Patents Represented by Attorney Ronald G. Brookens
  • Patent number: 4474599
    Abstract: Compounds are prepared which correspond to the formula ##STR1## wherein R represents C.sub.1 -C.sub.12 alkyl, C.sub.1 -C.sub.12 alkoxyalkyl, --CH.sub.2 Ar, Ar';Ar represents ##STR2## each X independently represents halo, C.sub.1 -C.sub.6 alkyl, --OCH.sub.3, --CF.sub.3, --OCF.sub.3, --NO.sub.2, --CN or --CO.sub.2 R.sup.2 ;each n independently represents 0, 1 or 2;Ar' represents ##STR3## R.sup.1 represents C.sub.1 -C.sub.8 alkyl, C.sub.2 -C.sub.6 alkenyl, C.sub.2 -C.sub.6 alkynyl, C.sub.2 -C.sub.6 alkoxyalkyl, CF.sub.3 or Ar";Ar" represents Ar, ##STR4## R.sup.2 represents C.sub.1 -C.sub.6 alkyl. These compounds have been found to be effective pre- and post-emergent herbicides and as active agents in herbicidal compositions.
    Type: Grant
    Filed: July 14, 1982
    Date of Patent: October 2, 1984
    Assignee: The Dow Chemical Company
    Inventors: Richard B. Rogers, Ben C. Gerwick, Eric A. Egli
  • Patent number: 4472193
    Abstract: Novel 2-naphthyridinyloxy(or thio)phenoxy propanoic acid compounds of the formula ##STR1## wherein ##STR2## represents a 6 membered nitrogen containing an aromatic ring which forms a 1,5-, 1,6-, 1,7- or 1,8-naphthyridinyl moiety with the adjoining pyridine ring, said naphthyridinyl moiety optionally substituted at the 6 position of the naphthyridinyl moiety with a chloro, bromo, iodo, CF.sub.3, or fluoro atom;A represents O or S; andagriculturally acceptable salts, esters, ethers, and amides thereof, are useful as fungicides and herbicides, particularly effective against grassy weeds.
    Type: Grant
    Filed: July 6, 1982
    Date of Patent: September 18, 1984
    Assignee: The Dow Chemical Company
    Inventor: James A. Turner
  • Patent number: 4472583
    Abstract: A compound having the formula ##STR1## wherein R is halogen, trichloromethyl, trifluoromethyl, nitro, cyano, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy; X is NH, O or S and n is an integer of from 1 to 5, which is useful as a fungicide on plants and other substrates susceptible to fungicidal attack.
    Type: Grant
    Filed: December 8, 1982
    Date of Patent: September 18, 1984
    Assignee: The Dow Chemical Company
    Inventor: David P. Clifford
  • Patent number: 4459302
    Abstract: New acyl-1H-1,2,4-triazole derivatives of the formula ##STR1## wherein R may be located on one of the two adjacent nitrogen atoms and may represent hydrogen; a group R.sub.5 -CO wherein R.sub.5 is selected from (C.sub.1-4)alkyl, (C.sub.2-4)alkenyl, (C.sub.2-4)alkynyl, phenyl, phenyl substituted by one to three groups independently selected from halo, (C.sub.1-4)alkyl, (C.sub.1-4)alkoxy, trifluoromethyl, cyano, nitro, amino, di-(C.sub.1-4)alkylamino, (C.sub.2-4)acylamino and methylenedioxy, benzyl, cinnamyl, amino, (C.sub.1-4)alkylamino, di-(C.sub.1 -C.sub.4)alkylamino, phenylamino, phenylamino wherein the phenyl ring may be substituted by one to three groups independently selected from halo, (C.sub.1-4)alkyl, (C.sub.1-4)alkoxy, trifluoromethyl, cyano, nitro, amino, di-(C.sub.1-4)alkylamino, (C.sub.2-4)acylamino and methylenedioxy, halo(C.sub.1-4)alkyl, (C.sub.1-4)alkoxy and benzyloxy;a group R.sub.6 -SO.sub.2 wherein R.sub.6 may represent (C.sub.
    Type: Grant
    Filed: October 23, 1979
    Date of Patent: July 10, 1984
    Assignee: Gruppo Lepetit, S.p.A.
    Inventors: Amedeo Omodei-Sale, Pietro Consonni, Giulio Galliani
  • Patent number: 4455313
    Abstract: Crop plants are protected from attack by soil-borne plant disease organisms of the Genera Rhizoctonia and Sclerotium employing 2-halo-4-halomethyl 6-pyridinols and their metal and amine salts.
