Abstract: The product prepared by the process consisting of the steps of (a) reacting a nitroalcohol of the formula ##STR1## where R and R.sup.1 can be hydrogen, methyl, ethyl or hydroxymethyl in about a 1:1 mole ratio with an alkylamine represented by the formula R.sup.2 NH.sub.2 where R.sup.2 is alkyl of from 1 to 4 or more carbon atoms or phenyl, benzyl, toluyl, or xylyl at about 50.degree.-70.degree. thereby effecting formation of a nitroalkylamine; (b) reacting the nitroalkylamine with nitrous acid at about 0.degree.-5.degree., thereby forming a nitroso compound; and (c) reducing the nitroso compound.
Type:
Grant
Filed:
September 14, 1978
Date of Patent:
August 28, 1979
Assignee:
International Minerals & Chemical Corporation
Abstract: The product prepared by the process consisting of the steps of (a) reacting a nitroalcohol of the formula ##STR1## where R and R.sup.1 can be hydrogen, methyl, ethyl or hydroxymethyl in about a 1:1 mole ratio with an alkylamine represented by the formula R.sup.2 NH.sub.2 where R.sup.2 is alkyl of from 1 to 4 or more carbon atoms or phenyl, benzyl, toluyl, or xylyl at about 50.degree.-70.degree. thereby effecting formation of a nitroalkylamine; (b) reacting the nitroalkylamine with nitrous acid at about 0.degree.-5.degree., thereby forming a nitroso compound; and (c) reducing the nitroso compound.
Abstract: A foundry core composition comprising a foundry aggregate, a resin base such as styrene-allyl alcohol copolymer or alkylene oxide derivative thereof, a polyisocyanate, and a catalyst therefor; the compositions being suitable for use in cold box, no-bake, and rapid no-bake processes.
Abstract: In a process for the production of 2-nitrobutylmorpholine from 1-nitropropane, morpholine and formaldehyde the improvement comprising mixing 1-nitropropane and morpholine, heating to about 55-60.degree. C., adding formaldehyde over about a 3-4 hour period, holding the reaction mixture at about 55-60.degree. C. for about a 2-3 hour period to make a total addition/holding period of at least six hours, cooling the reacton mixture to form a two phase oil/aqueous system and concentrating the oil layer to 2-nitrobutylmorpholine by removing excess water and 1-nitropropane.
Abstract: An acrylate modified alkyd resin obtained by the process consisting of the steps (a) forming an alkyd resin by reacting a conjugated fatty acid and an aromatic dicarboxylic acid or anhydride, and dimethylolpropionic acid with an excess of polyol, and (b) reacting the alkyd so formed with an alkyl-substituted or un-substituted acrylic acid or ester thereof or mixture thereof.
Abstract: A method of controlling the growth of microorganisms by applying to them or to their habitat an imidazoline represented by the formula ##STR1## where R can be hydrogen or methyl, R.sup.1 can be hydrogen, or alkyl of 1-3 carbon atoms, R.sup.2 can be hydrogen or methyl, R.sup.3 can be alkyl of 6-10 carbon atoms and x is 1 or 2.
Type:
Grant
Filed:
March 11, 1977
Date of Patent:
December 5, 1978
Assignee:
International Minerals & Chemical Corp.
Inventors:
Jerry H. Hunsucker, James R. Selleck, Jr.
Abstract: A modified clay paper coating composition comprising a montmorillonite clay having at least partially hydrolyzed aluminum chloride bonded thereto is made by treating montmorillonite clay with a non-aqueous solution of anhydrous aluminum chloride following by hydrolyzing with hot water. A paper substrate coated with this composition exhibits improved image light fastness when employed in a pressure-sensitive duplication system.
Type:
Grant
Filed:
May 26, 1977
Date of Patent:
December 5, 1978
Assignee:
International Minerals & Chemical Corp.
Inventors:
James T. Traxler, Emil P. Lira, John F. Kraemer
Abstract: A method of promoting the growth and improving the feed efficiency of animals using substituted quinoxalines represented by the formula: ##STR1## where R is hydrogen or lower alkyl of 1 to about 4 carbon atoms.
