Patents Represented by Attorney, Agent or Law Firm Norvell E. Wisdom
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Patent number: 6579434Abstract: A free fluoride ion sensitive electrode with longer service life can be obtained by eliminating the use of any cement or similar adhesive to hold the fluoride sensing crystal of the electrode in place within the rest of the structure of the electrode, using instead a pressure sealed combination of the fluoride sensing crystal and upper and lower elastomeric gaskets. This arrangement also permits replacing the crystal and sealing gaskets if needed, without replacing any of the other components of the electrode.Type: GrantFiled: September 17, 1996Date of Patent: June 17, 2003Assignee: Henkel CorporationInventors: Kevin H. Cornell, Joseph C. Topping, Thaddeus J. Szynal
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Patent number: 6432899Abstract: Cleaning and deoxidizing aluminum surfaces can be accomplished simultaneously by contacting the surfaces with an aqueous liquid composition that contains as its cleaning active ingredients (i) alcohols and/or ether alcohols, (ii) alkaline builders, and (iii) alkali stable surfactants, and, optionally but preferably, also contains fluoride and chelating agents.Type: GrantFiled: July 13, 2000Date of Patent: August 13, 2002Assignee: Henkel CorporationInventor: Terry D. Sjostrom
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Patent number: 6096806Abstract: Epoxy resins, particularly those based on bisphenol A, can constitute the principal film forming polymer component of a storage stable autodepositable composition wherein the particle size distribution of all the film forming polymers in the composition satisfies certain criteria of size distribution, and an accelerator component which is an acid, oxidizing agent or complexing agent is present in amount sufficient to provide an oxidation-reduction potential at least 100 mV more oxidizing than a standard hydrogen electrode. Such dispersions can conveniently be prepared using a two stage process in which a solution of the film forming polymers is emulsified into water to form a preliminary dispersion and this preliminary dispersion is subjected to at least one particle size refinement stage in which the preliminary dispersion is forced through a narrow aperture.Type: GrantFiled: February 17, 1998Date of Patent: August 1, 2000Assignee: Henkel CorporationInventors: Brian L. Mueller, Elizabeth J. Siebert
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Patent number: 5993561Abstract: A process for removing dried paint residues from a difficultly accessible surface is provided. The surface is contacted with a slurry of particulate solids such as sodium hydrogen carbonate in a first liquid such as N-methyl pyrrolidone which is a solvent or swellant for the paint residues, followed by a different liquid such as isopropyl alcohol in which the first liquid is soluble (and which may also optionally contain particulate solids).Type: GrantFiled: January 27, 1998Date of Patent: November 30, 1999Assignee: Henkel Corp.Inventor: Chester P. Jarema
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Patent number: 5954024Abstract: This invention relates to a method applied in combustion engines having two spark plugs in each combustion chamber for controlling ignition and ionization current measurements, one of the spark plugs acting as a sensor for the ionization current measurements. The ignition voltage supplied to each of the spark plugs in a chamber is controlled such that the spark duration of the spark plug acting as the sensor is less than 50% of the other spark plug in the chamber.Type: GrantFiled: February 19, 1998Date of Patent: September 21, 1999Assignee: Henkel CorporationInventors: Joel Duhr, Anders J Goras
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Patent number: 5516447Abstract: A process for the production of washing- and cleaning-active surfactant granules containing 60 to 70% by weight of surfactant and having an apparent density above 500 g/l, wherein a formulation containing a non-surface-active liquid component and having a liquid to paste-like form under normal pressure at temperatures of 20.degree. to 40.degree. C. is introduced to a fluidized bed and granulated and, at the same time, totally or partially freed from the non-surface-active liquid compound, optionally with addition of an inorganic or organic solid, and wherein the granules are discharged from the fluidized bed via a grading step by a countercurrent air-stream which is adjusted so that only particles above a predetermined size are removed from the granules.Type: GrantFiled: February 22, 1994Date of Patent: May 14, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Volker Bauer, Jochen Jacobs, Ditmar Kischkel, Peter Kraeplin, Andreas Syldath
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Patent number: 5503682Abstract: The invention relates to a process for degreasing and cleaning metal surfaces with surfactant containing aqueous cleaning liquids in baths and/or by spraying. In order to obtain an exact measurement of the bath load and cleaning reserve economically and quickly to allow more accurate subsequent metering of the cleaning agent, the invention provides that, as a measure of the current reserve of cleaning liquid, a bubble tensiometer is used to measure a value correlated with the dynamic surface tension and operated with a sufficiently constant gas flow, the measurements are compared with a predetermined set value obtained for the cleaning agent used by calibration, and, depending on the results of comparison, appropriate steps are taken to treat the cleaning liquid.Type: GrantFiled: May 5, 1994Date of Patent: April 2, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Thomas Mueller-Kirschbaum, Wolfgang Hater, Dieter Knapp, Thomas Vienenkoetter
