Abstract: Sodium Aluminate when used to adjust pH of paint detackifying systems improves the efficiency of polymeric paint detackifiers used in the detackification of paint from paint spray booths and similar equipment.
Abstract: A polymer having pendant fluorescent groups is prepared by (trans)amidation of a preformed polymer by reaction with an amine-containing organic fluorescent composition of the Formula III ##STR1## wherein one of R.sub.5 and R.sup.6 may be hydrogen, and wherein within at least one of R.sub.5 and R.sub.6, or within R.sub.5 and R.sub.6 taken together, is an organic fluorescent group wherein the organic fluorescent group includes a polynuclear aromatic ring system. A degree of (trans)amidation derivatization of the polymer is accomplished by heating the admixture of polymer and fluorescent agent for a sufficient period of time.
Abstract: The invention is directed generally to controlling corrosion in boiler systems and more particularly to treating boiler water to remove dissolved oxygen and to passivate metal surfaces.
Type:
Grant
Filed:
April 22, 1992
Date of Patent:
November 2, 1993
Assignee:
Nalco Chemical Company
Inventors:
Douglas G. Kelley, Deborah M. Rogers, Frederick J. Swiecinski
Abstract: A method of controlling pitch deposits in a pulp and papermaking process comprising adding lipase and a cationic polymer to a cellulosic slurry in amounts effective for diminishing pitch deposits from the cellulosic slurry in a pulp and/or paper mill. The method may include adding lipase and a cationic polymer to a cellulosic slurry in amounts effective for both reducing the triglyceride content of a cellulosic slurry by hydrolysis and diminishing the concentration of fatty acids released by the hydrolysis in the aqueous phase of a cellulosic slurry. The triglyceride hydrolysate content of the aqueous phase of a cellulosic slurry, formed by the action of lipase on triglyceride within the cellulosic slurry, is reduced when the amount of lipase and the amount of a cationic polymer is maintained for a time period sufficient to hydrolyze at least some of the triglyceride in the cellulosic slurry and reduce the triglyceride hydrolysate in the aqueous phase of the cellulosic slurry.
Abstract: Sulfonated alkylphenol is added to crude oil at 5 to 200 ppm to inhibit naphthenic acid corrosion of ferrous metal process piping and equipment in contact with the crude oil at naphthenic acid corrosion conditions. There are disclosed corrosion-inhibited hydrocarbon fluids, an improvement in hot hydrocarbon processing with sulfonated alkylphenol, a method for inhibiting naphthenic acid corrosion therewith, and a method for catalytically processing hydrocarbons with sulfonated alkylphenol to avoid catalyst poisoning by iron compounds.
Abstract: The discharge of copper from isothiazolone biocides into industrial waste water streams is prevented by contacting the isothiazolone biocide as it is withdrawn from a point of use storage container with an ion exchange resin capable of removing copper from aqueous solutions. When the treated isothiazolone biocide is added to an industrial process water which will produce waste stream, potential copper contamination is virtually eliminated.
Type:
Grant
Filed:
November 23, 1992
Date of Patent:
October 12, 1993
Assignee:
Nalco Chemical Company
Inventors:
Walter H. Goodman, Nicholas J. Furibondo
Abstract: A method for preventing fouling of ethylene dichloride distillation units which comprises treating the feed to such units with a fouling preventing amount of a composition comprising:______________________________________ INGREDIENTS WEIGHT % ______________________________________ a) An oil soluble polymethacrylate 2-15 ester which contains from between .1-25 mole % of amino alcohol ester groups with the balance of the alcohol radical of the ester group containing from C.sub.4 -C.sub.22 carbon atoms, b) a phenylene diamine compound 20-40 having the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are the same or different and are hydrogen, C.sub.1 -C.sub.20 alkyl, C.sub.1 -C.sub.20 aryl, C.sub.1 -C.sub.20 alkaryl or C.sub.1 -C.sub.20 aralkyl, with the proviso that at least one of R.sub.1, R.sub.2, R.sub.3 or R.sub.
Abstract: A method for determining the presence of ferrous ion in boiler waters is described. The method can be used to directly measure the rate of corrosion occurring in boiler waters, and can measure the corrosion rates in the presence of boiler water treatment chemicals. The method uses a complex formed between only ferrous ion and a chemical 3-(2-pyridyl)-5,6-diphenyl-1,2,4-triazine-p,p'-disulfonic acid monohydrate reagent.
Type:
Grant
Filed:
October 22, 1992
Date of Patent:
August 17, 1993
Assignee:
Nalco Chemical Company
Inventors:
Claudia C. Pierce, Roger W. Fowee, Rodney H. Banks
Abstract: A method is disclosed for dispersing gums in hydrocarbon streams, particularly low molecular weight, sticky polymeric materials formed in refinery and petrochemical plant operation. The dispersant comprises a free radically polymerized copolymer of an .alpha.-olefin of from about 10 to about 36 carbon atoms and maleic anhydride wherein the anhydride moieties along the copolymer backbone are substantially unhydrolyzed. The copolymer has a ratio of olefin to maleic anhydride of from about 1 to about 0.5 and a molecular weight of from 5000 to about 100,000. The dispersant alternatively comprises a dispersant mixture wherein the first component comprises the .alpha.-olefin/maleic anhydride copolymer and the second component comprises an alkyl substituted phenol/formaldehyde liquid polymer, such as nonyl phenol/formaldehyde polymer, or a lipophilic/hydrophilic vinylic polymer, such as hydroxyethyl methacrylate/lauryl acrylate copolymer. Also disclosed is a hydrocarbon dispersion made by the method.
Abstract: Pitch control agents comprising a combination of water-soluble zirconium compounds and cationic polymers are described.Ammonium zirconium carbonate is preferred in combination with poly DADMAC and/or with EPI-DMA polymers.
