Abstract: Compositions and methods for treating substrates are disclosed. The compositions are generally described as epoxy-novolac resins containing a Mannich derivatized bisphenol side chain. The methods, which comprise contacting the surface to be treated with these compositions, improve the corrosion resistance and/or adhesion properties of the treated surface.
Type:
Grant
Filed:
December 23, 1998
Date of Patent:
June 19, 2001
Assignee:
Calgon Corporation
Inventors:
Hong Ding, Shih-Ruey Thomas Chen, Yi Jin Warburton
Abstract: The invention provides novel cationic flocculant dispersion polymers that can be utilized in the methods disclosed herein. This invention also provides methods for detecting cationic flocculants wherein said flocculants may be made via a dispersion process, a latex process or a dry polymer process. The flocculants are used to flocculate solids from liquid components of an industrial food process. The detection method involves the use of monoclonal antibodies to determine the presence or concentration of the cationic flocculants in the liquids.
Type:
Grant
Filed:
March 10, 1999
Date of Patent:
May 29, 2001
Assignee:
Nalco Chemical Company
Inventors:
Andrew J. Dunham, Cathy C. Johnson, Kristine S. Salmen, John W. Sparapany, Anthony G. Sommese
Abstract: A method for determining wafer cleanliness by fluorometric monitoring of the impurities in the semiconductor chip wafer rinse solution. A clean chip is indicated by a leveling off of increased concentration of impurities as the rinsing of the chip progresses. A method for optimizing reuse or recyling of the water discharged from the rinse process which accurately measures the contaminants in that water.
Abstract: A papermaking process consisting essentially of:
forming an aqueous cellulosic papermaking slurry;
adding to the slurry certain additives, with said certain additives selected from the group including: coagulants; sizing agents; and mineral fillers;
draining the slurry to form a sheet; and
drying the sheet to form a paper sheet;
the improvement comprising adding to the slurry, prior to it being drained; an effective amount of a cationic dispersion polymer; which cationic dispersion polymer is a copolymer comprising about 30 mole % diallyldimethylammonium chloride (DADMAC) and about 70 mole % acrylamide (AcAm); and
adding to the slurry, either before or after said cationic dispersion polymer is added and the slurry is drained,
a microparticle selected from the group consisting of
a) copolymers of acrylic acid and acrylamide;
b) bentonite; and
c) dispersed silica;
with the proviso that said coagulant cannot be a cationic dispersion copolymer comprising about 30 mole % diallyldimethylammonium chloride
Type:
Grant
Filed:
May 21, 1999
Date of Patent:
May 29, 2001
Assignee:
Nalco Chemical Company
Inventors:
Jane B. Wong Shing, Chidambaram Maltesh, Ramasubramanyam Nagarajan
Abstract: The present invention is directed to an improved process for inhibiting calcium carbonate scaling in aqueous systems such as that employed in the kraft process for the production of wood pulp. Such an improved process is achieved by the addition to the system of at least one antiscalant comprising at least one monomer unit derived from the group consisting of 1,2-dihydroxy-3-butene, N-(hydroxymethyl) acrylamide, and N-(sulfomethyl) acrylamide, and at least one monomer unit derived from the group consisting of maleic acid, acrylic acid, acrylamide, methacrylic acid, itaconic acid, vinyl sulfonic acid, styrene sulfonic acid, N-tertbutylacrylamide, butoxymethylacrylamide, N,N-dimethylacrylamide, sodium acrylamidomethyl propane sulfonic acid, and salts thereof, with with the proviso that said polymers do not contain the monomer unit —(CH2—CH═CH—CH2—O)—.
Type:
Grant
Filed:
November 9, 1999
Date of Patent:
May 22, 2001
Assignee:
Nalco Chemical Company
Inventors:
Prasad Yogendra Duggirala, John David Morris, Peter Edward Reed, Steven John Severtson
Abstract: The present invention provides a novel class of polymer antiscalants which are polymers comprising a 1,2-dihydroxy-3-butene monomer unit and at least one monomer unit derived from the groups consisting of maleic acid, acrylic acid, acrylamide, methacrylic acid, itaconic acid, vinyl sulfonic acid, styrene sulfonic acid, N-tertbutylacrylamide, butoxymethylacrylamide, N,N-dimethylacrylamide, sodium acrylamidomethyl propane sulfonic acid, and salts thereof, with the proviso that said polymers do not contain the monomer unit —(CH2—CH═CH—CH2—O)—.
