Abstract: The efficiency with which a sulfur getter such as limestone captures sulfur produced during combustion of a coal getter mixture is enhanced by intimately mixing the coal and the getter together in the form of an aqueous slurry also containing a gelling agent.
Abstract: An oxydehydrogenation process for producing indene and substituted indenes from indene precursors more saturated than indene is described and comprises contacting said precursor with oxygen and a catalyst comprising cobalt oxide and molybdenum oxide at an elevated temperature above about 300.degree. C. Preferably the reaction is conducted at a temperature of about 500.degree.-650.degree. C. for a period of from 0.1 to about 30 seconds.
Abstract: A dehydrogenation process for producing indene and substituted indenes from tetrahydroindene or substituted tetrahydroindene is described and comprises contacting said tetrahydroindene or substituted tetrahydroindene with a catalyst comprising cobalt oxide and molybdenum oxide at an elevated temperature for a period of from about 0.1 to 30 seconds. The tetrahydroindene and substituted tetrahydroindenes may be prepared from cyclopentadiene or dicyclopentadiene and a butadiene.
Abstract: A process for the co-production of indene and styrene from a mixture of cyclopentadiene or dicyclopentadiene and butadiene is disclosed. The process comprises the steps of reacting cyclopentadiene or dicyclopentadiene with butadiene in a Diels-Alder reaction to form a mixture of tetrahydroindene, vinylcyclohexene and vinylnorbornene followed by the recovery of the tetrahydroindene and vinylcyclohexene, and the oxydehydrogenation of the tetrahydroindene/vinylcyclohexene mixture utilizing a composite catalyst comprising cobalt oxide and molybdenum oxide.
Abstract: Cyclohexanone and/or cyclohexanol can be oxidized in the vapor phase to phenol by contacting the cyclohexanone and/or cyclohexanol with a suitable oxidation catalyst in the presence of molecular oxygen. Suitable catalysts are solids comprising Mo, W, Sb and/or V oxides or complexes thereof. The catalysts may be promoted with additional elements.
Abstract: In situ shale oil recovery from oil shale deposits using radio frequency energy as a heat generator is facilitated by rubblizing the shale oil deposits before application of radio frequency energy.
Abstract: The present invention is a homogeneous liquid phase process for the preparation of methyl-t-butyl ether by reacting isobutylene and methanol in the presence of a heteropoly acid of molybdenum, tungsten or vanadium. Other tertiary ethers may be obtained by substituting a different tertiary olefin for isobutylene, e.g. t-amyl methyl ether from 2-methylbutene-2 and methanol.
Type:
Grant
Filed:
September 4, 1979
Date of Patent:
March 31, 1981
Assignee:
The Standard Oil Company
Inventors:
Andrew T. Guttmann, Robert K. Grasselli
Abstract: Propylene and benzene are directly reacted in a single step process for making indene by means of a liquid phase catalytic reaction using a gold complex as the catalyst.
Abstract: Tellurium catalysts containing at least iron, tellurium and molybdenum plus one of nickel, cobalt or magnesium have been discovered to be especially useful for ammoxidation reactions.
Type:
Grant
Filed:
February 14, 1977
Date of Patent:
January 20, 1981
Assignee:
The Standard Oil Company
Inventors:
Robert K. Grasselli, Arthur F. Miller, Dev D. Suresh
Abstract: In the production of lubricating oil blend stocks obtained by the distillation, extraction, dewaxing and clay contacting of atmospheric crude distillation column residue, the improvement comprising using a hydrogenated gas oil to supplement the atmospheric crude distillation column residue feedstock.
Abstract: In the manufacture of a complex bismuth molybdate catalyst, bismuth molybdate is preformed prior to addition to the other ingredients in the catalyst.
Type:
Grant
Filed:
April 21, 1978
Date of Patent:
July 15, 1980
Assignee:
Standard Oil Company
Inventors:
James F. Brazdil, Dev D. Suresh, Robert K. Grasselli
Abstract: Catalysts containing a rare earth, tantalum or niobium plus iron, bismuth and molybdenum and at least one element of nickel, cobalt, magnesium, zinc, cadmium or calcium are especially effective for the ammoxidation of olefins.
Type:
Grant
Filed:
January 3, 1978
Date of Patent:
March 11, 1980
Assignee:
The Standard Oil Company
Inventors:
Robert K. Grasselli, Arthur F. Miller, Harley F. Hardman
Abstract: The present invention is a process for the oxidation of olefins to unsaturated aldehydes and acids using a catalyst containing iron, bismuth, molybdenum plus at least one of nickel, cobalt, magnesium, zinc, cadmium or calcium and according to the invention, an element selected from germanium, cerium, thorium, manganese, niobium, chromium, praseodymium, yttrium, zirconium, ruthenium, gallium, tin, indium, copper, lanthanum, tantalum or tungsten. These catalysts may also contain certain elements that further enhance the desirability of the oxidation process.
Type:
Grant
Filed:
August 26, 1976
Date of Patent:
February 26, 1980
Assignee:
Standard Oil Company
Inventors:
Robert K. Grasselli, Dev D. Suresh, Harley F. Hardman
Abstract: Certain catalysts containing iron, bismuth and molybdenum plus nickel, cobalt, manganese, magnesium, zinc, cadmium or calcium have been found to give especially large volumes of acrylonitrile or methacrylonitrile in a given time when germanium, tin, copper, silver, chromium, ruthenium, titanium, tungsten and/or beryllium are incorporated into the catalyst.
Type:
Grant
Filed:
August 1, 1977
Date of Patent:
February 26, 1980
Assignee:
Standard Oil Company
Inventors:
Robert K. Grasselli, Dev D. Suresh, Arthur F. Miller
Abstract: Urea is destroyed in aqueous waste streams containing various anions and cations plus urea by contacting the stream with a cation exchange resin, then reacting the resulting stream with nitric oxide, nitrous acid or a nitrite salt to convert the urea to nitrogen, carbon dioxide and water and treating the resulting stream with an anion exchange resin. A pure aqueous stream is obtained which does not adversely affect the environment and which may be recycled to a plant as fresh water resulting in large monetary savings in fresh water cost.
Abstract: Exceptionally reproducible catalysts comprising vanadium and phosphorus are obtained when an aqueous oxide slurry comprising vanadium, phosphorus and a mineral acid-free, inorganic reducing agent, which is capable of reducing the vanadium in the catalyst to a valence state below +5, is heated at an elevated temperature of at least 120.degree. C. under autogenous pressure so that substantial evaporation of the water in said oxide slurry is prevented. Especially preferred catalysts comprise vanadium, phosphorus, uranium and oxygen. Catalysts prepared in accordance with the invention are especially desirable in the oxidation of n-butane, n-butenes, 1,3-butadiene or mixture thereof.
Abstract: Catalysts having a substantially spherical shape, a void center and a hole in the external surface communicating to the void center have been found to be especially effective in the oxidation of monoolefins to the corresponding unsaturated oxygenated compounds.
Type:
Grant
Filed:
April 10, 1975
Date of Patent:
October 16, 1979
Assignee:
The Standard Oil Company
Inventors:
Arthur F. Miller, James L. Callahan, Wilfrid G. Shaw
Abstract: The pyritic sulfur content of coal can be significantly reduced by contacting the coal with an aqueous solution of a salt which increases the dielectric constant of the solution.