Abstract: Monomeric polysiloxanes end-capped with activated unsaturated groups and polymers and copolymers thereof are disclosed herein for use as contact lenses and biomedical devices with improved properties, such as, oxygen transportability, hydrolytic stability, biological inertness, transparency and improved strength without the use of fillers. The polymer composition comprises a poly(organosiloxane) monomer .alpha.,.omega. terminally bonded through divalent hydrocarbon groups to polymerized free radical polymerizably activated unsaturated groups. Contact lenses and biomedical devices i.e. shaped article for use in biomedical applications made therefrom can be "hard" or "soft". This hardness or softness is a function of the comonomer or the molecular weight of the monomers. Preferably the contact lenses and biomedical devices are "soft".The copolymer compositions of the instant invention comprise the polymerization product of the polysiloxane monomers and monomer or monomers containing an activated vinyl group.

Abstract: Monomeric polysiloxanes end-capped with activated unsaturated groups and polymers and copolymers thereof are disclosed herein for use as contact lenses with improved properties, such as, oxygen transportability, hydrolytic stability, biological inertness, transparency and improved strength without the use of fillers. The polymer composition comprises a poly(organosiloxane) .alpha., .omega. terminally bonded through a divalent hydrocarbon group to a polymerized activated unsaturated group. Contact lenses made therefrom can be, as commonly referred to, "hard" or "soft". This hardness or softness is a function of the comonomer or the molecular weight of the monomers. Preferable the contact lenses are "soft".The copolymer compositions of the instant invention comprise the polymerization product of the polysiloxane monomers and monomer or monomers containing an activated vinyl group. These polymers are employed to make optical products, e.g. contact lenses, intraocular implants, etc.

Abstract: The surface of a contact lens is modified by deposition of an ultrathin coating of a hydrophilic polymer under the influence of plasma glow discharge so as to integrally bond the coating to the surface of the hydrophobic lens thereby effecting a hydrophilic lens.

Abstract: Cleaning imaging material from a xerographic imaging surface with a cleaning blade with reduced friction between the blade and the surface is provided without image degredation by an appropriately roughened surface, which roughness is formed on the photoconductive surface by substrate pre-etching to provide a final or post coated roughness pattern of 3 to 5 microns and less than 20 microns.

Abstract: A photoconductive member for xerographic applications comprising a mixture of particles of at least two photoconductive pigments capable of generating and injecting holes and electrons dispersed in an insulating binder, capable of transporting holes and electrons in response to imagewise radiation. The photoconductors which are preferred also have a coefficient of absorption between 1/L and 8/L wherein L is the thickness of the photoconductive member in microns. The photoconductive member thus formed is capable of continuous tone reproduction and has improved xerographic characteristics. In a particularly preferred embodiment, one of the photoconductive materials is cadmium sulfoselenide.

Abstract: A photoreceptor used in xerographic imaging process and normally including a photoconductive layer comprising a mixture of photoconductive particles dispersed throughout the layer with resinous binder material is joined by bonding to a conductive base layer through an intermediate layer which provides a charge carrier injecting interface between the photoconductive particles and the base layer. The charge carrier interface is obtained by forming the intermediate layer from high mass conductive particles dispersed within an insulating resinous material, and causing photoconductive particles in the photoconductor layer to contact conductive particles in the intermediate layer along the bond interface. The conductive particles are selected so as to have available charge carriers at suitable energy levels whereby the photoconductor to conductor particle contact points form individual charge carrier injection contacts which permit certain xerographic imaging processes to be used.

Abstract: A process for nickel plating a cylindrically shaped hollow core mandrel suitable for chromium plating for use in an electroforming process for the production of endless seamless nickel xerographic belts, is disclosed. The process comprises providing a hollow core aluminum or aluminum alloy cylindrically shaped member and (1) anodizing this core member by using this core member as an anode in an anodizing bath where the cathode comprises lead or lead alloys and (2) nickel plating this anodized core member in a nickel electroforming bath where the core member becomes the cathode and the anode is nickel or nickel alloy. Additionally and optionally, this core member may then be (3) subjected to an acid dip bath where the core member remains for a particular length of time and, additionally, then the core member is (4) plated with chromium by placing the core member in a chromium electroplating bath with a metal anode of lead or lead alloys.

