Abstract: The present invention describes a method for the synthesis of saturated aliphatic polyesters by reaction of saturated or aromatic diacid chlorides with oligomeric aliphatic polyester diols, a method to thermally crosslink membranes prepared from the above saturated aliphatic polyesters, and the use of the crosslinked membranes to separate aromatics from saturates.
Type:
Grant
Filed:
April 16, 1992
Date of Patent:
January 5, 1993
Assignee:
Exxon Research and Engineering Company
Inventors:
Guido Sartori, W. S. Winston Ho, Bruce H. Ballinger
Abstract: The present invention describes a method for separating mixtures of aromatics and non-aromatics into aromatic-enriched and non-aromatic-enriched streams by contacting the mixture with one side of a polysulfone membrane and selectively permeating the aromatic components through the membrane.
Type:
Grant
Filed:
June 24, 1991
Date of Patent:
October 27, 1992
Assignee:
Exxon Research and Engineering Company
Inventors:
Guido Satori, W. S. Winston Ho, Robert E. Noone
Abstract: The present invention describes a method for the synthesis of unsaturated aliphatic polyesters, their crosslinking by thermal treatment and the use of the corresponding crosslinked membranes to separate aromatics from saturates.
Type:
Grant
Filed:
October 11, 1991
Date of Patent:
August 11, 1992
Assignee:
Exxon Research and Engineering Company
Inventors:
Guido Sartori, W. S. Winston Ho, Robert E. Noone
Abstract: An improved method of preparing crystalline aluminosilicate zeolite ZSM-20, that involves preparing a reaction mixture having the formula, expressed in terms of mole ratio of oxides:(9-12)TEA.sub.2 O:(1-1.4)Na.sub.2 O:Al.sub.2 O.sub.3 :(20-28)SiO.sub.2 :(270-340)H.sub.2 Ofrom an alkali metal oxide source, tetraethylammonium (TEA) oxide, an aluminum oxide, a silicon oxide, tetraethylorthosilicate (TEOS) and water and seeding the reaction mixture with a seed solution having the formula, expressed in terms of mole ratio of oxides:(12-16)Na.sub.2 O:(0.8-1.2)Al.sub.2 O.sub.3 :(10-18)SiO.sub.2 :(250-500)H.sub.2 Oand heating the reaction mixture at temperatures ranging from about 80.degree. C. to about 120.degree. C. for a time sufficient to form crystals, wherein the time required for crystallization is shortened.
Type:
Grant
Filed:
April 17, 1991
Date of Patent:
July 28, 1992
Assignee:
Exxon Research and Engineering Company
Inventors:
David E. W. Vaughan, Karl G. Strohmaier
Abstract: The present invention described a method for the synthesis of saturated aliphatic polyesters by reaction of saturated or aromatic diacid chlorides with oligomeric aliphatic polyester diols, a method to thermally crosslink membranes prepared from the above saturated aliphatic polyesters, and the use of the crosslinked membranes to separate aromatics from saturates.
Type:
Grant
Filed:
October 11, 1991
Date of Patent:
July 7, 1992
Assignee:
Exxon Research and Engineering Company
Inventors:
Guido Sartori, W. S. Winston Ho, Bruce H. Ballinger
Abstract: A synthetic large pore crystalline metalsilicate zeolite composition, designated as ECR-35, having the formula, expressed in term of mole ratio of oxides: ##STR1## where T is an organic cation selected from the group consisting of tetraethylammonium and methyltriethyl ammonium, and mixtures thereof and X is Al or Ga; wherein the composition consists of an X-ray diffraction pattern having the line intensities:______________________________________ Line # d(.ANG.) Intensity ______________________________________ (1) 15.00 .+-. 0.2 weak to very strong (2) 14.20 .+-. 0.2 very strong (3) 13.40 .+-. 0.2 weak to medium (4) 8.70 .+-. 0.2 medium (5) 8.03 .+-. 0.2 zero to medium (6) 7.40 .+-. 0.15 medium (7) 5.65 .+-. 0.
Type:
Grant
Filed:
July 9, 1991
Date of Patent:
May 26, 1992
Assignee:
Exxon Research and Engineering Company
Inventors:
David E. W. Vaughan, Karl G. Strohmaier, Michael M. J. Treacy, John M. Newsam
Abstract: A class of new oxide structures containing octahedral molybdenum and tetrahedral phosphorous has been generated using hydrothermal techniques. These materials are produced by the reaction of a molybdenum oxide source with phosphate and any one, or combination of organic cation/alkali-metal cation/organic amine as a templating/mineralizing agent. A reducing agent is necessary to convert the Mo(VI) to a lower valent form and can be either added to the reaction mixture or is provided in the form of one of the reactants.
