Patents Represented by Attorney Jeremy J. Kliebert
  • Patent number: 7425258
    Abstract: The present invention relates to a process for selectively producing C3 olefins from a catalytically cracked or thermally cracked naphtha stream. The process is practiced by recycling a C6 rich fraction of the catalytic naphtha product to the riser upstream the feed injection point, to a parallel riser, to the spent catalyst stripper, and/or to the reactor dilute phase immediately above the stripper.
    Type: Grant
    Filed: January 20, 2004
    Date of Patent: September 16, 2008
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Tan Jen Chen, Brian Erik Henry, Paul F Keusenkothen, Philip A. Ruziska
  • Patent number: 7381354
    Abstract: Flame retardant formulations comprised of at least one bromine-containing polyol are produced by a process which comprises: A) heating a mixture formed from components comprised of (i) tetrabromophthalic anhydride, (ii) at least one aliphatic polyol, and (iii) at least one liquid straight chain aliphatic diester of a straight-chain alkane dicarboxylic acid to form an intermediate composition; and B) contacting all or a portion of the intermediate composition one or more times with (iv) at least one alkylene oxide that results in the formation of a liquid product formulation, and optionally, removing any excess alkylene oxide present; the amounts of (i), (ii), (iii), and (iv) used being proportioned to form a formulation having a bromine content of at least about 40 wt %, a viscosity at 25° C. of about 20,000 cps or less, and an acid number as determinable by aqueous sodium hydroxide titration and expressed in terms of potassium hydroxide, of less than about 1 milligram of KOH per gram of the formulation.
    Type: Grant
    Filed: May 21, 2007
    Date of Patent: June 3, 2008
    Assignee: Albemarle Corporation
    Inventors: Elbert F. Feske, Nelson E. Clark, Arthur G. Mack, Jeffrey Todd Aplin
  • Patent number: 7297306
    Abstract: A new class of amines is incorporated into phtopolymerizable systems employing type I or type II photoinitiators. These amines are trialkylamines having a total of 10 to about 36 carbon atoms in the molecule and wherein at least one alkyl group has a chain length of at least 8 carbon atoms. Preferably, one or two of the alkyl groups are methyl or ethyl or one of each. Short chain amines as defined herein provide synergistic results when used with such trialkylamines.
    Type: Grant
    Filed: April 24, 2003
    Date of Patent: November 20, 2007
    Assignee: Albemarle Corporation
    Inventors: John G. Santobianco, Chau K. Nguyen, Charles A. Brady
  • Patent number: 7288677
    Abstract: This invention provides aromatic diimines which have imino hydrocarbylidene groups with at least two carbon atoms, and aromatic secondary diamines which have amino hydrocarbyl groups with at least two carbon atoms. Both the aromatic diimines and the aromatic secondary diamines either are in the form of one phenyl ring, or are in the form of two phenyl rings connected by an alkylene bridge; each position ortho to an imino group or an amino group bears a hydrocarbyl group. When in the form of one phenyl ring, there are two imino groups on the ring or two amino groups on the ring; the imino groups or amino groups are meta or para relative to each other. When in the form of two phenyl rings connected by an alkylene bridge, there is either one imino group or one amino group on each phenyl ring. Also provided are processes for forming diimines and secondary diamines.
    Type: Grant
    Filed: March 27, 2006
    Date of Patent: October 30, 2007
    Assignee: Albemarle Corporation
    Inventors: John Y. Lee, Paul L. Wiggins, Judit Orgad, Mahmood Sabahi, Vernon O. Brandt
  • Patent number: 7270739
    Abstract: The present invention relates to a process for selectively producing C3 olefins from a catalytically cracked or thermally cracked naphtha stream by fractionating the naphtha feed to obtain at least a C6 rich fraction and feeding the C6 rich fraction into a reaction stage at a point wherein the residence time of the C6 rich fraction is minimized.
