Abstract: The present invention is a non-emulsifying, chlorine-free metal working or cutting oil which exhibits the same or superior performance as heretofore exhibited by chlorine containing fluids. The metal working oil contains cosulfurized olefins, polysulfurized hydrocarbon, phosphate esters, animal triglycerides, high molecular weight polyolefins in a mineral oil basestock. The oil may also contain metal deactivators, antioxidants and preservatives such as BHT, and mixtures of the above.
Type:
Grant
Filed:
January 3, 1997
Date of Patent:
September 28, 1999
Assignee:
Exxon Research and Engineering Co.
Inventors:
William Donald Hewson, Gerald Keith Gerow
Abstract: A sulfur free lubricating composition comprises a major portion of a synthetic base lubricating oil and a minor portion of a tri(alkyl phenyl) phosphate or di(alkylphenyl)phosphoric acid antiwear agent, an amine antioxidant a substituted succinamide rust inhibitor and a tolytriazole. The tri(alkylphenyl)phosphate antiwear agent is incorporated in the oil in an amount ranging between about 0.1 to 2.0 wt % and the amine antioxidant in amount ranging from about 0.1 to 5 wt %. The succinamide is present in an amount ranging from about 0.01 to 0.5 wt % and the tolytriazole, from about 0.01 to 0.5 wt %. In the foregoing, the wt % is based on the weight of oil.
Abstract: Elemental sulfur present in fluids such as refined petroleum products, e.g., gasoline, jet, diesel, kerosene or fuel additives such as ethers, is removed from such fluids by contacting the contaminated fluid with an adsorbent of Mg2AlNO3 or Mg3AlNO3 or by adding to the fluids a quantity of hydrocarbyl mercaptan and passing the resulting mixture through an adsorbent selected from the group consisting of alumina, bayerite, brucite and hydrotalcite like materials of the formula M.sub.x.sup.2+ M.sub.y.sup.3+ (OH).sub.2x+3y-z (NO.sub.3)mH.sub.2 O wherein M.sup.2+ is Magnesium, M.sup.3+ is aluminum, and x, y and z are values from 1 to 6 and m is the number of waters of hydration.
Type:
Grant
Filed:
October 31, 1997
Date of Patent:
September 14, 1999
Inventors:
Marc-Andre Poirier, Christian Detellier
Abstract: A lubricating oil for improving the fuel economy of internal combustion engines is disclosed comprising a major amount of a lubricating oil base stock and a minor amount of an additive package which comprises in combination a molybdenum dithiocarbamate friction modifier, a mixture of calcium and magnesium salicylate and magnesium sulfonate detergent, and alkylated (alkoxy) amine. In addition the engine lubricant can include other typical engine oil lubricant additives including dispersants, anti-foaming agents, anti-oxidants, anti-wear additives, demulsifiers, etc.
Abstract: A distillate fuel composition for reducing nickel corrosion in internal combustion engine by contaminants in the motor fuel such as sulfuric acid, alkyl sulfate esters, comprising a motor fuel and a combination of at least one 2,5 dihydrocarbyldithio-1,3,4 thiadiazole of the formula ##STR1## wherein R.sub.1 and R.sub.2 are independently H or R.sub.3 S, where R.sub.3 is a hydrocarbyl group containing from 1 to 16 carbon atoms with the proviso that at least one of R.sub.1 and R.sub.2 is not hydrogen, and an adduct of benzotriazole or tolyltriazole and an amine.
Abstract: A lubricating oil composition comprising (A) a base oil containing 3% by weight or less of aromatics, 20% by weight or more of monocyclic naphthenes, 50 ppm by weight or less of N and 50 ppm by weight or less of S, having a viscosity (100.degree. C.) of 2 to 50 mm.sup.2 /s, (B) alkyldiphenylamines and/or phenyl-alpha-naphthylamines in an amount of 0.05 to 2% by weight of the total weight of the composition, and (C) C.sub.8 -C.sub.23 MoDTC and/or C.sub.8 -C.sub.18 MoDTP and/or C.sub.8 -C.sub.18 MoDTX in such an amount that the amount of Mo is 50 to 2000 ppm by weight of the total weight of the composition. The lubricating oil composition has high heat resistance, high oxidation stability and excellent lubricating properties, and is particularly useful for a lubricating oil for internal combustion engines and the like.
