Abstract: Passive coustic method for monitoring and controlling flow state of two phase fluids through feed nozzles and thereby improving operating stability and high product value yields in major refinery processes or any other process where a finely atomized liquid stream exiting the nozzle is important.
Type:
Grant
Filed:
October 30, 1989
Date of Patent:
April 2, 1991
Assignee:
Exxon Research & Engineering Company
Inventors:
Charles L. Baker, George D. Cody, Craig A. Joseph, Uri Sela
Abstract: The present invention relates to an aluminosilicate, designated as ECR-15, having the mazzite structure and containing dimethylammonium organic ions. It also relates to a process for preparation of the zeolite.
Abstract: A crosslinked copolymer composition is derived from an aliphatic polyester, a dianhydride and a diisocyanate. The copolymer membrane has high thermal stability and good aromatic/saturate selectivity and permeability.
Type:
Grant
Filed:
April 3, 1990
Date of Patent:
March 5, 1991
Assignee:
Exxon Research & Engineering Company
Inventors:
Warren A. Thaler, W. S. W. Ho, Guido Sartori
Abstract: A new copolymer composition comprising the hard segment of a polyimide and the soft segment of an oligomeric aliphatic polyester. The new polyimide copolymer membranes have exhibited high thermal stability for separation of an aromatic/saturate mixture. These new membranes have higher aromatic/saturate selectivity than polyurethanes.
Type:
Grant
Filed:
May 4, 1990
Date of Patent:
February 5, 1991
Assignee:
Exxon Research and Engineering Company
Inventors:
W. S. Winston Ho, Guido Sartori, Warren A. Thaler, David C. Dalrymple
Abstract: The present invention is a method for examining at least a portion of an object using penetration radiation. The method includes the steps of transmitting radiation from an external source through the object in a plurality of coplanar rays, detecting the attenuated transmitted radiation after it has passed through the object, determining the projection data for said rays, and inverting said projection data to generate the distribution of the attenuation coefficient, wherein said inverting step includes the Direct Fourier Inversion Method such that the projection data is padded and the Fourier coefficients are filtered.
Abstract: Polyester membranes show good selectivity for aromatics vs. saturates. Modified, e.g., crosslinked, polyesters and their blends can also be used.
Abstract: A process for the detection and measurement of wall coke at a specific location in a fluid bed coker through the measurement of the vibrations of the external shell of the coker at the location.
Type:
Grant
Filed:
June 29, 1988
Date of Patent:
November 27, 1990
Assignee:
Exxon Research and Engineering Company
Inventors:
Andrew J. Callegari, Eugene R. Elzinga, Jr., George D. Cody, Roger W. Cohen
Abstract: A synthetic crystalline zeolite is provided characterized by having a composition, in terms of mole ratios of oxides, in the range:0.9 to 1.1 M.sub.2/n O:Al.sub.2 O.sub.3 :2.5 to 5.1 SiO.sub.2 :xH.sub.2 Owherein M is at least one exchangeable cation, n is the valence of M, and x is 0 to 6, and characterized by having a specified x-ray powder diffraction pattern. The zeolite may be prepared by crystallization from a reaction mixture of KOH (and optionally a minor amount of NaOH), water, a source of silica, and a source of alumina preferably derived from kaolin or halloysite. Most preferably, the source of alumina is metakaolin and the source of silica is potassium silicate.
Abstract: An aluminosilicate characterized by having a faujasite structure, a silica to alumina mole ratio of at least six and unbalanced tetra alkylammonium ions within the large cages of the aluminosilicate. This composition may be prepared by crystallization from an aged reaction mixture of an oxide of sodium, tetra alkyl or hydroxy alkyl ammonium, salt, water, a source of silica, a source of alumina and sodium aluminosilicate nucleating seeds in specified relative amounts.
Abstract: The present invention relates to a new alkaline absorbent solution that reduces the H.sub.2 S content in a treated gas to below 10 vppm. The absorbent solution contains two severely-hindered amines, such as bis(tertiarybutylaminoethoxy)-ethane (BTEE) and ethoxyethoxyethanol-tertiarybutylamine (EEETB), a severely hindered amine salt, and/or a severely hindered aminoacid. This invention also describes a process for the removal of H.sub.2 S from fluid mixtures using this absorbent solution to produce a very low level of H.sub.2 S in the treated fluid. The process is also suitable for the selective removal of H.sub.2 S from fluid mixtures comprising H.sub.2 S and CO.sub.2.
