Abstract: A refractory clad metallurgical lance comprises a temperature sensing thermocouple means in combination with an internal gas conduit encased within exterior refractory cladding material wherein the conduit provides a passage way for transmitting inert gas under pressure. The thermocouple means is disposed within the refractory cladding and directed radially outward toward the outer peripherary of the refractory cladding whereby the temperature sensing portion is located near the peripheral surface of the cladding. The thermocouple is disposed within a ceramic protective tube which in turn is embedded within the refractory material secured around the internal gas conduit. In use, the metallurgical lance is operative to process molten metal by submerging the lower portion of the lance below the molten metal surface and bubbling inert gas through the metal while simultaneously directly measuring the temperature of the molten metal.

Abstract: Fibrous board transition parts are produced on the job site from standard lengths of preformed fiberboard duct units. Transition parts are interposed between linear runs of duct pieced together to change direction of the duct work. The transition parts, sometimes referred to as elbows or bends, can be easily fabricated on the job site by modifying standard lengths of preformed linear duct by cutting and removing pie-shaped sections from the duct. The modified duct can be bent inwardly to form a one-piece arcuate transition part wherein the outer wall section remains intact and provides structural strength to the transition part. The seams are secured with structural adhesive tape wrapped around the transition part.

Abstract: Provides new and improved water-reducible coating compositions and methods of making them. Three preferred processes are disclosed. These differ in the manner of incorporating and chemical nature of an extender polymer.Broadly, the process of the invention is one for forming an aqueous dispersion of a fluent resinous composition ofa. a mixture in an organic solvent of(i) an ionizable graft polymer of an epoxy resin and an addition polymerized resin, the addition polymerized resin being bonded to aliphatic backbone carbon atoms of the epoxy resin by carbon-to-carbon bonds, and(ii) an extender resin;b. an aqueous vehicle, andc. an ionizing agent;the ionization present from said combined components being sufficient to establish the components as a dispersion in the aqueous vehicle, and then addition polymerizing a quantity of addition polymerizable monomer, under addition polymerizing conditions, in said aqueous dispersion, the aqueous dispersion serving as a vehicle therefor.

Abstract: A lightweight extrudible or trowellable caulk or sealant composition can be compounded from polymeric acrylic binders containing dispersed therein sufficient microballoons with minor amounts of the ingredients to provide a pliable caulk material exhibiting good heat insulation properties, low shrinkage, and flexability in use.

Abstract: An aqueous dispersed thermosetting coating composition comprises a high Tg acrylic latex polymer containing reactive hydroxyl and/or carboxyl groups, or similar reactive groups, for cross-linking the acrylic polymer, and a polyvinylidene fluoride polymer, wherein the composition is adapted to be heat cured at temperatures above about 350.degree. F. The polyvinyl fluoride polymer fuses and becomes homogenously dispersed throughout the thermoset acrylic-melamine matrix polymer.

Abstract: Resinous coating compositions can be expediently heat cured by phenol compounds containing at least two methylene amine groups which are conjugated with the aromatic alcohol group or phenol group. The hydroxyl group substantially increase the reactivity of the aminomethyl functionality whereby active hydrogen containing resins can be effectively cross-linked.

Abstract: An aqueous polymeric composition comprises a stabilized mixture of an amino polymer and an oxirane polymer stabilized in water which maintains the polymers non-reactive. The composition can be cured in use at relatively low temperatures by evaporation of water whereby the amino groups coreact with the oxirane groups to provide a cured composition such as a protective coating or an adhesive.

Abstract: A polyspirolactone polymer particularly suitable for protective surface coatings comprises a spirolactone structure in the polymer structure adapted to be cross-linked with a primary or secondary amine compound to produce a thermoset protective coating.

Abstract: A base-functional graft polymer-containing resinous reaction product is made by incorporating an amine in a graft polymer molecule. An epoxy resin is reacted with ethylenically unsaturated monomer in the presence of a free radical initiator having hydrogen abstraction capability, to form a graft polymer resinous reaction product. The monomer may comprise a copolymerizable unsaturated amine or an unsaturated epoxide that, after the addition polymerization - grafting reaction, is reacted with a primary or secondary amine. Upon the addition of an ionizing agent and water, an aqueous dispersion or solution can be established.The resinous reaction products are useful in the formulation of coating compositions, and particularly, coating compositions useful for cathodic electrocoating.

Abstract: Room temperature curable latices can be produced by copolymerizing ketimine derivative ethylenically unsaturated monomers with conventional ethylenically unsaturated monomers in an emulsion process at a controlled pH greater than about 7.2 to produce a coagulum-free latex containing blocked amine (--NH.sub.2) groups. In use, the pH of the latex can be adjusted to acidic below 7 to generate unblocked reactive amino groups which can be cured or cross-linked at about room temperature with water-dispersed polymers such as epoxy, double bond or isothiocyanate containing polymers.

