Patents Represented by Attorney, Agent or Law Firm Michael F. Esposito
  • Patent number: 6362355
    Abstract: A molybdated dispersant composition represented by the formula: (R1—NR2R3H+)m−nXn(MoHPA)m− provides good friction properties to lubricants. In the formula, R1—NR2R3 represents an amine-containing dispersant, R1 is a group providing dispersant properties to said dispersant composition, each of R2 and R3 is independently hydrogen, a hydrocarbyl group, or an additional R1 group; X is hydrogen, a monovalent metal ion, a single valence of a polyvalent metal ion, an ammonium ion, or an amine cation, m is 3 or 4, n is 0 to about 2.5 when m is 3 and 0 to about 3.5 when m is 4, and (MoHPA)m− is a molybdenum heteropolyacid anion of charge m.
    Type: Grant
    Filed: January 21, 2000
    Date of Patent: March 26, 2002
    Assignee: The Lubrizol Corporation
    Inventors: Thomas F. Steckel, Ping Y. Zhu
  • Patent number: 6362136
    Abstract: This invention relates to compositions containing a sulfur containing antiwear/extreme pressure agent, basic nitrogen compound or a mixture thereof together with a hydrocarbyl mercaptan. The composition may additionally contain a phosphorus or boron antiwear or extreme pressure agent, a dispersant or an overbased metal salt. The invention also relates to lubricants, functional fluids, and concentrates containing the same. Seals, e.g. nitrile, polyacrylate, and fluoroelastomer, in contact with these composition have reduced deterioration. With the use of these compositions, lubricants, and functional fluids, the seals' useful life is extended.
    Type: Grant
    Filed: March 26, 1996
    Date of Patent: March 26, 2002
    Assignee: The Lubrizol Corporation
    Inventors: Robert C. Richardson, Donald J. Marn
  • Patent number: 6346585
    Abstract: Calcined ammonium salts of phosphotungstic acid salts are used to polymerize C2-C30 &agr;-olefins and derivatives thereof to form highly reactive products having a high content of terminal vinylidene groups and &bgr;-isomers in resonance therewith.
    Type: Grant
    Filed: June 24, 1999
    Date of Patent: February 12, 2002
    Assignee: The Lubrizol Corporation
    Inventors: John R. Johnson, James D. Burrington
  • Patent number: 6344517
    Abstract: The present invention relates to a metalworking fluid composition comprising an aqueous composition or dispersion containing a water-soluble or water-dispersible synthetic polymer, and method of use thereof. The aqueous composition or dispersion is added to a metal working fluid composition to impart aerosol control and shear stability.
    Type: Grant
    Filed: December 28, 1999
    Date of Patent: February 5, 2002
    Assignee: The Lubrizol Corporation
    Inventors: Robert E. Quinn, Richard A. Denis, Sanjay N. Kalhan
  • Patent number: 6342551
    Abstract: This invention relates to a powder coating composition made by combining at least two components comprising (A) a film forming thermosetting resin composition; and (B) a transfer-efficiency enhancing amount of at least one amide; wherein component (B) is incorporated into the powder coating composition by the addition of component (B) to an extruded composition comprising components other than (B). The invention also relates to a method for coating a substrate using the foregoing powder coating composition.
    Type: Grant
    Filed: November 25, 1998
    Date of Patent: January 29, 2002
    Assignee: The Lubrizol Corporation
    Inventors: Scott T. Jolley, Charles F. Williams
  • Patent number: 6340659
    Abstract: Lubricants which comprise, as an additive a salt of the reaction product of (i) glyoxylic acid or a hydrocarbyl substituted glyoxylic acid and (ii) a hydroxyaromatic compound, at least a portion of the molecules of which are alkyl-substituted, are useful for lubricating ceramic-containing engines, high temperature engines, and natural gas-fueled engines. Particularly useful additives are those in which the hydroxyaromatic compound is a dialkyl phenol containing a t-butyl group in an ortho position.
    Type: Grant
    Filed: December 13, 1995
    Date of Patent: January 22, 2002
    Assignee: The Lubrizol Corporation
    Inventors: Jody A. Kocsis, Sheri L. Blystone, Ewa A. Bardasz, Marvin B. DeTar
  • Patent number: 6331510
    Abstract: A lubricant containing (a) a synthetic base oil composition having an overall kinematic viscosity of at least about 4.8×10−6 m2/s (4.8 cSt) at 100° C. and a viscosity index of at least about 110; (b) a dispersant-viscosity modifier; and (c) a sulfur-free functionalized hydrocarbyl-substituted phenol detergent provides improved valve train wear, with longer drain intervals, to heavy duty diesel engines.
