Patents Represented by Attorney S. M. Tarter
  • Patent number: 4094865
    Abstract: The invention provides a process for the production of a polyester which comprises initiating a reaction between a poly-terminal epoxide, a mono-terminal epoxide and a cyclic diacid anhydride in the presence of a catalytically effective quaternary salt heating to a point at which the reaction becomes a self-sustaining exothermic reaction and controlling the reaction such that the temperature of the mixture is not reduced until after the exothermic reaction has begun to subside.
    Type: Grant
    Filed: January 2, 1976
    Date of Patent: June 13, 1978
    Assignee: Monsanto Company
    Inventors: James C. Hill, Walter R. Knox
  • Patent number: 4092332
    Abstract: The process for the conversion of saturated hydrocarbons having from 4 to 10 carbon atoms to maleic anhydride is enhanced when a mixture of oxygen and saturated hydrocarbon is contacted with catalysts comprising phosphorus, vanadium, oxygen and an element selected from the group consisting of titanium, silicon, or mixtures of these elements. The process is particularly useful for the conversion of butane to maleic anhydride.
    Type: Grant
    Filed: July 2, 1976
    Date of Patent: May 30, 1978
    Assignee: Monsanto Company
    Inventors: Marshall C. Freerks, Seth Randle, Sr.
  • Patent number: 4092348
    Abstract: This disclosure relates to:(a) Compounds having the molecular structure represented by the formula: ##STR1## wherein X = COOM, where M is alkali metal, ammonium or trialkanolamine, and preferably is sodium;(b) solid and liquid detergent compositions incorporating compounds of a) supra, and(c) processes for washing comprising the use of compounds of a) and compositions of b), supra.
    Type: Grant
    Filed: March 3, 1977
    Date of Patent: May 30, 1978
    Assignee: Monsanto Company
    Inventors: Marvin M. Crutchfield, Charles J. Upton
  • Patent number: 4092269
    Abstract: The prior art discloses that phosphorus-vanadium-oxygen catalysts wherein the phosphorus to vanadium atom ratio is between about 1:2 and about 2:1, and wherein at least about 20 atom percent of the vanadium is in the tetravalent state, are useful for the conversion of aliphatic hydrocarbons to maleic anhydride. It has now been found that when the pore volume of the catalysts from pores having diameters between about 0.8 micron and about 10 microns is greater than 0.02 cc/g, the catalyst is particularly useful for the conversion of saturated hydrocarbons, such as butane, to maleic anhydride.
    Type: Grant
    Filed: October 15, 1976
    Date of Patent: May 30, 1978
    Assignee: Monsanto Company
    Inventors: Ramon A. Mount, John F. Pysz, Jr., Harold Raffelson
  • Patent number: 4091019
    Abstract: A process for the production of unsaturated primary amines which comprises reacting, in the substantial absence of molecular oxygen, an amine having the formula (R.sub.1 HC=CR.sub.2 CH.sub.2)m N H (3-m), wherein m is 2 or 3 and R.sub.1 and R.sub.2 are hydrogen or C.sub.1 - C.sub.3 alkyl groups, with ammonia in the presence of a catalyst comprising palladium or platinum atoms bearing phosphorus-containing ligands, the reaction being carried out at a temperature of from 0.degree. to 250.degree. C in the presence of a solvent for the amine and the catalyst.
    Type: Grant
    Filed: April 27, 1976
    Date of Patent: May 23, 1978
    Assignee: Monsanto Company
    Inventors: Robert A. Keppel, John S. McConaghy, Jr.
  • Patent number: 4086195
    Abstract: Bitumen filled polyester foams are provided through a process which comprises forming a solution of a bitumen having a softening point of at least about 80.degree. C. and a cyclic diacid anhydride at a temperature above the softening point of a bitumen, the bitumen solution is then mixed with a monoterminal epoxide and a polyterminal epoxide in the presence of a blowing agent resulting in the initiation of an exothermic reaction. The process for producing bitumen filled polyester foams through the in situ polymerization of polyesters in a solution of bitumen and the foams produced by the process constitute the invention.
