Patents Represented by Attorney, Agent or Law Firm Michael J. Cronin
  • Patent number: 5336733
    Abstract: Disclosed are polyurethane base resins, and polyurethane composites and adhesive compositions formed using the base resins. The polyurethane base resins are formed by reacting a polycarbodiimide-modified 4, 4'-diphenylmethane diisocyanate with a mixture of the following polyols: (a) a hydroxyl-terminated, linear, saturated liquid copolyester diol having a glass transition temperature of at most -10.degree. C. and at least -60.degree. C.; and (b) a homopolyester polyol that is a ring-opened polymer of a cyclic ester. The polyurethane composites include typical active hydrogen-containing species that will react with isocyanates and promote curing, in addition to the polyurethane base resin. The polyurethane adhesive compositions, which are thermosetting, include the cured polyurethane base resin, cured by exposure to moisture or any other applicable curing mechanism. The adhesive compositions have improved performance (e.g.
    Type: Grant
    Filed: August 25, 1993
    Date of Patent: August 9, 1994
    Assignee: Rheox, Inc.
    Inventors: Terrence L. Hartman, Charles A. Cody
  • Patent number: 5336372
    Abstract: A process for deinking wastepaper, which comprises: (a) forming an organoclay deinking agent in an aqueous system; (b) contacting ink from wastepaper in the aqueous system with an amount of the organoclay deinking agent effective to deink the wastepaper; and ( c ) recovering deinked paper pulp from the aqueous system.
    Type: Grant
    Filed: September 14, 1992
    Date of Patent: August 9, 1994
    Assignee: Rheox, Inc.
    Inventors: Charles A. Cody, Edward D. Magauran
  • Patent number: 5334362
    Abstract: In order to treat metal chlorides obtained in the form of dust collector solids in the production of titanium dioxide by the chloride process, the inert constituents, especially particulate coke, is separated then the metals are selectively precipitated and a maturing phase under oxidative conditions is provided for. The residue consisting of metal hydroxides is also not thixotropic in the absence of inerts. As a result, the material to be deposited has been cut in half.
    Type: Grant
    Filed: September 23, 1992
    Date of Patent: August 2, 1994
    Assignee: Kronos, Inc.
    Inventors: Dieter Schinkitz, Hans Thumm
  • Patent number: 5298169
    Abstract: Disclosed is a process for treating waste sulfuric acid generated from a process for producing titanium dioxide pigment by treating titanium slag with sulfuric acid. The waste acid is treated in a first step with a calcium-containing material to produce a gypsum suspension which is filtered and from which a filtrate is recovered. The filtrate is treated in a second step with a calcium-containing substance and clarification solids from the treatment of the titanium slag with sulfuric acid. A precipitate is produced in this second step which is subsequently filtered. The precipitate is suitable for disposal in a landfill.
    Type: Grant
    Filed: August 21, 1992
    Date of Patent: March 29, 1994
    Assignee: Kronos, Inc.
    Inventors: Roger Laferriere, Pierre Beaupre
  • Patent number: 5282977
    Abstract: For economical and assured separation of chromium, vanadium and titanium ions from acidic waste waters, which accrue in great quantities in preparation of titanium dioxide, the pH is first raised to around a value of 3 by addition of dolomite brick powder. Directly thereafter, the pH is fine tuned into the range of 4.3 to 4.7 through addition of calcium hydroxide and/or sodium hydroxide, and the hydroxides are separated with the aid of a flocculating agent. Since iron ions and calcium ions remain mainly dissolved in the waste water through such selective precipitation, only a relatively small volume of slush has to be disposed of.
    Type: Grant
    Filed: September 24, 1992
    Date of Patent: February 1, 1994
    Assignee: Kronos, Inc.
    Inventor: Dieter Schinkitz
  • Patent number: 5264515
    Abstract: A moisture curable composition comprised of a moisture curable base and a curing agent which does not contain molecular water but which produces water upon activation so as to cure the curable base. The composition exhibits improved stability and shelf life and can be formulated so that curing of the composition can be controlled substantially independently of ambient conditions.
    Type: Grant
    Filed: December 23, 1991
    Date of Patent: November 23, 1993
    Assignee: Rheox, Inc.
    Inventors: Charles A. Cody, Terrence L. Hartman
  • Patent number: 5248497
    Abstract: This invention provides a process for the recovery of purified ferrous chloride resulting as a by-product during the production of titanium dioxide by the chloride process. The process involves a two-step cooling of a filtered solution containing ferrous chloride and other material in a manner to crystallize the ferrous chloride as a pure product. Such product can then be sold commercially including to companies involved in the waste water treatment business.
    Type: Grant
    Filed: August 7, 1992
    Date of Patent: September 28, 1993
    Assignee: Kronos, Inc.
    Inventors: Achim Hartmann, Erwin Schmeir
  • Patent number: 5231147
    Abstract: The present invention relates to thermosetting polyurethane structural adhesive composites and compositions and processes for producing the same comprising dispersing an amine-terminated solid polyamide resin into a polyurethane base resin to form a nonactivated adhesive composite, and activating the same by heating to form an adhesive composition. Another aspect of the invention relates to dispersing an amine-terminated solid polyamide resin and a water generating compound into the polyurethane base resin and heat-activating the same to form an adhesive composition. The invention also relates to polyurethane base resins suitable for use in the processes of the invention, which may also be moisture cured to form a reactive adhesive composition.
    Type: Grant
    Filed: February 28, 1992
    Date of Patent: July 27, 1993
    Assignee: Rheox, Inc.
    Inventors: Terrence L. Hartman, Charles A. Cody
  • Patent number: 5215580
    Abstract: A process produces fine particle titanium dioxide essentially transparent to visible light and essentially UV radiation absorbing. During preparation of the titanium dioxide product, tin dioxide with a particle size of 1 to 10 nm, and preferably 1 to 4 nm, is added, in an amount of 0.5 to 10 weight percent with respect to TiO.sub.2. The particle size of the titanium dioxide is specifically adjusted by the tin dioxide addition. Acicular particles are rounded by heat-treatment between 300.degree. and 800.degree. C., and preferably between 400.degree. and 600.degree. C. The particles can be post-treated to produce a coating of inorganic and/or organic substances. The fine particle titanium dioxide can be prepared by the decomposition of sodium titanate with hydrochloric acid or by suitable hydrolysis of a tetravalent titanium compound which leads to rutile formation.
    Type: Grant
    Filed: February 6, 1992
    Date of Patent: June 1, 1993
    Assignee: Kronos USA, Inc.
    Inventors: Lothar Elfenthal, Edgar Klein, Franz Rosendahl