Patents Represented by Attorney, Agent or Law Firm John Daniel Wood
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Patent number: 5491189Abstract: The adhesive strength of an aqueous binder dispersion consisting of: a halogenated copolymer which, in addition to other components, contains an alkylation-active monoalkenylaromatic alkyl halide; polyfunctional aromatic nitroso compounds; pigments; carbon black; anti-foaming agents; emulsifiers; and other additives, used for vulcanizing rubber onto substrates which are stable under the conditions of vulcanization, is improved, and the use of blocked isocyanates is avoided. This is achieved by adding, to increase the adhesive strength, homopolymers or copolymers of vinyl acetate that are also saponified to a certain extent, as well as, optionally, other customary additives.Type: GrantFiled: January 26, 1994Date of Patent: February 13, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Hans Scheer, Wolf-Dieter Beiersdorf, Hans-Joachim Purps
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Patent number: 5490943Abstract: The invention relates to spinning finishes in the form of aqueous emulsions or aqueous solutions containing water-soluble polymer compounds having weight average molecular weights of more than 10.sup.6.Type: GrantFiled: September 21, 1994Date of Patent: February 13, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Ulrich Eicken, Raymond Mathis, Heidi Fiedler, Manfred Gorzinski
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Patent number: 5478554Abstract: A process for reducing the content of free formaldehyde and formic acid in nonionic and anionic surfactants is provided. The process comprises adding an amine compound selected from the group consisting of a) alkanolamines, b) aminocarboxylic acids and c) oligopeptides to a surfactant comprised of a member selected from the group consisting of nonionic and anionic surfactants. The amine compound is preferably selected from the group consisting of a) an alkanolamine containing 2 to 15 carbon atoms, b) an aminocarboxylic acid containing 2 to 8 carbon atoms, and c) an oligopeptide with an average molecular weight of 500 to 5000. The nonionic and anionic surfactants preferably contain 1 to 100 ethylene oxide units in the form of at least one polyethylene glycol chain. The amine compound is preferably added in a quantity of 50 to 6000 ppm, based on active substance of said surfactant.Type: GrantFiled: September 23, 1994Date of Patent: December 26, 1995Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Ansgar Behler, Hermann Hensen, Uwe Ploog, Werner Seipel, Frank Clasen
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Patent number: 5478427Abstract: New contact adhesives which are designed as multifunctional contact reactive adhesives and which may be used in a multistage curing process, for example for bonding wood, plastic moldings, metals and the like, are provided. One of the functional substituents of the adhesive composition is characterized by the presence of an olefinic double bond which is accessible to radical reaction initiation. The other functional substituent is an isocyanate group which reacts off, e.g. under the effect of moisture. These different reaction mechanisms enable the reactive contact adhesive to be cured in stages, e.g. by forming contact-sensitive adhesive layers on hard surfaces in a first stage, subsequently fitting the correspondingly coated surfaces together and firmly bonding them together in a final stage, e.g. under the effect of atmospheric moisture. Also provided is a process for the production of the new reactive contact adhesives.Type: GrantFiled: June 24, 1993Date of Patent: December 26, 1995Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Thomas Huver, Winfried Emmerling, Michael Kux, Christian Nicolaisen, Wolfgang Klauck
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Patent number: 5466721Abstract: Provided are compounds having the formula: ##STR1## wherein: R.sup.1 and R.sup.2 are independently selected from the group consisting of a hydrogen atom, an aliphatic group, a hetero-aliphatic group, an aromatic group, and a heterocyclic group, provided that R.sup.1 and R.sup.2 may together form a divalent radical selected from the group consisting of an aliphatic radical and hetero-aliphatic group;each R.sup.3 is independently selected from the group consisting of an aliphatic group, a hetero-aliphatic group, an aromatic group, and a heterocyclic group;R.sup.4 is selected from the group consisting of an aliphatic group, a hetero-aliphatic group, an aromatic group, and a heterocyclic group; andn is an integer from 0 to 5.Also provided are polymerizable compositions containing such compounds and a method of coating a substrate which uses such polymerizable compositions.Type: GrantFiled: June 13, 1994Date of Patent: November 14, 1995Assignee: Henkel CorporationInventor: Paul E. Share
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Patent number: 5455066Abstract: An adhesive based on casein, water-soluble extenders, natural or synthetic resin acids, resin alcohols or resin esters, and an alcohol is provided. The adhesive has specific amounts of these ingredients which leads to a viscosity of the adhesive which is temperature dependent to a surprisingly large extent. The adhesive is particularly useful in the labelling of bottles wherein the surface of the bottles is wet and cold.Type: GrantFiled: February 3, 1994Date of Patent: October 3, 1995Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Ludwig Broich, Bernhard Herlfterkamp, Hermann Onusseit
