Patents Represented by Attorney Vincent J. Cavalieri
  • Patent number: 4187212
    Abstract: Stabilization system consisting of a triarylphosphite of the general formula ##STR1## wherein R.sub.1 represents tert.-butyl, 1,1-dimethylpropyl, cyclohexyl or phenyl, and one ofR.sub.2 and R.sub.3 is hydrogen and the other is hydrogen, methyl, tert.-butyl, 1,1-dimethylpropyl, cyclohexyl or phenyl,and a phenolic antioxidant, for stabilizing polyolefins.
    Type: Grant
    Filed: June 2, 1977
    Date of Patent: February 5, 1980
    Assignee: Ciba-Geigy Corporation
    Inventors: Horst Zinke, Hans J. Lorenz, Helmut Linhart
  • Patent number: 4186267
    Abstract: Nickel complexes containing ortho- or para-hydroxybenzoate anions and a non-ionic amine ligand are valuable light-stabilizers for polymers, particularly for polyolefins. The complexes may also contain a second carboxylate anion, different from the benzoate anion, and in this case also the amine-free nickel compounds show a high stabilizing action.
    Type: Grant
    Filed: August 24, 1977
    Date of Patent: January 29, 1980
    Assignee: Ciba-Geigy Corporation
    Inventors: Michael Rasberger, Jean Rody, Paul Moser, Helmut Muller
  • Patent number: 4185006
    Abstract: New phosphonites of the formula ##STR1## wherein R.sub.1 and R.sub.2 independently of one another are a substituted or unsubstituted hydrocarbon radical, or halogen,x and y independently of one another are 0, 1, 2 or 3,n is 2, 3, 4, 5 or 6, andR.sub.3 is a n-valent substituted or unsubstituted aliphatic, alicyclic, aromatic, araliphatic or heterocyclic hydrocarbon residue as stabilizers for organic materials.
    Type: Grant
    Filed: July 6, 1978
    Date of Patent: January 22, 1980
    Assignee: Ciba-Geigy Corporation
    Inventors: Michael Rasberger, John D. Spivack
  • Patent number: 4182704
    Abstract: Compounds of the formula ##STR1## wherein R.sub.1 and R.sub.2 are independently lower alkyl or hydrogen, provided that only one of R.sub.1 and R.sub.2 is hydrogen,R.sub.3 is --(A)--COOR.sub.4 or CN whereA is alkylene of 1 to 24 carbon atoms,R.sub.4 is alkyl of 1 to 24 carbon atoms, phenyl or alkyl substituted phenylq is 0 or 1m and n are each 1 or 2, the values of m and n being such that the trivalent state of is satisfied, andR.sub.5 is alkanoyl, benzoyl, or alkyl substituted benzoyl, are suitable for stabilizing organic material against thermal, oxidative and ultraviolet light degradation.
    Type: Grant
    Filed: May 8, 1978
    Date of Patent: January 8, 1980
    Assignee: Ciba-Geigy Corporation
    Inventor: John D. Spivack
  • Patent number: 4180497
    Abstract: Compounds of the formula ##STR1## wherein R.sub.1 and R.sub.2 are independently lower alkyl or hydrogen, provided that only one of R.sub.1 and R.sub.2 is hydrogen,m and n are each 1 or 2, the values of m and n being such that the trivalent state of P is satisfied,R is(a) halogen,(b) hydroxyl, provided that m is 2 and n is 1 when R is hydroxyl,(c) --XR.sub.5 wherein X is S or O and R.sub.5 is alkyl of 1 to 24 carbon atoms, phenyl, alkyl substituted phenyl, are suitable for stabilizing organic material against thermal, oxidative and ultraviolet light degradation.
    Type: Grant
    Filed: May 8, 1978
    Date of Patent: December 25, 1979
    Assignee: Ciba-Geigy Corporation
    Inventor: John D. Spivack
  • Patent number: 4180498
    Abstract: Compounds of the formula ##STR1## wherein R.sub.1 and R.sub.2 are independently lower alkyl or hydrogen, provided that only one of R.sub.1 and R.sub.2 is hydrogen,R.sub.3 is --(A).sub.g --COOR.sub.4 or CN whereA is alkylene of 1 to 6 carbon atoms,R.sub.4 is alkyl of 1 to 24 carbon atoms, phenyl or alkyl substituted phenyl, andq is 0 or 1 are suitable for stabilizing organic material against thermal, oxidative and ultraviolet light degradation.
