Patents Represented by Attorney Tyler A. Stevenson
  • Patent number: 7001644
    Abstract: A process for the production of coatings with scratch-resistant durable surfaces that comprise as photoinitiator (B) in a photocurable formulation at least one surface-active photoinitiator, concentrated at the surface of the formulation, of formula (Ia) or (Ib), wherein Ra is a radical of formula (IIa), Rb is a radical of formula (IIb)), or Ra and Rb are naphthyl, anthracyl, phenanthryl or a heterocyclic radical each of which is unsubstituted or substituted; R1, R2, R3, R4, R5, R6, R7, R8, R9 and R10 are, for example, each independently of the others hydrogen; A-Y; C1–C12alkyl, halogen or phenyl; R11 and R12 are, for example, C1–C12 alkyl; X is —OR20 or —N(R21)(R22); R20 is, for example, hydrogen or C1–C4alkyl; R21 and R22 are, for example, hydrogen or C1–C12 alkyl; X1 is, for example, —O—; Y is, for example, a single bond or —O—; Y1 is, for example, a single bond; and A is, for example, C6–C30alkyl.
    Type: Grant
    Filed: December 6, 2001
    Date of Patent: February 21, 2006
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Gisèle Baudin, Tunja Jung
  • Patent number: 6988823
    Abstract: Disclosed is an apparatus for wetting particulate material comprising a tank (1) that has an outlet (2) at its lower end and an inlet (3) at its upper end, into which is mounted a container (4) comprising a number of individual internal chambers (5) having horizontal baffles (6) which each have an orifice (7), a stirring rod (8) which is substantially coaxial with the tank passes through each orifice, and one or more impeller(s) (9) and one or more collar(s) (10) are attached to the stirring rod above each orifice and the apparatus additionally comprises a hopper (11) connected to a feeding device (12) which in turn is connected to an eductor (13) that is coupled to a water supply (24) and the inlet.
    Type: Grant
    Filed: April 30, 2002
    Date of Patent: January 24, 2006
    Assignee: Ciba Specialty Chemicals Corp.
    Inventor: Stephen Wilfred Wilson
  • Patent number: 6989449
    Abstract: Selected chlorohydrin and cationic compounds containing nitroxide or hydroxylamine moieties are effective in stabilizing pulp or paper, especially pulp or paper containing lignin, against yellowing and discoloration due to the adverse effects of light. These compounds are added at various points in the paper-making process, especially at the wet ends, making the need for water soluble or water dispersible materials having high affinity for pulp or paper essential. This performance is often further enhanced by the presence of one or more coadditives selected from the group consisting of the UV absorbers, the polymeric inhibitors, the nitrones, the fluorescent whitening agents and metal chelating agents. Combinations of hydroxylamines or their salts, benzotriazole or benzophenone UV absorbers and a metal chelating agent are particularly effective.
    Type: Grant
    Filed: September 11, 2000
    Date of Patent: January 24, 2006
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Glen T. Cunkle, David Devore, Thomas F. Thompson
  • Patent number: 6984682
    Abstract: A metallic effect pigment including a metallic, corrosion resistant reflective core of reflectivity from 40% to 80%; having deposited thereupon at least one dielectric coating layer formed of at least one metal oxide, the metal oxide layer having been formed by deposition on the core by hydrolysis of a hydrolyzable metal salt in an strongly acidic aqueous medium, and thereafter full transformation into the oxide by calcination.
    Type: Grant
    Filed: March 21, 2002
    Date of Patent: January 10, 2006
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Jack Polonka, Patrice Bujard, Natacha Bonnard Pillonel, Fritz Herren
  • Patent number: 6984690
    Abstract: The present invention relates to high-molecular-weight crosslinked polyvinyl butyrals obtainable by crosslinking a polyvinyl butyral with benzofuranone and/or with at least one derivative of the same, as crosslinking reagent, to their use, and to a process for their preparation.
    Type: Grant
    Filed: September 26, 2003
    Date of Patent: January 10, 2006
    Assignee: Ciba Specialty Chemicals Corp.
