Abstract: This invention relates to a two stage hydroprocessing process with stripping zones between the hydroprocessing zones and following the last hydroprocessing zone. The stripping occurs at high pressure and temperature with no disengagement between or following the hydroprocessing zones. There is recycle of high temperature gaseous effluent from the last stripping zone to the first stripping zone.
Type:
Grant
Filed:
September 21, 2001
Date of Patent:
October 21, 2003
Assignee:
ExxonMobil Research and Engineering Company
Abstract: A hydrocarbonaceous feed is hydroprocessed in a single vessel containing two reaction stages and a stripping stage. The feed is fed into the first reaction stage to produce a vapor and liquid effluent which are separated, and the liquid stripped. The stripped liquid is passed as feed into the second stage, in which it meets with fresh hydrogen to produce a hydroprocessed liquid product and a hydrogen-rich vapor. The vapor is passed into the first stage, to provide the hydrogen for that stage. The use of a single vessel provides an efficient and economical addition to, or replacement for, a vessel for an existing hydroprocessing facility.
Type:
Grant
Filed:
September 21, 2001
Date of Patent:
October 14, 2003
Assignee:
ExxonMobile Research and Engineering Company
Abstract: A process for upgrading a liquid petroleum or chemical stream wherein said stream flows countercurrent to the flow of a treat gas, such as a hydrogen-containing gas, in at least one reaction zone. The temperature of at least a portion of the liquid stream in the reactor is used to control the flooding characteristics of the reactor.
Type:
Grant
Filed:
December 7, 1999
Date of Patent:
September 23, 2003
Assignee:
ExxonMobil Research and Engineering Company
Inventors:
Larry L. Iaccino, Russell D. Sellen, David C. Dankworth, Edward S. Ellis, Jeffrey W. Frederick, Ramesh Gupta, James J. Schorfheide, Louis A. Curcio, Jr.
Abstract: Disclosed is a process for opening naphthenic rings of naphthenic ring-containing compounds, along with catalysts which can be used in that process. The ring opening is accomplished using a ring opening catalyst system which combines an Ir ring opening catalyst with a Pt and Pd catalyst. The combination of the Pt and Pd-containing catalyst with an Ir-containing catalyst incorporates desirable isomerization activity and also results in substantial ring opening activity that enables Ir to be loaded at a level that is substantially below that of Ir-only ring opening processes.
Type:
Grant
Filed:
July 2, 2001
Date of Patent:
September 23, 2003
Assignee:
ExxonMobil Research and Engineering Company
Inventors:
William C. Baird, Jr., Jingguang G. Chen, Gary B. McVicker
Abstract: A diesel fraction is purified by a process having two reaction stages and a stripping stage in a single vessel. Heteroatoms are removed in the first stage, to permit the use of a sulfur sensitive aromatics saturation catalyst in the second stage, to produce a purified diesel stock. The first stage liquid effluent is stripped in a stripping stage and then passed into the second reaction stage, in which it reacts with fresh hydrogen for aromatics removal. The second reaction stage produces a hydrogen-rich vapor effluent, which may provide all or a portion of the first stage reaction hydrogen. A noble metal catalyst is employed in the second stage. The diesel feed for the process may be one that has been at least partially refined with respect to either or both heteroatom or aromatics removal.
Type:
Grant
Filed:
September 21, 2001
Date of Patent:
September 23, 2003
Assignee:
ExxonMobil Research and Engineering Company
Abstract: Disclosed is a process for opening naphthenic rings of naphthenic ring-containing compounds, along with catalysts which can be used in that process. The naphthene ring opening catalyst is a catalyst which comprises at least one of a Group VIII metal selected from Ir, Pt, Pd, Rh, and Ru in an amount effective to ring open naphthene rings on naphthene ring-containing compounds, the metal being supported on a substrate comprising at least one Group IB, IIB, and IVA metal in an amount effective to moderate cracking of a naphthene ring-containing feed to form methane.
Type:
Grant
Filed:
July 2, 2001
Date of Patent:
September 23, 2003
Assignee:
ExxonMobil Research and Engineering Company
Inventors:
William C. Baird, Jr., Jingguang G. Chen, Gary B. McVicker
Abstract: A method for producing a lube basestock from a waxy feed is disclosed in which a feed containing to 50 wt % or more of wax is hydrotreated and stripped to lower the nitrogen and sulfur content of the feed. The feed is then hydroisomerized under conditions to 370° C. hydrocatalytically dewaxed with a catalyst comprising a mixture of a catalytically active metal on a zeolite dewaxing catalyst and an amorphous catalyst, or alternatively is solvent dewaxed and then hydrocatalytically dewaxed with the just described catalyst.
Type:
Grant
Filed:
October 25, 2000
Date of Patent:
September 16, 2003
Assignee:
Exxon Research and Engineering Company
Inventors:
William John Murphy, Ian Alfred Cody, Bernard George Silbernagel
Abstract: A fluidized catalytic cracking system includes a riser for contacting catalyst and hydrocarbon feedstock. The riser has an inner surface that defines a central passage. The central passage acts as a flow path for the catalyst and the hydrocarbon feedstock. A plurality of ribs are disposed on the riser inner surface. The ribs increase the degree of mixing that occurs between the catalyst and the hydrocarbon feedstock within the central passage. In particular, each rib has a contoured inner wall. The contour of the inner wall forces a portion of the catalyst flow inward, toward the hydrocarbon-rich center of the central passage.
Type:
Grant
Filed:
July 14, 2000
Date of Patent:
September 2, 2003
Assignee:
ExxonMobil Research and Engineering Company
Abstract: A process for producing a high VI/low volatility lubricating oil basestock and a lubricating oil basestock prepared by said process. The process comprises subjecting the raffinate from a solvent extraction step to a two step, single stage hydroconversion process wherein the first step involves severe hydroconversion of the raffinate followed by a cold hydrofinishing step.