Abstract: Aromatic hydrocarbons are selectively extracted from lube oil stocks comprising mixtures of same with non-aromatic hydrocarbons using tetramethyl sulfoxide as the extraction solvent. The oils so extracted are the heavier oils, those boiling above about 200.degree. C. and identified as being at least lube base stock grade 60N and higher.
Abstract: The present invention is directed to a fuel oil for diesel engines, which is reduced in the discharges of particulate matters (PM) and carbon dioxide (CO) in exhaust gas upon combustion while retaining a high cetane number, characterized in that the fuel oil composition comprises a mineral oil as a principal component; and(a) 2-13 wt % of one or more dialkyl phthalate compounds represented by the chemical formula (1), and(b) 2-13 wt % of one or more glycol ether compounds represented by the chemical formula (2); andthe total content of said components (a) and (b) is from 4 to 15 wt %.
Type:
Grant
Filed:
January 9, 1998
Date of Patent:
January 26, 1999
Assignee:
Exxon Research and Engineering Company
Inventors:
Masaharu Yamamoto, Naoki Kono, Naomi Murakami, Toshihiko Yoshida
Abstract: The present invention resides in a turbo oil composition exhibiting enhanced antioxidancy and resistance to deposit formation, and to a method for achieving that result in turbo oils. The gas turbine lubricating oil of the present invention comprises a major proportion of synthetic polyol ester based base stock including diesters and polyol esters, preferably polyol ester based base stock and a minor proportion of an antioxidant/deposit control additive, specifically a sulfur-containing carboxylic acid (SCCA) derivative. Other conventional additives such as extreme pressure, pour point reduction, oxidative stability, anti-foaming, hydrolytic stability, improved viscosity index performance, anti-wear, and corrosion inhibitor additives and others may also be employed. The use of SCCA derivative produces a turbo oil exhibiting markedly superior oxidation stability and deposit control performance compared to that exhibited by turbo oil without the SCCA derivative.
Type:
Grant
Filed:
February 4, 1997
Date of Patent:
January 5, 1999
Assignee:
Exxon Research and Engineering Company
Inventors:
Jeenok T. Kim, Patrick Edward Godici, Paul Joseph Berlowitz, Morton Beltzer
Abstract: The present invention is directed to a grease containing base oil, a thickener and a hydrocarbyl substituted diamine additive exhibiting enhanced resistance to corrosion.
Type:
Grant
Filed:
March 14, 1997
Date of Patent:
December 22, 1998
Assignee:
Exxon Research and Engineering Company
Inventors:
David Leslie Andrew, Brian Leslie Slack
Abstract: Multifunctional molybdenum compounds, which are the reactive product of molybdenum dithiocarbamates and metal dihydrocarbyl dithiophosphates, are new compositions which are useful as lubricant additives. They impart to the lubricant formulations to which they are added low friction and excellent wear properties at reduced phosphorous concentrations.
Type:
Grant
Filed:
December 13, 1996
Date of Patent:
September 29, 1998
Assignee:
Exxon Research and Engineering Company
Inventors:
Elisavet P. Vrahopoulou, Richard S. Polizzotti, Daniel Paul Leta, Stephan D. Cameron
Abstract: An automatic transmission fluid of low Brookfield viscosity and high shear stability is disclosed which contains a base oil of lubricating viscosity and a combination of a poly alkyl (meth) acrylate viscosity index improver of low Brookfield viscosity and high shear stability and a functionalized poly alkyl (meth) acrylate viscosity index improver with dispersant properties of high Brookfield viscosity and high shear stability.
Abstract: This invention relates to synthetic based turbo oils, preferably polyol ester-based turbo oils which exhibit exceptional load-carrying capacity by use of a synergistic combination of sulfur (S)-based and phosphorous (P)-based load additives. The S-containing additives of the present invention are DMTD and its derivative including the capped DMTD and the DMTD dimer, and the P-containing component is one or more amine phosphates. The turbo oil composition consisting of the dual P/S additives of the present invention achieves an excellent load-carrying capacity, which is better than that obtained when each additive was used alone at a treat rate higher than or comparable to the total combination additive treat rate, and the lower concentration requirement of the P-based additive allows the turbo oil composition to meet US Navy MIL-L-23699 requirement on the Si seal compatibility.