    Type: Grant
    Filed: August 20, 1982
    Date of Patent: June 19, 1984
    Assignee: The Dow Chemical Company
    Inventor: Robert J. Ehr
  • Patent number: 4451653
    Abstract: Compounds are prepared which correspond to the formulae ##STR1## wherein R represents a nitrogen containing heterocyclic radical corresponding to one of the formulae ##STR2## each X independently represents chloro, fluoro, bromo, nitro, alkyl of 1 to 4 carbon atoms, amino, mono- or dialkylamino wherein each alkyl group independently contains from 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, cyano, trifluoromethyl, trichloromethyl, phenoxy or substituted phenoxy of the formula ##STR3## wherein each Z independently represents chloro, fluoro, bromo, nitro, cyano, alkoxy of 1 to 4 carbon atoms or alkylthio of 1 to 4 carbon atoms, with the proviso that when either n is 2 or 3, all X groups are sterically compatible with each other and all Z groups are sterically compatible with each other; Y represents oxygen or sulfur; each n can independently represent an integer of from 0 to 3, inclusive; R.sup.
    Type: Grant
    Filed: November 12, 1982
    Date of Patent: May 29, 1984
    Assignee: The Dow Chemical Company
    Inventor: Chester E. Pawloski
  • Patent number: 4440943
    Abstract: 3,7-Substituted phenoxiodinin-5-ium compounds are effective against a variety of aerobic and anaerobic bacteria as well as fungi. The compounds of this invention may be prepared by the direct iodination of a suitably substituted diphenyl ether with iodosyl sulfate in concentrated sulfuric acid. The resulting bisulfate anion may be exchanged with a desired anion by standard metathetic processes.
    Type: Grant
    Filed: March 15, 1982
    Date of Patent: April 3, 1984
    Assignee: The Dow Chemical Company
    Inventor: Edward E. Flagg
  • Patent number: 4439431
    Abstract: O,O-Diethyl O-(4-(t-butylsulfonyl)-m-tolyl) phosphorothioate is an active insecticide for the kill and control of the copper bottle fly and the southern cattle tick.
    Type: Grant
    Filed: October 2, 1981
    Date of Patent: March 27, 1984
    Assignee: The Dow Chemical Company
    Inventor: Walter Reifschneider
  • Patent number: 4439430
    Abstract: O,O-diethyl O-[-4-(t-butylsulfinyl)phenyl]phosphorothioate is an active insecticide for the kill and control of cucumber beetle larvae.
    Type: Grant
    Filed: October 2, 1981
    Date of Patent: March 27, 1984
    Assignee: The Dow Chemical Company
    Inventor: Walter Reifschneider
  • Patent number: 4435381
    Abstract: Process and composition for dental hygiene in which the teeth of animals are contacted with a long-chain alkyl thiouronium phosphonate.
    Type: Grant
    Filed: July 18, 1983
    Date of Patent: March 6, 1984
    Assignee: The Dow Chemical Company
    Inventor: Edward E. Flagg
  • Patent number: 4433148
    Abstract: Compounds are prepared which correspond to the formula ##STR1## wherein R represents a nitrogen containing heterocyclic radical corresponding to one of the formulae ##STR2## each X independently represents chloro, fluoro, bromo, nitro, alkyl of 1 to 4 carbon atoms, amino, mono- or dialkylamino wherein each alkyl group independently contains from 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, cyano, trifluoromethyl, trichloromethyl, phenoxy or substituted phenoxy of the formula ##STR3## wherein each Z independently represents chloro, fluoro, bromo, nitro, cyano, alkoxy of 1 to 4 carbon atoms or alkylthio of 1 to 4 carbon atoms, with the proviso that when either n is 2 or 3, all X groups are sterically compatible with each other and all Z groups are sterically compatible with each other; Y represents oxygen or sulfur; each n can independently represent an integer of from 0 to 3, inclusive; R.sup.
    Type: Grant
    Filed: November 12, 1982
    Date of Patent: February 21, 1984
    Assignee: The Dow Chemical Co.
    Inventor: Chester E. Pawloski
  • Patent number: 4429125
    Abstract: Compounds of the formula: ##STR1## wherein R is hydrogen; alkyl of 1 to 8 carbons; alkylthiomethyl, alkylsulfinylmethyl or alkylsulfonylmethyl wherein alkyl contains 1 to 4 carbons; phenyl; phenylthio; alkylthio, alkylsulfinyl or alkylsulfonyl wherein alkyl contains 1 to 4 carbons; or alkylthio-ethylthio wherein alkyl contains 1 to 2 carbons;R' is hydrogen, methyl or alkylthio of 1 to 2 carbons;R" is hydrogen or methyl;X is oxygen or sulfur;R'" is alkyl of 1 to 2 carbons; andR"" is --OR'" or --S-alkyl of 1 to 4 carbons,are highly useful insecticides which are paricularly valuable when applied to the soil, but are also useful applied to foliage of crops or trees. Especially good control is obtained of corn rootworm, codling moth, thrips, leafhoppers, and nematodes. The compounds are conveniently applied in the form of a composition containing a pesticidal carrier such as an inert solvent or a finely divided inert solid in which case the composition is preferably granulated.
