Abstract: A diesel engine fuel is produced from Fischer-Tropsch wax by separating a light density fraction, e.g., C.sub.5 -C.sub.15, preferably C.sub.7 -C.sub.14 cut having at least 80+ wt % n-paraffins, no more than 5000 ppm alcohols as oxygen, less than 10 wt % olefins, twice aromatics and very low sulfur and nitrogen.
Type:
Grant
Filed:
August 2, 1996
Date of Patent:
September 15, 1998
Assignee:
Exxon Research and Engineering Company
Inventors:
Robert Jay Wittenbrink, Richard Frank Bauman, Daniel Francis Ryan, Paul Joseph Berlowitz
Abstract: A slurry hydrocarbon synthesis process employs a slurry filtration vessel external of the slurry reactor. Slurry from the reactor is passed through one or more gas and solids disengaging zones, one or more of which may be present in the reactor and vessel, to reduce the gas and solids content of the slurry before it contacts the filter in the vessel. The filter separates the slurry hydrocarbon liquid from the gas and solids as a filtrate which is sent to upgrading. Valves in gas and fluid conduits enable the filtration vessel to be isolated from the reactor for maintenance, to replace filters and to aid in controlling slurry flow through the vessel. A hydrogen rich gas may be injected into the filtration vessel to prevent catalyst deactivation. Slurry is hydraulically circulated between the reactor and vessel due to density differences while the reactor is operating.
Abstract: Clean distillate useful as a jet fuel or jet blending stock is produced from Fischer-Tropsch wax by separating wax into heavier and lighter fractions; further separating the lighter fraction and hydroisomerizing the heavier fraction and that portion of the light fraction above about 475.degree. F. The isomerized product is blended with the untreated portion of the lighter fraction to produce high quality, clean, jet fuel.
Type:
Grant
Filed:
February 7, 1997
Date of Patent:
June 16, 1998
Assignee:
Exxon Research and Engineering Company
Inventors:
Robert J. Wittenbrink, Paul J. Berlowitz, Bruce R. Cook
Abstract: Applicant has discovered a new zeolite containing composition and a process for preparing the same. The composition is unique in that the zeolite crystals making up one layer of the composition pack in a manner such that the composition is essentially continuous with no large scale voids even when the zeolite layer is <10 .mu.m thick. Thus, the present invention is directed toward a composition comprised of a porous substrate and a layer of zeolite crystals wherein said layer of zeolite crystals is a polycrystalline layer with at least 99% of said zeolite crystals having at least one point between adjacent crystals that is .ltoreq.20 .ANG. and wherein at least 90% of said crystals have widths of from about 0.2 to about 100 microns (preferably about 2 to about 50 microns) and wherein at least 75% of said crystals have a thickness of within 20% of the average crystal thickness. Preferably the composition has at most 1 Volume % voids in the zeolite layer. Use of the composition is also described.
Abstract: Hydroconversion of paraffin containing hydrocarbon feeds is effected over a supported Group VIII and Group VI metal containing catalyst also containing a hydrocracking suppressant such as a Group IB metal, wherein the catalyst is preferably prepared by fixing the Group IB metal on to the support prior to incorporating the Group VI metal on to the support.
Type:
Grant
Filed:
November 5, 1996
Date of Patent:
May 12, 1998
Assignee:
Exxon Research and Engineering Company
Inventors:
Robert J. Wittenbrink, Daniel F. Ryan, William C. Baird, Jr., Kenneth L. Riley, Jack W. Johnson
Abstract: A bioremediation process is provided comprising adding cedar pieces to a hydrocarbon contaminated soil in an amount ranging from about 5 to about 15 wt. % based on the weight of the contaminated soil and applying sufficient nitrogen and phosphorous nutrients to the soil to provide a C:N:P ratio in the range of about 100:10:1 to about 100:1:0:1.
Abstract: One embodiment of the present invention provides compounds comprising an adduct of urea with a non-ionic surfactant. Another embodiment of the present invention, there is provided a composition suitable for enhancing the bioremediation of contaminated soils and water which comprises at least one adduct of urea with a non-ionic surfactant, preferably in combination with a phosphorous source.
