Patents Represented by Attorney James W. Weinberger
  • Patent number: 4769225
    Abstract: The reversible reaction M+x/2 H.sub.2 .rarw..fwdarw.MH.sub.x, wherein M is a reversible metal hydride former that forms a hydride MH.sub.x in the presence of H.sub.2, generally used to store and recall H.sub.2, is found to proceed under an inert liquid, thereby reducing contamination, providing better temperature control, providing in situ mobility of the reactants, and increasing flexibility in process design. Thus, a slurry of particles of a metal hydride former with an inert solvent is subjected to a temperature and pressure controlled atmosphere containing H.sub.2, to store hydrogen and to release previously stored hydrogen. The direction of the flow of the H.sub.2 through the liquid is dependent upon the H.sub.2 pressure in the gas phase at a given temperature. When the actual H.sub.2 pressure is above the equilibrium absorption pressure of the respective hydride the reaction proceeds to the right, i.e., the metal hydride is formed and hydrogen is stored in the solid particles.
    Type: Grant
    Filed: February 22, 1985
    Date of Patent: September 6, 1988
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: James J. Reilly, Edward W. Grohse, John R. Johnson, Warren E. Winsche, deceased
  • Patent number: 4764627
    Abstract: A process of producing furan and derivatives thereof is disclosed. The process includes generating furfural aldehyde vapors and then passing those vapors over a zeolite catalyst at a temperature and for a residence time effective to decarbonylate the furfural aldehydes to form furans and derivatives thereof. The resultant furan vapors and derivatives are then separated. In a preferred form, the furfural aldehyde vapors are generated during the process of converting biomass materials to liquid and gaseous fuels.
    Type: Grant
    Filed: April 6, 1987
    Date of Patent: August 16, 1988
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: James P. Diebold, Robert J. Evans
  • Patent number: 4762694
    Abstract: A process for extracting transition metals and particularly cobalt and manganese together with iron, copper and nickel from low grade ores (including ocean-floor nodules) by converting the metal oxides or other compositions to chlorides in a molten salt, and subsequently using a combination of selective distillation at temperatures below about 500.degree. C., electrolysis at a voltage not more negative than about -1.5 volt versus Ag/AgCl, and precipitation to separate the desired manganese and cobalt salts from other metals and provide cobalt and manganese in metallic forms or compositions from which these metals may be more easily recovered.
    Type: Grant
    Filed: August 21, 1987
    Date of Patent: August 9, 1988
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Victor A. Maroni, Samuel von Winbush
  • Patent number: 4762298
    Abstract: A support and maneuvering device includes an elongated flexible inflatable enclosure having a fixed end and a movable end. The movable end is collapsible toward the fixed end to a contracted position when the enclosure is in a noninflated condition. Upon inflation, the movable end is movable away from the fixed end to an extended position. The movable end includes means for mounting an article such as a solar reflector thereon. The device also includes a plurality of position controlling means disposed about the movable end to effect adjusting movement of portions thereof by predetermined amounts and for controlling an angle at which the article disposed at the movable end is oriented. The plurality of position controlling means limits a suitable number degrees of freedom of the movable end for transmitting a steering motion thereto and for controlling the position thereof.
    Type: Grant
    Filed: March 23, 1987
    Date of Patent: August 9, 1988
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventor: Richard L. Wood
  • Patent number: 4761302
    Abstract: A method is disclosed for producing fluorine-containing amorphous semiconductor material, preferably comprising amorphous silicon. The method includes depositing amorphous thin-film material onto a substrate while introducing xenon fluoride during the film deposition process.
    Type: Grant
    Filed: May 1, 1987
    Date of Patent: August 2, 1988
    Assignee: The United States Department of Energy
    Inventor: Raoul B. Weil
  • Patent number: 4758345
    Abstract: The present invention relates to an anaerobic bacterial culture of Clostridium sp. ATCC No. 53464 which solubilizes lead oxide under anaerobic conditions in coal and industrial wastes and therefore presents a method of removing lead from such wastes before they are dumped into the environment. The rate of lead dissolution during logarithmic growth of the bacteria in 40 ml medium containing 3.32 .mu.moles of lead as lead oxide was 0.042 .mu.moles ml.sup.-1 hr.sup.-1. Dissolution of lead oxide by the bacterial isolate is due to the production of metabolites and acidity in the culture medium. The major metabolites are acetic, butyric and lactic acid. Clostridium sp. ATCC No. 53464 can be used in the recovery of strategic metals from ores and wastes and also for the production of lactic acid for commercial purposes. The process yields large quantities of lactic acid as well as lead complexed in a stable form with said acids.
    Type: Grant
    Filed: April 16, 1987
    Date of Patent: July 19, 1988
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Arokiasamy J. Francis, Cleveland Dodge, Krishnachetty Chendrayan, Helen L. Quinby
  • Patent number: 4756747
    Abstract: Amorphous metallic precipitates having the formula (M.sub.1).sub.a (M.sub.2).sub.b wherein M.sub.1 is at least one transition metal, M.sub.2 is at least one main group metal and the integers "a" and "b" provide stoichiometric balance; the precipitates having a degree of local order characteristic of chemical compounds from the precipitation process and useful electrical and mechanical properties.
