Abstract: Method of controlling the zebra mussel by direct contact with peracetic acid or indirectly by application to an environment where control is desired. The biofouling of environments, such as fresh water intakes, conduits and storage systems of power and water treatment systems, and of processing streams of industrial plants, is thereby reduced or eliminated.
Type:
Grant
Filed:
July 8, 1993
Date of Patent:
February 28, 1995
Assignees:
FMC Corporation, The Research Foundation of the State University of New York
Inventors:
Alexander M. Vegega, Claudio E. Manissero
Abstract: Phosphonic (co) telomers of the type described in U.S. Pat. Nos. 4,046,707 and 4,681,686 and European Patent Application 360746 may be produced by an aqueous process comprising (a) reacting hypophosphorous acid with a carbonyl compound which is preferably an aldehyde, a ketone or an imine, (b) reacting the product of (a) with an olefin or olefins in the presence of a suitable initiator especially a free radical initiator, and (c) converting the product obtained from (b) to a phosphonic (co) telomer, e.g., by reaction with hypochlorite. The (co) telomer products are useful as scale inhibitors in aqueous systems.
Abstract: A method of inhibiting the precipitation of barium scale from an aqueous system, comprising adding to the aqueous system a product having the formula I: ##STR1## in which M is hydrogen or an alkali metal ion, an ammonium ion or a quanternized amine radical; R.sub.1 is hydrogen or methyl; and n is an integer having an average value ranging from 4 to 20.
Abstract: Freeze-dried polymer latices, which can be reconstituted in water to give aqueous polymer dispersions having high polymer solids content, are described. The reconstituted polymer dispersions are useful in preparing sustained-release drug formulations, particularly of water-soluble drugs, by the wet granulation method without over wetting.
Type:
Grant
Filed:
March 5, 1990
Date of Patent:
July 5, 1994
Assignee:
FMC Corporation
Inventors:
Dev K. Mehra, Chimanlal I. Patel, Clayton I. Bridges, Jr.
Abstract: A corrosion- and/or scale inhibitor composition comprising: A) a corrosion- and/or scale inhibitor; and B) a compound having the formula (I): ##STR1## or a water-soluble salt thereof in which R.sub.1 is hydrogen or methyl, the weight ratio of component A) to component B), ranging from 10:90 to 90:10.The compounds of formula I are new compounds.
Abstract: 3,5-Dihalogeno-1,2,6-thiadiazin-4-ones of the formula ##STR1## in which R.sub.1 and R.sub.2 independently of one another are chlorine, fluorine or bromine, in particular 3,5-dichloro-1,2,6-thiadiazin-4-one, are excellently suitable for use as biocides for the protection of industrial materials and for water systems, for example for wood, plastics, paints, oils, adhesives and industrial water circulation systems.
Type:
Grant
Filed:
September 22, 1989
Date of Patent:
February 8, 1994
Assignee:
FMC Corporation
Inventors:
Joachim Lorenz, Reinhardt Grade, Peter Riebli
Abstract: The rate of disintegration in cold water of water soluble packaging films is improved by incorporating into a film forming polymer composition, to form a dry blend or aqueous dispersion, a substantially water insoluble cellulose material prepared from alkali metal salts of carboxy(lower alkyl) cellulose or hydroxy(lower alkyl) cellulose. The increased disintegration is achieved without loss of film stability and, in some cases, the film stability is improved.
Abstract: A water dispersible polymeric film-forming particulate composition for use in coating pharmaceuticals and foods or the like, produced by freeze-drying an aqueous solution of water-soluble cellulose acetate as the film-forming polymer, a plasticizer, and optionally a pigment, is described. The product mixes readily with water to form an aqueous dispersion which is applied in the conventional manner to solid pharmaceutical forms.
Type:
Grant
Filed:
September 23, 1991
Date of Patent:
November 2, 1993
Assignee:
FMC Corporation
Inventors:
Thomas A. Wheatley, Clayton I. Bridges, Jr., Carl R. Steuernagel
Abstract: A water dispersible film-forming particulate composition for use in coating pharmaceuticals and foods or the like, produced by freeze-drying an aqueous solution of a water-soluble polymer, a plasticizer, and optionally a pigment, is described. The product mixes readily with water to form an aqueous dispersion which is applied in the conventional manner to solid pharmaceutical forms.
Type:
Grant
Filed:
September 12, 1991
Date of Patent:
September 28, 1993
Assignee:
FMC Corporation
Inventors:
Thomas A. Wheatley, Clayton I. Bridges, Jr., Carl R. Steuernagel
Abstract: A method of inhibiting corrosion of metal surfaces in contact with an aqueous system, comprising contacting the metal surfaces with a telomer compound having the formula I: ##STR1## in which M is hydrogen or an alkali or alkaline earth metal ion, an ammonium ion or a quaternised amine radical; and n is an average integer ranging from 1 to 60.
Abstract: A water-dispersible, particulate film-forming composition is produced by blending a mixture of particles of water-soluble cellulose acetate; pigment particles, a plasticizer for the water-soluble cellulose acetate, and a surfactant. The composition is useful as a film-forming material for coating solid pharmaceutical forms.
Type:
Grant
Filed:
February 26, 1990
Date of Patent:
April 27, 1993
Assignee:
FMC Corporation
Inventors:
Thomas A. Wheatley, Clayton I. Bridges, Jr., Carl R. Steuernagel
Abstract: The present invention provides a melamine phosphonic acid salt of the general formula (I) ##STR1## in which R is hydrogen, methyl or a negative valency bond, and n is 1 when R is hydrogen or methyl, or 2 when R.sup.1 is a negative valency bond.The salts are useful as flame retardants in polymers.