Type:
Grant
Filed:
September 2, 1994
Date of Patent:
January 6, 1998
Assignee:
Exxon Research and Engineering Company
Inventors:
Ramesh Varadaraj, Cornelius Hendrick Brons
Abstract: The present invention provides an improved surfactant formulation for enhancing the extent of a bioremediation of hydrocarbon contaminated soil, especially hydrocarbon contaminated soil that has been subjected to nutrient assisted bioremediation previously. The formulation includes a mixture of methadienes and methadiene alcohols, certain surfactants and a hydrocarbon solvent.
Abstract: The present invention provides for microporous ceramic materials having a surface area in excess of 100 m.sup.2 /gm and an open microporous cell structure wherein the micropores have a mean width of less than 20 Angstroms and wherein said microporous structure comprises a volume of greater than about 0.05 cm.sup.3 /gm of the ceramic. The pyrolysis product of ceramic precursor oligomers or polymers having a number average molecular weight in the range of from about 200 to about 100,000 g/mole in an ammonia atmosphere at temperatures of up to less than about 1200.degree. C. gives rise to the microporous ceramics of the invention. Also provided is a process for the preparation of the microporous ceramics of the invention involving pyrolysis of the ceramic precursor under controlled conditions of heating and with intermediate hold times, up to temperatures of less than 1200.degree. C., preferably less than 1000.degree. C., to form a microporous ceramic product.
Type:
Grant
Filed:
February 10, 1995
Date of Patent:
December 9, 1997
Assignee:
Exxon Research & Engineering Company
Inventors:
John Pickett Dismukes, John Stewart Bradley, Jack Wayne Johnson, Edward William Corcoran, Jr.
Abstract: Clean distillate useful as a diesel fuel or diesel blending stock is produced from Fischer-Tropsch wax by separating wax into heavier and lighter fractions; further separating the lighter fraction and hydroisomerizing the heavier fraction and that portion of the light fraction below about 500.degree. F. The isomerized product is blended with the untreated portion of the lighter fraction.
Type:
Grant
Filed:
October 17, 1995
Date of Patent:
November 18, 1997
Assignee:
Exxon Research & Engineering Company
Inventors:
Paul Joseph Berlowitz, Bruce Randall Cook, Robert J. Wittenbrink
Abstract: In one embodiment of the present invention, there is provided a composition comprising a major amount of an ethylene alpha olefin copolymer and a minor amount of a lower molecular weight ethylene alpha olefin or a neutralized sulfonated ethylene alpha olefin.
Type:
Grant
Filed:
July 7, 1995
Date of Patent:
October 14, 1997
Assignee:
Exxon Research and Engineering Company
Inventors:
Dennis George Peiffer, James Joseph Chludzinski, Ching-Tai Lue, Thomas Craig Erderly
Abstract: The instant invention is directed toward a process for enhancing the permselective properties, selectively sealing defects and pinholes, controllably altering the pore size and stabilizing the permselective properties of articles having apperatures therein comprising the steps of: simultaneously contacting an article having a first and second surface, said first and second surfaces being capable of passing ozone and silicon compounds therethrough and said first and second surfaces being oriented such that said silicon compounds and ozone can react across said first and second surfaces, with ozone on said first surface and a silicon compound on said second surface and wherein said contacting is conducted for a time and at a temperature and pressure sufficient to allow said ozone and said silicon compound to form a silicon oxide.
Type:
Grant
Filed:
July 8, 1994
Date of Patent:
September 30, 1997
Assignee:
Exxon Research & Engineering Company
Inventors:
James Alexander McHenry, Harry William Deckman, Edward William Corcoran, Jr., Wenyih Frank Lai, Horst Witzke
Abstract: A compacted, single phase or multiphase composite article. Particles for use in the compacted article are produced by providing a precursor compound containing at least one or at least two metals and a coordinating ligand. The compound is heated to remove the coordinating ligand therefrom and increase the surface area thereof. It may then be reacted so that at least one metal forms a metal-containing compound. The particles may be consolidated to form a compacted article, and for this purpose may be used in combination with graphite or diamonds. The metal-containing compound may be a nonmetallic compound including carbides, nitrides and carbonitrides of a refractory metal, such as tungsten. The metal-containing compound may be dispersed in a metal matrix, such as iron, nickel or cobalt. The dispersed nonmetallic compound particles are no larger than about 0.1 micron in particle size and have a volume fraction greater than about 0.15 within the metal matrix.