Type:
Grant
Filed:
March 7, 1997
Date of Patent:
September 1, 1998
Assignee:
Exxon Research and Engineering Company
Inventors:
Manual A. Francisco, Paul Joseph Berlowitz, Jeenok T. Kim
Abstract: A turbo oil possessing improved rust inhibiting properties is provided by adding to the turbo oil base stock minor amounts of monobasic aminophosphates and dicarboxylic acids. The use of the recited combination produces unexpected superior rust resistance performance as compared to use of the individual components. The turbo oil benefitted by the additive is preferably a polyol ester-based oil.
Type:
Grant
Filed:
February 9, 1996
Date of Patent:
August 25, 1998
Assignee:
Exxon Research and Engineering Company
Inventors:
Max J. Wisotsky, Morton Beltzer, Thomas L. Ashcraft, Paul Joseph Berlowitz
Abstract: This invention relates to synthetic based turbo oils, preferably polyol ester-based turbo oils which exhibit exceptional load-carrying capacity by use of a synergistic combination of sulfur (S)-based and phosphorous (P)-based load additives. The S-containing additives of the present invention are thiosemicarbazide and its derivative, and the P-containing component is one or more amine phosphates. The turbo oil composition consisting of the dual P/S additives of the present invention achieves an excellent load-carrying capacity, which is better than that obtained when each additive was used alone at a treat rate higher than or comparable to the total combination additive treat rate, and the lower concentration requirement of the P-based additive allows the turbo oil composition to meet U.S. Navy MIL-L-23699 requirement on the Si seal compatibility.
Abstract: A method is disclosed for improving the thickener yield in soap thickened polyalphaolefin base oil greases comprising the steps of (a) producing a simple or complex soap thickener in a quantity of a first PAO of viscosity lower than that of the base oil component in the final grease composition to produce a thickened PAO and (b) adding to the thickened PAO a quantity of a second PAO of viscosity higher than that desired of the base oil component in the final grease composition sufficient to produce a final grease product having the desired base oil viscosity.
Type:
Grant
Filed:
March 28, 1997
Date of Patent:
July 21, 1998
Assignee:
Exxon Research and Engineering Company
Inventors:
David Leslie Andrew, Brian Leslie Slack
Abstract: It has been discovered that waxy feeds can be upgraded using a catalyst made by combining powdered dewaxing catalyst with powdered isomerization catalyst said mixture of powdered catalysts being formed into a discrete particle.
Type:
Grant
Filed:
February 5, 1997
Date of Patent:
June 23, 1998
Assignee:
Exxon Research & Engineering Company
Inventors:
Dee Anne Brandes, David N. Zinkie, Sandra J. Alward
Abstract: A combination of a fluorosilicone antifoamant and a polyacrylate antifoamant have been found to be effective in reducing foaming of lubricating oils at both low and high temperatures and without degrading the air release time to the extent that would occur with a conventional silicone antifoamant. Neither type of antifoamant is effective in reducing foaming at both low and high temperatures by itself.
Type:
Grant
Filed:
September 10, 1996
Date of Patent:
June 16, 1998
Assignee:
Exxon Research and Engineering Company
Inventors:
Lilianna Zofia Pillon, Andre Ernest Asselin
Abstract: Combustion chamber deposits and intake valve deposits in a spark ignition internal combustion engine which uses a liquid hydrocarbon or liquid hydrocarbon-oxygenate fuel, by using an unleaded fuel to which has been added an additive selected from the group consisting of low boiling alkyl pyridines, 4-vinylpyridine, DMF, N-formylpiperidine, sulfolane, polyolefin, polyether or polyether amine derivatives of DMF, amidene, or N-substituted-2 pyrrolidones, polyolefin in an amount of at least about 1,000 wppm and mixtures thereof. Functionalized polymer detergents can be used alone and added to the fuels in amounts in of about at least 3,000 wppm.
Abstract: The combination (mixture and/or reaction product) of an epoxy based demulsifier and a heterocyclic compound, e.g. dimercaptoth-iadiazole, has been found to exhibit synergistic activity in marine oil formulations especially Trunk Piston Oils. The combination produces Trunk Piston Oils with improved water-shedding properties.