Abstract: Microcrystalline cellulose intimately admixed with a galactomannan gum such as guar gum, in an aqueous medium and then dried, preferably by spray drying, forms a novel aggregate comprising a powder whose particles are spheroidal in shape. The resulting material may be used e.g., as a low-calorie fat-like material in certain foods. Optionally, a third, edible, component such as a lipophilic material, or a hydrophilic material, such as a proteinaceous material or a polysaccharide, or mixtures thereof, may be incorporated in this composition to enhance taste and/or other desired properties. When this composition, in colloidal form, is added to such foods as salad dressings or dairy products as a fat substitute, it imparts a fat-like mouth feel and consistency without the caloric value of fat.
Type:
Grant
Filed:
December 18, 1991
Date of Patent:
March 9, 1993
Assignee:
FMC Corporation
Inventors:
Emanuel J. McGinley, Domingo C. Tuason, Jr.
Abstract: Polymaleic anhydride having a weight average molecular weight by gel permeation chromatography of between 450 and 800 and a polydispersivity of between 1.0 and 1.15 is produced by polymerizing maleic anhydride, using a peroxide initiator in an amount not greater than 10% by weight of the anhydride, in a dilute solution in o-xylene or a substituted o-xylene.
Abstract: Hydroxamic acids are efficiently isolated from aqueous reaction media in which they are produced as solids by adding to the reaction mixture with agitation, a coalescing amount of a water insoluble organic liquid, such as a light hydrocarbon or halohydrocarbon, which is a non-solvent for the hydroxamic acids. The coalesced particles float to the surface of the medium leaving behind a clear, aqueous phase which can be drained from the reaction vessel to leave the discrete particles of hydroxamic acid. Buoyancy of the particles is assisted by adding hydrogen peroxide to the reaction mixture or by bubbling air therethrough, usually after the coalescence.
Type:
Grant
Filed:
September 20, 1989
Date of Patent:
May 14, 1991
Assignee:
FMC Corporation
Inventors:
Gerald J. Murphy, John W. Ager, Matthew I. Levinson
Abstract: Crystallizable pyrethroid isomers or enantiomer pairs are converted to more pesticidally active isomers by contacting a hydrocarbon slurry of the starting isomers with a base and a catalyst, the catalyst being substantially soluble in the slurry and selected from a quaternary ammonium compound, a quaternary phosphonium compound and a crown ether, agitating the slurry while maintaining a temperature effective for conversion, and recovering the resulting isomers. The tendency to form benzoin ester by-product is reduced by including in the slurry a weak base, an aldehyde scavenger such as a metabisulfite, and/or a tetraalkyl (C.sub.1 -C.sub.5) ammonium halide catalyst dissolved in an aprotic solvent such as an organic nitrile. The process typically is effective for enriching cypermethrin, cyfluthrin and (cyano (3-phenoxyphenyl)methyl 3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropanecarboxylate in the more active species.
Abstract: Nematodes and insects are controlled by application of vinyl fluorides of the formula ##STR1## where R is CH.sub.2 X--, CHX.sub.2 --, CX.sub.3 --, XCH.dbd.CH--, CH.sub.2 .dbd.CX-- or straight chain alkyl(C.sub.2 -C.sub.8);R.sup.1 is hydrogen, fluoro, chloro, bromo, CH.sub.2 Z--, CHZ.sub.2 -- or CZ.sub.3 --;R.sup.2, X and Z independently are hydrogen, fluoro, chloro or bromo; Y.sup.1, Y.sup.2, Y.sup.3, and Y.sup.4 independently are CH.sub.3 or any value of R.sup.2, X and Z; a is 0-12; n is 7-13; and n is greater than a.Particular species controlled are the root-knot, stunt, lesion, cyst and free-living nematodes, and the southern corn rootworm. The vinyl fluorides also have anthelmintic utility.
Abstract: Purified agarose is recovered from agar or impure agarose by dissolving the agar or agarose in a lower alkylene glycol at elevated temperature, cooling the agar- or agarose-containing glycol solution to induce precipitation of a purified agarose product, and recovering the precipitated agarose product.
Abstract: Purified agarose suitable for rapid electrophoresis, characterized by a sulfate content of less than 0.2 wt % but greater than zero, a pyruvate content of 0-0.1 wt %, and a nitrogen content of 0-0.02 wt %. Gels prepared from the agarose exhibit a gel strength at 1.0 wt % concentration of at least 1200 g/cm.sup.2, substantial absence of DNA binding in 0.07 M or less tris acetate buffer, and an electroendosmosis (EEO) at 1.0 wt % concentration of 0.05 or less. Agaroses are purified to provide the low EEO material by dissolving agarose or alkali-modified agar in an aqueous medium buffered at a pH of 6.0 to 8.0 and containing no more than 2.0 nM salt as chloride, and precipitating the agarose by contact with a lower alkanol.
Type:
Grant
Filed:
August 3, 1989
Date of Patent:
January 8, 1991
Assignee:
FMC Corporation
Inventors:
Francis H. Kirkpatrick, Kenneth Guiseley, Richard Provonchee, Samuel Nochumson
Abstract: A stabilizing agent for dry mix food products in powder form, the individual particles of which consist essentially of microcrystalline cellulose, sodium carboxymethyl cellulose, and maltodextrin.
Type:
Grant
Filed:
July 18, 1990
Date of Patent:
September 7, 1993
Assignee:
FMC Corporation
Inventors:
Emanuel J. McGinley, Domingo C. Tuason, Gregory R. Krawczyk