Patents Represented by Attorney, Agent or Law Firm William A. Teoli, Jr.
  • Patent number: 5387304
    Abstract: A carrier film is coated on one side with a radiation curable paint and on the other with an adhesive. The paint is partially cured by irradiation, the carrier film is heated and, in the thermoplastic state, applied by deep drawing to a three-dimensional substrate. In a final step the paint is completely cured by heat.
    Type: Grant
    Filed: March 15, 1993
    Date of Patent: February 7, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Godwin Berner, Ljubomir Misev
  • Patent number: 5380882
    Abstract: The invention relates to compounds of formula I ##STR1## wherein A is a radical of formula ##STR2## R.sub.1 and R.sub.2 are each independently of the other hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen or a radical of formula ##STR3## wherein X is --O--, --CH.sub.2 --, --C(CH.sub.3).sub.2 -- or --SO.sub.2 --, and R.sub.3 and R.sub.4 are each independently of the other hydrogen, C.sub.1 -C.sub.4 alkyl or phenyl, as well as compositions comprising these compounds.The compositions are particularly suitable for making integrated circuits.
    Type: Grant
    Filed: March 30, 1993
    Date of Patent: January 10, 1995
    Assignee: Ciba-Geigy Corporation
    Inventor: Alfred Steinmann
  • Patent number: 5380881
    Abstract: Non-polymeric compounds which contain at least one aromatic ring system carrying one or more one or more tetrahydropyranyloxy substituents of formula I ##STR1## wherein R.sub.1 is hydrogen, halogen, alkyl, cycloalkyl, aryl, alkoxy or aryloxy,R.sub.2 is hydrogen, alkyl, cycloalkyl or aryl,R.sub.3 is a saturated or unsaturated hydrocarbon radical,R.sub.4 and R.sub.5 are each independently of the other hydrogen, halogen, alkyl, alkoxy or aryloxy, andX is a direct single bond or a methylene or ethylene bridge.These compounds are especially suitable for the preparation of photoresist compositions which can be used both for the production of positive as well as negative images. The photoresists are preferably used for deep-UV microlithography.
    Type: Grant
    Filed: January 22, 1993
    Date of Patent: January 10, 1995
    Assignee: Ciba-Geigy Corporation
    Inventor: Ulrich Schadeli
  • Patent number: 5380344
    Abstract: Compositions comprisinga) a functional liquid or an internal combustion engine fuel andb) at least one compound of the general formula I ##STR1## wherein R.sub.1 is --(CH.sub.2 --X).sub.n --R, where X.dbd.--S-- or --O--, n=0 or 1 and R is an alkyl group of 1 to 18 carbon atoms, a phenyl group, a phenyl group which is substituted by at least one C.sub.1 -C.sub.18 alkyl group, a phenyl-C.sub.1 -C.sub.4 alkyl group or a phenyl-C.sub.1 -C.sub.4 alkyl group which is substituted by at least one C.sub.1 -C.sub.4 alkyl group, or R.sub.1 is an alkyl group of 1 to 18 carbon atoms which is substituted by at least one OH group, or R.sub.1 is a ##STR2## group in which the alkyl moiety contains 1 to 18 carbon atoms, and R.sub.2 and R.sub.3 are the same or different and are --H or, independently of R.sub.1, have the same meanings as R.sub.1, and M is B, Al, Fe, Cr, Sb or Bi, or M is a group M'--R' or a group M'--OR", where M' is Ti, Zr or Sn, and R' and R" is C.sub.1 -C.sub.