Abstract: Disclosed is a method for enhancing the resistance to crystallization of solid solutions containing electron acceptor molecules. According to this method, electron acceptor molecules are chemically modified whereby the resulting compound is capable of undergoing polymerization. This modified material is thereafter dissolved in a suitable polymeric resin and subsequently exposed to a source of activating energy thereupon causing such modified material to polymerize within the polymeric resin. The resulting composition exhibits enhanced resistance to crystallization and thus is suitable for use in electrophotographic devices and methods.

Abstract: A photosensitive member having at least two electrically operative layers is disclosed. The first layer comprises a photoconductive layer which is capable of photogenerating holes and injecting the photo-generated holes into a contiguous charge transport layer. The charge transport layer comprises poly(N-vinylcarbazole) which contains an electrically active plasticizer comprising from about 1 to about 25 percent by weight of bis(4-diethylamino-2-methylphenyl)phenylmethane. The charge transport layer while substantially non-absorbing in the spectral region of intended use, is "active" in that it allows injection of photo-generated holes from the photoconductive layer, and allows these holes to be transported through the charge transport layer. This structure may be imaged in the conventional xerographic mode which usually includes charging, exposure to light and development.

Abstract: Novel photoconductive imaging members are provided comprising a layer of inorganic photoconductive material contained on a supporting substrate with a contacting layer of an electrically active organic material contiguous with the photoconductive layer comprising a plasticizer of an alkyl substituted anthracene.

Abstract: A photosensitive member having at least two electrically operative layers is disclosed. The first layer comprises trigonal selenium which is capable of photogenerating holes and injecting the photo-generated holes into a contiguous charge transport layer. The charge transport layer comprises a transparent electrically inactive organic resinous material containing from about 15 to about 75 percent by weight (throughout) of bis(4-diethylamino-2-methylphenyl)phenylmethane. The charge transport layer while substantially non-absorbing in the spectral region of intended use, is "active" in that it allows injection of photo-generated holes from the trigonal selenium carrier generating layer, and allows these photo-generated holes to be transported through the charge transport layer. This structure may be imaged in the conventional xerographic mode which usually includes charging, exposure to light and development.

Abstract: A method of making a flexible seamless brass cylinder which comrises forming a thin continuous layer of brass of uniform thickness on the surface of a cylindrically shaped vertical rotating mandrel by electrolitic deposition in an electrolic bath containing at least one brass anode. Apparatus for carrying out the electroforming process is also disclosed.

Abstract: A photoreceptor used in xerographic imaging process and normally including a photoconductive layer comprising a mixture of photoconductive particles dispersed throughout the layer with resinous binder material is joined by bonding to a conductive base layer through an intermediate layer which provides a charge carrier injecting interface between the photoconductive particles and the base layer. The charge carrier interface is obtained by forming the intermediate layer from high mass conductive particles dispersed within an insulating resinous material, and causing photoconductive particles in the photoconductor layer to contact conductive particles in the intermediate layer along the bond interface. The conductive particles are selected so as to have available charge carriers at suitable energy levels whereby the photoconductor to conductor particle contact points form individual charge carrier injection contacts which permit certain xerographic imaging processes to be used.

Abstract: A photoconductive layer comprising a block copolymer which exhibits a lamellar morphology, said copolymer having lamellae of at least 2 phases, one phase comprising a photoconductive material and the other phase an elastomeric material, with said lamellae being disposed in a direction substantially normal to the horizontal plane of said layer. The method of making the block copolymer is also disclosed.

Abstract: An imaging member comprising a first layer of electrically active charge transport material contained on a supporting substrate, a photoconductive layer overlaying said active layer, and a second layer of electrically active charge transport material overlaying said photoconductive layer.

Abstract: A cylindrically shaped hollow mandrel is disclosed which is suitable in an electroforming process used for the production of an endless seamless nickel xerographic belt. The mandrel set forth comprises a metal core member with a thin removable metal sleeve having a thickness between about 10 and 60 mils which is fitted over said core member to provide a surface for electroforming of the nickel belt. Mandrels disclosed in the present invention have the advantage of a longer lifetime of use in a continuous electroforming process because of the replaceable nature of the metal sleeve.

Abstract: A method of forming an electrophotographic coating which includes preparing a mixture which comprises finely divided photoconductive material dispersed in an organic resin binder. The resin, which exhibits an acid value of at least 3, or a hydroxyl value of at least 15, is heat-treated for a time and temperature enclosed within the area ABCDEFGH of the temperature-treating diagram shown in the accompanying drawing. Following this treatment, the mixture is dissolved in a volatile solvent for the binder resin, and the dispersion is coated onto a conductive backing to form a substantially uniform layer.