Abstract: Magnesium hydroxide is added to aqueous sprays used in the cooling of steel produced by continuous casting to reduce the corrosion of ferrous metals in contact with these sprays. The magnesium hydroxide when added to aqueous sprays used in the cooling of steel produced by continuous casting further reduces the potential for calcium fluoride scale formation by reducing the fluoride content of the system water.
Abstract: A method of inhibiting corrosion of iron and steel alloys in contact with industrial waters is claimed. The method comprises treating said waters with an effective corrosion inhibiting amount of a water soluble polymer having an average molecular weight ranging from about 2,000 to about 50,000, said polymer containing at least four mole percent of a hydroxamic acid mer unit.
Abstract: Leakage is detected between a process fluid and a temperature-conditioning fluid, or from a process fluid to a temperature-conditioning fluid, in an industrial process. The industrial process includes an A and a B fluid, and one of the A and B fluids receives heat from or transfer heat to the other of the A and the B fluids by an indirect contact method, and one but not both of the A and the B fluids is an industrial process fluid. At least one specie of tracer chemical is maintained in the A fluid, and that specie of tracer chemical is not a normal component of the B fluid. At least one of the A and the B fluids is subjected to at least one analysis at least one site. Such analysis at least detects the presence of the specie of tracer chemical when the fluid subjected to the analysis is the B fluid, and such analysis at least determines the concentration of the specie of tracer chemical when the fluid subjected to the analysis is the A fluid.
Type:
Grant
Filed:
November 10, 1992
Date of Patent:
April 19, 1994
Assignee:
Nalco Chemical Company
Inventors:
John E. Hoots, Brian V. Jenkins, Philip M. Eastin, Eric R. Brundage
Abstract: The present invention provides a process for stabilizing iron oxides and iron hydroxides in produced oil field waters. A water soluble polymer containing pendant N-substituted amide functionality units is added at a rate of about 6 parts by weight polymer to 10 parts by weight iron in the produced water.
Abstract: 3-acrylamido-3-methylbutanoic acid copolymers of acrylamide or acrylic acid are selective flocculant for coal present in coal refuse slurries.
Type:
Grant
Filed:
November 20, 1992
Date of Patent:
March 22, 1994
Assignee:
Nalco Chemical Company
Inventors:
Peter E. Reed, Ram-Aiyangar Venkatadri, Lawrence J. Connelly
Abstract: One aspect of the invention provides a method of removing emulsified oil from ethylene quench water. According to the method, the oil-containing water is treated with an effective amount of a dispersion of a water-soluble cationic polymer.
Type:
Grant
Filed:
December 16, 1992
Date of Patent:
March 15, 1994
Assignee:
Nalco Chemical Company
Inventors:
Norman E. Byrne, Belinda K. Williams, Sherri L. Fisher
Abstract: A method for preventing the precipitation of ethylene-vinyl alcohol copolymers in a distillation vessel. The vessel contains water, methanol, and ethylene-vinyl alcohol copolymers. The method includes the step of adding to the distillation vessel from 1 to about 1,000 ppm of at least one surfactant selected from the group consisting of alkyl, aryl, alkylaryl and arylalkyl sulfonic acids having a carbon length of from 4 to about 30 carbons. Preferably, the surfactant is dodecylbenzenesulfonic acid.
Abstract: A process for improving the flocculation of suspended solids in a Bayer process liquor in a primary settler stage. The method includes the step of adding to a primary settler feed from about 1 to about 100 parts per million of a composition including a non-inverted, water-continuous polymer, said polymer being hydrolyzable in a Bayer process liquor to an acid form, said acid form being an active red mud flocculant.
Abstract: Lead and cadmium ions are selectively removed and reclaimed from aqueous liquids containing the ions of these metals using an ion exchange resin which comprises a modified silica gel.
Abstract: In a method for reducing the fouling of a compressor of a vinyl acetate production unit having a light ends stream feed, a hindered phenol is added to the compressor feed. The method retards the loss of compressor efficiency with run time and increases the run time before clean-out is required. The hindered phenol is added in a dosage amount effective for reducing the fouling of the compressor.