    Inventor: Bernd Papenfuhs
  • Patent number: 6967252
    Abstract: Novel flame retarding compounds that comprise at least one sterically hindered nitroxyl, hydroxylamine or hydrocarbyloxyamine moiety and at least one conventional organohalogen or organophosphorus flame retardant moiety, represented by where HA is independently of each other a sterically hindered nitroxyl, sterically hindered hydroxylamine or sterically hindered hydrocarbyloxyamine moiety, L is independently of each other a direct bond or chemical linking group, FRM is independently of each other an organohalogen or an organophosphorus flame reatardant moiety, and x, y and z are each independently greater than or equal to 1, are especially effective towards providing flame retardancy to organic polymer substrates.
    Type: Grant
    Filed: December 16, 2002
    Date of Patent: November 22, 2005
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Malisa V. Troutman, Ramanathan Ravichandran, Redina Kote, Roswell E. King
  • Patent number: 6951075
    Abstract: The present invention relates to the use of a pigment form or pigment concentrate comprising of an organic pigment, a growth-promoting additive, and optionally inorganic filler and/or an organic additive for coloring of seeds. Seeds colored by the dry pigment forms or pigment concentrates show homogeneous color and in some cases growth promotion effects.
    Type: Grant
    Filed: March 27, 2003
    Date of Patent: October 4, 2005
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Fridolin Bäbler, Kenneth Schumann
  • Patent number: 6949594
    Abstract: The invention relates to a process for the molecular weight increase/crosslinking of non-halogen-containing thermoplastic polymers, in which process a composition comprising a) a non-halogen-containing thermoplastic polymer; b) a functional compound having at least two unsaturated carbon bonds; and c) an alkoxyamine having a structural unit (I), which forms free radicals at the melting temperature/processing temperature of the polymer, is mixed and heated above the melting point of the polymer in the case of crystalline polymers or the softening point in the case of amorphous polymers.
    Type: Grant
    Filed: May 22, 2001
    Date of Patent: September 27, 2005
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Michael Roth, Rudolf Pfaendner, Dirk Simon
  • Patent number: 6949678
    Abstract: Compounds of the formulae I, II, III, IV and V wherein R1 i.a. is C4-C9cycloalkanoyl, C1-C12alkanoyl, C4-C6alkenoyl, or benzoyl; R2 is for example phenyl, C1-C20alkyl, C3-C8cycloalkyl, C2-C20alkanoyl, or benzoyl; Ar1 is R4S-phenyl or NR5R6-phenyl, each of which optionally is substituted; or Ar1 i.a. is optionally substituted; or Ar1 is naphthyl or anthracyl each of which is unsubstituted or substituted; or Ar1 is benzoyl, naphthalenecarbonyl, phenanthrenecarbonyl, anthracenecarbonyl or pyrenecarbonyl, each of which is unsubstituted or substituted, or Ar1 is 3,4,5-trimethoxyphenyl, phenoxyphenyl or biphenyl; Ar2 i.a.
    Type: Grant
    Filed: December 12, 2000
    Date of Patent: September 27, 2005
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Kazuhiko Kunimoto, Hidetaka Oka, Masaki Ohwa, Junichi Tanabe, Hisatoshi Kura, Jean-Luc Birbaum
  • Patent number: 6946550
    Abstract: Azo compounds of formula (I), wherein X stands for halogen, in particular for chlorine, or C1-C4alkoxy, in particular for methoxy, Y stands for —CH2— or —O—, R1 and R2, independently from each other, stand for hydrogen, C1-C8alkyl, or C6-C14aryl, which may be substituted up to three times with C1-C8alkyl, C1-C4alkoxy or halogen, a process for their preparation and their use as fluorescent compounds, in particular as solid fluorescent compounds, such as for special effect printing, sectrity printing or in the opto-electronic field.
