Patents Represented by Attorney L. Wayne White
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Patent number: 4629570Abstract: A process is described for removing dissolved iron from an aqueous liquid containing iron in the form of a soluble complex with alkylenepolyamine polyacetic acids or salts thereof. The process comprises the steps of (a) adjusting the pH of said aqueous liquid to at least about 12.5, (b) adding sufficient quantities of a soluble calcium salt to facilitate the growth of insoluble iron hydroxide particles, and (c) separating the resulting insoluble mass containing iron hydroxide from the liquid effluent.Type: GrantFiled: July 18, 1985Date of Patent: December 16, 1986Assignee: Dowell Schlumberger IncorporatedInventor: Weldon C. Kennedy, Jr.
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Patent number: 4623399Abstract: Liquid and foam formulations useful for removing iron oxide deposits, for example from heat transfer equipment, comprising an organic solution or foam of N-hydroxylethyl ethylenediamine triacetic acid and an organic acid (for example, formic acid); and a method of removing iron oxide deposits from encrusted equipment surfaces by injecting the liquid or foam formulation, preferably also containing a corrosion inhibitor, into equipment to be cleaned, and circulating the liquid or foam formulation.Type: GrantFiled: February 4, 1985Date of Patent: November 18, 1986Assignee: Dowell Schlumberger IncorporatedInventor: Wayne W. Frenier
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Patent number: 4614435Abstract: The machine disclosed herein is useful for blending solids with fluids. In a typical operation, sand is mixed with a gel composition to obtain a fluid mixture suitable for stimulation treatments of oil and gas wells. The machine includes a slinger member, of a toroidal shape, and an impeller, of a vortex configuration, that is fastened underneath the slinger. In this machine entrained air is carried into the fluid phase by the sand, but the air is then "exhausted" from the sand-gel mixture through interior and exterior air exhaust channels and spaces that are built into the machine.Type: GrantFiled: March 21, 1985Date of Patent: September 30, 1986Assignee: Dowell Schlumberger IncorporatedInventor: William R. McIntire
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Patent number: 4612814Abstract: The instrument disclosed herein is designed for measuring flow rates and densities of moving fluid streams, including liquids, gases, slurries, and fluids which contain solid materials. In one embodiment of this instrument, a conduit section, which has a 90 degree bend therein, is placed in a transfer line which carries the fluid stream to its use point. Defined within the conduit section is a chamber, which is located at the bend in the conduit. Installed within the chamber is a force measuring transducer and a piston, which is in contact with the diaphragm assembly of the transducer. In operation, part of the moving fluid is diverted into the chamber, to equalize fluid pressure across the diaphragm assembly of the transducer and the piston. This removes the effect of fluid pressure on the flow rate and density measurement, and allows the moving fluid to displace the piston by the force exerted by the fluid.Type: GrantFiled: June 29, 1983Date of Patent: September 23, 1986Assignee: Dowell Schlumberger IncorporatedInventor: Keith S. Campman
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Patent number: 4601758Abstract: A salt water hydraulic cement slurry and method of use in oil and gas well cement jobs involving a novel fluid loss additive comprising an admixture of sulfonated aromatic polymers. An effective amount of an admixture of water soluble salts of a sulfonated styrene/maleic anhydride copolymer, sulfonated polystyrene, sulfonated polyvinyltoluene and sulfonated polynaphthalene/formaldehyde condensate when added to a salt water/Portland cement slurry provides fluid loss control to the Portland cement slurry at bottomhole circulating temperature between 80.degree. and 210.degree. F. Further, addition of and/or the replacement of the sulfonated polystyrene by a water soluble lignosulfonate further enhances the high temperature properties of the salt water cement slurry.One exception to this appears in British Pat. No.Type: GrantFiled: February 25, 1985Date of Patent: July 22, 1986Assignee: Dowell Schlumberger IncorporatedInventor: Erik B. Nelson
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Patent number: 4591447Abstract: A novel buffered gelling/foaming agent and resulting gelled aqueous inorganic acid solution involving a N,N-bis (2-hydroxyethyl) fatty amine acetic acid salt (e.g., N,N-bis (2-hydroxyethyl) tallow ammonium acetate); alkali metal acetate; and acetic acid buffered system. The buffered gelling/foaming agent compositions exhibit pragmatic advantages in preparation, handling and use particularly at low temperatures because of low pour points (e.g., 5.degree.-10.degree. F.). Furthermore, the buffered gelling agent more efficiently utilizes the active ingredients in terms of desired viscosity rise as a function of concentration. The resulting gelled aqueous inorganic acid solutions using the buffered gelling agent exhibit a novel viscosity rise and calcium ion viscosity contribution as the concentrated acid is partially spent (i.e., approaches 12%), yet the totally spent acid returns to a nominal viscosity and is a foaming medium.Type: GrantFiled: March 16, 1984Date of Patent: May 27, 1986Assignee: Dowell Schlumberger IncorporatedInventor: Gregory Kubala
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Patent number: 4574050Abstract: The formation and subsequent precipitation of undesirable ferric compounds during the acid treatment of wells is substantially eliminated by incorporating in said treating acid an inhibiting amount of a monobasic alkanoic and/or alkenoic acid having at least four carbon atoms and bearing at least two alcoholic hydroxyl groups per molecule, and/or a soluble salt or .gamma.-lactone of said acid. E.g. ascorbic acid or erythorbic acid.Type: GrantFiled: July 18, 1985Date of Patent: March 4, 1986Assignee: Dowell Schlumberger IncorporatedInventors: Curtis W. Crowe, Charles M. Maddin