Type:
Grant
Filed:
August 24, 1989
Date of Patent:
October 9, 1990
Assignee:
Exxon Research and Engineering Company
Inventors:
W. S. Winston Ho, Guido Sartori, Eugene L. Stogryn
Abstract: The present invention relates to a gallo-aluminosilicate zeolite designated as ECR-10 which contains cesium. It also relates to a process for preparation of the zeolite. It may be employed in absorbent or separation applications, particularly in separation of small molecules.
Type:
Grant
Filed:
October 28, 1988
Date of Patent:
October 2, 1990
Assignee:
Exxon Research and Engineering Company
Inventors:
David E. W. Vaughan, Karl G. Strohmaier
Abstract: A class of new oxide structures containing octahedral molybdenum and tetrahedral phosphorous has been generated using hydothermal techniques. These materials are produced by the reaction of a molybdenum oxide source with phosphate and any one, or combination of organic cation/alkali-metal cation/organic amine as a templating/mineralizing agent. A reducing agent is necessary to convert the Mo(VI) to a lower valent form and can be either added to the reaction mixture or is provided in the form of one the reactants.
Type:
Grant
Filed:
May 12, 1989
Date of Patent:
September 11, 1990
Assignee:
Exxon Research and Engineering Company
Inventors:
Edward W. Corcoran, Jr., Robert C. Haushalter, Wen-Yih F. Lai
Abstract: A crosslinked copolymer composition is derived from an aliphatic polyester, a dianhydride and a diicoyanate. The copolymer membrane has high thermal stability and good aromatic/saturate selectivity and permeability.
Type:
Grant
Filed:
October 16, 1989
Date of Patent:
August 7, 1990
Assignee:
Exxon Research and Engineering Company
Inventors:
Warren A. Thaler, W. S. Winston Ho, Guido Sartori
Abstract: A new copolymer composition comprising the hard segment of a polyimide and the soft segment of an oligomeric aliphatic polyester. The new polyimide copolymer membranes have exhibited high thermal stability for separation of an aromatic/saturate mixture. These new membranes have higher aromatic/saturate selectivity than polyurethanes.
Type:
Grant
Filed:
October 16, 1989
Date of Patent:
July 31, 1990
Assignee:
Exxon Research and Engineering Company
Inventors:
W. S. Winston Ho, Guido Sartori, Warren A. Thaler, David C. Dalrymple
Abstract: This invention relates to novel zeolitic compositions having tin substituted into the framework positions and a method for their preparation. The process of preparation more specifically involves hydrothermally treating aluminosilicate silica zeolite in the presence of tin compounds.
Abstract: A faujasite polymorph having a silica to alumina ratio greater than 6, and containing tetrapropyl ammonium and/or tetrabutyl ammonium trapped within the supercages of said structure.
Type:
Grant
Filed:
May 23, 1989
Date of Patent:
June 5, 1990
Assignee:
Exxon Research and Engineering Company
Inventors:
David E. W. Vaughan, Karl G. Strohmaier
Abstract: Disclosed are primary sterically hindered aminoacids for use as promoters for alkali metal salts in acid gas scrubbing. The primary sterically hindered aminoacid is selected from 1-amino-cyclopentane carboxylic acid and those represented by the formula: ##STR1## where R.sub.1 and R.sub.2 are independently selected from CH.sub.3, C.sub.2 H.sub.5, and C.sub.3 H.sub.7 ; R.sub.3 and R.sub.4 are independently selected from hydrogen and CH.sub.3 ; and n is 0, 2, or 3.
Type:
Grant
Filed:
April 11, 1988
Date of Patent:
April 24, 1990
Assignee:
Exxon Research and Engineering Company
Inventors:
Larry J. Shulik, Guido Sartori, W. S. Winston Ho, Warren Thaler, George E. Milliman
Abstract: A process for diffusing silicon into iron or iron alloy by heating the iron or iron alloy with silica and a suitable reducing agent in the presence of a catalyst.
Abstract: A new alkaline absorbent solution containing a severely-hindered amine and a severely-hindered aminoacid is provided. A process for the removal of H.sub.2 S from fluid mixtures using this absorbent solution to produce a very low level of H.sub.2 S in the treated fluid is also provided. The process is also suitable for the selective removal of H.sub.2 S from fluid mixtures comprising H.sub.2 S and CO.sub.2. Use of the above absorbent solution leads to higher selectivity for H.sub.2 S than observed when the severely-hindered amine is used alone without the severely-hindered aminoacid.