Type:
Grant
Filed:
November 17, 1995
Date of Patent:
September 9, 1997
Assignee:
Exxon Research & Engineering Company
Inventors:
Richard S. Polizzotti, Larry E. McCandlish, Edwin L. Kugler
Abstract: Nickel-copper catalysts supported on an acidic carrier, preferably containing a binder, are used to hydroisomerize paraffins, particularly Fischer-Tropsch paraffins, boiling at 350.degree. F.+ into lighter, more valuable products.
Type:
Grant
Filed:
June 25, 1996
Date of Patent:
August 26, 1997
Assignee:
Exxon Research and Engineering Company
Inventors:
Robert Jay Wittenbrink, Stephen Mark Davis, Kenneth Lloyd Riley
Abstract: A high strength steel composition comprising ferrite and martensite/banite phases, the ferrite phase having primarily vanadium and mobium carbide or carbonitride precipitates, is prepared by a first rolling above the austenite recrystallization temperature; a second rolling below the anstenite recrystallization temperature; a third rolling between the Ar.sub.3 and Ar.sub.1 transformation points, and water cooling to below about 400.degree. C.
Abstract: The invention is directed to a catalyst composition comprising a Group VIII metal, preferably a Group VIII noble metal, and a zirconia support impregnated with silica and tungsten oxide and its use in an isomerization process.
Type:
Grant
Filed:
April 21, 1995
Date of Patent:
July 15, 1997
Assignee:
Exxon Research & Engineering Company
Inventors:
Stuart L. Soled, William E. Gates, Enrique Iglesia
Abstract: The present invention is directed toward a catalyst composition prepared by a process comprising: (a) impregnating an oxide precursor selected from the group consisting of rare earth oxide precursors, yttria precursors and mixtures thereof, onto an inorganic refractory oxide support; (b) drying said support at a temperature of about 100.degree. to about 120.degree. C. followed by calcining said support at a temperature of about 400.degree. to about 600.degree. C.; and (c) compositing or depositing on said support of step (b), a catalyst precursor salt represented by (ML)(Mo.sub.y W.sub.1-y O.sub.4).sub.a wherein M comprises Cr and/or one or more divalent promoter metals selected from the group consisting of Mn, Fe, Co, Ni, Cu, Zn and mixtures thereof, wherein y is any value ranging from 0 to 1, and wherein L is one or more neutral, nitrogen-containing ligands at least one of which is a chelating polydentate ligand; a=1 when chromium is not one of the promoter metals and 0.5.ltoreq.a.ltoreq.
Type:
Grant
Filed:
June 2, 1995
Date of Patent:
July 15, 1997
Assignee:
Exxon Research and Engineering Company
Inventors:
Teh Chung Ho, Stuart Leon Soled, Sabato Miseo, Gary Brice McVicker, Michel Daage, Viktor Buchholz
Abstract: The present invention provides for microporous ceramic materials having a surface area in excess of 70 m.sup.2 /gm and an open microporous cell structure wherein the micropores have a mean width of less than 20 Angstroms and wherein said microporous structure comprises a volume of greater than about 0.03 cm.sup.3 /gm of the ceramic. The invention also provides for a preceramic composite intermediate composition comprising a mixture of a ceramic precursor and finely divided silicon carbide or silicon nitride, whose pyrolysis product in inert atmosphere or in an ammonia atmosphere at temperatures of up to less than about 1100.degree. C. gives rise to the microporous ceramics of the invention. Also provided is a process for the preparation of the microporous ceramics of the invention involving pyrolysis of the ceramic intermediate under controlled conditions of heating up to temperatures of less than 1100.degree. C. to form a microporous ceramic product.
Type:
Grant
Filed:
May 24, 1994
Date of Patent:
July 1, 1997
Assignee:
Exxon Research and Engineering Company
Inventors:
John Pickett Dismukes, Jack Wayne Johnson, Edward William Corcoran, Jr., Joseph Vallone, James J. Pizzulli, Jr., Michael P. Anderson
Abstract: The present invention provides an enhanced biodegradation process by applying to petroleum contaminated soil or water essential microbial nutrients in a form capable of releasing the nutrients over time at a rate which, at 25.degree. C., is substantially linear. Importantly, in a preferred embodiment of the present invention, the microbial nutrients that are applied to the soil or water are in a form such that the release of nutrients at 38.degree. C. will be greater than that at 25.degree. C. by a factor of about 2.5 to 6.0, and preferably from a factor of about 3 to about 5.0.