Abstract: A method for regenerating a Group VIII noble metal catalyst which has been contaminated with coke during a reforming process. The method comprises (a) burning off the coke from the catalyst, (b) redispersing the noble metal on the surface of the catalyst support by contacting the catalyst with halogen gas and carbon dioxide, and (c) chemically reducing the catalyst. The presence of carbon dioxide in the redispersing step improves the activity of the regenerated catalyst.
Abstract: The present invention relates to a metallo gallium silicate zeolite, designated as ECR-9. It also relates to a process for preparation of the zeolite. The zeolite may be employed in catalytic, absorbent or separation applications, particularly in the separation of small molecules, or normal from iso-paraffins, or the preferential reaction of n-paraffins in a mixed hydrocarbon stream.
Type:
Grant
Filed:
October 9, 1990
Date of Patent:
March 17, 1992
Assignee:
Exxon Research and Engineering Company
Inventors:
David E. W. Vaughan, Karl G. Strohmaier
Abstract: A new copolymer composition comprising the soft segment of an aliphatic polyester and the hard segment of a highly halogenated polyurethane containing from 3 to 36 halogen atoms is disclosed. The new halogenated polyurethane copolymer membrane has high thermal stability, and good selectivity and permeability for separation of an aromatic/saturate mixture.
Type:
Grant
Filed:
March 25, 1991
Date of Patent:
March 3, 1992
Assignee:
Exxon Research and Engineering Company
Inventors:
W. S. Winston Ho, Guido Sartori, Warren A. Thaler, Bruce H. Ballinger, David C. Dalrymple, Robert P. Mastondrea
Abstract: The present invention is a system and method for identifying a vehicle in a prescribed area of a service station and associating services with the vehicle. Each vehicle includes a transponder. Communication between the transponder and the service stations is via radio frequency signals.
Abstract: The present invention describes a method for separating mixtures of aromatics and non-aromatics by permeation through a sulfonated polysulfone membrane which is selective for aromatics.
Type:
Grant
Filed:
July 11, 1990
Date of Patent:
October 8, 1991
Assignee:
Exxon Research & Engineering Company
Inventors:
Guido Sartori, W. S. Winston Ho, Robert E. Noone, Abraham D. Cohen
Abstract: A new copolymer composition comprising the soft segment of an aliphatic polyester and the hard segment of a highly halogenated polyurethane containing from 3 to 36 halogen atoms is disclosed. The new halogenated polyurethane copolymer membrane has high thermal stability, and good selectivity and permeability for separation of an aromatic/saturate mixture.
Type:
Grant
Filed:
October 16, 1989
Date of Patent:
July 2, 1991
Assignee:
Exxon Research & Engineering Company
Inventors:
W. S. Winston Ho, Guido Sartori, Warren A. Thaler, Bruce H. Ballinger, David C. Dalrymple, Robert P. Mastondrea
Abstract: Vibrational Analysis technology translates acoustic/vibratory energy created by industrial processes into useful, process-related information. This invention enables a non-acoustical expert to easily collect and interpret the data.
Abstract: The present invention is a method for separating aromatics from saturates using a non-porous polycarbonate membrane. In a preferred embodiment, the polycarbonate membrane may be crosslinked.
Type:
Grant
Filed:
March 9, 1990
Date of Patent:
May 28, 1991
Assignee:
Exxon Research and Engineering Company
Inventors:
Guido Sartori, W. S. Winston Ho, David W. Savage, Robert E. Noone, Robert P. Mastondrea
Abstract: ECR-5, a twelve-ring zeolite isostructural with cancrinite, has been synthesized in an ammonia free system for the first time. A range of Li-Na alumino silicate compositions yields porous materials useful as catalysts and sorbents.
Abstract: This invention relates to a synthetic zeolite, designated as ECR-18, having a structure similar to the mineral paulingite, a process for preparation of the zeolite, and processes for the use of such products.
Type:
Grant
Filed:
August 22, 1988
Date of Patent:
May 7, 1991
Assignee:
Exxon Research and Engineering Company
Inventors:
David E. W. Vaughan, Karl G. Strohmaier
Abstract: The present invention describes a method for separating mixtures of aromatics and non-aromatics into aromatic-enriched and non-aromatic-enriched streams by contacting the aromatic/non-aromatics mixture with one side of a polyarylate membrane and selectively permeating the aromatic components through the membrane.
Type:
Grant
Filed:
July 11, 1990
Date of Patent:
April 30, 1991
Assignee:
Exxon Research and Engineering Company
Inventors:
Guido Sartori, W. S. Winston Ho, Robert E. Noone
Abstract: The present invention describes a method for separating mixtures of aromatics and non-aromatics into aromatic-enriched and non-aromatic-enriched streams by contacting the mixture with one side of a polyphthalate-carbonate membrane and selectively permeating the aromatic components of the mixture through the membrane.
Type:
Grant
Filed:
July 11, 1990
Date of Patent:
April 30, 1991
Assignee:
Exxon Research and Engineering Company
Inventors:
Guido Sartori, W. S. Winston Ho, Robert E. Noone