Abstract: The oxidation of uranium is catalyzed with water-soluble copper or zinc chelates. An aqueous solution is prepared containing carbonate or bicarbonate ion, an oxidizer such as hydrogen peroxide or oxygen, and a water-soluble copper or zinc chelate which has at least two amino, carboxylic acid, or thiocarboxylic acid donor groups. The solution is pumped into an underground deposit of uranium. The water-soluble +4 state uranium is oxidized to the water-soluble +6 state which forms a complex with the carbonate ion. The solution is pumped to the surface and is recycled after precipitation of the uranium.
Abstract: A wire coating powder is prepared by first formulating a solventless, aromatic polyester-amide-imide which is the reaction product of an aromatic diamine, an aromatic compound consisting of trimellitic anhydride, acid, or acid halide, and about 35 to about 100 mole % in excess of the stoichiometric amount needed to react with said aromatic compound of polyol.A coating powder is prepared by hot melt mixing, cooling, and grinding a mixture of the polyester-amide-imide with straight polyester and a reactive solid or liquid aromatic monomer or prepolymer.
Abstract: A non-pulverulent solid polymeric structure is disclosed which has at least one pendant diaminotriazine ring. The structure is made by immersing a non-pulverulent solid structure which has at least one pendant nitrile group into a basic solution of cyanoguanidine at a temperature which does not dissolve the structure.
Abstract: Stereo-regular polymers are produced by forming a moving stream of gaseous monomer having an electric dipole moment, irradiating the monomer with monochromatic light of a wavelength suitable for activating it, and orientating the activated monomer in an electric field. The activated, orientated monomer then polymerizes to form a stereo-regular polymer.Alternatively, a monomer of the general formula ##STR1## can be used, where at least one of the R groups, the resonating R group, forms an electric dipole moment with the remainder of the monomer. The monomer is then irradiated with a monochromatic light beam having a frequency which resonates with a harmonic frequency resulting from the bond between the resonating R group and the remainder of the monomer. Activation of that particular bond on that particular type of monomer results in a stereo-regular polymer.For best results, however, the two methods are combined.
Abstract: Alpha particles emitted from radon 220, a daughter product formed from the decay of thorium, are prevented from reaching an alpha particle detector by enclosing the detector in a volume into which alpha-emitting radioactive gases can only enter through a semipermeable membrane at least about 10 mg/cm.sup.2 in thickness. The enclosed volume must be between 30 and 2000 cm.sup.3 and the (AP)/(VL) ratio must be between 10.sup.-7 and 10.sup.-5. Also, the detector must be positioned so as to expose it to gas from the membrane for a distance of at least 2 cm through a solid angle of at least one steradian.
Abstract: An amorphous film of As.sub.2 S.sub.5 on a substrate is disclosed for use in various optical applications. The film can be shaped as a lens to focus light. By mounting an acoustic transducer on the film to produce surface or bulk acoustic waves light moving in the film can be deflected or modulated respectively. The film can also be used in anti-reflective, high reflectivity, and photoconductive coatings.
Abstract: A composition is disclosed of a solution of a resinous carrier and at least two compounds which thermoparticulate at different temperatures between 60.degree. and 200.degree. C. A coating is made by applying the composition to a portion of an electrical apparatus exposed to a gas stream. As the temperature of the coating increases the compounds therein thermoparticulate. The time between which the compounds thermoparticulate indicates the rate of rise of the temperature and analysis of the products of thermoparticulation indicates the location of the coating in the electrical apparatus. Alternatively, the coating can consist of several layers with a thermoparticulating compound in each layer which thermoparticulates at different temperatures.
Type:
Grant
Filed:
May 12, 1977
Date of Patent:
December 25, 1979
Assignee:
Westinghouse Electric Corp.
Inventors:
David C. Phillips, William M. Hickam, James D. B. Smith
Abstract: A reaction system is disclosed wherein a moving, unidirectional stream of an activatable gaseous species is produced, the individual members of which have the forward components of their velocities at least 10 times greater than the lateral components of their velocities. The stream is irradiated with substantially monochromatic light having a frequency which activates at least some of the individual members of the species. The activated members can then be reacted with another stream or otherwise utilized.
Abstract: A stripper composition for thermoset resins is disclosed which comprises about 1 to about 99% of an aromatic compound which has a boiling point over 180.degree. C. and is a phenol or a primary or secondary amine, and about 1 to about 99% of a carboxylic acid compound which has a boiling point over 180.degree. C. and is a rosin acid or a mono- or di-carboxylic fatty acid or an ester thereof. The composition also preferably includes sufficient hydrogen bonding compound to react with any acid present in the composition plus about 20 to about 50% in excess of that amount. A swelling agent is also preferably included.
Type:
Grant
Filed:
April 25, 1977
Date of Patent:
September 25, 1979
Assignee:
Westinghouse Electric Corp.
Inventors:
Leonard E. Edelman, Gerhard R. Sprengling, Louis A. Cargnel
Abstract: A composition is disclosed of an N-thiophthalimide, a resinous carrier, and a solvent. The composition is applied to a portion of an electrical apparatus which is exposed to a gas stream. The solvent in the composition is evaporated to produce a thermoparticulating coating. When the electrical apparatus overheats the N-thiophthalimide in the coating forms particles in the gas stream which are detected by a monitor.