    Type: Grant
    Filed: July 28, 1978
    Date of Patent: January 31, 1984
    Assignee: The Dow Chemical Co.
    Inventor: Walter Reifschneider
  • Patent number: 4424217
    Abstract: O,O-Dialkyl O-?4-(tert-alkylsulfinyl)-2-chlorophenyl! phosphorothioate and the corresponding sulfonyl compounds are active insecticides for the kill and control of codling moth larvae.
    Type: Grant
    Filed: October 2, 1981
    Date of Patent: January 3, 1984
    Assignee: The Dow Chemical Company
    Inventor: Walter Reifschneider
  • Patent number: 4423222
    Abstract: Suitably substituted 2-aminomethyl pyridines and suitably substituted 2-pyridinylcarbinols are reacted with 3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane carboxoyl chloride in an inert solvent to form a group of biologically active organic compounds. These compounds are active as fungicides, herbicides, or both.
    Type: Grant
    Filed: May 21, 1982
    Date of Patent: December 27, 1983
    Assignee: The Dow Chemical Company
    Inventors: Mary L. Ash, Richard G. Pews
  • Patent number: 4419514
    Abstract: Method for converting carboxylic acid groups to trichloromethyl groups which comprises contacting a compound containing a carboxylic acid group with a phenylphosphonic dichloride and phosphorus pentachloride and recovering the thus produced product.
    Type: Grant
    Filed: May 18, 1981
    Date of Patent: December 6, 1983
    Assignee: The Dow Chemical Company
    Inventors: Lennon H. McKendry, Michael J. Ricks, Richard B. Rogers
  • Patent number: 4418198
    Abstract: The invention is directed to the novel 2-(((substituted pyridinyl)carbonyl)amino)ethyl esters of 2-methyl-2-propenoic acid and their method of preparation. The compounds are prepared by reacting an appropriately substituted pyridinol, pyridinethiol, aminopyridine, or hydroxyalkyloxypyridine with isocyanatoethyl methacrylate in an appropriate solvent in the presence of an activating agent. These compounds may be utilized as herbicides, fungicides, or both.
    Type: Grant
    Filed: November 16, 1981
    Date of Patent: November 29, 1983
    Assignee: The Dow Chemical Company
    Inventor: Chester E. Pawloski
  • Patent number: 4413009
    Abstract: The present invention is directed to N-((alkylamino)carbonyl)-N-(((alkylamino)carbonyl)oxy)acylamides and their use in inhibiting the growth of HeLa cells, P.sub.388 leukemia or MX-1 carcinomas in mammals.
    Type: Grant
    Filed: February 17, 1982
    Date of Patent: November 1, 1983
    Assignee: The Dow Chemical Company
    Inventor: Walter Reifschneider
  • Patent number: 4400516
    Abstract: Compounds are prepared which correspond to the formula ##STR1## wherein R represents a nitrogen containing heterocyclic radical corresponding to one of the formulae ##STR2## each X independently represents chloro, fluoro, bromo, nitro, alkyl of 1 to 4 carbon atoms, amino, mono- or dialkylamino wherein each alkyl group independently contains from 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, cyano, trifluoromethyl, trichloromethyl, phenoxy or substituted phenoxy of the formula ##STR3## wherein each Z independently represents chloro, fluoro, bromo, nitro, cyano, alkoxy of 1 to 4 carbon atoms or alkylthio of 1 to 4 carbon atoms, with the proviso that when either n is 2 or 3, all X groups are sterically compatible with each other and all Z groups are sterically compatible with each other; Y represents oxygen or sulfur; each n can independently represent an integer of from 0 to 3, inclusive; R.sup.
    Type: Grant
    Filed: May 4, 1981
    Date of Patent: August 23, 1983
    Assignee: The Dow Chemical Co.
    Inventor: Chester E. Pawloski
  • Patent number: 4390543
    Abstract: Substituted pyridine methyl esters of 2-isopropyl-2-(4-chlorophenyl)acetic acid are prepared which correspond to the formula: ##STR1## wherein n represents an integer of 0 to 2; X independently represents alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, trifluoromethyl, nitro, cyano, chloro, fluoro, bromo, or 3,4-methylenedioxy (when n is 2 and both X's are taken together); and R represents hydrogen, cyano or ethynyl. These compounds have been found to exhibit a high degree of insecticidal activity and compositions containing said compounds are so employed.
    Type: Grant
    Filed: April 21, 1980
    Date of Patent: June 28, 1983
    Inventors: Sudarshan K. Malhotra, John C. Van Heertum
  • Patent number: 4388251
    Abstract: The present application is directed to the preparation of 2-chlorobenzoyl chloride by the reaction of 2-chlorobenzaldehyde with chlorine in the presence of phosphorus pentachloride.
    Type: Grant
    Filed: January 28, 1982
    Date of Patent: June 14, 1983
    Assignee: The Dow Chemical Company Limited
    Inventor: David P. Clifford