Abstract: The waste product from the synthesis of trimethylgallium is reacted with a hydride selected from an alkali metal hydride, a group IIIA hydride, or a group III hydride to produce dimethylaluminum hydride of high purity.

Abstract: Coating compositions comprise a clear, homogeneous binder mixture of polyether or polyester polymer, an amine-formaldehyde condensate resin, and an organic solvent; the mixture being miscible with water to application viscosity. The coating composition typically contains suspended solid particulates, including pigments and metal flakes.

Abstract: LOVA gun propellants are formed from a thermoplastic elastomer and particulates of high-energy oxidizers, e.g., RDX and HMX.

Abstract: A method is provided for highly pure mono- and dialkylarsines, particularly removing substantially all silicon-containing impurities. A mono- or dialkylarsine is reacted with either an alkali metal or an alkali metal hydrocarbyl, thereby producing an alkali metal alkylarsenide. Silicon, germanium, zinc and other metallic impurities are removed from the alkali alkylarsenide. Mono- and dialkylarsine is then regenerated by reaction of the alkali metal alkylarsenide with a proton donor.

Abstract: Waste material containing substantial amounts of Li(MH.sub.3 R) compounds where M is Al or Ga are deactivated by dissolving and/or dispersing the waste material in a solvent in which ionic deactivation products are soluble and then adding a carbonyl-containing compound which reacts with the Li(MH.sub.3 R) compound.

Abstract: A propellant formulation includes energetic particulate solids dispersed in a binder system of high molecular weight 1,2 syndiotactic butadiene and a plasticizer. The propellant is prepared by mixing above the melting temperature of the butadiene and without the use of solvents. The propellant is castable without curing.

Abstract: A dry film for forming a solder mask includes a cover sheet, a photoimageable composition layer which is curable to form a solder mask and a top coat interposed between the cover sheet and the photoimageable composition layer which is selectively adherent to the photoimageable composition layer. The dry film is applied to a surface of a printed circuit board with a minor portion of the area of the photoimageable composition layer tacked to the printed circuit board. The cover sheet is peeled away. With heat and vacuum, the photoimageable composition layer is laminated to the irregular surface of the printed circuit board, conforming the photoimageable composition layer to the contours thereof and leaving the top coat as a protective covering over the photoimageable composition layer. The photoimageable composition layer is exposed to patterned actinic radiation, developed and cured to form a hard, permanent solder mask.

Abstract: Binders for propellants for the like comprise elastomers which are based on block copolymers in which a pair of poly(caprolactone) blocks flank a central hydroxyl-terminated poly(butadiene) block. The block polymers are cured with isocyanates through the OH termini of the poly(caprolactone) blocks. The elastomers have inherent energies and other characteristics intermediate those of PCP and HTPB and have good compatibility with nitrate ester plasticizers.

Abstract: A lubricating composition for PVC or the like is provided by partially saponifying a triglyceride material, such as an animal tallow, with calcium hydroxide in the presence of at least about 10% water. The minor amount of oxidized polyethylene admixed with the saponified material maintains the resulting soap and esters in a homogeneous lubricating compositions. The lubricating compositions are particularly suitable for preparing rigid resin compositions.

Abstract: Compositions comprising the combination of an organotin mercaptide and a polyformal of a dithiodiglycol are useful for stabilizing halogen-containing organic polymers against the deteriorative effects of heat, light and weathering.

Abstract: A method of preparing a thermoplastic elastomer having A blocks and at least one B block, wherein said A blocks are crystalline at temperatures below about 60.degree. C. and said B block(s) is amorphous at temperatures above about -20.degree. C., said A blocks each being polyethers derived from monomers of oxetane and its derivatives and/or tetrahydrofuran and its derivatives, the method comprisingproviding hydroxyl terminated A blocks which are crystalline at temperatures below about 60.degree. C. and separately providing hydroxyl terminated B blocks which are amorphous at temperatures above about -20.degree. C.