    Type: Grant
    Filed: July 30, 1993
    Date of Patent: January 10, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Hermann O. Wirth, Hans-Helmut Friedrich
  • Patent number: 5374006
    Abstract: A substrate capable of being wound is transported to a substrate carrier and wound onto the latter. For that purpose the substrate is first held in a defined storage position. With the substrate in that storage position the substrate carrier is moved into a threading position and brought into engagement with the substrate. The substrate is then automatically threaded around the substrate carrier. When the threading operation is complete, the substrate carrier is moved into a winding position in which the substrate is wound onto the substrate carrier. The rate of feed at which the substrate is transported by a motor to the substrate carrier is regulatable. The substrate carrier is motor-driven in a controllable manner, at a uniform torque and in dependence on the feed rate at which the substrate is transported to the substrate carrier.
    Type: Grant
    Filed: February 24, 1993
    Date of Patent: December 20, 1994
    Assignee: Ciba-Geigy Corporation
    Inventor: Mickael Mheidle
  • Patent number: 5374697
    Abstract: Sulfonium compounds of formula 1 or 2 ##STR1## wherein R is a mononuclear cycloalkyl radical containing 3 to 8 ring carbon atoms or a mononuclear cycloalkyl radical which contains 3 to 8 ring carbon atoms and to which at least one further ring containing carbon atoms is fused,X is a non-nucleophilic anion, andZ is a single bond, an oxygen or sulfur atom, a group of formula >S.sup..sym. --R X.sup..crclbar., wherein R and X are as defined above, or is >C.dbd.O or a methylene bridge,which sulfonium compounds are either unsubstituted or carry one or more than substituent selected from the group consisting of halogen, nitro, C.sub.1 -C.sub.8 alkyl, phenyl, hydroxyl, C.sub.1 -C.sub.8 alkoxy, phenoxy, benzyloxy, alkoxycarbonyl containing 1 to 4 carbon atoms in the alkoxy moiety or acyl of 1 to 12 carbon atoms.
    Type: Grant
    Filed: July 14, 1993
    Date of Patent: December 20, 1994
    Assignee: Ciba-Geigy Corporation
    Inventor: Beat Muller
  • Patent number: 5371259
    Abstract: Compounds of the formula I are described[R.sup.1 (Fe.sup.II R.sup.2 .sub.a ].sub.q.sup.+an anX.sup.-q (I)in which a is 1 or 2, n is 1 or 2, R.sup.1 is a substituted or unsubstituted .pi.-arene, R.sup.2 is a substituted or unsubstituted .pi.-arene or cyclopentadienyl anion or indenyl anion, q is an integer from 1 to 3, and X is FSO.sup.-.sub.3 or a q-valent anion of an organic sulfonic acid or of a carbocyclic acid; R.sup.1 can also be a polymeric, aromatic ligand. The invetion particularly relates to the compounds of the formula I wherein a is 1 and q is 1 and X.sup.
    Type: Grant
    Filed: April 8, 1993
    Date of Patent: December 6, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Kurt Meier, Roger P.-E. Salvin
  • Patent number: 5371115
    Abstract: A hardenable composition containing:a) a material polymerizable by free radical or cationic polymerization,b) at least one iron compound of the formula I ##EQU1## wherein a is 1 or 2 and q is 1, 2 or 3,L is a divalent to heptavalent metal or non-metal,Q is a halogen atom,m is an integer corresponding to the sum of the values of L and q,R.sup.1 is an unsubstituted or substituted .eta..sup.6 -benzene andR.sup.2 is an unsubstituted or substituted cyclopentadienyl anion, andc) at least one sensitizer for the compound of the formula I,and, in the case of materials polymerizable by free radical polymerization, also d) an electron acceptor as an oxidizing agent, which is also advantageously used concomitantly for the material polymerizable by cationic polymerization. The composition is suitable for the production of protective layers and photographic images.