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Patent number: 4572519Abstract: In plunger-type pumps a packing assembly is installed around the plunger to prevent fluid from leaking past the moving plunger. The packing assembly includes male and female adaptor rings, which are in face-to-face contact with the packing rings, but provide only a "sloppy" fit. The practice of this invention involves shaping the adaptor ring faces to conform precisely to the shape of the packing ring faces against which they are seated.Type: GrantFiled: June 14, 1984Date of Patent: February 25, 1986Assignee: Dowell Schlumberger IncorporatedInventors: Donald C. Cameron, Homer V. Cobb, Fred M. Winn
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Patent number: 4556109Abstract: A pumpable slurry of coal-filled furfuryl alcohol, furfural, and/or a low molecular weight mono- or copolymer thereof containing, preferably, a catalytic amount of a soluble acid catalyst is used to cement a casing in a geothermal well.Type: GrantFiled: July 2, 1979Date of Patent: December 3, 1985Assignee: The Dow Chemical CompanyInventor: Louis H. Eilers
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Patent number: 4548270Abstract: Aqueous silicate solutions when admixed, intermingled or otherwise contacted with hydraulic cement slurries cause a very rapid gelation and accelerated setting of the hydraulic cement composition.It has now been discovered that this rapid gelation/accelerated setting phenomenon can be controlled and substantially delayed by incorporating a water soluble inorganic phosphate salt into an aqueous spacer fluid positioned between said silicate solution and said cement slurry as such materials are being sequentially injected into a subterranean formation.Type: GrantFiled: October 6, 1983Date of Patent: October 22, 1985Assignee: The Dow Chemical CompanyInventor: Louis H. Eilers
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Patent number: 4397351Abstract: A packer tool, and method for permanently setting the tool, in a packed off position, in a well casing, is disclosed. The tool includes lower slips which are slideable upwardly on a lower cone, and upper slips which are slideable downwardly on an upper cone. The lower slips are set against the casing wall first by applying downward force against the lower cone. After the lower slips have been set, additional downward force is applied against the packer tool to set the upper slips against the casing wall.Type: GrantFiled: April 27, 1981Date of Patent: August 9, 1983Assignee: The Dow Chemical CompanyInventor: Monty E. Harris
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Patent number: 4382003Abstract: Aqueous compositions having properties making them suitable for use as a hydraulic fracturing fluids are disclosed. These compositions comprise (a) an uncrosslinked aqueous polysaccharide solution, and (b) a 4,4'-thiodiphenol. Ingredient (b) acts as a "breaker" and causes the composition to lose viscosity at a controlled rate.Type: GrantFiled: February 2, 1981Date of Patent: May 3, 1983Assignee: The Dow Chemical CompanyInventors: Clare H. Kucera, Richard B. Connell
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Patent number: 4367651Abstract: A pressure transducer body is described which has a bore running its length and contains (a) a means for receiving a pressure transducer, (b) a fluid reservoir, (c) a stationary elastic plug member having embedded therein a T-shaped rigid pin member, and (d) a chamber for receiving a fluid under pressure. The elements of the transducer body are combined in such a way that pressures of fluids flowing into chamber (d) are accurately measured using conventional pressure transducers even at very high pressures (e.g. 20,000 psi). More importantly, perhaps, the configuration of the transducer body permits accurate pressure measurements on pressurized fluids which are corrosive and/or abrasive. This makes the pressure transducer bodies particularly useful in the oilfield service industries for measuring the pressure of acidizing or hydraulic fracturing fluids used in stimulation.Type: GrantFiled: March 30, 1981Date of Patent: January 11, 1983Assignee: The Dow Chemical CompanyInventors: Donald C. Cameron, Donnie L. Stufflebeam, John W. Ekey
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Patent number: 4278809Abstract: 2-Isocyanatoalkyl esters of organic carboxylic acids are prepared by reacting (a) an aqueous solution of a 2-oxazoline with (b) an organic solution of phosgene dissolved in a water-immiscible organic solvent in the presence of (c) a hydrochloric acid acceptor. As an example, 2-isocyanatoethyl methacrylate was prepared by concurrently blending an aqueous stream of 2-isopropenyl-2-oxazoline, a methylene chloride stream of phosgene and an aqueous stream of sodium hydroxide at a temperature of from about 0.degree. C. to about 10.degree. C. The reaction rate is very high and the reaction is essentially complete upon blending the reactants.Type: GrantFiled: June 15, 1977Date of Patent: July 14, 1981Assignee: The Dow Chemical CompanyInventor: Kenneth A. Burdett
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Patent number: 4261925Abstract: Surfactants having an HLB of from about 12 to about 20, preferably 14 to about 20, are disclosed which correspond to formulas I and II: ##STR1## wherein: R.sub.1 is a nonpolymerizable hydrocarbyl or inertly-substituted hydrocarbyl group of at least 8 carbon atoms; R.sub.2 is hydrogen or alkyl; X is ##STR2## Y is a terminal inorganic or organic group; and n is at least 2.Type: GrantFiled: April 5, 1978Date of Patent: April 14, 1981Assignee: The Dow Chemical CompanyInventors: Donald A. Tomalia, James D. Huffines
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Patent number: 4254559Abstract: The interior surface of a pipeline is dried by sequentially passing through the pipeline (a) an aqueous cross-linked gelled pig, (b) a fluid mobility buffer comprising a non-crosslinked gelled ankanol of from one to three carbon atoms, (c) a dessicating amount of a liquid alkanol from one to three carbon atoms. For example, a pipeline was dried by sequentially passing through it (a) a borate cross-linked hydroxypropyl guar gum pig, (b) a fluid mobility buffer comprising methanol thickened with hydroxypropyl cellulose, and (c) methanol.Type: GrantFiled: February 19, 1980Date of Patent: March 10, 1981Assignee: The Dow Chemical CompanyInventor: Robert J. Purinton, Jr.