    Type: Grant
    Filed: May 8, 1978
    Date of Patent: December 25, 1979
    Assignee: Ciba-Geigy Corporation
    Inventor: John D. Spivack
  • Patent number: 4171301
    Abstract: A monoazo pigment of the formula ##STR1## wherein R.sub.1 denotes a halogen atom or an alkyl or alkoxy group containing 1-4 carbon atoms, R.sub.2 denotes a H atom, an alkyl group containing 1-4 carbon atoms or a phenyl group, X denotes a --NH-- or --CH.sub.2 O group, Y denotes an O atom or S atom or an imino group and Z denotes an O atom or an imino group are prepared. The pigments may be used to color high molecular weight organic materials such as polyamides, polyesters and polyolefins. The pigments possess excellent fastness to light, weathering and migration.
    Type: Grant
    Filed: April 26, 1977
    Date of Patent: October 16, 1979
    Assignee: Ciba-Geigy Corporation
    Inventor: Rudolf Mory
  • Patent number: 4166814
    Abstract: Polyalkylpiperidines of formula I, ##STR1## wherein R.sup.1 is H or lower alkyl, R.sup.2 is H, O or a monovalent organic residue and Z is a divalent aromatic residue, are excellent light stabilizers for plastics. These compounds can be prepared from the according 4-oxopiperidines by Wittig-Horner reaction with diphosphonates of the formula IV,(ro).sub.2 (o)p--ch.sub.2 --z--ch.sub.2 --p(o)(or).sub.2 ivwherein R denotes lower alkyl, and subsequent hydrogenation of the resulting diolefines. The compounds of formula I are especially suitable for the stabilization of polyolefins, styrene polymers and polyurethanes.
    Type: Grant
    Filed: October 11, 1977
    Date of Patent: September 4, 1979
    Assignee: Ciba-Geigy Corporation
    Inventor: Friedrich Karrer
  • Patent number: 4165319
    Abstract: Bis-isoindoline pigments of the formula ##STR1## wherein A represents a carbocyclic or heterocyclic aromatic radical,Q represents an oxygen atom or an imino group,E represents a cyano or acetyl group, a group of the formula --COOR, wherein R represents a C.sub.1 -C.sub.4 -alkyl group or a phenyl group which is unsubstituted or substituted in the o-, p- or m-position by halogen atoms, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy groups, or represents a group of the formula --CONHR.sub.1, wherein R.sub.1 represents a hydrogen atom, a C.sub.1 -C.sub.4 -alkyl group or a phenyl group which is unsubstituted or substituted in the o-, p- or m-position by halogen atoms or C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy groups,X represents a hydrogen atom,Y represents a chlorine or bromine atom,M and n are integers from 0 to 4,P is an integer from 0 to 1, while the sum of m+n+p must be 4, andZ if p is 1 and m is 3, represents a nitro or C.sub.2 -C.sub.
    Type: Grant
    Filed: July 18, 1977
    Date of Patent: August 21, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Jost von der Crone, Christoph Frey
  • Patent number: 4163007
    Abstract: The invention relates to compounds of the general formula I ##STR1## wherein R.sub.1 and R.sub.2 independently of one another are C.sub.1 -C.sub.8 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl or C.sub.7 -C.sub.9 -aralkyl,R.sub.3 is --CN or a group either of the formula II or III--(c.sub.n H.sub.2n)--COOR.sub.4 (II)or--[(C.sub.n H.sub.2n)--COO].sub.q M.sup.q+ (III)wherein n is 0 to 6,R.sub.4 is C.sub.1 -C.sub.24 -alkyl, phenyl, or alkyl-substituted phenyl having 1-12 C atoms in the alkyl moiety,Q is 1, 2 or 3,M.sup.q+ is H.sup.+ or a mono-, bi- or trivalent metallic cation, andX.sub.1 and X.sub.2 are --O-- or --S--, which are suitable as antioxidants and light stabilizers for organic material.