Type:
Grant
Filed:
September 23, 1976
Date of Patent:
September 25, 1979
Assignee:
Westinghouse Electric Corp.
Inventors:
James D. B. Smith, Joseph F. Meier, David C. Phillips
Abstract: Halogenated acetylenic compounds are prepared by irradiating a mixture of a reactant and a sensitizer with coherent light. The reactant has the general formula R--C.sub.2 HX.sub.4, R--C.sub.2 H.sub.2 X.sub.3, or R--C.sub.2 HX.sub.2 where X is Cl, Br, or I, and R is H or another non-interfering group. The sensitizer has a higher thermal activation energy for its lowest energy dissociation reaction than does any part of said reactant.
Abstract: Water is decomposed into hydrogen and oxygen in a series of steps. In the first step hydrogen sulfide is reacted with cuprous sulfide to produce the hydrogen and cuprous sulfide. The cupric sulfide is then decomposed to produce sulfur and to regenerate the cupric sulfide. The sulfur is reacted with water to produce the hydrogen sulfide and sulfur dioxide. The sulfur dioxide is reacted with water to produce sulfuric acid. The sulfuric acid is decomposed to produce the sulfur dioxide, oxygen, and water.The decomposition of the sulfuric acid can be performed in four steps. In the first step the sulfuric acid is reacted with a metallic oxide to produce a solution of a metallic sulfate. The hydrate of the metallic sulfate is crystallized from the solution and is decomposed into the metallic sulfate and water. The metallic sulfate is decomposed into the metallic oxide, oxygen, and the sulfur dioxide.
Abstract: A composition is disclosed of a non-metallic, non-ionic organo-sulfur compound, a resinous carrier, and a solvent. The composition is applied to a portion of an electrical apparatus which is exposed to a gas stream. The solvent in the composition is evaporated to produce a thermoparticulating coating. When the electrical apparatus overheats, the organo-sulfur compound in the coating forms particles in the gas stream which are detected by the monitor.
Type:
Grant
Filed:
January 11, 1978
Date of Patent:
May 8, 1979
Assignee:
Westinghouse Electric Corp.
Inventors:
James D. B. Smith, Joseph F. Meier, David C. Phillips
Abstract: A composition is disclosed of a cyanoethylated compound, a resinous carrier, and a solvent. The composition is applied to a portion of an electrical apparatus which is exposed to a gas stream. The solvent in the composition is evaporated to produce a thermoparticulating coating. When the electrical apparatus overheats, the cyanoethylated compound in the coating forms particles in the gas stream which are detected by a monitor.
Type:
Grant
Filed:
July 2, 1976
Date of Patent:
May 1, 1979
Assignee:
Westinghouse Electric Corp.
Inventors:
Joseph F. Meier, James D. B. Smith, David C. Phillips
Abstract: Electrical apparatus cooled with a stream of hydrogen gas is protected from overheating by applying a coating to a portion of the apparatus which is exposed to the gas stream. The coating contains a compound which decomposes between 80.degree. and 200.degree. C. to produce a gas detectable by a monitor. The monitor detects gases heavier than hydrogen in the gas stream and sounds an alarm when they are present.
Abstract: Hydrogen and carbon dioxide are produced by activating a mixture of carbon monoxide and water with monochromatic light. Preferably, a unidirectional stream of steam activated with a laser at 5400 cm..sup.-1 collides with a carbon monoxide stream to effect the reaction. The carbon dioxide can then be reacted with water to produce formaldehyde. Ketene and water are produced by exposing the formaldehyde to ultraviolet light.
Abstract: A composition is disclosed of a carboxylic acid, a resinous carrier, and a solvent. The composition is applied to a portion of an electrical apparatus which is exposed to a gas stream. The solvent in the composition is evaporated to produce a thermoparticulating coating. When the electrical apparatus overheats the carboxylic acid in the coating forms particles in the gas stream which are detected by the monitor.
Abstract: A composition is disclosed of malonic acid, a resinous carrier, and a solvent. The composition is applied to a portion of an electrical apparatus which is exposed to a fluid stream. The solvent in the composition is evaporated to produce a thermo-particulating coating. When the electrical apparatus overheats the malonic acid in the coating forms particles in the fluid stream which are detected by a monitor.
Abstract: A solventless impregnating composition is disclosed which is made by forming a mixture of a liquid diepoxide and about 10 to about 80 phr of a diglycidyl ether of a glycol. To this mixture is added a titanate catalyst in an amount sufficient to cure the composition.
Abstract: A wire coating powder is prepared by first formulating a solventless, aromatic polyester-amide-imide which is the reaction product of an aromatic diamine, an aromatic compound consisting of trimellitic anhydride, acid, or acid halide, and about 35 to about 100 mole % in excess of the stoichiometric amount needed to react with said aromatic compound of polyol.A coating powder is prepared by hot melt mixing, cooling, and grinding a mixture of the polyester-amide-imide with straight polyester and a reactive solid or liquid aromatic monomer or prepolymer.