    Type: Grant
    Filed: February 13, 2001
    Date of Patent: December 18, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Thomas T. Curtis, Gordon D. Lamb, William D. Abraham
  • Patent number: 6326187
    Abstract: Soil, which is contaminated by one or more hydrophobic organic chemicals, can be cleaned or remediated using an aqueous composition with a surfactant prepared by reacting an alkenylsuccinic anhydride or acid with an amine acid or salt of an amine acid. The surfactant allows at least a portion of the hydrophobic organic chemical to be removed from the soil by becoming associated with the aqueous composition, which is then separated from the soil.
    Type: Grant
    Filed: October 14, 1999
    Date of Patent: December 4, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Robert N. Jones, James H. Bush, Stuart L. Bartley, John J. Mullay, Gregory M. Mlachak
  • Patent number: 6310011
    Abstract: Lubricants containing metal salts of hydrocarbyl-substituted carboxyalkylene-linked phenols, dihydrocarbyl esters of alkylene dicarboxylic acids, the alkylene group being substituted with a hydroxy group and an additional carboxylic acid group, or alkylene-linked polyaromatic molecules, the aromatic moieties whereof comprise at least one hydrocarbyl-substituted phenol and at least one carboxy phenol, where the hydrocarbyl groups are of sufficient length to provide oil solubility to the salt, exhibit good asphaltene suspension for marine diesel applications. Preferably the salts are overbased.
    Type: Grant
    Filed: October 17, 1994
    Date of Patent: October 30, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Jack L. Karn, Jody A. Kocsis, Laurence E. King, Paul E. Adams, Vincent A. Notaro
  • Patent number: 6310009
    Abstract: A saligenin derivative such as the magnesium salt represented by the formula is useful as an additive for a lubricating composition. Preferably X is —CHO or —CH2OH, and Y is —CH2— or —CH2OCH2—. R1 is a hydrocarbyl group containing 1 to 60 carbon atoms and m is 0 to 10. At least one aromatic ring should contain an R1 substituent and the total number of carbon atoms in all R1 groups should be at least 7.
    Type: Grant
    Filed: January 16, 2001
    Date of Patent: October 30, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Jody A. Kocsis, James P. Roski, Virginia A. Carrick, Richard A. Denis, Thomas J. Wolak, Gordon D. Lamb, Paul E. Adams, William D. Abraham, Susan V Cowling
  • Patent number: 6306816
    Abstract: The reaction product of an alkylenediamine, each amino group thereof being a primary or secondary amino group; with at least two equivalents of an acrylamidoalkanesulfonic acid or a salt thereof, wherein each amine nitrogen atom of said alkylenediamine is reacted with a single molecule of the acrylamidoalkane sulfonic acid or salt thereof provides a useful surfactant or hydrotrope.
    Type: Grant
    Filed: January 9, 2001
    Date of Patent: October 23, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Philip W. Pike, Bryan A. Grisso, Richard W. Jahnke
  • Patent number: 6303795
    Abstract: A surfactant which is the reaction product of a hydrocarbyl-substituted succinic anhydride or a reactive equivalent thereof with at least one water-dispersible amine-terminated poly(oxyalkylene), is effective for use in soil remediation.
    Type: Grant
    Filed: April 28, 2000
    Date of Patent: October 16, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Richard W. Jahnke, Bryan A. Grisso
  • Patent number: 6300288
    Abstract: A grease of an oil of lubricating viscosity, a polyolefin having grafted acid functionality, a metallic species capable of interacting with the acid functionality of said polyolefin to cause association among the acid groups and a co-thickening agent, has improved rheological properties. The co-thickening agent and the metallic species can together comprise a gelled overbased material, particularly an overbased carboxylate.
    Type: Grant
    Filed: March 31, 1994
    Date of Patent: October 9, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Curtis R. Scharf, Steven R. Twining, Patricia R. Todd
  • Patent number: 6280485
    Abstract: This invention relates to an emulsified water-blended fuel composition comprising: (A) a hydrocarbon boiling in the gasoline or diesel range; (B) water; (C) a minor emulsifying amount of at least one fuel-soluble salt made by reacting (C)(I) at least one acylating agent having about 16 to 500 carbon atoms with (C)(II) ammonia and/or at least one amine; and (D) about 0.001 to about 15% by weight of the water-blended fuel composition of a water soluble, ashless, halogen-, boron-, and phosphorus-free, amine salt, distinct from component (C). In one embodiment, the composition further comprises (E) at least one cosurfactant distinct from component (C); in one embodiment, (F) at least one organic cetane improver; and in one embodiment, (G) at least one antifreeze. The invention also relates to a method for fueling an internal combustion engine comprising fueling said engine with the composition of the present invention.