Abstract: An opacified latex paint comprising small particle film-forming latex binders in combination with minor amounts of opacifying pigment, and substantial amounts of non-film-forming polymeric particles (plastic pigment) provides a semi-gloss latex paint composition having excellent hard enamel surfaces along with desirable film integrity properties. The plastic pigment particles are between about 0.1 and 0.5 microns and contain 0.2 to 2% copolymerized monomers containing carboxylic acid groups. The semi-gloss plastic pigment latex paint is compounded at pigment-volume-content (PVC) between about 30% and 45% and considerably higher than conventional high quality enamel latex paints. The opacified semi-gloss paint films exhibit excellent physical properties such as hard enamel surfaces, scrub resistance, burnish resistance, mar resistance, stain resistance, and other desirable paint film integrity properties.

Abstract: An opacified latex paint comprising acrylic film-forming latex binders in combination with minor amounts of opacifying pigment and substantial amounts of non-film-forming polymeric particles (plastic pigment) provides a latex paint composition having desirable film integrity properties. The plastic pigment latex paint is compounded at a substantially high pigment-volume-content (PVC) greater than 75% PVC and yet produces a continuous crack-free paint film even though the dried paint film is highly loaded with non-film-forming components. The opacified paint films maintain excellent physical properties such as scrub resistance, burnish resistance, mar resistance, stain resistance, and other desirable paint film integrity properties.

Abstract: A process for dispersion strengthening metal alloys comprising the steps of separating metal powder particles larger than about 180 microns, flattening the particles to provide flake particles having a thickness less than 180 microns, and then internally oxidizing the flake particles. The flaked particles can be combined and consolidated with atomized particles less than about 180 microns on a 20% to 80% and preferably 40% to 60% weight basis to provide improved dispersion strengthened metal products.

Abstract: Thermosetting powder coatings comprising reactive polymers containing reactive carboxyl, hydroxyl, and/or amide groups and adapted to be cross-linked with aminoplast resins are substantially improved by the inclusion of at least about 0.25% by weight of a heat curing catalyst. The catalyst is an amine salt of cyclohexyl sulfamic acid.

Abstract: Particle size of suspension polymer particles is controlled in the suspension polymerization of a mixture of ethylenically unsaturated monomers including an ethylenically unsaturated monocarboxylic acid and pentaerythritol triacrylate by increasing the proportion of pentaerythritol triacrylate in said monomer mixture to increase the size of the suspension polymer particles.

Abstract: An electrocoating composition useful for electrocoating a paint coating from an aqueous solution onto an anode electrical conductive substrate. The electrocoating composition is based upon a fatty acid ester and .alpha.,.beta.-unsaturated dicarboxylic acid modified styrene-allyl alcohol copolymer further modified with an acid-functional acrylic copolymer. The electrocoated film can be air dried or heat cured.

Abstract: The invention pertains to thermosetting powder paint compositions adapted to fuse and thermoset upon exposure to heat. The powder paint is based upon a one-component, self-curing polymeric binder comprising a thermosetting glycoluril copolymer containing methylol or alkoxy methyl glycoluril groups adapted to cross-link with reactive hydroxyl, carboxyl, or amide groups on the copolymer. The copolymer is produced by partial condensation of tetramethylol or tetra-alkoxy methyl glycoluril with units containing reactive hydroxyls, carboxyls, or amide groups.

Abstract: An improved two-step process for producing bimodal emulsion polymer particles includes the steps of first providing uniform size polymer particles in the first stage by feeding monomers to the reaction mixture at a rate faster than the rate the monomers polymerize, and followed by a controlled second stage monomer polymerization by feeding monomers to the reaction mixture at a rate slower than the rate of polymerization of the monomers. The polymer particles are bimodal and are particularly useful in coatings, adhesives, and plastics.

Abstract: The invention pertains to thermosetting powder paints adapted to fuse and thermoset upon exposure to heat. The powder paint is based upon a two-component binder system comprising a polymeric glycoluril adapted to cross-link a matrix polymer having reactive hydroxyl, carboxyl, or amide groups.

Abstract: An improved electrocoating composition can be produced by first reacting an isocyanate terminated prepolymer with a minor amount of peroxide to provide a polyurethane polymer blocked with pendant peroxide groups, and then coreacting acrylic monomers with minor amounts of other ethylenically unsaturated monomers in the presence of the preformed polyurethane-peroxide polymer to provide polyurethane copolymer with said monomers. The resulting polyurethane acrylic block copolymer can contain carboxyl or amine groups for dispersing into a dilute aqueous solution and provide an anodic or cathodic electrocoating composition.