    Type: Grant
    Filed: January 20, 2004
    Date of Patent: September 18, 2007
    Assignee: Exxonmobil Research and Engineering Company
    Inventors: Tan Jen Chen, Brian Erik Henry, Paul F Keusenkothen, Philip A. Ruziska
  • Patent number: 7267759
    Abstract: The present invention relates to a process for selectively producing C3 olefins from a catalytically cracked or thermally cracked naphtha stream by fractionating the naphtha feed to obtain a C6 fraction and feeding the C6 fraction either in the riser downstream of the injection point for the reminder of the naphtha feed, in the stripper, and/or in the dilute phase immediately downstream or above the stripper of a process unit.
    Type: Grant
    Filed: January 20, 2004
    Date of Patent: September 11, 2007
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Tan Jen Chen, Brian Erik Henry, Paul F Keusenkothen, Philip A. Ruziska
  • Patent number: 7261805
    Abstract: A process for upgrading a hydrocarbon feedstock containing waxy components and having an end boiling point exceeding 650° F., which includes contacting the feedstock at superatmospheric hydrogen partial pressure with an isomerization dewaxing catalyst that includes ZSM-48 and contacting the feedstock with a hydrocracking catalyst to produce an upgraded product with a reduced wax content. Each catalyst is present in an amount sufficient to reduce the cloud point and the pour point of the feedstock at a conversion of greater than about 10%, and an overall distillate yield of greater than about 10% results from the process.
    Type: Grant
    Filed: May 2, 2003
    Date of Patent: August 28, 2007
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Michael T. Grove, Randall D. Partridge, Terry E. Helton, David A. Pappal, Philip J. Angevine, Dominick N. Mazzone
  • Patent number: 7258823
    Abstract: Flame retardant formulations comprised of at least one bromine-containing polyol are produced by a process which comprises: A) heating a mixture formed from components comprised of (i) tetrabromophthalic anhydride, (ii) at least one aliphatic polyol, and (iii) at least one liquid straight chain aliphatic diester of a straight-chain alkane dicarboxylic acid to form an intermediate composition; and B) contacting all or a portion of the intermediate composition one or more times with (iv) at least one alkylene oxide that results in the formation of a liquid product formulation, and optionally, removing any excess alkylene oxide present; the amounts of (i), (ii), (iii), and (iv) used being proportioned to form a formulation having a bromine content of at least about 40 wt %, a viscosity at 25° C. of about 20,000 cps or less, and an acid number as determinable by aqueous sodium hydroxide titration and expressed in terms of potassium hydroxide, of less than about 1 milligram of KOH per gram of the formulation.
    Type: Grant
    Filed: May 20, 2004
    Date of Patent: August 21, 2007
    Assignee: Albemarle Corporation
    Inventors: Elbert F. Feske, Nelson E. Clark, Arthur G. Mack, Jeffrey Todd Aplin
  • Patent number: 7195782
    Abstract: Described is a process of producing a concentrated liquid biocide formulation. Mixed together are (a) bromine chloride or bromine and (b) an aqueous solution of alkali metal salt of sulfamic acid having a pH of at least about 7, in amounts such that (i) the active bromine content of the solution is at least about 100,000 ppm (wt/wt), and (ii) the atom ratio of nitrogen to active bromine from (a) and (b) is greater than 1 when bromine is used and is greater than 0.93 when bromine chloride is used. Use of bromine chloride as the source of the active bromine in the process is preferred because in the resulting aqueous compositions, all of the bromine of the bromine chloride is made available as active bromine in solution. In other words, the chlorine of the bromine chloride is converted in the process to dissolved alkali metal chloride salt, thereby liberating all of the bromine in the biocidal composition as active bromine capable of providing biocidal activity.
    Type: Grant
    Filed: October 10, 2002
    Date of Patent: March 27, 2007
    Assignee: Albemarle Corporation
    Inventors: Robert M. Moore, Christopher J. Nalepa
  • Patent number: 7182966
    Abstract: In the processing of poultry, equipment, instruments, apparatus and/or water used in such processing, and/or carcasses and/or parts of poultry resulting from the processing of poultry, are disinfected with aqueous solutions of certain halogen-based microbiocides, especially certain bromine-based microbiocides. Described are the particular microbiocides used and the substantial advantages of using such materials, in some cases as concentrated solutions and in other cases as dilute solutions.
