphology rubber particles in combination with relatively small (i.e., 0.25 to 1 micron) entanglement morphology rubber particles. It has been found that such resins are capable of providing Izod impact strength values in the range of 2.5 to 3.5 ft-lb/in (133.4 to 186.7 J/m) and higher at an overall volume average rubber size of less than 0.4 micron with corresponding gloss values in excess of 90 percent.Type: GrantFiled: September 2, 1993Date of Patent: June 27, 1995Assignee: The Dow Chemical CompanyInventors: David Schrader, Mark E. Soderquist, Mark D. Heires
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Patent number: 5412036Abstract: Graft copolymerized maleimide-modified, impact resistant monovinylidene aromatic copolymer compositions have substantially improved impact strength and fatigue resistance properties when the swelling index thereof is 12 or greater and when the numerical difference in maleimide monomer content as between the grafted copolymer and matrix copolymer portions thereof differ by no more than 9 percentage points from each other. Such compositions are conveniently prepared by mass, solution or mass/suspension graft copolymerization processes and by deferring the addition of at least about 30 percent of the maleimide monomer ingredient to a point in the process after (and preferably only shortly after) phase inversion of the dissolved impact modifying rubbery polymer ingredient.Type: GrantFiled: September 27, 1993Date of Patent: May 2, 1995Assignee: The Dow Chemical CompanyInventors: Thomas D. Traugott, Shari L. Workentine
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Patent number: 5334657Abstract: A thermoformable chemical resistant polymer blend, useful in the preparation of refrigerator and freezer liners comprising:A) from 45 to 70 parts by weight impact modified monovinylidene aromatic polymer, comprising from 1 to 25 weight percent of a rubber and 75 to 99 weight percent of a monovinylidene aromatic polymer matrix having a molecular weight (Mw) from 50,000 to 400,000, said weight percents being based on the total weight of said impact modified, vinylaromatic polymer;B) from 15 to 40 parts by weight of an olefin polymer, selected from the group consisting of homopolymers of ethylene or propylene and copolymers of ethylene with one or more C.sub.4-8 .alpha.-olefins; andC) from 5 to 25 parts by weight of a compatibilizing polymer, adapted to increase interfacial adhesion between components A) and B), components A) and B) or components A), B) and C) existing in said blend as co-continuous phases, and the sum of A),B) and C) being 100 parts.Type: GrantFiled: December 18, 1992Date of Patent: August 2, 1994Assignee: The Dow Chemical CompanyInventors: Steven B. Swartzmiller, Robert J. Donald, Jeffrey E. Bonekamp
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Patent number: 5196461Abstract: Thermoplastic polymer blends comprising a major proportion by weight of certain monovinylidene aromatic copolymers and a minor proportion by weight of an acetal polymer have good processability and a beneficial combination of physical and chemical properties including thermal/dimensional stability, chemical resistance and creep resistance. Said polymer blends are suitable for use in the preparation of a variety of molded utilitarian articles having good appearance and paintability.Type: GrantFiled: September 16, 1991Date of Patent: March 23, 1993Assignee: The Dow Chemical CompanyInventors: Martin J. Guest, P. F. M. v/d Berghen, Ludo M. Aerts, Antonios Gkogkidis, Abraham F. de Bert
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Patent number: 5194494Abstract: Polymer blend compositions having an advantageous combination of low temperature toughness, solvent resistance, scratch resistance, paintability and elevated temperature resistance comprise from about 20 to about 65 weight percent of a rubber modified monovinylidene aromatic/ethylenically unsaturated nitrile/N-arylmaleimide copolymer and from about 35 to about 80 weight percent of certain selected polyester-based elastomeric thermoplastic polyurethane ingredients. The resulting polymer blend compositions are especially well suited for use in the preparation of molded articles or thermoformed sheet materials intended for use in relatively low temperature environments including, for example, in various motor vehicle and/or recreational vehicle applications, as freezer and refrigerator liners, snow removal equipment housings or accessories, and the like.Type: GrantFiled: February 23, 1990Date of Patent: March 16, 1993Assignee: The Dow Chemical CompanyInventors: David E. Henton, Duane M. Naeger, F. Michael Plaver, Robert S. Drzal
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Patent number: 5188888Abstract: A multilayered structural article having improved resistance to delamination and having a reduced coefficient of linear thermal expansion (CLTE) relative to that of the thermoplastic resin(s) employed in its preparation comprises a core layer of a highly filled composite paper having outer layers of thermoplastic resin adhered thereto.Type: GrantFiled: July 1, 1991Date of Patent: February 23, 1993Assignee: The Dow Chemical CompanyInventor: Kent B. McReynolds
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Patent number: 5091470Abstract: Thermoplastic rubber modified molding compositions containing N-phenyl maleimide, acrylonitrile, and at least one copolymerizable comonomer suitable for preparing moldings having low surface gloss.Type: GrantFiled: September 10, 1990Date of Patent: February 25, 1992Assignee: The Dow Chemical CompanyInventors: Hendrick W. Wolsink, John J. Plomer, Thomas D. Traugott
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Patent number: 5068139Abstract: A multilayered structural article having improved resistance to delamination and having a reduced coefficient of linear thermal expansion (CLTE) relative to that of the thermoplastic resin(s) employed in its preparation comprises a core layer of a highly filled composite paper having outer layers of thermoplastic resin adhered thereto.Type: GrantFiled: November 14, 1989Date of Patent: November 26, 1991Assignee: The Dow Chemical CompanyInventor: Kent B. McReynolds
