Patents Represented by Attorney, Agent or Law Firm John Daniel Wood
  • Patent number: 5824765
    Abstract: Process for the preparation of polycondensates of amino acids or of the polypeptide hydrolysates thereof, by bulk thermal polycondensation of amino acids in pulverulent medium, in the presence of phosphoric acid, phosphorus pentoxide or polyphosphoric acid (catalyst) which is uniformly distributed in the said pulverulent medium, optionally followed by hydrolysis. The said pulverulent medium may be obtained by empasting the amino acid and the catalyst with water, removal of the water and grinding.Use of polyimide polycondensates or the polypeptide hydrolysates thereof in detergent compositions.
    Type: Grant
    Filed: August 12, 1997
    Date of Patent: October 20, 1998
    Assignee: Rhone-Poulenc Chimie
    Inventor: Jean-Luc Lepage
  • Patent number: 5802815
    Abstract: A process for filling and self-sealing containers with molten materials is provided. The process comprises filling a container with a molten material and covering the surface of the molten material which is still at elevated temperature after filling with an insert consisting of a plastic film and a plastic disk. The plastic film faces the molten material and is larger than the plastic disk. The diameter of the plastic disk is slightly smaller than the internal diameter of said container.
    Type: Grant
    Filed: August 14, 1996
    Date of Patent: September 8, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Christoph Lohr, Krebs Michael, Robert Magunia
  • Patent number: 5789371
    Abstract: According to the invention, an improved class of amphoteric surfactants having improved surfactant properties charaterized as mild and environmentally benign has been provided comprising a compound of the general formula: ##STR1## wherein R independently represents a C.sub.5 to C.sub.22 alkyl or acyl (RCO--); R.sub.1 represents a C.sub.1 to C.sub.6 alkyl; R.sub.2 independently represents --O--; R.sub.3 represents a C.sub.2 to C.sub.20 alkylene, arylene, or alkylarylene and M is Na, K, NH.sub.4, an organic base, or hydrogen.In addition to the novel compounds per se, the invention also provides new methods for the preparation of the amphoteric gemini surfactants as well as improved synergistic compositions that are obtained when the amphoteric geminis are blended with other surfactants.
    Type: Grant
    Filed: April 22, 1997
    Date of Patent: August 4, 1998
    Assignee: Rhodia Inc.
    Inventors: David James Tracy, Ruoxin Li, Jiang Yang
  • Patent number: 5773398
    Abstract: The present invention relates to a cleaning compound comprising, by volume:1% to 99% of at least one compound (a) comprising a straight or branched hydrocarbon chain which is saturated or which has at least one unsaturation, and comprising at least two aryl or alkylaryl radicals, the aromatic nucleus of at least two aryl and/or alkylaryl radicals comprising 6 carbon atoms.99% to 1% of at least one polar aprotic compound (b) which is at least partly soluble in water and in compound (a).
    Type: Grant
    Filed: July 29, 1996
    Date of Patent: June 30, 1998
    Assignee: Rhone-Poulenc Chimie
    Inventors: Jean-Luc Joye, Marie-Madeleine Vincent
  • Patent number: 5770657
    Abstract: Provided are epoxy curing agents comprising the reaction product of reactants consisting essentially of a mono-alkylene polyamine having less than about 12 carbon atoms, an alicyclic diamine in an amount of greater than about 10% of the amine equivalents of said amine component, an aromatic mono-glycidyl ether having less than about 18 carbon atoms, and a diglycidyl ether of an aromatic diol having an average degree of oligomerization of less than about 3.5, wherein the ratio of primary amine equivalents of said alkylene polyamine to the total epoxide equivalents of said aromatic glycidyl ether and said diglycidyl ether of an aromatic diol is are greater than one, and the ratio of epoxide equivalents of said aromatic mono-glycidyl ether to epoxide equivalents of said diglycidyl ether of an aromatic diol is greater than one.
    Type: Grant
    Filed: July 3, 1996
    Date of Patent: June 23, 1998
    Assignee: Henkel Corporation
    Inventors: Jason L. Chou, Shailesh Shah, Brian G. Jewell, Robert M. Moon
  • Patent number: 5770662
    Abstract: A composition of matter comprising a resin obtained by a process comprising reacting at an elevated temperature an epoxidized ester of an unsaturated fatty acid with an aliphatic alcohol with a resin acid is provided. The equivalent ratio of epoxy groups of said epoxidized ester to carboxyl groups of said resin acid is in the range from 1.5:1 to 0.01:1. The resin is useful as a tackifier for adhesives and has a reduced tendency to crystallize.