    Type: Grant
    Filed: April 11, 2005
    Date of Patent: February 27, 2007
    Assignee: Albemarle Corporation
    Inventor: Jonathan N. Howarth
  • Patent number: 7172782
    Abstract: A method of controlling microbial contamination of poultry carcasses in the processing of poultry as food products is described. The method comprises contacting the carcasses with an aqueous medium containing an effective microbial inhibiting amount of active bromine resulting from the addition to the medium of (i) at least one 1,3-dibromo-5,5-dialkylhydantoin in which one of the alkyl groups is a methyl group and the other alkyl group contains in the range of 1 to about 4 carbon atoms or (ii) a solution thereof, or (iii) both of (i) and (ii). Such contacting inhibits contamination of the carcasses by microorganisms, even at least some bacteria that are resistant to antibiotics or antibacterials. Also described are improvements in a poultry chill tank containing an aqueous medium and a plurality of poultry carcasses in contact with the medium.
    Type: Grant
    Filed: July 12, 2005
    Date of Patent: February 6, 2007
    Assignee: Albemarle Corporation
    Inventor: Jonathan N. Howarth
  • Patent number: 7166756
    Abstract: The present invention is directed at a process to isomerize C10+ hydrocarbon feedstreams by contacting a C10+ hydrocarbon feedstream with a steamed catalyst.
    Type: Grant
    Filed: November 25, 2003
    Date of Patent: January 23, 2007
    Assignee: Exxonmobil Research and Engineering Company
    Inventors: Madhav Acharya, David L. Stern
  • Patent number: 7160437
    Abstract: The present invention relates to a method for determining the source of fouling in petroleum thermal conversion process units. More particularly, the invention distinguishes whether fouling occurs due to feed entrainment of small feed droplets or vapor phase condensation.
    Type: Grant
    Filed: October 8, 2003
    Date of Patent: January 9, 2007
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Leo D. Brown, Peter S. Maa, William N. Olmstead, Michael Siskin
  • Patent number: 7153901
    Abstract: Provided are new flame retardants and liquid flame retardant additive compositions of low viscosity for use in flexible polyurethane foams. The new flame retardants are the reaction product of at least one brominated aromatic diester diol with at least one alcohol-reactive agent. Preferred liquid flame retardant additive compositions are capable of minimizing visible scorching of the foam during its production. Flexible flame retardant polyurethane foams and methods for their production are also provided. The flame retardant additive compositions are formed at least from a) at least one reaction product of a brominated aromatic diester diol and an alcohol-reactive agent; b) at least one hindered amine antioxidant; and c) at least one phenolic antioxidant in which the phenolic ring is substituted by an alkanoic acid alkyl ester group in which alkanoic acid moiety has in the range of 2 to about 4 carbon atoms and the alkyl group has in the range of about 6 to about 16 carbon atoms.
    Type: Grant
    Filed: November 21, 2003
    Date of Patent: December 26, 2006
    Assignee: Albemarle Corporation
    Inventors: Saadat Hussain, Jeffrey Todd Aplin, William R. Brown, Charles H. Kolich, Arthur G. Mack
  • Patent number: 7087152
    Abstract: A waxy hydrocarbon feed is catalytically dewaxed with a catalyst that has been selectively activated. The selective activation of the catalyst involves contacting the dewaxing catalyst with a feed mixture containing waxy hydrocarbon and at least one oxygenate. The process results in improved catalyst performance resulting in improved yield of isomerate at equivalent pour.
    Type: Grant
    Filed: October 3, 2003
    Date of Patent: August 8, 2006
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Ian A. Cody, William J. Murphy, Sylvain Hantzer
  • Patent number: 7077947
    Abstract: A process for preparing high VI lubricating oil basestocks comprising hydrotreating, hydrodewaxing and optionally hydrofinishing. The hydrotreated feedstock is hydrodewaxed using a dewaxing catalyst that has been selectively activated by oxygenate treatment. The hydrodewaxed product may then be hydrofinished.