    Type: Grant
    Filed: July 24, 1986
    Date of Patent: July 12, 1988
    Assignee: The United States of America as represented by the Department of Energy
    Inventor: Robert C. Haushalter
  • Patent number: 4749489
    Abstract: A semipermeable, inorganic membrane is disclosed; the membrane is prepared from a phosphazene polymer and, by the selective substitution of the constituent groups bound to the phosphorous in the polymer structure, the selective passage of fluid from a feedstream can be controlled. Resistance to high temperatures and harsh chemical environments is observed in the use of the phosphazene polymers as semipermeable membranes.
    Type: Grant
    Filed: May 30, 1986
    Date of Patent: June 7, 1988
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Charles A. Allen, Robert R. McCaffrey, Daniel G. Cummings, Alan E. Grey, Janine S. Jessup, Richard E. McAtee
  • Patent number: 4741857
    Abstract: A method for removing acidic contaminants from neutral mono and bifunctional organophosphorous extractants by contacting the extractant with a macroporous cation exchange resin in the H.sup.+ state followed by contact with a macroporous anion exchange resin in the OH.sup.- state, whereupon the resins take up the acidic contaminants from the extractant, purifying the extractant and improving its extraction capability.
    Type: Grant
    Filed: October 6, 1986
    Date of Patent: May 3, 1988
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: E. Philip Horwitz, Ralph C. Gatrone, Renato Chiarizia
  • Patent number: 4729954
    Abstract: Disclosed is recombinant plasmid pLS101, consisting essentially of a 2.0 Kb malM gene fragment ligated to a 4.4 Kb T.sub.c r DNA fragment, which is particularly useful for transforming Gram-positive bacteria. This plasmid contains at least four restriction sites suitable for inserting exogeneous gene sequences. Also disclosed is a method for plasmid isolation by penicillin selection, as well as processes for enrichment of recombinant plasmids in Gram-positive bacterial systems.
    Type: Grant
    Filed: February 19, 1985
    Date of Patent: March 8, 1988
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Sanford A. Lacks, Tanjore S. Balganesh
  • Patent number: 4719383
    Abstract: An acoustic shear wave resonator comprising a piezoelectric film having its C-axis substantially inclined from the film normal such that the shear wave coupling coefficient significantly exceeds the longitudinal wave coupling coefficient, whereby the film is capable of shear wave resonance, and means for exciting said film to resonate. The film is prepared by deposition in a dc planar magnetron sputtering system to which a supplemental electric field is applied. The resonator structure may also include a semiconductor material having a positive temperature coefficient of resonance such that the resonator has a temperature coefficient of resonance approaching 0 ppm/.degree.C.
    Type: Grant
    Filed: September 30, 1986
    Date of Patent: January 12, 1988
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Jin S. Wang, Kenneth M. Lakin, Allen R. Landin
  • Patent number: 4718361
    Abstract: A high temperature combustion process for an organic fuel containing sulfur n which the nitrogen of air is replaced by carbon dioxide for combination with oxygen with the ratio of CO.sub.2 /O.sub.2 being controlled to generate combustion temperatures above 2000 K. for a gas-gas reaction with SO.sub.2 and an alkali metal compound to produce a sulfate and in which a portion of the carbon-dioxide rich gas is recycled for mixing with oxygen and/or for injection as a cooling gas upstream from heating exchangers to limit fouling of the exchangers, with the remaining carbon-dioxide rich gas being available as a source of CO.sub.2 for oil recovery and other purposes.
    Type: Grant
    Filed: November 21, 1986
    Date of Patent: January 12, 1988
    Assignee: The United States of America as represented by the Department of Energy
    Inventor: Gregory F. Berry
  • Patent number: 4709848
    Abstract: 1. A method of making a fuel-containing structure for nuclear reactors, comprising providing an assembly comprising a plurality of fuel units; each fuel unit consisting of a core plate containing thermal-neutron-fissionable material, sheets of cladding metal on its bottom and top surfaces, said cladding sheets being of greater width and length than said core plates whereby recesses are formed at the ends and sides of said core plate, and end pieces and first side pieces of cladding metal of the same thickness as the core plate positioned in said recesses, the assembly further comprising a plurality of second side pieces of cladding metal engaging the cladding sheets so as to space the fuel units from one another, and a plurality of filler plates of an acid-dissolvable nonresilient material whose melting point is above 2000.degree. F.
    Type: Grant
    Filed: October 2, 1957
    Date of Patent: December 1, 1987
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Henry A. Saller, deceased, Edwin S. Hodge, Stanley J. Paprocki, Russell W. Dayton
  • Patent number: 4707322
    Abstract: Beryllium-7 labeled carbon particles made from the proton irradiation of carbon materials, preferably from dry carbon black are disclosed. Such particles are useful as gamma emitting radiotracers.