    Type: Grant
    Filed: March 2, 1977
    Date of Patent: April 25, 1978
    Assignee: Monsanto Company
    Inventors: Walter R. Knox, James C. Hill, Lawrence J. Hughes, Paul W. Foerst
  • Patent number: 4080404
    Abstract: Disclosed herein are polyblend molding compositions which comprise (A) poly(styrene/acrylonitrile/methylmethacrylate) matrix polymer; (B) polychloroprene rubber which is grafted with monomers of the type used to prepare the matrix; (C) a metal oxide; and (D) smoke suppressants. Specimens molded from these polyblends have a UL-94 rating of at least V-1 and a smoke level of less than 360 D.sub.m Flaming as measured using the NBS smoke test.
    Type: Grant
    Filed: April 12, 1976
    Date of Patent: March 21, 1978
    Assignee: Monsanto Company
    Inventor: Gary L. Deets
  • Patent number: 4079006
    Abstract: The precipitation of scale forming salts in an aqueous system is inhibited by adding either stoichiometric or substoichiometric, including threshold, amounts to said system of a phosphonomethylene amino carboxylate of the general formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.5, Q and Z are hereinafter defined.
    Type: Grant
    Filed: August 2, 1976
    Date of Patent: March 14, 1978
    Assignee: Monsanto Company
    Inventor: Robert S. Mitchell
  • Patent number: 4052333
    Abstract: A process for the regeneration of a spent molybdenum-containing ammoxidation catalyst which comprises heating the catalyst at atmospheric pressure or higher and at 400.degree. C or higher for at least 1 hour in an atmosphere comprising 20-45% by volume of steam, the balance being air or a gas inert to the catalyst under the above conditions.
    Type: Grant
    Filed: June 25, 1976
    Date of Patent: October 4, 1977
    Assignee: Monsanto Company
    Inventor: Emerson H. Lee
  • Patent number: 4051311
    Abstract: Disclosed herein are interpolymers of a styrenic monomer, a maleic or halomaleic anhydride monomer and a brominated monomer selected from the group consisting of bromophenyl acrylates, bromophenyl methacrylates, bromoneopentyl acrylates and bromoneopentyl methacrylates. These polymers when formulated with various additives, have a UL-94 rating of at least V-1. The polymers are especially useful for use in radio and T.V. cabinets, furniture, appliance housings and other similar applications.
    Type: Grant
    Filed: December 29, 1975
    Date of Patent: September 27, 1977
    Assignee: Monsanto Company
    Inventor: Yoon C. Lee
  • Patent number: 4048274
    Abstract: Disclosed herein is an improvement in the process for manufacturing thermal insulation panels, especially those panels used in refrigerator cabinets. The panels are composite structures which comprise a layer of a gas filled cellular insulation material combined with a layer of impact resistant thermoplastic sheet material, wherein a film of a rubber modified high nitrile polymer containing at least 45% by weight of nitrile monomer units (calculated as acrylonitrile) is interposed between the gas filled cellular material and the thermoplastic sheet. The rubber modified high nitrile polymer film presents an effective barrier to the gas in the cellular material and provides improved impact strength in the composite while retaining good rigidity of the composite structure.
    Type: Grant
    Filed: May 26, 1976
    Date of Patent: September 13, 1977
    Assignee: Monsanto Company
    Inventors: A. Russell Hoge, Robert A. Myers
  • Patent number: 4048263
    Abstract: Disclosed herein are rubber modified fire retardant polymer compositions based on interpolymers of styrene, maleic anhydride and a brominated monomer such as tribromophenyl acrylate, which have been formulated with various additives. These compositions, which have a UL-94 rating of at least V-1, are especially useful for use in radio and T.V. cabinets, furniture, appliance housings and other similar applications.
    Type: Grant
    Filed: December 29, 1975
    Date of Patent: September 13, 1977
    Assignee: Monsanto Company
    Inventor: Yoon C. Lee
  • Patent number: 4035549
    Abstract: Disclosed herein is an improved interlayer for laminated safety glass. The improved interlayer is characterized by having at least one surface which is more printable without sacrificing the surface roughness required to prevent blocking of the sheet and to facilitate de-airing of laminates prepared from the interlayer.