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Patent number: 5444127Abstract: Curable systems for the preparation of polymeric products in which the curable system comprises an epoxy resin or an isocyanate, wherein the system contains a condensation reaction product ofa) a polyamine having only one primary amino group and only one tertiary amino group, and a non-cyclic backbone containing from 1 to 18 carbon atoms; andb) at least one of urea, guanidine, guanylurea, thiourea, and a mono-N,N' alkyl substituted urea or thiourea having from 1 to 3 carbon atoms in the alkyl moieties.Type: GrantFiled: September 13, 1993Date of Patent: August 22, 1995Assignee: Henkel CorporationInventors: John J. Miskel, Jr., Reuben H. Grinstein, Stephen A. Fischer
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Patent number: 5435845Abstract: Compositions and methods relating to cementitious compositions are provided. The use of a glucoheptonate in the alpha form to prolong the workability of cementitious compositions is provided. The alpha form of glucoheptonate (found to have properties superior to the beta form when used to retard the hydration of cementitious compositions) can be used in combination with a plasticizing resin, e.g. a naphthalenesulfonate/formaldehyde condensate resin, to prolong the workability of a cementitious composition, without unacceptably delaying green strength development. Also provided are mixtures of a glucoheptonate in the alpha form and a naphthalenesulfonate/formaldehyde condensate resin plasticizer.Type: GrantFiled: November 2, 1993Date of Patent: July 25, 1995Assignee: Henkel CorporationInventors: Jose L. Villa, Zvi Grauer
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Patent number: 5434301Abstract: A process for recovering sulfuric acid from a mixture containing sulfuric acid and organic sulfonation products is provided. The process comprises contacting a mixture comprised of sulfuric acid and (i) a naphthalene-based material selected from the group consisting of naphthalenesulfonic acids, lower-alkyl substituted naphthalenesulfonic acids, and mixtures of two or more of such materials, or (ii) an aromatic-based carbonyl condensate (preferably a material selected from the group consisting of formaldehyde condensates of naphthalenesulfonic acids, formaldehyde condensates of lower-alkyl substituted naphthalenesulfonic acids, and mixtures of two or more of such materials), with a basic anion exchange resin in essentially the sulfate form (and preferably in the form of essentially non-porous particles) to provide a raffinate liquid phase enriched with respect to said mixture in said naphthalene-based material and depleted with respect to said mixture in sulfuric acid.Type: GrantFiled: December 1, 1993Date of Patent: July 18, 1995Assignee: Henkel CorporationInventor: William G. Kozak
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Patent number: 5434230Abstract: Compositions containing a radical-polymerizable olefinically unsaturated compound and a hydrazone of an aromatic aldehyde or ketone are provided. Also provided are methods for the production of such compositions and methods for the use of such compositions as an adhesive and sealing compound or its use for the coating and production of plastic moldings. The compositions polymerize radically at room temperature upon exposure to ambient air.Type: GrantFiled: January 11, 1994Date of Patent: July 18, 1995Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Thomas Huver, Petra P. Kremeyer, Wolfgang Klauck, Christian Nicolaisen, Lothar Kammer
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Patent number: 5433775Abstract: The invention relates to a dimensionally stable, soft-rubbing adhesive stick consisting of a water-based preparation of starch derivatives and a soap gel as the shaping gel-forming component and, optionally, other auxiliaries. To obtain an adhesive stick which is largely based on natural raw materials and which may therefore be regarded as safe from ecological and toxicological standpoints, the invention is characterized in that viscosity-reduced starch ethers are present as the starch derivatives.Type: GrantFiled: February 28, 1994Date of Patent: July 18, 1995Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Karl-Josef Gardenier, Gerhard Gierenz, Wolfgang Klauck, Bernd Peters, Horst Donothek, Norbert Doering
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Patent number: 5431729Abstract: Compositions and methods relating to cementitious compositions are provided. The use of a blend of a rosin and a tannin to entrain air into cementitious compositions is provided. A blend of a rosin and a tannin in a weight ratio of 10:1 to 1:10 are added to a wet cementitious composition at levels of less than 1% by weight based on the weight of the cement and air is mixed into the cement. The resulting cement will contain, e.g. 5% to 10% by volume air which improves the resistance of the set cement to freeze damage. Also provided is a method of entraining air into a cementitious composition which employs such a blend.Type: GrantFiled: April 12, 1994Date of Patent: July 11, 1995Assignee: Henkel CorporationInventor: Timothy Hegge
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Patent number: 5428115Abstract: An activator for cyanoacrylate adhesives based on N,N-dialkyl aniline derivatives is provided. The activators are characterized by a molecular weight of more than 200 and by at most 3 carbon atoms for both N,N-dialkyl substituents together. Also provided are methods of production and use of the activator and to the combination product of the activator and the cyanoacrylate adhesive.Type: GrantFiled: October 12, 1993Date of Patent: June 27, 1995Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Thomas Huver, Christian Nicolaisen, Susanne Camp