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Patent number: 5439953Abstract: Disclosed are materials and/or shaped articles based on a starch which has been thermomechanically digested at elevated pressures and temperatures and with the addition of water and/or lower molecular weight plasticizing agents, said starch containing thermoplastic synthetic polymer compounds in an at least largely homogeneous mixture. The materials and/or shaped articles according to the invention are characterized in that their contents of synthetic thermoplastic polymer compounds is derived from aqueous polymer dispersions comprising a disperse polymer phase in an aqueous phase and that the synthetic thermoplastic polymer compounds have been incorporated in the starch in combination with the aqueous phase in such a manner that the starch digestion has been effected by the concomitant use of the aqueous phase of the polymer dispersions.Type: GrantFiled: October 12, 1993Date of Patent: August 8, 1995Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Wolfgang Ritter, Rainer Bergner, Wolfgang Kempf
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Patent number: 5404606Abstract: The invention concerns a process for washing fibrous materials, skins, textile materials or the like using an aqueous, surfactant containing washing liquid obtained by adding washing agents to water. The minimal dispensed amounts as determined in subsequent washing tests are always obtained automatically, without the cleaning power and the cleaning efficiency being reduced to unacceptable levels. To this end, the surface tension of the washing liquid is measured during the washing process using a tensiometer. The actual washing agent concentration is derived from these measured values and an initial concentration is derived from the quantity of washing agent added. The detergency is calculated from this initial concentration. The addition of a washing agent is discontinued when no further increase occurs in the detergency. The invention also concerns a device for carrying out the process. The device has capillaries connected to constant gas flow sources and immersed to the same depth in the washing liquid.Type: GrantFiled: December 13, 1993Date of Patent: April 11, 1995Assignee: Henkel Kommanditgesellscaft auf AktienInventors: Thomas Mueller-Kirschbaum, Eduard Smulders, Wolfgang Hoefer
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Patent number: 5062979Abstract: The invention relates to aqueous, clear solution-forming, substantially soap free lubricant compositions and to the use of the lubricant compositions according to the invention, especially as lubricants for the transport of glass bottles or poly(ethylene terephthalate) bottles. The substantially neutral aqueous lubricant compositions (pH 6-8) contain alkyl benzenesulfonates, partial phosphate esters with alkoxylated aliphatic alcohols, and aliphatic carboxylic acids, optionally in addition to typical solubilizers, solvents, foam inhibitors and disinfectants.Type: GrantFiled: September 13, 1989Date of Patent: November 5, 1991Assignee: Ecolab Inc.Inventors: Rolf Scharf, Karl-Heinz Schmitz
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Patent number: 4919923Abstract: Cosmetic emulsions of the oil-in-water type which are pourable at 20.degree. C. contain as an oil component dialkyl ethers corresponding to the formula R.sup.1 --O--R.sup.2, in which R.sup.1 and R.sup.2 independently of one another represent a linear or single-branch C.sub.6-22 alkyl. Even a content of only 0.5 to 5% by weight of dialkyl ethers can considerably reduce the viscosity of the emulsions. Preferred emulsions contain from 1 to 30% by weight of discontinuous lipophilic phase and from 70 to 99% by weight of continuous aqueous phase.Type: GrantFiled: January 5, 1989Date of Patent: April 24, 1990Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Horst Hoeffkes, Fritz Lange, Achim Ansmann
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Patent number: 4898690Abstract: Bubble-bath foam concentrate compositions showing high structural viscosity and good solubility in water contain 35 to 45% by weight alkyl ether sulfate surfactants, 5 to 15% by weight nonionic polyglycolether surfactants, 1 to 5% by weight of one or more amphoteric or zwitterionic surfactants, 1 to 5% by weight glycerol polyglycol ether monofatty acid esters or fatty acid mono- or diglyceride polyglycol ethers, 2 to 10% by weight of a water-insoluble perfume oil and 30 to 50% by weight water. The compositions have a gel-like appearance and show high foaming power and high compatability with the skin. The combination of the compositions with suitable dispensing containers and a method for using such compositions to provide bubble-baths.Type: GrantFiled: April 28, 1988Date of Patent: February 6, 1990Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Ingrid Bitter, Wolfhard Scholz, Werner Schneider