Abstract: A new foundry binder composition comprises a selected phenol-formaldehyde resin, a polyisocyanate, and a selected solvent therefor. A preferred solvent is ketal or an acetal such as butyl acetal. The resole is essentially anhydrous, should contain about 8% free phenol, and is further preferably characterized by the presence of substituent --(CH.sub.2 --O).sub.n --R groups replacing a phenolic hydrogen, R being a hydrocarbon radical such as butyl. Methylene and ether bridges linking phenolic nuclei are predominantly ortho-para with some para-para bridges. Also disclosed is the admixture of a reactive polyisocyanate and a solvent such as butyl acetal.
Abstract: A polyurethane-modified alkyd resin obtained by the process consisting of the steps (a) forming an alkyd resin by reacting an unsaturated fatty acid with an aromatic dicarboxylic acid or anhydride, and dimethylolpropionic acid with an excess of polyol, and (b) reacting the alkyd so formed with toluene diisocyanate.
Type:
Grant
Filed:
October 5, 1977
Date of Patent:
September 26, 1978
Assignee:
International Minerals & Chemical Corp.
Inventors:
Robert Richard Harris, Warren John Pollack
Abstract: Water base latex compositions suitable for coating corrodible metals, such as sand blasted ferrous metal, are prepared by a process characterized by the essential steps of (1) emulsifying under alkaline conditions a film forming oxidatively curable oil or alkyd modified polyurethane, and (2) blending therewith a copolymeric or homopolymeric acrylic or vinyl acetate latex.For metal coatings or for universal coatings for both (bleeding) woods and metal, a single pigment or a combination of pigments with corrosion inhibiting characteristics can be used with the polyurethane-acrylic latex, or polyurethane vinyl latex.
Abstract: A product obtained by reacting an alkanolamine represented by the formula ##STR1## where R is methyl, ethyl or hydroxymethyl and R.sup.2 is hydrogen, methyl or hydroxymethyl, with oiticica oil at ambient temperatures or above having utility as a dispersing agent in water-based paints.
Abstract: A method of controlling the growth of microorganisms by applying to them or to the environment inhabited by them a compound represented by the formula ##STR1## where R can be hydrogen, methyl or ethyl and x is 1 or 2.
Type:
Grant
Filed:
May 16, 1977
Date of Patent:
August 8, 1978
Assignee:
IMC Chemical Group, Inc.
Inventors:
Jerry H. Hunsucker, James R. Selleck, Jr.
Abstract: A process for the recovery of bacitracin from a fermented beer containing it comprising the steps of:A. screening the fermented beer through a 100-150 mesh screen,B. adjusting the pH of the fermented beer to about 7.5 to about 8.7,C. ultrafiltering the fermented beer in an ultrafilter having a molecular weight cut off of from 30,000 to 80,000, andD. collecting and holding the bacitracin containing permeate at a temperature of less than 30.degree. C.
Type:
Grant
Filed:
October 17, 1977
Date of Patent:
July 18, 1978
Assignee:
IMC Chemical Group, Inc.
Inventors:
James Alexander Kindraka, John Bernard Gallagher
Abstract: A composition consisting essentially of tris(hydroxymethyl)nitromethane and about an equal part of a mixture consisting of 4-(2-nitrobutyl)morpholine and 4,4-(2-ethyl-2-nitromethylene)dimorpholine in a ratio of about 3.5:1 respectively. The composition is useful as an antimicrobial.
Type:
Grant
Filed:
March 25, 1977
Date of Patent:
July 18, 1978
Assignee:
IMC Chemical Group, Inc.
Inventors:
Robert F. Purcell, James R. Selleck, Jr.
Abstract: The disclosed oxazolidines are useful as anti-algal and anti-viral agents. The compounds are of a low order of toxicity to warm-blooded animals.
Abstract: A method for the production of 2-[(2-hydroxymethyl)phenyl]-2-oxazolines by condensing o-phthalaldehyde with an alkanolamine represented by the formula ##STR1## where R is an alkyl group of 1 to 3 carbon atoms and R.sup.1 is hydrogen or methyl. The compounds have utility as tranquilizing agents.
Abstract: An improvement in the process for the production of P-1487 from the reaction of 1-nitropropane, 37% formaldehyde and morpholine, the improvement comprising mixing 1-nitropropane and 37% formaldehyde at a temperature of 40.degree.-42.degree. C., adding morpholine maintaining the temperature at 40.degree.-42.degree. C., holding the mixture for two hours at 40.degree.-42.degree. C., cooling to allow layer separation, separating the upper oil layer and concentrating the oil layer to P-1487 by removing excess water.