Abstract: The concentration of at least one metal species in an aqueous system is at least reduced in an aqueous system that contains at least one kind of chelating agent, by adding to such system a species or plurality of species of bacteria that have a low toxicity for the metal species, and establishing and maintaining a biomass in the system for a sufficent time period to reduce the metal concentration.
Type:
Grant
Filed:
June 28, 1991
Date of Patent:
July 6, 1993
Assignee:
Nalco Chemical Company
Inventors:
Nhuan P. Nghiem, Thomas M. Miller, Richard J. Mouche
Abstract: In a papermaking process a paper product is formed from a mineral filler containing cellulosic slurry. Retention performance is provided by the sequential addition of a cationic charge-biasing species, an anionic flocculant, and then a certain microparticle. A shear stage is interposed between the flocculant addition and the microparticle addition. The microparticle is a inorganic, cationic source of aluminum.
Abstract: A process for improved flocculation of Bayer process red mud-containing liquor uses a conventional water soluble anionic flocculant to form a red mud phase and a supernatant from the red mud-containing liquor, the supernatant containing suspended solids. The process is characterized by the addition of a water soluble clarification aid in addition to the conventional flocculant, wherein the clarification aid is pullulan, lactan, zooglan, rhamsan, or combinations thereof. The clarification aid is added to the red mud-containing liquor in an amount sufficient to reduce the concentration of suspended solids in the supernatant.
Type:
Grant
Filed:
November 23, 1992
Date of Patent:
June 8, 1993
Assignee:
Nalco Chemical Company
Inventors:
Robert P. Mahoney, Lawrence J. Connelly, Robert L. Wetegrove
Abstract: Oversprayed paint in a paint spray operation is detackified by dosing the water of the waste water system of such operation with a composition comprising an amphoteric polymer and aluminum salts. The amphoteric polymer contains at least about 10 mole percent of cationic mer units of monoethylenically unsaturated monomer and at least 1 mole percent of anionic mer units. The aluminum salt preferred is aluminum sulfate, or its hydrates, for example alum. The amphoteric polymers preferably contain DMAEM, DMAEM.multidot.H.sub.2 SO.sub.4, DMAEM.multidot.MCQ, or mixtures thereof, with acrylic acid, methacrylic acid, AMPS, or mixtures thereof. The amphoteric polymers may also contain neutral monomers such as (meth)acrylamide.
Type:
Grant
Filed:
July 31, 1991
Date of Patent:
June 1, 1993
Assignee:
Nalco Chemical Company
Inventors:
Bhupati R. Bhattacharyya, deceased, Shu-Jen W. Huang, Chandrashekar S. Shetty, Nang T. Bui, Yvonne O. Dunn
Abstract: Polymers tagged with pendant fluorescent groups are prepared by the (trans)amidation derivatization of pre-existing polymers having carbonyl-type pendant groups. Polymers having pendant amide groups wherein the amide nitrogen is substituted with fluorescent moieties, prepared by (trans)amidation derivatization, are provided. Polymers having pendant (sulfonated) napthalene moieties substituted to amide nitrogen are provided.
Abstract: Dilute solutions of diallydimethyl ammonium chloride polymers are effective as dust suppressants for finely divided mineral and coal particles.
Abstract: Dispersing asphaltenes in liquid hydrocarbons, particularly formed during the refining of crude petroleum, is disclosed. The dispersant comprises a free radically polymerized copolymer of an .alpha.-olefin of from about 10 to about 36 carbon atoms and maleic anhydride wherein the anhydride moieties along the copolymer backbone are substantially unhydrolyzed or otherwise not derivatized. The copolymer has a ratio of .alpha.-olefin to maleic anhydride of from about 1:1 to about 1:5 and a molecular weight of from 5000 to about 100,000. Alternatively the dispersant comprises a mixture of the .alpha.-olefin/maleic anhydride copolymer and an alkyl substituted phenol/formaldehyde liquid polymer, such as nonyl phenol/formaldehyde polymer, or a lipophilic/hydrophilic vinylic polymer, such as hydroxyethyl methacrylate/lauryl acrylate copolymer. Also disclosed is a liquid hydrocarbon dispersion containing asphaltenes and 1-100 ppm of the .alpha.-olefin/maleic anhydride copolymer.
Abstract: A method for controlling microorganisms in aqueous paper mill systems which comprises treating such systems with a biocidal amount of a composition comprising: Glutaraldehyde, and a biocidal active dithiocarbamate.
Abstract: A solid film prelube comprising a polyacrylic acid-fatty acid tryglyceride composition in the form of an aqueous dispersion having the formula designed for use on all ferrous and non-ferrous metals at coating weight from 50 to 500 mg/ft.sup.2 :______________________________________ INGREDIENTS % BY WEIGHT ______________________________________ A. Polyacrylic acid salt-MW 10-20 10,000 to 200,00 B. 2-amino-2methyl-1-propanol 2-6 as salt of A C. Free 2-amino-2-methyl-1-propanol 0.05-1 D. Ammonium Benzoate 0.05-1 E. Alkyl C.sub.10 to C.sub.20 betaine 0.1-5 F. The Fatty Triglyceride 1-5 G. Ammonium hydroxide Sufficient to form a partial Salt of Ingredient A H. Ammonia-Zinc Oxide Complex 0.1-2.0 I.
Abstract: Diallyl dimethyl ammonium chloride copolymers are effective in removing color from paper mill wastes when anionic vinyl monomers are used as the co-monomers.
Type:
Grant
Filed:
June 29, 1992
Date of Patent:
May 11, 1993
Assignee:
Nalco Chemical Company
Inventors:
Peter E. Reed, Chandrashekar S. Shetty, Martha R. Finck