    Type: Grant
    Filed: November 19, 2002
    Date of Patent: September 20, 2005
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Iain Frank Fraser, Ian Alexander Macpherson, David Macdonald Smith, Simon Martyr, Greig Chisholm, Stephen John Coughlin
  • Patent number: 6936670
    Abstract: The instant invention relates to multifunctional alkoxyamines based on polyalkylpiperidines, polyalkylpiperazinones and polyalkylmorpholinones and their use as polymerization regulatros/initiators. Further subjects of the invention are a polymerizable composition comprising an ethylenically unsaturated monomer or oligomer and the alkoxyamine compound as well as a process for polymerization and a process for preparation of the compounds.
    Type: Grant
    Filed: June 27, 2002
    Date of Patent: August 30, 2005
    Assignee: Ciba Specialty Chemical Corp.
    Inventors: Andreas Kramer, Andreas Mühlebach, Peter Nesvadba, Marie-Odile Zink, Tobias Hintermann
  • Patent number: 6936656
    Abstract: The invention relates to comb polymers and macromonomers based on acrylates prepared by the ATRP (Atom Transfer Radical Polymerization) method. These polymers have an improved capability of dispersing pigments in the given solvent. The invention also relates to compositions comprising the comb polymers and macromonomers dispersible inorganic or organic pigment particles. The compositions are used by applying them to any suitable substrate, for example to metal, wood plastic or ceramic materials.
    Type: Grant
    Filed: January 4, 2001
    Date of Patent: August 30, 2005
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Andreas Mühlebach, François Rime, Clemens Auschra, Ernst Eckstein
  • Patent number: 6927295
    Abstract: The present invention relates to 1-alkoxy-polyalkyl-piperidine derivatives containing a structural element of formula (I) G1, G2, G3, G4 are independently C1-C6alkyl with the proviso that at least one is not methyl or G1 and G2 or G3 and G4, or G1 and G2 and G3 and G4 together form a C5-C12cycloalkyl group; G5, G6 independently are H, C1-C18alkyl, phenyl, naphthyl or a group COOC1-C18alkyl and X represents a group such that the free radical X? derived from X is capable of initiating polymerization of ethylenically unsaturated monomers, with the proviso that compounds A1 and A2 are excluded Further subjects of the invention are a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) a 1-alkoxy-polyalkyl-piperidine derivative, a process for polymerizing ethylenically unsaturated monomers, and the use of 1-alkoxy-polyalkyl-piperidine derivatives for controlled polymerization.
    Type: Grant
    Filed: April 24, 2003
    Date of Patent: August 9, 2005
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Andreas Kramer, Peter Nesvadba
  • Patent number: 6919454
    Abstract: Biphenyl-substituted triazines of the formula which are notable for high thermal stability, are used as stabilizers for organic polymers to counter damage thereto caused by light, oxygen and heat, as light stabilizers for textile fiber materials and as sunscreens for the human skin.
    Type: Grant
    Filed: August 18, 2004
    Date of Patent: July 19, 2005
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Ian John Fletcher, Jürgen Kaschig, Georges Metzger, Dieter Reinehr, Pascal Hayoz
  • Patent number: 6916867
    Abstract: The present invention relates to polyolefin compositions which comprise as UV absorber a synergistic mixture of a) at least one hydroxybenzophenone and at least one 2-hydroxyphenylbenzotriazole with the proviso that the polyolefin is a high density polyethylene of the “Phillips” type or a polyethylene of the metallocene type; b) at least one hydroxybenzophenone and at least one 2-hydroxyphenyltriazine, with the proviso that if the polyolefin is polypropylene, no polyvinylpyridin is present c) at least one hydroxybenzophenone and at least one oxanilide; d) at least one 2-hydroxyphenylbenzotriazole and at least one oxanilide; e) at least one 2-hydroxyphenyltriazine and at least one oxanilide; f) at least one hydroxybenzophenone, at least one 2-hydroxyphenylbenzotriazole and at least one oxanilide; g) at least one hydroxybenzophenone, at least one oxanilide and at least one 2-hydroxyphenyltriazine; or h) at least one 2-hydroxyphenylbenzotriazole, at least one oxanilide and at least one 2-hydroxy phenyltriazin
    Type: Grant
    Filed: March 30, 2001
    Date of Patent: July 12, 2005
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: François Gugumus
  • Patent number: 6916881
    Abstract: A mixture of a polyester, such as poly(ethylene terephthalate) PET, and a second polymer which is polyacrylamide, polymethacrylamide or copolymer of acrylamide or methacrylamide when extrusion compounded exhibits a lower residual acetaldehyde content than does PET alone when similarly treated. The invention pertains to any polyester used in the manufacture of bottles or containers which in turn are used to store consumer materials, especially food, beverages and most especially water.