    Type: Grant
    Filed: July 27, 1977
    Date of Patent: July 31, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Hanns Lind, Paul Moser
  • Patent number: 4163006
    Abstract: Organic materials are stabilized against oxidative and ultraviolet light degradation by incorporating therein polyalkylthiobenzenes having the formula ##STR1## WHEREIN R is alkyl or cycloalkyl, R' is alkyl, n is 2 to 6 and x is 0 to 4, provided that n+x is not greater than 6.
    Type: Grant
    Filed: May 9, 1977
    Date of Patent: July 31, 1979
    Assignee: Ciba-Geigy Corporation
    Inventor: John D. Spivack
  • Patent number: 4161594
    Abstract: New dialcohols of mononuclear, five-membered or six-membered, unsubstituted or substituted N-heterocyclic compounds which contain two NH-groups in the molecule, by reaction of mononuclear, five-membered or six-membered, unsubstituted or substituted N-heterocyclic compounds, for example hydantoin, barbituric acid, uracil, dihydrouracil, parabanic acid and the corresponding derivatives, with ethylene oxide or propylene oxide to give dialcohols. These diols are useful as intermediates for the preparation of polymers, such as polyesters or polyurethanes, or of epoxy resins.
    Type: Grant
    Filed: January 17, 1975
    Date of Patent: July 17, 1979
    Assignee: Ciba-Geigy AG
    Inventors: Hans Batzer, Jurgen Habermeier, Daniel Porret
  • Patent number: 4161602
    Abstract: The invention is directed to fluorinated compounds of the formula ##STR1## wherein R.sub.f is a perfluoroalkyl or perfluoroalkoxyperfluoroalkyl group, R.sup.1 is a branched or straight chain alkylene, alkylenethioalkylene, alkyleneoxyalkylene or alkyleneiminoalkylene group, X is oxygen or an amino group, Q is an organic group containing at least one amino group and y is zero or 1, and the corresponding succinimides. These compounds are useful as surfactants.
    Type: Grant
    Filed: January 12, 1978
    Date of Patent: July 17, 1979
    Assignee: Ciba-Geigy Corporation
    Inventor: Karl F. Mueller
  • Patent number: 4154722
    Abstract: Polyalkylpiperidinyl esters of diazocarboxylic acids are prepared, which compounds protect organic polymers against UV light degradation. The light stabilizers have the ability to react with the organic polymeric substrates thus making the piperidinyl esters migration and extraction resistant. Polymers which may be stabilized with the compounds of this invention include polypropylene, polyethylene, polystyrene and polyamides.
    Type: Grant
    Filed: June 20, 1977
    Date of Patent: May 15, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Roger Malherbe, Michael Rasberger
  • Patent number: 4153601
    Abstract: A compound having the formula ##STR1## wherein A denotes an optionally substituted aromatic, isocyclic or heterocyclic residue; R is H, an alkyl residue having from 1 to 6 carbon atoms, an aryl residue having from 6 to 10 carbon atoms or an aralkyl residue having from 7 to 10 carbon atoms; Q is H or a methyl group; X and Y are the same or different and each is a non-water solubilizing group, or X and Y together form a fused aromatic ring system; and R.sub.1 and R.sub.2 are the same or different and each is H or an alkyl radical having from 1 to 22 carbon atoms, and R.sub.3 is hydrogen, an alkyl radical having from 1 to 22 carbon atoms or an aryl radical having from 6 to 10 carbon atoms, the alkyl radicals in R.sub.1, R.sub.2 and R.sub.3 being unsubstituted and uninterrupted or being substituted by an OH, NH.sub.2 or CN group and/or being interrupted by an ethylenic group or an oxygen, sulphur or nitrogen bridge, or two or all three of R.sub.1, R.sub.2 and R.sub.