Type:
Grant
Filed:
June 26, 1992
Date of Patent:
February 8, 1994
Assignee:
Nalco Chemical Company
Inventors:
Michael K. Poindexter, Vincent E. Lewis
Abstract: Bayer process liquors derived from the digestion of bauxites with a caustic solution are purified by removing the organic impurities present in the liquors. Removal of these impurities is accomplished by treating the liquor containing dispersed solids with a high viscosity polymer which includes diallyl dimethyl ammonium monomers.
Abstract: In a diagnostic method wherein steam condensate is evaluated, the proportion of condensate water from one steam source, versus other steam sources, is determined by adding at an addition point a tracer that is selectively carried over into the steam.
Type:
Grant
Filed:
April 3, 1992
Date of Patent:
February 1, 1994
Assignee:
Nalco Chemical Company
Inventors:
Scott R. Harder, Claudia C. Pierce, Brian F. Post
Abstract: The concentration of an aromatic azole corrosion inhibitor in the water of an aqueous system is monitored by a fluorometric method which is based upon the measurement of the fluorescence intensity of the aromatic azole corrosion inhibitor itself, and the precise determination of concentration permits control of the dosage of such aromatic azole corrosion inhibitor.
Type:
Grant
Filed:
April 22, 1992
Date of Patent:
January 11, 1994
Assignee:
Nalco Chemical Company
Inventors:
Narasimha M. Rao, Frank F.-Y. Lu, John E. Hoots
Abstract: A method for defoaming a Bayer process liquor, the method comprising the steps of adding to the Bayer process liquor an effective amount of an antifoam/defoamer composition comprising a water-soluble polypropylene glycol having an average molecular weight of from about 200 to about 600 daltons.
Abstract: A method and apparatus is provided for measuring underdeposit localized corrosion rate of a metal structure under differential flow conditions encountered in actual cooling water systems. A first electrode defining a slow flow electrode is immersed in an electrolytic liquid. A second electrode defining a fast flow electrode is also immersed in the electrolytic liquid. Different fluid dynamic conditions are created on the slow flow and fast flow electrodes. There are three (3) techniques for obtaining measurement from a differential flow cell so as to determine the underdeposit localized corrosion rate due to differential flow conditions. In one embodiment, the different fluid dynamic conditions are created by rotating the slow flow electrode at a first speed and by rotating the fast flow electrode at a second speed which is higher than the first speed.
Abstract: A method of corrosion inhibition using a gelled inhibitor is disclosed. The method comprises consecutively introducing into an annular region of a jacketed pipeline a hydrogel slurried in an environmentally innocuous oil medium and a corrosion inhibitor dissolved in an aqueous medium. The liquid media are contacted to form a gelled corrosion inhibitor in the annulus. The method is particularly useful in buried pipelines where corrosion monitoring is difficult.
Abstract: The concentration of a water soluble corrosion inhibitor formulation in the water of an aqueous system is monitored by a UV absorption method which is based upon the measurement of the absorbance of a component of corrosion inhibitor formulation. The method is particularly suited to on-site determinations of inhibitor residuals in large aqueous systems, such as in oil field applications, which have an acute need for rapid and adaptable assays, so as to provide precise information before corrosion damage can occur.
Abstract: A process monitors boric acid or other boron compounds in a fluid system. At least one specie of tracer chemical is added to a fluid system and at least one sample of fluid from the fluid system is analyzed for at least the presence of the tracer, and the presence of the specie of tracer chemical in such sample determines at least the presence of boric acid or other boron compounds in the sample.
Abstract: The invention provides a method for improving the retention of mineral fillers and cellulose fibers on a cellulosic fiber sheet. The method comprising the steps of preparing a cellulose pulp slurry; adding before a shearing step an effective amount of a copolymer flocculant to the cellulose pulp slurry, the copolymer flocculant is a high molecular weight cationic copolymer of acrylamide and diallyl dimethyl ammonium chloride, the flocculant copolymer should contain from about 20 to about 60 mole percent diallyl dimethyl ammonium chloride mer units. After a shearing step adding an effective amount of a high molecular weight water-soluble anionic flocculant. A cellulosic fiber sheet is then formed from the cellulose pulp slurry which includes both the copolymer flocculant and anionic flocculant.