    Type: Grant
    Filed: September 7, 1999
    Date of Patent: August 28, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Daniel T. Daly, John J. Mullay, Elizabeth A. Schiferl, Deborah A. Langer, David L. Westfall, Harshida Dave, Brian B. Filippini, William D. Abraham
  • Patent number: 6268320
    Abstract: This invention relates to a composition comprising at least one sulphur-containing calixarene represented by formula (I) or a metal salt of said calixarene, wherein in formula (I): Y is a divalent bridging group, at least one of said bridging groups being a sulphur atom; R3 is hydrogen, a hydrocarbyl or a hetero-substituted hydrocarbyl group; either R1 is hydroxyl and R2 and R4 are independently either hydrogen, hydrocarbyl or hetero-substituted hydrocarbyl, or R2 and R4 are hydroxyl and R1 is either hydrogen, hydrocarbyl or hetero-substituted hydrocarbyl; and n is a number having a value of at least 4. In one embodiment, the foregoing salt is an overbased salt. The invention also relates to additive compositions and finished lubricating oil compositions containing the foregoing overbased salt. The invention also relates to a process for making the foregoing overbased salt.
    Type: Grant
    Filed: May 5, 1999
    Date of Patent: July 31, 2001
    Assignee: Lubrizol Adibis Holdings (UK) Limited
    Inventor: John Crawford
  • Patent number: 6265360
    Abstract: The present invention relates to a wax-containing liquid hydrocarbon fuel composition comprising (a) at least one wax-containing liquid hydrocarbon; and b) a transesterified acrylate polymer obtained by transesterifying a starting acrylate polymer with at least one higher alcohol, the transesterified acrylate polymer being present in an amount sufficient to modify the cold flow properties of the wax containing liquid hydrocarbon fuel.
    Type: Grant
    Filed: November 12, 1999
    Date of Patent: July 24, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Marvin B. DeTar, Richard M. Lange, John S. Manka
  • Patent number: 6264399
    Abstract: A method for remediating soil which is contaminated by one or more hydrophobic organic chemicals, comprising: contacting the contaminated soil with an aqueous composition comprising a surfactant prepared by reacting a sulfonate of the formula an amine wherein R1 is hydrogen or methyl, R2 is hydrogen or an alkyl group containing up to 18 carbon atoms, and each of R3, R4 and R5 is individually hydrogen or an alkyl group containing up to 7 carbon atoms and M is an alkali metal, an alkaline earth metal or —NR10R11R12 wherein R10, R11 and R12 are independently hydrogen or hydrocarbyl groups containing from 1 to 22 carbon atoms and removing said aqueous compositions and organic chemicals associated therewith from the soil.
    Type: Grant
    Filed: October 14, 1999
    Date of Patent: July 24, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Bryan A. Grisso, Richard W. Jahnke
  • Patent number: 6257051
    Abstract: A viscometer for sensing or characterizing the stress required to shear a fluid at a given rate includes a pair of members coaxially mounted for relative rotation. Between the members is an annular gap defining a flow path for the fluid. The flow path is configured such that during differential rotation of the members, fluid is caused to flow through the annular gap that is a function of the differential rotation and the viscosity of the fluid. A sensor measures the torque or torque equivalent required to achieve such differential rotation between the members.
    Type: Grant
    Filed: March 11, 1999
    Date of Patent: July 10, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Frederick P. Boyle, Gary Garvin, Klaus-Werner Damm, Daniel H. Heath, Herman F. George, Peter John Moore, Dale Hicks, Terence Edward Robinson
  • Patent number: 6251840
    Abstract: A lubricating/functional fluid composition which exhibits in use improved antiwear and antifoaming properties. The improvements result from use of 2,5-dimercapto-1,3,4-thiadiazole and derivatives thereof together with silicone and/or fluorosilicone antifoam agents.
    Type: Grant
    Filed: January 14, 1997
    Date of Patent: June 26, 2001
    Assignee: The Lubrizol Corporation
    Inventors: William C. Ward, Jr., Craig D. Tipton, Kathleen A. Murray
  • Patent number: 6245839
    Abstract: This invention relates to a powder-coating composition made from at least two components comprising: (a) a film-forming resin composition; and (b) a transfer efficiency-enhancing amount of at least one additive compound comprising a 5- or 6-membered ring, the ring atoms of the ring comprising at least two heteroatoms; one heteroatom being nitrogen, the second heteroatom being selected from the group consisting of nitrogen, oxygen, and sulfur; said compound having at least one hydrocarbyl substituent of 1 to about 50 carbon atoms; wherein component (B) is incorporated into the powder coating composition by addition of component (B) to an extruded composition comprising components other than component (B). The invention also relates to a method of coating a substrate using the foregoing powder coating composition.
    Type: Grant
    Filed: November 25, 1998
    Date of Patent: June 12, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Scott T. Jolley, Charles F. Williams