Type:
Grant
Filed:
June 26, 2001
Date of Patent:
July 15, 2003
Assignee:
ExxonMobil Research and Engineering Company
Inventors:
Ian A. Cody, William J. Murphy, John E. Gallagher, Joseph P. Boyle, Anne M. Zinicola, Christopher J. May, Jeenok T. Kim, John A. Groestch, Sylvain S. Hantzer
Abstract: Disclosed is a process for opening naphthenic rings of naphthenic ring-containing compounds, and catalysts which can be used in that process. The naphthene ring opening catalyst is a polymetallic catalyst comprising Group VIII metals. In a preferred embodiment the naphthene ring opening catalyst comprises Ir in combination with a Group VIII metal selected from at least one of Pt, Rh, and Ru, in an amount effective for opening a naphthene ring-containing compound at a tertiary carbon site.
Type:
Grant
Filed:
July 2, 2001
Date of Patent:
July 8, 2003
Assignee:
ExxonMobil Research and Engineering Company
Inventors:
William C. Baird, Jr., Darryl P. Klein, Michele S. Touvelle, Jingguang G. Chen
Abstract: A process for opening naphthenic rings of naphthenic ring-containing compounds, along with catalysts which can be used in that process. The naphthene ring opening catalyst is a catalyst comprising at least one Group VIII metal selected from Ir, Pt, Rh, and Ru, wherein these metals are supported on an alkali metal or alkaline-earth metal modified support in an amount effective for opening a naphthene ring-containing compound at a tertiary carbon site.
Type:
Grant
Filed:
July 2, 2001
Date of Patent:
July 1, 2003
Assignee:
ExxonMobil Research and Engineering Company
Inventors:
William C. Baird, Jr., Darryl P. Klein, Michele S. Touvelle, Jingguang G. Chen, Gary B. McVicker
Abstract: A process for upgrading a liquid petroleum or chemical stream wherein said feedstream flows countercurrent to the flow of a treat gas, such as a hydrogen-containing gas, in at least one reaction zone. The feedstream is treated so that it is substantially free of particulate matter and foulant precursors.
Type:
Grant
Filed:
December 7, 1999
Date of Patent:
June 17, 2003
Assignee:
ExxonMobil Research and Engineering Company
Inventors:
Larry L. Iaccino, Edward S. Ellis, Ramesh Gupta, Brenda A. Raich
Abstract: A process for removing sulfur compounds from hydrocarbon feedstreams, particularly those boiling in the naphtha range, by contacting the feedstream with an adsorbent comprised of cobalt and one or more Group VI metals selected from molybdenum and tungsten on a refractory support. This invention also relates to a process wherein a naphtha feedstream is first subjected to selective hydrodesulfurization to remove sulfur but not appreciably saturate olefins. A product stream is produced containing mercaptans that are removed by use of the cobalt-containing adsorbents of the present invention.
Type:
Grant
Filed:
December 17, 2001
Date of Patent:
June 17, 2003
Assignee:
ExxonMobil Research and Engineering Company
Inventors:
Joseph L. Feimer, David N. Zinkie, Myles W. Baker, Bal K. Kaul, Gordon F. Stuntz, Joseph T. O'Bara
Abstract: A method for producing a hydrotreating catalyst which relates to the production of a solid catalyst composed of a carrier impregnated with an active component, to give a catalyst for hydrotreating hydrocarbon oils, which contains a large quantity of a hydrogenation-active component and uniform, crystalline composite metal compound, and shows high catalytic activity.
Abstract: A process for upgrading oil feedstock wherein the feedstock is hydrotreated, hydrocracked, and flashed and/or distilled. The bottoms are then vacuum distilled to adjust viscosity and volatility. The refined feed is then extracted, dewaxed, and cascaded to a hydrofinishing step, where it is contacted with a catalyst having a metal hydrogenation function in order to produce lubricant products.
Type:
Grant
Filed:
November 13, 2000
Date of Patent:
May 27, 2003
Assignee:
ExxonMobil Research and Engineering Company
Inventors:
Michael B. Carroll, Gary P. Schleicher, Joseph P. Boyle
Abstract: A process for upgrading oil feedstock wherein the feedstock is hydrocracked, flashed and/or distilled. The bottoms are then vacuum distilled to adjust viscosity and volatility. The refined feed is then dewaxed under high pressure by a medium pore molecular sieve. The dewaxed material is then cascaded to a hydrofinishing step, where it is contacted with an aromatics saturation catalyst having a metal hydrogenation function in order to produce, after appropriate flashing and distillation, lubricant products having high Viscosity Index, low aromatics content, low volatility and excellent stability to light in the presence of oxygen.
Type:
Grant
Filed:
November 13, 2000
Date of Patent:
May 27, 2003
Assignee:
ExxonMobil Research and Engineering Company
Inventors:
Michael B. Carroll, Fritz A. Smith, John C. Bixel
Abstract: A process for upgrading oil feedstock wherein the feedstock is hydrocracked, and flasked and/or distilled. A distillate fraction boiling in the diesel range is isolated and dewaxed under high pressure by a medium pore molecular sieve. The dewaxed material is then cascaded to a hydrofinishing step, where it is contacted with an aromatics saturation catalyst having a metal hydrogenation function in order to produce diesel fuels having low aromatics content.
Type:
Grant
Filed:
November 13, 2000
Date of Patent:
February 11, 2003
Assignee:
ExxonMobil Research and Engineering Company
Inventors:
Michael B. Carroll, Fritz A. Smith, John C. Bixel