Type:
Grant
Filed:
November 9, 1999
Date of Patent:
May 15, 2001
Assignee:
Nalco Chemical Company
Inventors:
Prasad Yogendra Duggirala, John David Morris, Peter Edward Reed, Steven John Severtson
Abstract: A method for measuring the concentration of an anionically charged polymer in an aqueous solution is described and claimed. The method requires a reagent solution that is also described and claimed. The reagent solution comprises water, Nile Blue Dye and chelant, with the chelant being selected from the group consisting of the alkali metal or ammonium salts of phosphonobutane tricarboxylic acid. The method involves using absorbance measurements to determine the amount of anionically charged polymer present in an aqueous sample. The method is very rapid and thus is very useful under field conditions.
Abstract: Anionic nanocomposites for use as retention and drainage aids in papermaking are prepared by adding an anionic polyelectrolyte to a sodium silicate solution and then combining the sodium silicate and polyelectrolyte solution with silicic acid.
Abstract: An improved process for inhibiting calcium carbonate scaling in aqueous systems such as that employed in the kraft process for the production of wood pulp. Such an improved process is achieved by the addition to the system of at least one antiscalant comprising at least one monomer unit derived from the group consisting of 1,2-dihydroxy-3-butene, N-(hydroxymethyl) acrylamide, and N-(sulfomethyl) acrylamide, and at least one monomer unit derived from the group consisting of maleic acid, acrylic acid, acrylamide, methacrylic acid, itaconic acid, vinyl sulfonic acid, styrene sulfonic acid, N-tertbutylacrylamide, butoxymethylacrylamide, N,N-dimethylacrylamide, sodium acrylamidomethyl propane sulfonic acid, and salts thereof, with the proviso that said polymers do not contain the monomer unit --(CH.sub.2 --CH.dbd.CH--CH.sub.2 --O)--.
Type:
Grant
Filed:
August 31, 1998
Date of Patent:
November 14, 2000
Assignee:
Nalco Chemical Company
Inventors:
Prasad Yogendra Duggirala, John David Morris, Peter Edward Reed, Steven John Severtson
Abstract: Improved performance in the phase separation of aqueous brines from hydrocarbons within an electrostatic desalter operation is obtained by the addition to the crude oil emulsions entering the desalter of an effective asphaltene dispersing amount of an alkyl phenol-formaldehyde liquid resin polymer, optionally in the presence of a lipophilic/hydrophilic vinylic polymer. The preferred resin is a nonyl phenol-formaldehyde resin having a molecular weight of from 1,000-20,000, and the preferred vinylic polymer is a copolymer of lauryl (meth)acrylate and hydroxyethyl (meth)acrylate. Best results from the electrostatic desalter are obtained when also using a demulsifier chemical treatment along with the asphaltene dispersing treatments. Desalter efficiency is increased and desalter brine effluent quality is greatly increased.
Type:
Grant
Filed:
October 5, 1993
Date of Patent:
September 19, 2000
Assignee:
Nalco Chemical Company
Inventors:
William K. Stephenson, Joe Scott Walker, Bordan W. Krupay, Sheraldean A. Wolsey-Iverson
Abstract: Methods for controlling wax and other contaminants by improving the dispersion of these materials through the addition of treatment agents such as plasticizers, dispersants or wetting agents to the process of recycling paper and paperboard are disclosed. Preferred treatment agents include polymeric wetting agents, dispersants, plasticizers and combinations thereof.
Abstract: Anionic nanocomposites for use as retention and drainage aids in papermaking are prepared by adding an anionic polyelectrolyte to a sodium silicate solution and then combining the sodium silicate and polyelectrolyte solution with silicic acid.
Abstract: The present invention provides for an improved method for monitoring the concentration of molecules and chemical treatment agents in ceramic slurries and powders.
Type:
Grant
Filed:
December 31, 1998
Date of Patent:
May 9, 2000
Assignee:
Nalco Chemical Company
Inventors:
Kevin J. Moeggenborg, James E. Whitten, Joseph C. Alfano
Abstract: A method for increasing the separation of solids from an aqueous slurry containing such solids is disclosed. The separation process is particularly useful in the separation of the solid components of a papermill furnish from water in the manufacture of paper. The method comprises the steps of adding to a paper mill slurry from about 0.003 to about 1.0% by weight based on total solids in the slurry of a phenolic enhancer and a nonionic (meth)acrylamide homopolymer methacrylamide, or anionic or cationic flocculant is added to the slurry in an amount of from about 0.003 to about 0.5% by weight based on total solids in the slurry. Addition order is non-critical. The flocculation of solid components of the paper mill slurry is increased leading to improved retention of filler and fiber on the sheet and increased drainage of water from the cellulosic sheet produced. The method is also applicable to the treatment of waste waters, mineral tailings, oily waste waters, municipal and industrial wastes, and the like.