    Type: Grant
    Filed: April 15, 1992
    Date of Patent: December 6, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Kurt Meier, Hans Zweifel
  • Patent number: 5368643
    Abstract: A board to be coated is conveyed by means of first transport means in the form of a roller conveyor to a curtain coating device. The latter comprises second transport means in the form of two conveyor belts, each of which runs round an associated straightening bar in the direction of transport of the board. The straightening bars are movable and as they move towards one another they align the boards at the side edges thereof in such a manner that the side edges extend approximately parallel to the direction of transport of the board. Conical rollers are connected to the straightening bars. During alignment, that is to say, when the straightening bars are moved towards one another, the board to be coated is at the same time lifted from the roller conveyor by means of the conical rollers and conveyed via the surfaces of the conical rollers to the conveyor belts. The latter engage laterally at the board edges and transport the board through a pouring curtain for the purpose of coating.
    Type: Grant
    Filed: November 9, 1992
    Date of Patent: November 29, 1994
    Assignee: Ciba-Geigy Corporation
    Inventor: Kaspar Kuster
  • Patent number: 5366947
    Abstract: Initiator compositions for materials which can be polymerized cationically are described, these containingi) an anhydride of a polycarboxylic acid, a polyisocyanate, a cyclic carbonate, a lactone or a mixture of such compounds, and dissolved thereinii) at least one compound of the formula I[M.sup.+n (L).sub.x ].sup.n+ n X.sup.- (I)in which n is 2 or 3, M is a metal cation selected from the group consisting of Zn.sup.2+, Mg.sup.2+, Fe.sup.2+, Co.sup.2+, Ni.sup.2+, Cr.sup.2+, Ru.sup.2+, Mn.sup.2+, Sn.sup.2+, VO.sup.2+, Fe.sup.3+, Al.sup.3+ and Co.sup.3+, X.sup.- is an anion which is selected from the group consisting of AsF.sub.6.sup.-, SbF.sub.6.sup.-, BiF.sub.6.sup.- and derivatives derived from these anions in which a fluorine atom is replaced by hydroxyl groups, or in which up to 50% of the anions X.sup.-, based on the total amount of anions, can also be any desired anions, L is water or an organic .sigma.
    Type: Grant
    Filed: August 18, 1992
    Date of Patent: November 22, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Beat Muller, Dieter Baumann
  • Patent number: 5362835
    Abstract: A process for the production of a material having an increased molecular weight relative to the diepoxide starting material the material being either a hydroxy-terminated or an epoxy-terminated material comprisinga) reacting a diepoxide with a dihydroxy compound, in the presence, as catalyst, of a triflate salt of a metal of Group IIA, IIB, IIIA, IIIB, or VIIIA of the Periodic Table of Elements (according to the IUPAC 1970 convention);b) de-activating the triflate salt catalyst; andc) optionally advancing the material produced in step b), with an aromatic diol or phenol.
    Type: Grant
    Filed: December 9, 1991
    Date of Patent: November 8, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: William M. Rolfe, Michael R. Thoseby, Bryan Dobinson
  • Patent number: 5362849
    Abstract: The new compound N,N,N'N'-tetraglycidyl-3,3'-diethyl-4,4'-diaminodiphenylmethane and curable resin compositions containing it.
    Type: Grant
    Filed: November 4, 1993
    Date of Patent: November 8, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Bryan Dobinson, Michael R. Thoseby
  • Patent number: 5359020
    Abstract: Compositions comprisingA) compounds of formula I ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are identical or different and each is hydrogen or methyl, and X is a divalent organic radical comprising from 2 to 60 carbon atoms,B) compounds of formula II, III or IV ##STR2## wherein each of R.sub.11, R.sub.12 and R.sub.13, independently of the others, is a hydrogen atom or a C.sub.3 -C.sub.10 alkenyl group, at least one of the radicals R.sub.11 to R.sub.13 being an alkenyl group, ##STR3## wherein Q is a direct bond, methylene, 2,2-propylidene, --CO--, --O--, --S--, --SO-- or --SO.sub.2 -- and each of R.sub.14, R.sub.15, R.sub.16 and R.sub.17, independently of the others, is a hydrogen atom or a C.sub.3 -C.sub.10 alkenyl group, at least one of the radicals R.sub.14 to R.sub.17 being an alkenyl group, or ##STR4## wherein each of R.sub.18, R.sub.19, R.sub.20, R.sub.21, R.sub.22 and R.sub.23, independently of the others, is a hydrogen atom, C.sub.1 -C.sub.4 alkyl or C.sub.3 -C.sub.