    Type: Grant
    Filed: January 13, 2003
    Date of Patent: July 12, 2005
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Stephen Mark Andrews, James J. Usilton
  • Patent number: 6913642
    Abstract: Substantially crystalline organic pigments characterized by small particle size and narrow particle size distribution.
    Type: Grant
    Filed: July 8, 2004
    Date of Patent: July 5, 2005
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Yves Grandidier, Albert Riegler, Klaus Ruf, Urs Schlatter
  • Patent number: 6913640
    Abstract: Novel improved single-phase mixed crystals of monoazo dyes laked with alkaline earth metal cations and ammonium cations in a molar ratio of about 1:2 having a fine particle size and substantially better fastness properties than similar known products are excellently suitable as tinctorially strong pigments. Also claimed is a process for the preparation of a single-phase mixed crystal pigment of formula wherein E is Mg, Ca or Sr, by crystallisation from an inert hydrophilic liquid in the presence of solvated catiens E++, NR5R6R7R8+, x is a number from 0.33 to 0.62 and y is a number from 0.76 to 1.34, and the concentration of solvated catiens E++ at the beginning of the crystallisation is higher than the concentration of solvated cations NR5R8R7R8+.
    Type: Grant
    Filed: January 15, 2002
    Date of Patent: July 5, 2005
    Assignee: CIBA Specialty Chemicals
    Inventors: Philippe Bugnon, Carolin Sansonnens, Greig Chisholm
  • Patent number: 6913712
    Abstract: Mixtures of compounds comprising a compound G2 and at least one further compound from the group G0, G1, G3, G4, G5, G6, the compounds G0-G6 corresponding to formula (I) in which, in the compound G0, the radicals R1, R2, R3, R4, R5 and R6 are each hydrogen; G1, the radical R1 is Q and R2, R3, R4, R5 and R6 are each hydrogen; G2, the radicals R1 and R2 independently of one another are each Q and R3, R4, R5 and R6 are each hydrogen; G3 the radicals R1, R2 and R3 independently of one another are each Q and R4, R5 and R6 are each hydrogen; G4, the radicals R1, R2, R3 and R4 independently of one another are each Q and R5 and R6 are each hydrogen; G5, the radicals R1, R2, R3, R4 and R5 independently of one another are each Q and R6 is hydrogen; G6, the radicals R1, R2, R3, R4, R5 and R6 independently of one another are each Q; and Q and the other symbols are as defined in claim 1, are effective as stabilizers for organic material with respect to damaging exposure to light, oxygen and/or heat.
    Type: Grant
    Filed: December 14, 2000
    Date of Patent: July 5, 2005
    Assignee: CIBA Specialty Chemicals Corp.
    Inventor: Pascal Hayoz
  • Patent number: 6911074
    Abstract: This invention relates to 1,4-diketopyrrolo[3,4c]-pyrrole pigments of the formula characterized by desirable color properties and novel visible absorbance spectra with a steep slope on the bathochromic side of the absorption maximum in the range of from 500 to 650 nm.
    Type: Grant
    Filed: July 8, 2004
    Date of Patent: June 28, 2005
    Assignee: CIBA Specialty Chemicals Corp.
    Inventors: Yves Grandidier, Albert Riegler, Klaus Ruf, Urs Schlatter