    Type: Grant
    Filed: April 29, 1985
    Date of Patent: November 17, 1987
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Powell Richards, Leonard F. Mausner, Thomas F. Prach
  • Patent number: 4702853
    Abstract: A thermal energy storge composition is disclosed. The composition comprises a non-chloride hydrate having a phase change transition temperature in the range of 70.degree.-95.degree. F. and a latent heat of transformation of at least about 35 calories/gram.
    Type: Grant
    Filed: October 6, 1986
    Date of Patent: October 27, 1987
    Assignee: The United States of America as represented by the Department of Energy
    Inventors: David K. Benson, Richard W. Burrows
  • Patent number: 4687570
    Abstract: This invention relates to a process for converting solid carbonaceous material, such as coal, to liquid and gaseous hydrocarbons utilizing methane, generally at a residence time of about 20-120 minutes at a temperature of 250.degree.-750.degree. C., preferably 350.degree.-450.degree. C., pressurized up to 6000 psi, and preferably in the 1000-2500 psi range, preferably directly utilizing methane 50-100% by volume in a mix of methane and hydrogen. A hydrogen donor solvent or liquid vehicle such as tetralin, tetrahydroquinoline, piperidine, and pyrolidine may be used in a slurry mix where the solvent feed is 0-100% by weight of the coal or carbonaceous feed. Carbonaceous feed material can either be natural, such as coal, wood, oil shale, petroleum, tar sands, etc., or man-made residual oils, tars, and heavy hydrocarbon residues from other processing systems.
    Type: Grant
    Filed: June 19, 1985
    Date of Patent: August 18, 1987
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Muthu S. Sundaram, Meyer Steinberg
  • Patent number: 4686979
    Abstract: Removal of abnormal human tissue with reduced thermal damage is achieved by selecting a laser having a wavelength in the order of 290-400 nm, orienting a laser-transmitting glass member toward the abnormal tissue and directing the laser through the glass member at power densities, pulse rates, and times sufficient to cause multiphoton absorption and bond breaking by Coulomb repulsion rather than thermal destruction. The glass member may include a laser beam concentrator provided by a lens or cone at the tissue-treatment end to increase the beam energy per unit area and reduce the treatment area.
    Type: Grant
    Filed: February 19, 1985
    Date of Patent: August 18, 1987
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Dieter M. Gruen, Charles E. Young, Michael J. Pellin
  • Patent number: 4686833
    Abstract: A method of forming clathrate ice in a supercooled water-based liquid contained in a vessel is disclosed. Initially, an oscillator device is located in the liquid in the vessel. The oscillator device is then oscillated ultrasonically so that small crystals are formed in the liquid. These small crystals serve as seed crystals for ice formation in the liquid and thereby prevent supercooling of the liquid. Preferably, the oscillating device is controlled by a thermostat which initiates operation of the oscillator device when the temperature of the liquid is lowered to the freezing point. Thereafter, the operation of the oscillator device is terminated when ice is sensed in the liquid by an ice sensor.
    Type: Grant
    Filed: July 28, 1986
    Date of Patent: August 18, 1987
    Assignee: The United States of America as represented by the United State Department of Energy
    Inventors: Toshiyuki Hino, Anthony J. Gorski
  • Patent number: H410
    Abstract: A magnetohydrodynamic (MHD) power generating system in which ionized combustion gases with slag and seed are discharged from an MHD combustor and pressurized high temperature inlet air is introduced into the combustor for supporting fuel combustion at high temperatures necessary to ionize the combustion gases, and including a heat exchanger in the form of a continuous loop with a circulating heat transfer liquid such as copper oxide. The heat exchanger has an upper horizontal channel for providing direct contact between the heat transfer liquid and the combustion gases to cool the gases and condense the slag which thereupon floats on the heat transfer liquid and can be removed from the channel, and a lower horizontal channel for providing direct contact between the heat transfer liquid and pressurized air for preheating the inlet air. The system further includes a seed separator downstream of the heat exchanger.
    Type: Grant
    Filed: November 2, 1981
    Date of Patent: January 5, 1988
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Gregory F. Berry, Vladimir Minkov, Michael Petrick
  • Patent number: H505
    Abstract: A stable boronated (.sup.10 B-labeled) compound, sodium mercaptoundecahydrododecaborate is infused in the form of the disulfide dimer, [.sup.10 B]Na.sub.4 B.sub.24 H.sub.22 S.sub.2, at a dose of about 200 .mu.g .sup.10 B per gm body weight. The infusion is performed into the blood or peritoneal cavity of the patient slowly over a period of many days, perhaps one week or more, at the rate of roughly 1 .mu.g .sup.10 B per gm body weight per hour. Use of this particular boronated dimer in the manner or similarly to the manner so described permits radiotherapeutically effective amounts of boron to accumulate in tumors to be treated by boron neutron capture radiation therapy and also permits sufficient retention of boron in tumor after the cessation of the slow infusion, so as to allow the blood concentration of .sup.10 B to drop or to be reduced artificially to a radiotherapeutically effective level, less than one-half of the concentration of .sup.10 B in the tumor.
    Type: Grant
    Filed: March 11, 1986
    Date of Patent: August 2, 1988
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Daniel N. Slatkin, Peggy L. Micca, Ralph G. Fairchild