    Type: Grant
    Filed: June 27, 1977
    Date of Patent: May 8, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Terence R. Chamberlain, Colin D. Campbell, James M. McCrae
  • Patent number: 4153800
    Abstract: Isoindolinone pigments of the formula ##STR1## wherein R represents an aliphatic or cycloaliphatic radical, a cycloaliphatic, aromatic or heterocyclic radical to which the oxygen atoms are attached through alkyl or alkoxy groups, V.sub.1 and V.sub.2 represent hydrogen or halogen atoms, alkyl or alkoxy groups of 1 to 4 carbon atoms, X represents a halogen atom, Y and Z represent halogen atoms, alkoxy or alkylmercapto groups of 1 to 6 carbon atoms, cycloalkoxy groups of 5 to 6 carbon atoms, aralkoxy, aryloxy or arylmercapto groups, and n is an integer from 2 to 6, are valuable pigments coloring plastics, lacquers and printing inks in various yellow shades of excellent fastness properties and high color strength.
    Type: Grant
    Filed: November 10, 1977
    Date of Patent: May 8, 1979
    Assignee: Ciba-Geigy Corporation
    Inventor: Ernst Model
  • Patent number: 4152324
    Abstract: A metal complex having the formula ##STR1## or the formula ##STR2## wherein A is an aryl or heterocyclic residue, B is an aliphatic, aryl or heterocyclic residue, R is an alkyl, cycloalkyl, aryl, aralkyl or heterocyclic residue or R is the atoms required to complete, together with residue B, a heterocyclic residue, R' is a carbon chain which may form part of an aromatic or heterocyclic ring and containing 2 or 3 carbon atoms between the nitrogen atom and the substituent Y, X and Y are the same or different and each is O,S,N,CO.sub.2 or N--R wherein R has its previous significance, M is Cu, Zn or ni, p is 1 or 2 and when p is 1, E is a hydrogen atom attached to one of residue A, B, R of R', and when p is 2, E is either a direct bond linking two residues, A, B, R or R' or is an alkylene, arylene or aralkylene residue linking two residues, A, B, R or R', which is useful for pigmenting organic material, preferably a lacquer, paint or printing ink.
    Type: Grant
    Filed: August 11, 1976
    Date of Patent: May 1, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: James M. McCrae, Christopher Midcalf, Alexander M. Irvine
  • Patent number: 4152171
    Abstract: A process for the production of alpha-, beta-, and gamma-copper phthalocyanine pigments by reacting an aromatic or aromatic heterocyclic ortho-dinitrile compound and copper or a copper compound capable of providing the centrol metal atom of a phthalocyanine pigment at a temperature below 100.degree. C. in the presence of a alkaline substance in a hydrophilic aliphatic organic solvent containing one or more hydroxy groups and adding as catalyst or crystal form controller or both from the beginning of the reaction:(a) for alpha-, beta- or gamma pigments, a copper phthalocyanine in conventional pigmentary form or(b) for alpha pigments, a copper phthalocyanine derivative with a limited degree of substitution.
    Type: Grant
    Filed: January 25, 1978
    Date of Patent: May 1, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Ronald Barraclough, Robert Langley
  • Patent number: 4151229
    Abstract: The invention relates to a process for the manufacture of aminoalkyl-phosphonic acid esters by catalytic hydrogenation of cyanoalkylphosphonic acid esters. After having separated the catalyst and solvents, in general the crude product is distilled.The esters which can be obtained by the process of this invention are of importance as intermediate products, because all reactions of amines can be carried out with these products. They can also be used as additives for amine curing agents for epoxide resins in order to achieve flame-retarding properties.
    Type: Grant
    Filed: May 2, 1975
    Date of Patent: April 24, 1979
    Assignee: Ciba-Geigy Corporation
    Inventor: Helmut Zondler
  • Patent number: 4150229
    Abstract: 2,5-di-(.omega.-aminoalkyl-1')-pyrazines are obtained by catalytic hydrogenation of nitro compounds of the formula ##STR1## They are suitable as hardeners for epoxides or for the manufacture of polyamides.
    Type: Grant
    Filed: December 27, 1977
    Date of Patent: April 17, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Srinivasachari Rajappa, Helmut Zondler