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Patent number: 4250044Abstract: A tertiary amine/persulfate breaker system is disclosed which effects complete breaks of polysaccharide based water-gels or fluids in the ambient temperature range. Induction time may be controlled over wide permissible limits. The invention claims improved compositions and methods, particularly advantageously applied to the treatment and stimulation of shallow oil and gas wells (formation temperatures from about 50.degree. to 125.degree. F.).Type: GrantFiled: June 26, 1978Date of Patent: February 10, 1981Assignee: The Dow Chemical CompanyInventor: Jerald J. Hinkel
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Patent number: 4247430Abstract: An aqueous based slurry is described comprising (1) a thickened water-based carrying fluid, (2) a particulate solid, e.g., gravel, and (3) a resin system comprising an epoxy resin and a novel crosslinking agent. The cross-linking agent is a polymethylene polyphenylamine bearing one or more silane groups of the formula--CH.sub.2 CH(OH)CH.sub.2 O--C.sub.3 -C.sub.6 alkylene --Si(OR').sub.3,wherein each R' independently is hydrogen or lower alkyl. This pumpable slurry is suitable for use in emplacing a permeable, consolidated gravel pack between the casing of a well and an incompetent subterranean formation. The slurry is easily formed on site by merely blending the components in an appropriate ratio using conventional equipment.Type: GrantFiled: April 11, 1979Date of Patent: January 27, 1981Assignee: The Dow Chemical CompanyInventor: Vernon G. Constien
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Patent number: 4245063Abstract: A thermosetting powder coating composition is disclosed herein. The composition comprises a solid pulverulent mixture of (A) a substantially linear vinyl addition interpolymer having a plurality of pendant 2-oxazoline and/or 2-oxazine groups, a number average molecular weight of from about 5,000 to about 25,000, and a melting point of from about 60.degree. C. to 90.degree. C., and (B) a solid polycarboxylic acid melting in the range of 70.degree. C. to 175.degree. C. which is included in an amount of from 0.75 to 1.25 carboxy equivalents per pendant oxazoline or oxazine group on the interpolymer. The utility of the above composition as a powder coating is further enhanced by inclusion of a plasticizer (e.g., a long chain monocarboxylic acid) and in practice, the powder compositions also normally include pigments and minor amounts of flow control agents. The instant powder coatings are applied by conventional techniques and cured at temperatures normally in the range of from about 150.degree. C. to about 200.Type: GrantFiled: October 16, 1978Date of Patent: January 13, 1981Assignee: The Dow Chemical CompanyInventors: Bruce P. Thill, Donald A. Tomalia
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Patent number: 4225718Abstract: Substantially pure 2,3,5,6-tetrachloropyridine is recovered from a mixture of chlorinated pyridines containing initially 2,3,5,6-tetrachloropyridine and other chlorinated pyridines in an improved process which comprises (a) reacting by contacting a first mixture of chlorinated pyridines with chlorine in the presence of a strong Lewis acid catalyst to thereby obtain a second mixture consisting essentially of 2,3,5,6-tetrachloropyridine and pentachloropyridine, and (b) recovering the 2,3,5,6-tetrachloropyridine from said second mixture. The reaction is normally conducted at a temperature of from about 150.degree. C. to about 300.degree. C. by pressurizing chlorine into a molten mixture of the chlorinated pyridines and maintaining such conditions until substantially all of the isomers have been converted to the symmetrical tetrachloropyridine or pentachloropyridine.Type: GrantFiled: February 22, 1979Date of Patent: September 30, 1980Assignee: The Dow Chemical CompanyInventors: Donald J. Perettie, Norman L. Dean