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Patent number: 4879414Abstract: Polythiols prepared by the reaction of hydrogen sulfide or organic dithiols with polyglycidyl substituted amines have been found to be outstanding curing agents for epoxy resins. Epoxy resins cured with these polythiols are characterized by not only improved gel times, but also improved cure rates, better heat resistance and greater resistance to absorption of water.A useful polythiol is the reaction product of N,N,N',N'-tetraglycidyl-m-xylylenediamine with hydrogen sulfide.Type: GrantFiled: February 17, 1988Date of Patent: November 7, 1989Assignee: Henkel CorporationInventors: Grannis S. Johnson, Reuben H. Grinstein, Stuart J. Hartman, Raymond P. Dallago
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Patent number: 4877495Abstract: A process for the electrolytic coloring of anodized surfaces of aluminum or aluminum alloys using alternating current or direct current superimposed on alternating current, the electrolytic coloring being carried out with an electrolyte which contains cationic organic dyes and, optionally, conducting salts.Type: GrantFiled: February 2, 1989Date of Patent: October 31, 1989Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Willi Buchmeier, Dieter Brodalla
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Patent number: 4876339Abstract: A reaction medium of ethanol condensed with 1-20, most preferably 4-6 moles, of ethylene or propylene oxide per mole of ethanol greatly improves the practicality of the preparation of azacycloalkane-2,2-diphosphonic acids of the general formula I: ##STR1## where R means a hydrogen or a lower alkyl radical with from 1 to 3 carbon atoms, and n means an integer between 3 and 11, by phosphonylating the corresponding lactams with phosphonic acid and phosphorous trihalides in the presence of water.Type: GrantFiled: March 10, 1989Date of Patent: October 24, 1989Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Helmut Blum, Siglinde Hemmann
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Patent number: 4874480Abstract: A method of producing titanium and titanium alloys having improved lubricity and cold working characteristics includes immersing titanium or titanium alloy as the cathode in an electrolytic conversion coating bath containing acidified zinc phosphate and forming a zinc phosphate coating on the titanium or titanium alloy by maintaining electrolysis conditions in the bath. Further improvements are achieved by pretreatment of the titanium or titanium alloy with a surface adjustment agent prior to immersion in the electrolytic conversion coating bath. The products are further treated with conventional lubricants and exhibit improved working characteristics.Type: GrantFiled: April 20, 1988Date of Patent: October 17, 1989Assignee: Henkel CorporationInventors: Sakae Sonoda, Kouji Hetsugi, Yoshihiko Sawasaki, Kouji Kaburagi, Yasunobu Matsushima
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Patent number: 4871777Abstract: A composition for suppository bases consisting of a water-insoluble fat and an adduct of 5 to 50 mol ethylene oxide with 1 mol hardened castor oil as emulsifier enables suppositories containing aqueous active-principle solutions to be prepared. The emulsifier is preferably present in a quantity of 0.2 to 10% by weight. Suppositories containing up to 30% by weight water dispersed therein can be prepared using the above composition.Type: GrantFiled: March 24, 1988Date of Patent: October 3, 1989Assignee: Henkel Kommanditgesellschaft auf AktienInventor: Willi Breitzke
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Patent number: 4865653Abstract: The present invention relates to a composition and process for metal finishing involving the formation of zinc phosphate coatings of desired morphology on a ferrous surface. The inclusion of a hydroxylamine agent in the phosphating bath expands the range of zinc concentrations over which the desired coating morphology is obtained. Zinc and aluminum surface can also be coated with this composition and process.Type: GrantFiled: October 30, 1987Date of Patent: September 12, 1989Assignee: Henkel CorporationInventor: Linda S. Kramer
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Patent number: 4859206Abstract: This invention encompasses compounds of the formula ##STR1## wherein R.sup.1 and R.sup.2 independently are hydrogen, C.sub.1-4 alkyl, or C.sub.2-4 hydroxyalkyl; one of R.sup.3 to R.sup.7 is --SO.sub.3 H or --COOH; and the remaining of R.sup.3 to R.sup.7 independently are hydrogen, chlorine, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, or --NR.sup.8 R.sup.9, where R.sup.8 and R.sup.9 independently are hydrogen, C.sub.1-4 alkyl, C.sub.2-4 alkoxy, or where --NR.sup.8 R.sup.9 is piperidine, morpholine, piperazine, or pyrrolidone; or a water soluble salt thereof; hair dye preparation containing these compounds, and methods for dyeing hair using such preparation.Type: GrantFiled: February 26, 1988Date of Patent: August 22, 1989Assignee: Henkel Kommanditgesellschaft auf AktienInventors: David Rose, Edgar Lieske, Horst Hoeffkes, Norbert Maak
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Patent number: 4834971Abstract: A method for the permanent shaping of hair, in which the hair is treated with an aqueous preparation of a keratin-reducing substance before and/or after a mechanical shaping step, rinsed with water and fixed by treatment with an aqueous preparation of an oxidizing agent and rinsed with water, wherein, after the oxidative fixing step, the mechanically shaped hair is aftertreated with an aqueous composition comprising a dissolved aluminium (III) salt and a hydroxydi- or tri-C.sub.4-6 -carboxylic acid; the novel composition itself; and a kit for effecting such method.Type: GrantFiled: August 5, 1987Date of Patent: May 30, 1989Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Adolf Klenk, Detlef Hollenberg, Horst Hoeffkes