    Type: Grant
    Filed: September 18, 1996
    Date of Patent: June 23, 1998
    Assignee: Henkel Kommanditgesellschaft Auf Aktien (Henkel KGaA)
    Inventors: Ulrich Eicken, Manfred Gorzinski, Paul Birnbrich, Thomas Tamcke
  • Patent number: 5766521
    Abstract: The present invention relates to a novel presentation of a product exhibiting the phenomenon of supercooling. More precisely, the subject of the invention is cristallized pearls of a product exhibiting strong supercooling. The invention also relates to the preparation of the said pearls. The characteristic feature of the process of the invention is to melt, if necessary, the product to be shaped; to break up the molten mass into droplets; to cool the droplets to a temperature below the glass transition temperature of the product, so that these droplets harden by vitrification; to maintain the pearls thus vitrified at a temperature below the glass transition temperature and to place them in contact with crystallization seeds; to crystallize the pearls by raising the temperature above the glass transition temperature and then to recover the crystallized pearls.
    Type: Grant
    Filed: April 9, 1996
    Date of Patent: June 16, 1998
    Assignee: Rhone-Poulenc Chimie
    Inventors: Jean-Claude Le Thiesse, Eraclis Statiotis
  • Patent number: 5763506
    Abstract: A self-dispersing curable epoxy composition is prepared upon contacting (a) 1.0 reactive equivalents of an epoxy resin, (b) from about 0.01 to 1.0 reactive equivalents of a polyhydric phenol, and (c) between 0.005 and 0.025 reactive equivalents of an amine-epoxy adduct, wherein the amine-epoxy adduct is formed upon contacting 1.0 equivalents of an aliphatic polyepoxide and between 0.3 and 0.9 reactive equivalents of a polyoxyalkyleneamine. The self-dispersing curable epoxy resin forms an aqueous dispersion upon mixing with water. When cured, the dispersion is useful as a coating composition.
    Type: Grant
    Filed: September 26, 1996
    Date of Patent: June 9, 1998
    Assignee: Henkel Corporation
    Inventors: John G. Papalos, Reuben H. Grinstein, Shailesh Shah, Joseph L. Mulvey, Brian G. Jewell
  • Patent number: 5760108
    Abstract: Self-dispersing curable epoxy resin ester dispersions prepared by a process comprising reacting a self-dispersing curable epoxy resin based on a polyoxyalkyleneamine with a fatty acid selected from the group consisting of drying oil and semi-drying oil fatty acids, are provided. The self-dispersing curable epoxy resin is based on a polyoxyalkyleneamine. Thus, a polyoxyalkyleneamine was present as a chemical precursor of the epoxy resin or a starting material therefor. The self-dispersing curable epoxy resin ester of the invention is in the form of an aqueous dispersion. When dried, films of the self-dispersing curable epoxy resin ester dispersion are useful as a coating composition.
    Type: Grant
    Filed: October 22, 1996
    Date of Patent: June 2, 1998
    Assignee: Henkel Corporation
    Inventors: Kartar S. Arora, Grannis S. Johnson, James Aloye
  • Patent number: 5756624
    Abstract: A method of tackifying an adhesive is provided, the improvement comprising the use of a copolymer consisting of monomer units derived monomers consisting of:(A) 10 to 50% by weight of a terpene with no conjugated double bonds,(B) 20 to 50% by weight of a member selected from the group consisting of olefinically unsaturated monocarboxylic acids containing 3 to 5 carbon atoms and anhydrides thereof, and olefinically unsaturated dicarboxylic acids containing 3 to 5 carbon atoms and anhydrides thereof, and(C) 40 to 50% by weight of an ester selected from the group consisting of esters and semiesters of olefinically unsaturated monocarboxylic containing 3 to 5 carbon atoms and esters and semiesters of olefinically unsaturated dicarboxylic acids containing 3 to 5 carbon atoms, with the proviso that the sum total of said monomers is 100% by weight.
    Type: Grant
    Filed: November 4, 1996
    Date of Patent: May 26, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Arno Behr, Wolfgang Ritter, Hans-Peter Handwerk, Oliver Pietsch
  • Patent number: 5756742
    Abstract: Polymerizable compounds based on N-acylamido-piperazines are provided. Such compounds have the formula: ##STR1## wherein: a, b, c and d are independently 0 or 1 and the sum of a, b, c and d is at least 3.R.sup.1, R.sup.2, and R.sup.3 are hydrogen and/or lower alkyl,B.sup.1, B.sup.2, B.sup.3, and B.sup.4 are independently carbonyl, sulfonyl, amide, or carboxyl;m, n, x, and y are independently one or zero;R.sup.23 is a group selected from, substituted and unsubstituted phenyl and phenonyl.These compounds are particularly useful as polymerizable monomers in radiation curable coatings. The compound preferably has at least one group ##STR2## substituted on R.sup.23 wherein M is H or a counterion to the carboxyl group which can be present in place of a ##STR3## group.