    Type: Grant
    Filed: May 19, 1975
    Date of Patent: July 12, 1977
    Assignee: Monsanto Company
    Inventor: George A. Kennar
  • Patent number: 4035564
    Abstract: There is disclosed a polymerization process for the preparation of large chloroprene polymer particles having an average diameter in the range of from 0.15 to 2.0 microns. The process utilizes a polymerization medium and catalyst system that produces a substantially monodisperse particle size distribution of polychloroprene rubber particles in an aqueous dispersion, said particles having great utility as a rubber phase in thermoplastic polyblends.
    Type: Grant
    Filed: January 3, 1974
    Date of Patent: July 12, 1977
    Assignee: Monsanto Company
    Inventor: Alexander A. Bibeau
  • Patent number: 4033896
    Abstract: Phosphonomethyl amino carboxylates of the general formula ##STR1## wherein M.sub.1, M.sub.2 and M.sub.3 are each hydrogen, metal ion, ammonium ion or alkyl ammonium ion, Z is --CH.sub.2 PO.sub.3 M.sub.1 M.sub.2, C.sub.1.sub.-4 alkanol, C.sub.1.sub.-4 alkyl carboxylic acid, or C.sub.1.sub.-10 alkaminomethylene phosphonic acid radical, and Q is C.sub.3.sub.-15 alkylene, C.sub.3.sub.-15 alkenylene, or alkaryl radical are useful alone or in combination with one or more conventional corrosion inhibitor compounds to inhibit the corrosion of metals in aqueous systems.
    Type: Grant
    Filed: June 18, 1976
    Date of Patent: July 5, 1977
    Assignee: Monsanto Company
    Inventors: Robert S. Mitchell, Thomas M. King
  • Patent number: 4026007
    Abstract: Disclosed herein is an improved process for finishing a die roll which is used to prepare interlayers for laminated safety glass. The improvement comprises the blasting of the roll with glass beads after the conventional grit blasting steps and before chrome plating. Interlayers prepared using rolls made by this process are characterized by having surfaces which are more printable without sacrificing the surface roughness required to prevent blocking of the sheet and to facilitate de-airing of laminates prepared from the interlayer.
    Type: Grant
    Filed: May 19, 1975
    Date of Patent: May 31, 1977
    Assignee: Monsanto Company
    Inventor: Van Pelt Brower
  • Patent number: 4027061
    Abstract: Disclosed herein is a laminated glazing unit for vehicle and architectural uses which comprises glass, an interlayer and a high nitrile polymer in a laminated configuration wherein the interlayer is sandwiched between the glass and the high nitrile polymer.
    Type: Grant
    Filed: November 18, 1975
    Date of Patent: May 31, 1977
    Assignee: Monsanto Company
    Inventors: George E. Cartier, James A. Snelgrove
  • Patent number: 4027069
    Abstract: Disclosed herein is a laminated safety glass prepared from a buffered polyvinyl acetal sheet. The sheet contains a pH buffer having an aqueous solution pH in the range of from 3 to 7 which stabilizes the sheet against viscosity degradation.
    Type: Grant
    Filed: August 13, 1975
    Date of Patent: May 31, 1977
    Assignee: Monsanto Company
    Inventors: George E. Mont, James A. Snelgrove
  • Patent number: 4022733
    Abstract: Disclosed herein is a latex polymerization process for grafting styrene and acrylonitrile type monomers onto a rubber latex which has been stabilized with a substance which inhibits polymerization. The process involves carrying out the graft polymerization reaction in the presence of from 1 to 10 parts of latex seed particles per hundred parts of rubber using a chain transfer agent that doesn't inhibit the graft polymerization reaction.
    Type: Grant
    Filed: June 25, 1975
    Date of Patent: May 10, 1977
    Assignee: Monsanto Company
    Inventors: Fred M. Peng, William O. Dalton