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Patent number: 5416135Abstract: Halogen-containing synthetic resins can be stabilized with calcium and zinc soaps of which the effectiveness is enhanced by co-stabilizers.The invention relates to special cationic layered hydrotalcite compounds having a specific BET surface of at least 50 m.sup.2 /g which are modified with at least one polymeric additive, to processes for the production of these cationic layer compounds and to their use as co-stabilizers for halogen-containing synthetic resins stabilized with calcium and/or zinc salts.Type: GrantFiled: January 24, 1994Date of Patent: May 16, 1995Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Helmut Endres, Herbert Fischer, Frido Loeffelholz, Peter Wedl, Kurt Worschech, Angela Hansen, Guenther Geismar
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Patent number: 5416141Abstract: Halogen-containing synthetic resins can be stabilized with calcium and/or zinc soaps. Co-stabilizers are necessary for enhancing their stabilizing effect. The invention relates to special cationic layered hydrotalcite compounds having a specific BET surface of at least 50 m.sup.2 /g which are modified with polyols, epoxidized esters, full and partial esters of polyols and/or phosphites, to a process for their production and to their use as co-stabilizers for halogen-containing synthetic resins stabilized with calcium and/or zinc salts.Type: GrantFiled: January 24, 1994Date of Patent: May 16, 1995Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Helmut Endres, Frido Loeffelholz, Peter Wedl, Kurt Worschech, Angela Hansen, Guenther Geismar
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Patent number: 5412022Abstract: A lyo gel is provided in which the gelling agent is an organic, fully synthetic polymer, which is crosslinked via its carboxylic acid groups and via metal compounds, and the swelling agent is a low-volatility, inert organic liquid having a volatility, as defined by its evaporation loss, of less than 0.5% by weight after 2 hours at 105.degree. C. in accordance with ASTM D 972. The lyo gel is useful for sealing devices involving the use of electrical current because the initially two-component reaction solution is sufficiently liquid at room temperature to fill even small spaces, such as gaps and joints between bodies.Type: GrantFiled: June 14, 1993Date of Patent: May 2, 1995Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Johannes Andres, Juergen Wichelhaus, Reimar Heucher
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Patent number: 5393826Abstract: An activator for cyanoacrylate adhesives based on N,N-dialkyl aniline derivatives is provided. The activators are characterized by a molecular weight of more than 200 and by at most 3 carbon atoms for both N,N-dialkyl substituents together. Also provided are methods of production and use of the activator and to the combination product of the activator and the cyanoacrylate adhesive.Type: GrantFiled: October 12, 1993Date of Patent: February 28, 1995Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Thomas Huver, Christian Nicolaisen, Susanne Camp
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Patent number: 5382372Abstract: The invention relates to spinning finishes in the form of aqueous emulsions or aqueous solutions containing water-soluble polymer compounds hvaing weight average molecular weights of more than 10.sup.6.Type: GrantFiled: July 8, 1992Date of Patent: January 17, 1995Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Ulrich Eicken, Raymond Mathis, Heidi Fiedler, Manfred Gorzinski
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Patent number: 5380886Abstract: A process for the production of epoxide ring opening products having a defined residual epoxide oxygen content by reaction of epoxides with nucleophiles in the presence of medium-strength acids is provided. The products have a defined residual epoxide oxygen content of 10 to 80% by weight based on the epoxide. In the process, aliphatic epoxidized olefins or aliphatic epoxidized esters are reacted with nucleophiles in the presence of 1 to 4 g phosphoric acid, phosphorous acid, or hypophosphorous acid per mol epoxide and the ring opening product is directly obtained without neutralization of the catalyst acid.Type: GrantFiled: November 4, 1993Date of Patent: January 10, 1995Assignee: Henkel Kommanditgesellschaft Auf AktienInventors: Peter Daute, Roland Gruetzmacher, Nicole Mertscheit
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Patent number: 5378485Abstract: Methods of use of carbonic acid esters corresponding to general formula I: ##STR1## in which R.sup.1 is an alkyl radical derived from an aliphatic saturated primary alcohol containing 1 to 22 carbon atoms and R.sup.2 is an alkyl radical derived from an aliphatic, saturated primary alcohol containing 1 to 8 carbon atoms and/or has the same meaning as R.sup.1 and n is a number of 2 to 20 while m is 0 or has the same meaning as n, as foam control agents for the sugar beet or potato-processing food industry and/or in fermentation processes are provided. In the industrial processing of sugar-containing plant juices, as carried out on an industrial scale in the case of sugar beet, particular difficulties are caused by excessive foaming in the defecation units, during transport of the beet, in the diffusors and in the carbonizing tanks and before the evaporators, thus, use of the esters in these processes is advantageous.Type: GrantFiled: August 17, 1993Date of Patent: January 3, 1995Assignee: Henkel Kommanditgesellschaft Auf AktienInventors: Ulrike Mahler, Alfred Westfechtel, Hans-Juergen Sladek, Sylke Kielmann