    Type: Grant
    Filed: December 22, 1995
    Date of Patent: May 26, 1998
    Assignee: Henkel Corporation
    Inventor: Paul E. Share
  • Patent number: 5741824
    Abstract: The invention relates to acoustically active sprayable plastisol compositions based on styrene copolymers and/or alkyl methacrylate homopolymers and/or copolymers of methyl methacrylate which, in addition to the favorable abrasion properties and corrosion-preventing properties of the plastisols, have a good vibration-damping effect and distinctly reduce the noise caused by particle impact (chippings, water, sand).
    Type: Grant
    Filed: December 7, 1995
    Date of Patent: April 21, 1998
    Assignee: Teroson GmbH
    Inventors: Gunter Butschbacher, Manfred Rein, Klaus Ruch, Karl Wesch
  • Patent number: 5728895
    Abstract: Latexes are thickened by compounds of the formula ##STR1## wherein R.sup.1 is an aliphatic, substituted aliphatic, aromatic, or substituted aromatic radical having a valence of from 2 to 8; each of B.sub.1 -B.sub.8 is independently an ester, amide, amine, ether, sulfide, disulfide, thiocarbamate, urea, thiourea, urethane, sulfate, phosphate, carbonyl, methylene, thioamide, carbonate, or imide linkage; each of X.sup.1 -X.sup.8 is independently -A.sub.1 -R.sup.2 -A.sub.2 - or -A.sub.1 - wherein each of A.sub.1 and A.sub.2 is independently an ester, amide, amine, ether, sulfide, disulfide, urethane, thiocarbamate, urea, thiourea, sulfate, phosphate, carbonyl, methylene, thioamide, carbonate, or imide linkage and R.sup.2 is a divalent aliphatic, substituted aliphatic, aromatic, or substituted aromatic radical with the proviso that only one of B.sub.1 -B.sub.8 is urethane and that when one of B.sub.1 -B.sub.8 is urethane, one of A.sub.1 and A.sub.
    Type: Grant
    Filed: October 9, 1996
    Date of Patent: March 17, 1998
    Assignee: Henkel Corporation
    Inventors: Michael S. Wiggins, Reuben Grinstein, Stephen A. Fischer
  • Patent number: 5728404
    Abstract: Methods of virucidal disinfection with virucidal disinfectants containing an active quantity of salts of metals of the alkaline earth metals, alkali metals, earth metals and/or metals of the first, second or third secondary group of the periodic system of elements in the form of a solution in water and/or alcohol are provided. The virucidal activity of alcohols or alcohol/water mixtures with a total alcohol concentration of 40 to 90% and preferably 50 to 80% can be considerably increased by addition of base- or acid-hydrolyzed salts of metal ions of the earth metal and meta metal group of the periodic system of elements in quantities of 0.1 to 1% by weight and preferably in quantities of 0.2 to 0.6% by weight. Normally ineffectual alcohol mixtures or alcohol/water mixtures thus develop far-reaching virucidal activity. The disinfectants may also contain small quantities of substances for improving compatibility with the skin, wetting agents and corrosion inhibitors.
    Type: Grant
    Filed: October 31, 1994
    Date of Patent: March 17, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Friedrich von Rheinbaben, Klaus-Peter Bansemir, Beate Mainz, Klaus Hachmann
  • Patent number: 5719210
    Abstract: A method of preparing a self-dispersing epoxy resin composition is provided. The method comprises reacting a polyepoxide with a polyoxyalkylene polyol wherein the equivalent ratio of epoxide groups of said polyepoxide to hydroxyl groups of said polyoxyalkylene polyol is greater than 10:1, to form an polyol-epoxy adduct and reacting said polyol-epoxy adduct with a polyepoxide and a polyhydric alcohol to form a self-dispersing epoxy resin. Also provided are aqueous dispersions of the self-dispersing epoxy resin and coating compositions comprising the same. The coating compositions are particularly useful as industrial maintenance coatings.
    Type: Grant
    Filed: November 26, 1996
    Date of Patent: February 17, 1998
    Assignee: Henkel Corporation
    Inventors: Kartar S. Arora, Shailesh Shah
  • Patent number: 5719202
    Abstract: Polymerizable compounds based on N-acylamido-piperazines are provided. Such compounds have the formula: ##STR1## wherein: R.sup.1, R.sup.2, and R.sup.3 are each independently selected from the group consisting of hydrogen and lower alkyl,B is a linking group selected from the group consisting of carbonyl, sulfonyl, amide, and carboxyl;n is one or zero;R.sup.4 is a radical selected from the group consisting of a higher aliphatic group (i.e. at least four carbon atoms, preferably from about 6 to about 50 carbon atoms), a substituted higher aliphatic group, an alicyclic group, a heterocyclic group a non-benzenoid aromatic group, and a substituted aromatic group. These compounds can be incorporated into a polymerizable composition. The compounds is preferably present in said composition in a major amount on a mole percent basis of th polymerizable monomers. These polymerizable compositions are useful as coatings, particularly in formulations containing a photoinitiator susceptible to ultra-violet radiation.