Abstract: Polyethers are formed by polymerizing oxetanes having one or two pendant groups which contain cyano moieties, particularly 3-cyanomethyl-3-methyl oxetane and 3,3-Bis(cyanomethyl) oxetane. The polyethers may also contain mer units derived from other cyclic ethers, including other oxetanes and tetrahydrofurans. The cyano group gives the polyether improved compatibility with nitrate ester plasticizers. The polyethers are curable with polyfunctional isocyanates to form binders for propellants, explosives or the like.

Abstract: Surface-conforming materials, such as sheets, ribbons, tapes or moldable material may be adhered to a wide variety of underwater target surfaces with a cyanoacrylate adhesive. The cyanoacrylate adhesive is evacuated from it container under water, applied to a surface of the surface-conforming material, and then the surface-conforming material is pressed against the target surface for a relatively short period of time. The method provides a method, for example, of attaching a plastic explosive to the hull of a ship entirely under water.

Abstract: For providing biocides in concentrated, immobilized form to an end use resin composition containing a primary thermoplastic resin with which the primary resin is incompatible at high concentrations, solid biocide resin concentrates are provided which immobilize high concentrations of biocide. The solid biocide resin concentrates may contain an alloy of two thermoplastic resins, one of which is substantially identical to the primary resin and one of which enables incorporation and immobilization of high concentrations of biocide in the solid biocide resin concentrates. The solid biocide resin concentrate may contain, in whole or in part, a thermoplastic copolymer having mer units such as are present in the primary resin in addition to dissimilar mer units which enhance compatibility of the biocide with the copolymer.

Abstract: Poly(caprolactone) polymers are provided having molecular weights of 4000 or higher, are used to form propellant binders. When the high molecular weight poly(caprolactone) polymers are used in propellant formulations and cured with isocyanates of adequate functionality, propellants are produced having improved stress and strain characteristics relative to presently formulated propellants having binders of cured, lower molecular weight poly(caprolactone) polymers.

Abstract: Thermoplastic elastomer particulates, oxidizer particulates, fuel particulates, plasticizers and other propellant formulation ingredients are mixed to produce a dry blend. The dry blend is tightly packed into a rocket motor casing or mold. The dry blend is then heated in place, beginning at the bottom and continuing upward, to fuse the thermoplastic elastomer. During fusion, vacuum and mechanical compaction pressure are used to eliminate interstices. Upon cooling, a solid propellant grain is produced.

Abstract: Internally plasticized elastomeric binders for projectile propellants are cured polyethers containing THF, CYMMO plus BMEMO, BEEMO and/or OMMO mer units. The polyethers are fluid at room temperature and are miscible with nitrate ester plasticizers. Propellant binders prepared from these polyethers are curable, have low T.sub.g 's, good mechanical properties, and I.sub.sp 's comparable to PEG-based binders.

Abstract: An electroless copper plating bath is improved so as to facilitate its regeneration in an electrodialysis cell. The bath includes elevated amounts of an added salt, preferably as Na salt. The elevated sodium ion level serves as additional counter-cation to hydroxyl ion which is produced at the cathode of the electrodialysis cell. The excess anion from the added salt increases the rate of out-migration of by-products, such as formate ions and sulfate ions, relative to hydroxyl ions through an anion permselective membrane.

Abstract: Solutions of microbiocides in cosolvents having alkanol moieties and concentrate compositions of carriers, microbiocides and cosolvents having alkanol moieties are stabilized against UV-catalyzed oxidation by the addition of phenolic antioxidants. The solutions or concentrate compositions are added to polymeric resins and formed, e.g., by fusion, into polymer compositions exhibiting microbiocidal properties.

Abstract: Niobium (V) and tantalum (V) halides are converted to Nb.sub.2 O.sub.5 and Ta.sub.2 O.sub.5 that are free of detectable levels of halide in a two step process. In the first step, the metal halide is reacted with an alcohol and with a replacement species, such as ammonia, which reacts with the halide. This produces a metal alkoxide which is soluble and a halide salt of the replacement species which is insoluble in the alcohol and precipitates. After physically separating the alkoxide in alcohol solution from the precipitate, in a second step, the metal alkoxide is hydrolyzed with purified water to produce the oxide.