Type:
Grant
Filed:
November 26, 1997
Date of Patent:
April 11, 2000
Assignee:
Nalco Chemical Company
Inventors:
Scott W. Rosencrance, Przemyslaw Pruszynski, Shamel M. Shawki, Regina Jakubowski, Jeff F. Lin
Abstract: A method for increasing retention and drainage of filling components in a paper making furnish in a paper making process comprising the steps of: making a slurry of filling components, treating the slurry with from about 0.003% to about 2.0% by weight based on total solids of a phenolic enhancer to form a pretreated filling components slurry, adding to the furnish the pretreated slurry and adding to the furnish from about 0.003 to about 0.5% by weight based on total solids in the slurry of a polymeric flocculent, whereby retention and drainage of filling components in the paper making furnish is increased. A preferred enhancer is a condensate of phenol and formaldehyde and preferred flocculants contain acrylamide, methacrylamide, and/or N-vinylformamide.
Type:
Grant
Filed:
November 24, 1997
Date of Patent:
March 7, 2000
Assignee:
Nalco Chemical Company
Inventors:
Przemyslaw Pruszynski, Regina Jakubowski, John R. Armstrong, Scott W. Rosencrance
Abstract: The invention relates to a paper making process in which improved drainage and retention is obtained by the addition of an effective amount of a cationic dispersion polymer to an aqueous cellulosic paper making slurry prior to shearing the slurry; which cationic dispersion polymer is selected from a group of copolymers consisting of:i) a copolymer of about 10 mole % DMAEA.BCQ and about 90 mole % AcAm;ii) a copolymer of about 10 mole % DMAEA.MCQ and about 90 mole % AcAm; andiii) a copolymer of about 20 mole % DMAEA.MCQ and about 80 mole % AcAm; andadding to the slurry, after said cationic dispersion polymer is added and the slurry is sheared,a microparticle selected from the group consisting ofa) copolymers of acrylic acid and acrylamide;b) bentonite; andc) dispersed silica.
Abstract: A method is disclosed for controlling anionic trash and pitch deposition and treating coated broke which comprises the step of adding a polyammonium quaternary to a pulp and papermaking system. The polyammonium quaternary, which may be either branched or crosslinked, comprises at least one cationic monomer, preferably diallyldimethylammonium chloride, and at least one branching or crosslinking monomer, preferably N,N,N-triallylamine or N,N,N-triallylamine hydrochloride.
Type:
Grant
Filed:
September 10, 1997
Date of Patent:
November 23, 1999
Assignee:
Nalco Chemical Company
Inventors:
Jiansheng Tang, Jeffrey R. Cramm, Michael R. St. John, Laura M. Sherman
Abstract: A cationic water-soluble polymer comprising from 0.001 to 10 mole percent of a repeating mer unit represented by the formula ##STR1## wherein a is an integer of from 1 to 10, R.sub.1 is selected from the group consisting of hydrogen and methyl groups, R.sub.2 and R.sub.3 are methyl groups, fluor is a fluorescing moiety and X is selected from the group consisting of chloride, iodide and bromide ions and wherein the polymer also contains from 90 to 99.
Abstract: Processes for removing color from a paper mill waste effluent and for removing color from a textile plant waste effluent utilizing an amphoteric copolymer/polyamine combination are described. A preferred amphoteric copolymer is poly(dimethylaminoethylacrylate methyl chloride quaternary salt/acrylic acid) and a preferred polyamine is a polymeric reaction product of epichlorohydrin and dimethylamine.
Type:
Grant
Filed:
December 18, 1997
Date of Patent:
October 5, 1999
Assignee:
Nalco Chemical Company
Inventors:
Michael L. Braden, Richard E. Metzgar, Jitendra T. Shah
Abstract: Deadburned magnesium oxides (calcined at a temperature of above about 4000.degree. F.) can be advantageously utilized as an expanding additive in cements utilized to seal a metallic casing into the bore hole of a well. The deadburned magnesium oxide additives are particularly effective when used in cements having a curing temperature of about 120-200.degree. C. and particularly at temperatures greater than about 150.degree. C.