    Type: Grant
    Filed: February 27, 1996
    Date of Patent: February 17, 1998
    Assignee: Henkel Corporation
    Inventor: Paul E. Share
  • Patent number: 5714526
    Abstract: A method of preparing a pigment dispersion useful in the preparation of printing inks is provided. Said method comprises dispersing a pigment in an aqueous medium further comprised of a dispersing binder resin composition, said aqueous medium being essentially free of volatile organic solvents and said dispersing binder resin consisting essentially of the reaction product of a mixture of X equivalent percent of an acid component and Z equivalent percent of an amine component wherein the acid component is comprised of an aromatic dicarboxylic acid alone or in a mixture with an aliphatic dicarboxylic acid having from 2-25 carbon atoms, and said amine component is comprised of a mixture of a diamine and monoalkanol amine and the ratio of Z:X is less than 1 to provide a polyamide having an acid value greater than about 35. This invention also relates to printing inks comprising the pigment dispersion composition of this invention and a method of preparation thereof.
    Type: Grant
    Filed: December 13, 1995
    Date of Patent: February 3, 1998
    Assignee: Henkel Corporation
    Inventor: Paul D. Whyzmuzis, deceased
  • Patent number: 5710117
    Abstract: Detergent formulation for washing laundry characterized in that it comprises:from about 10 to 80% of its weight of at least one hydrated zeolite (z) of formulaxNa.sub.2 O.yAl.sub.2 O.sub.3.zSiO.sub.2.wH.sub.2 Oin which, if y=1, x is from about 0.7 to 1.1, z is from about 1.3 to 3.3 and w is from about 10 to 264from about 0.005 to 5%, of its weight of a least one polyalkylene terephthalate-polyoxyalkylenebisurethane (PET-UPOEU) copolymeric nonionic or anionic anti-soiling agent, said copolymer being obtained by reaction of a polyalkylene terephthalate (PET) and a polyoxyalkylnebisurethane (UPOEU), the molar ratio of the NCO functions to all of the OH functions or OH function equivalents being from about 0.5 to 1,from about 3 to 40%, of its weight of a least one saturated C.sub.5 -C.sub.24, aliphatic or hydroxyaliphatic alkyl sulphate anionic surfactant (FAS) optionally condensed with approximately 0.
    Type: Grant
    Filed: April 4, 1996
    Date of Patent: January 20, 1998
    Assignee: Rhone-Poulenc Chimie
    Inventors: Claire David, Etienne Fleury
  • Patent number: 5709739
    Abstract: A composition useful as a release agent for hydraulic binders is provided. The composition comprises water, an oil component comprising a water-immiscible monohydric alcohol component liquid at temperatures of 5.degree. to 15.degree. C. and selected from the group consisting of unsaturated fatty alcohols containing 12 to 22 carbon atoms and having iodine values of 40 to 170, Guerbet alcohols containing 16 to 28 carbon atoms, oxoalcohols containing 8 to 15 carbon atoms, and saturated alcohols containing 6 to 10 carbon atoms, and 0.5 to 5% by weight of an emulsifier, based on the oil component. The release agent is particularly useful for the treatment of formwork material in concrete construction.
    Type: Grant
    Filed: August 16, 1996
    Date of Patent: January 20, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Leonhard Wittich, Stephan Heck, Lothar Friesenhagen, Guenther Demmering, Horst-Dieter Komp, Michael Koehler, Ingo Wegener, Hans-Juergen Sladek
  • Patent number: 5710207
    Abstract: A method of using compositions as foam regulators for water-based systems with a tendency to foam is provided. The method employs a block copolymer containing ester groups corresponding to general formula (I):A--(CH.sub.2 CH.sub.2 O).sub.n --B (I)in which n is an integer of 4 to 300, A is an optionally polymeric hydroxycarboxylic acid function and B is hydrogen, an alkyl or alkenyl radical containing 1 to 22 carbon atoms, a phenyl or benzyl radical or has the same meaning as A. Also provided is a granular free-flowing foam regulating formulation which contains 0.5% by weight to 30% by weight of the block copolymer containing ester groups adsorbed onto from 70% by weight to 99.5% by weight of a granular, substantially inorganic phosphate-free support material.
    Type: Grant
    Filed: April 10, 1996
    Date of Patent: January 20, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Thomas Moller, Ulrich Eicken, Herbert Fischer, Horst-W. Wollenweber, Wolfgang Gress, Christian de Haut, Ulrike Mahler, Manfred Gorzinski, Hans-Jurgen Sladek