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Patent number: 5055525Abstract: Polymer blend compositions having an advantageous combination of low temperature toughness, solvent resistance, scratch resistance and paintability comprise from about 19 to about 64 weight percent of a mass, solution, mass/suspension or mass/solution polymerized rubber modified monovinylidene aromatic/ethylenically unsaturated nitrile polymer; from about 35 to about 80 weight percent of certain selected polyester-based elastomeric thermoplastic polyurethane ingredients; and from about 1 to about 30 weight percent of a relatively high rubber content emulsion polymerized rubber modified graft copolymer ingredient. The resulting polymer blend compositions are especially well suited for use in the preparation of molded articles intended for use in relatively low temperature environments including, for example, in various motor vehicle and/or recreational vehicle applications, as freezer and refrigerator liners, snow removal equipment housings or accessories, and the like.Type: GrantFiled: February 23, 1990Date of Patent: October 8, 1991Assignee: The Dow Chemical CompanyInventors: David E. Henton, F. Michael Plaver, Duane M. Naeger, Robert S. Drzal
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Patent number: 5041498Abstract: Rubber modified styrene-acrylonitrile (ABS) resins are provided which have three different types of rubber particles. One particle type is a small, emulsion-produced particle and another is a large emulsion-produced particle. The third particle type is a large, mass-polymerized graft copolymer particle which comprisees as its rubbery substrate a diene polymer ingredient containing at least about 80 weight percent of a polymerized diene monomer and which constitutes no more than about 30 weight percent of the total rubber components contained within the compositions of interest. The resulting compositions have very high gloss characteristics and reduced gloss sensitivity to molding condition variations.Type: GrantFiled: January 2, 1990Date of Patent: August 20, 1991Assignee: The Dow Chemical CompanyInventors: Marie L. Hare, Patricia B. Leng, Nigel Shields, David E. Henton
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Patent number: 4946894Abstract: Rubber reinforced thermoplastic resins are provided comprising specific proportions of grafted EPDM terpolymer elastomers and grafted arcylate elastomers.Type: GrantFiled: August 15, 1988Date of Patent: August 7, 1990Assignee: The Dow Chemical CompanyInventors: David E. Henton, Douglas E. Beyer
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Patent number: 4795675Abstract: The transfer printability of fabric materials containing at least a minor proportion of cellulosic or natural proteinaceous fibers such as, for example, cotton, rayon, cellulose acetate, wool, silk, etc. is notably improved by a treatment in which said fabric material is impregnated with certain glycoside reagents. Especially preferred glycoside reagents for use in such treatment are C.sub.2 -C.sub.6 alkyl monoglucosides.Type: GrantFiled: February 12, 1988Date of Patent: January 3, 1989Assignee: Staley ContinentalInventors: Larson B. Dunn, Jr., Kenneth B. Moser, Panemangalore S. Pai
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Patent number: 4781725Abstract: The transfer printability of fabric materials containing at least a minor proportion of cellulosic or natural proteinaceous fibers such as, for example, cotton, rayon, cellulose acetate, wool, silk, etc. is notably improved by a treatment in which said fabric material is impregnated with certain glycoside reagents. Especially preferred glycoside reagents for use in such treatment are C.sub.2 -C.sub.6 alkyl monoglucosides.Type: GrantFiled: September 17, 1986Date of Patent: November 1, 1988Assignee: Staley Continental, Inc.Inventors: Larson B. Dunn, Jr., Kenneth B. Moser, Panemangalore S. Pai
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Patent number: 4780250Abstract: Substantially builder-free fine fabric detergent compositions are provided which comprise an aqueous solution containing from about 10 to 70 weight percent of a surfactant mixture consisting essentially of a 1:3 to about 10:1 weight ratio combination of a glycoside surfactant and an antistatic amine oxide surfactant.Type: GrantFiled: October 27, 1986Date of Patent: October 25, 1988Assignee: Staley Continental, Inc.Inventors: Allen D. Urfer, Gail M. Howell
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Patent number: 4780234Abstract: A homogeneous and single-phase liquid laundry detergent contains alkyl glycoside nonionic surfactant and a detergent builder having a water solubility at 25.degree. C. of less than about 55 weight percent.Type: GrantFiled: October 26, 1987Date of Patent: October 25, 1988Assignee: Staley Continental, Inc.Inventors: Arshad H. Malik, Robert S. McDaniel, Allen D. Urfer, Gail M. Howell
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Patent number: 4775545Abstract: A sweetened fruit having a low water activity relative to its moisture content is prepared by bathing a dry fruit in an aqueous sugar solution having about 70 to 95 weight percent sugar, at least about 75 weight percent of which is fructose.Type: GrantFiled: March 12, 1987Date of Patent: October 4, 1988Assignee: Staley Continental, Inc.Inventors: Michael E. Augustine, Jane L. Dunn, Donald W. Lillard, Carol A. O'Brien, Walter C. Yackel
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Patent number: 4769081Abstract: The rate and ease of water dispersibility and/or water solubility of powdered or granular starch materials are substantially enhanced by the incorporation therein of a small but effective amount of a glycoside surfactant ingredient.Type: GrantFiled: September 18, 1987Date of Patent: September 6, 1988Assignee: A. E. Staley Manufacturing Division of Staley Continental, Inc.Inventor: Stephen L. Maher
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Patent number: H561Abstract: A cold process fruit filling for pastry and bakery products is prepared ug two different starch components. The first starch component is a cold water swelling granular starch, while the second starch component is a pregelatinized starch. Such a combination of starches provided a means to produce a fruit filling without heating. The filling possesses heat stability to maintain the desired properties when the bakery product containing the filling is cooked.Type: GrantFiled: June 28, 1988Date of Patent: December 6, 1988Assignee: A. E. Staley Manufacturing Division of Staley Continental, Inc.Inventors: Cheryl C. Brown, John H. Woerman