    Type: Grant
    Filed: October 3, 2003
    Date of Patent: July 18, 2006
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Ian A. Cody, William J. Murphy, Sylvain Hantzer, David W. Larkin, John E. Gallagher, Jr., Jeenok T. Kim
  • Patent number: 7063883
    Abstract: Laminates for printed circuit boards having surface layers of curable resin impregnated woven glass fabric and intermediate layers of curable resin impregnated non-woven glass. The intermediate layers contain 200 percent by weight to 275 percent by weight, based on the resin in the intermediate layers, of a thermally stable aluminum hydroxide of the molecular formula Al2O3.nH2O, wherein n has a value of 2.6<n<2.9. The aluminum hydroxide has a specific surface area, measured by the BET method, of 2 to 10 m2/g and a particle size in the D50% range of 5 to 10 ?m.
    Type: Grant
    Filed: October 25, 2002
    Date of Patent: June 20, 2006
    Assignee: Albemarle Corporation
    Inventors: Neil Brown, Michael Aggleton
  • Patent number: 7045564
    Abstract: A flame retardant formulation which is the combination of at least (1) at least one bromine-containing polyol flame retardant formed from the reaction of (a) tetrabromophthalic anhydride, (b) an aliphatic polyol, and (c) an epoxide, and (2) at least one aliphatic diester of an alkane dicarboxylic acid, with the proviso that the formulation has a viscosity at 25° C. of about 20,000 cps or less, and a bromine content of at least about 40 wt %. A flame retardant compound formed from A) tetrabromophthalic anhydride; B) diethylene glycol; C) at least one alpha-omega alkane diol, or at least one alpha-omega alkane diol and at least one aliphatic monool; and D) at least one alkylene oxide; with the proviso that the compound has a viscosity at 25° C. of about 60,000 cps or less, and a bromine content of at least about 43 wt %. Polymer compositions formed from (a) a polyurethane or a polyisocyanurate and (b) a formulation of the invention.
    Type: Grant
    Filed: August 29, 2003
    Date of Patent: May 16, 2006
    Assignee: Albemarle Corporation
    Inventors: Elbert F. Feske, Nelson E. Clark, Arthur G. Mack, Jeffrey Todd Aplin
  • Patent number: 7029746
    Abstract: Printed circuit boards of a laminate having surface layers of curable resin impregnated woven glass fabric and intermediate layers of curable resin impregnated non-woven glass. The intermediate layers contain 200 percent by weight to 275 percent by weight, based on the resin in the intermediate layers, of a thermally stable aluminum hydroxide of the molecular formula Al2O3.nH2O, wherein n has a value of 2.6<n<2.9. The aluminum hydroxide has a specific surface area, measured by the BET method, of 2 to 10 m2/g and a particle size in the D50% range of 5 to 10 ?m.
    Type: Grant
    Filed: October 25, 2002
    Date of Patent: April 18, 2006
    Assignee: Albemarle Corporation
    Inventors: Neil Brown, Michael Aggleton
  • Patent number: 7029551
    Abstract: Method for the preparation of a laminate for printed circuit boards by composing together surface layers of curable resin impregnated woven glass fabric and intermediate layers of curable resin impregnated non-woven glass. The intermediate layers contain 200 percent by weight to 275 percent by weight, based on the resin in the intermediate layers, of a thermally stable aluminum hydroxide of the molecular formula Al2O3.nH2O, wherein n has a value of 2.6<n<2.9. The aluminum hydroxide has a specific surface area, measured by the BET method, of 2 to 10 m2/g and a particle size in the D50% range of 5 to 10 ?m.
    Type: Grant
    Filed: October 25, 2002
    Date of Patent: April 18, 2006
    Assignee: Albemarle Corporation
    Inventors: Neil Brown, Michael Aggleton