Abstract: Lubricant additives having antioxidant and antiwear properties are made by reacting an oolefin such as dicyclopentadiene with sulfur and a mercaptan.
Abstract: The reaction product of (a) high molecular weight hydrocarbon-substituted phenols, (b) aldehydes, (c) ammonia or amines having a reactive hydrogen atom, and (d) alkylene oxides are effective dispersants for lubricating oil and impart detergent properties to liquid hydrocarbon fuels such as gasoline.
Abstract: The useful life of a catalyst being used in an engine exhaust system to lower the undesirable constituents in the exhaust gas of an engine being operated on gasoline containing a cyclopentadienyl manganese antiknock is greatly prolonged by providing an exhaust system having a plurality of substantially parallel proximately spaced vanes in the exhaust flow path upstream from the catalyst.
Abstract: Lubricating oil adapted for use in spark ignited and diesel engines containing an antiwear amount of a molybdenum bis(dialkyldithiocarbamate).
Abstract: Lubricating oil adapted for use in diesel engines containing a sulfurized fatty acid ester of a polyhydric alkanol, e.g. sorbitan mono-ester of sulfurized oleic acid.
Abstract: A process for making a low viscosity, low volatility .alpha.-olefin oligomer suitable for use as a functional fluid or lubricating oil comprising dimerizing a C.sub.6-12 .alpha.-olefin, reacting the resultant dimer with a C.sub.6-18 .alpha.-olefin in the presence of a Friedel-Crafts catalyst, distilling out volatile components and hydrogenating the residual product.
Type:
Grant
Filed:
April 10, 1978
Date of Patent:
October 30, 1979
Assignee:
Ethyl Corporation
Inventors:
Ronald L. Shubkin, Ellis B. Rifkin, Martin E. Gluckstein
Abstract: A tubing connection comprising an elongated opening in a first tube member and a pair of opposed slots cut in the end of a second tube forming a pair of tabs which are flattened and inserted through the elongated opening. The tabs are spread to conform with the inside contour of the first tube member and a tubular insert is press fit between the spread tabs. A perforation is punched through the first tube member at a location such that it penetrates one of the spread tabs and the tubular insert. The perforation is indented locking the tab to the first tube member to prevent rotation giving a strong rigid connection.
Abstract: Lubricating oils for internal combustion engine containing a minor amount of a combination of(A) an oil soluble basic organic nitrogen compound having a total base number of at least 300 and a pH of at least 9.5, and(B) an alkyl or alkenyl succinic acid containing 10-50 carbon atoms have improved corrosion properties.
Abstract: Ethylene/C.sub.3-12 .alpha.-monoolefin copolymers having an average molecular weight of about 10,000-1,000,000 containing about 1-10 pendent amide and/or ester groups per each 10,000 molecular weight are effective ashless dispersants and impart viscosity lift to lubricating oils. They are made by the permanganate oxidation of ethylene/C.sub.3-12 .alpha.-monoolefin/non-conjugated diene terpolymers which oxidizes the residual olefinic double bond of the diene unit to a carboxylic acid which is amidated and/or esterified.
Abstract: Lubricating oils having improved antioxidant and antiwear properties are obtained by adding a minor amount of a reaction product made by reacting an olefinic hydrocarbon containing about 6-18 carbon atoms and about 1-3 olefinic double bonds concurrently with sulfur and hydrogen sulfide to obtain a reaction intermediate and reacting this intermediate with additional olefin hydrocarbon which may be the same or different. Preferred olefinic hydrocarbons are dicyclopentadiene and alloocimene.
Type:
Grant
Filed:
August 17, 1977
Date of Patent:
April 3, 1979
Assignee:
Edwin Cooper and Company Limited
Inventors:
Gerald J. J. Jayne, David R. Woods, Joseph P. O'Brien
Abstract: New compounds are derived from intra-molecular and inter-molecular, in the case of a polymer, sulphur bridged hydrocarbon rings of 12 carbon atoms. The hydrocarbon ring is preferably 1,5,9-cyclododecatriene. The compound also contains the residue of a dithiophosphoric acid containing two organic moieties. The new compounds are useful in major or minor amounts in lubricating oil compositions. The lubricating oil may be a hydraulic oil. The composition may also contain other conventional lubricant additives.
Abstract: New compounds are derived from intramolecular and intermolecular, in the case of a polymer, sulfur-bridged hydrocarbon rings containing from 6 to 12 carbon atoms. The hydrocarbon ring is preferably derived from 1,5-cyclooctadiene. The compounds also contain the residue of an alkoxyalkyl or aryloxyalkyl xanthate and may also contain the residue of a further nucleophilic group. The new compounds are useful in lubricating oil compositions. The compositions may also contain other conventional lubricant additives.
Abstract: Iodine is recovered from an aqueous solution containing iodide such as underground brine by repeated cycles of (1) passing the brine through a basic anion exchange resin to adsorb iodide, and (2) oxidizing adsorbed iodide to iodine by passing an acidified aqueous iodate solution (e.g., NaIO.sub.3) through the resin. The cycle is repeated many times until the resin is iodine-loaded. Iodine is then eluted from the resin, for example, with aqueous NaOH and recovered from the eluate by conventional means.
Abstract: Aromatic amines (e.g., aniline) are selectively alkylated in an ortho nuclear position by reaction with an olefin (e.g., ethylene) in the presence of an aluminum anilide catalyst. Hydrogen halides (e.g., HCl) are added to increase the reaction rate.
Abstract: Polyesters suitable for use as lubricant additives are prepared by reacting a di-carboxylic acid or anhydride having a branched chain alkyl or alkenyl substituent containing at least 30 carbon atoms with a compound having the formula: ##STR1## wherein R and R.sup.1 are specified substituents which between them possess from 2 to 6 free hydroxyl groups. Lubricating compositions containing these polyester additives are also described.
Type:
Grant
Filed:
November 23, 1977
Date of Patent:
November 28, 1978
Assignee:
Ethyl Corporation
Inventors:
John S. Elliott, Bryan T. Davis, Stephen Norman
Abstract: Mono-alkenes, aliphatic conjugated dienes and unsaturated fatty acids or esters thereof copolymerize with a Friedel-Crafts catalyst to yield a copolymer containing carboxylic acid or ester groups which are reacted with a polyamine to amidate the carboxyl group leaving free amine groups. The free amine groups are reacted with polycarboxylic acids to form inter- and intra-molecular bridged polyamides. These compounds are effective ashless dispersants in lubricating oil and have detergency properties in distillate fuels.
Abstract: The reaction of a boron compound (e.g., boric acid) with an alkylphenoxy alkanoic acid amide (polyisobutylphenoxyacetamide of tetraethylenepentamine) forms a boronated product useful as a lubricating oil dispersant having improved properties.
Type:
Grant
Filed:
February 22, 1977
Date of Patent:
October 10, 1978
Assignee:
Edwin Cooper and Company Limited
Inventors:
Bryan Terence Davis, Monty Frederick Crook
Abstract: The reaction product of (a) high molecular weight hydrocarbon-substituted phenols, (b) aldehydes, (c) ammonia or amines having a reactive hydrogen atom, and (d) alkylene oxides are effective dispersants for lubricating oil and impart detergent properties to liquid hydrocarbon fuels such as gasoline.
Abstract: High molecular weight N-hydrocarbyl-substituted quaternary ammonium salts in which the hydrocarbyl group has a molecular weight of from about 350-3,000 such as a polybutene ammonium chloride are effective detergents and dispersants for gasoline and lubricating oils.