    Type: Grant
    Filed: May 16, 1991
    Date of Patent: October 25, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Rudolf Brunner, Rene Huwyler, Andreas Kramer
  • Patent number: 5356740
    Abstract: Radiation-sensitive compositions comprising(a) a polyester containing structural repeating units of formula (I) ##STR1## wherein Z is a radical of formulae (IIa)-(IIh) ##STR2## wherein Y is a direct bond, C.sub.1 -C.sub.20 alkylene, phenylene, --CH.sub.2 --C.sub.6 H.sub.4 --CH.sub.2 --, cyclopentylene or cyclohexylene, and R.sub.1 and R.sub.2 are each independently of the other hydrogen, methyl or ethyl, with the proviso that R.sub.1 and R.sub.2 are not simultaneously hydrogen, and(b) a substance that generates acid upon exposure to actinic radiation,form a highly sensitive high resolution positive photoresist formulation which is suitable for DUV lithography and, in particular, for making integrated circuits.
    Type: Grant
    Filed: November 20, 1992
    Date of Patent: October 18, 1994
    Assignee: Ciba-Geigy Corporation
    Inventor: Alfred Steinmann
  • Patent number: 5354939
    Abstract: Compositions comprising(a) a liquid epoxy resin,(b) a filler containing at least 50% by weight of quartz flour,(c) a polyether polyol, and(d) an organically modified sheet silicate,show a constant viscosity under thermal and mechanical stress and are suitable for applications in vacuum casting technology, especially as encapsulating material for electrical and electronic components.
    Type: Grant
    Filed: December 20, 1993
    Date of Patent: October 11, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Werner Hollstein, Peter Ruger, Claus W. Rabener
  • Patent number: 5344992
    Abstract: There is disclosed a process for the preparation of 1,3-diketones of formula I ##STR1## wherein R.sub.1 and R.sub.2 are each independently of the other C.sub.1 -C.sub.20 alkyl, phenyl or phenyl which is substituted by halogen, hydroxy, NO.sub.2, C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy, C.sub.7 -C.sub.9 phenylalkyl or a radical of formula II--A--X--R.sub.4 (II)whereinA is C.sub.1 -C.sub.12 alkylene, phenylene or phenylene which is substituted by halogen, hydroxy, NO.sub.2, C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy, or is C.sub.1 -C.sub.12 alkylene which is substituted by hydroxy, halogen and/or alkoxy,X is oxygen or sulfur, andR.sub.4 is hydrogen, C.sub.1 -C.sub.18 alkyl, phenyl or phenyl which is substituted by halogen, hydroxy,C.sub.1 -C.sub.4 alkyl, NO.sub.2 and/or C.sub.1 -C.sub.4 alkoxy, or is C.sub.7 -C.sub.9 phenylalkyl, andR.sub.3 is hydrogen, C.sub.1 -C.sub.20 alkyl, phenyl or phenyl which is substituted by halogen, hydroxy, C.sub.1 -C.sub.4 alkyl, NO.sub.2 and/or C.sub.1 -C.
    Type: Grant
    Filed: May 11, 1993
    Date of Patent: September 6, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Rolf Drewes, Hans-Helmut Friedrich, Hans-Ludwig Mehner, Bernd Braun, Walter Wecht
  • Patent number: 5342903
    Abstract: A process for the preparation of adducts by reacting an alcohol with an epoxy compound in the presence of a catalyst, which comprises reacting an alcohol of formula I ##STR1## wherein A is an aliphatic, cycloaliphatic or araliphatic radical and r is a number from 1 to 10, with a mono- or diepoxide in the equivalent ratio of 1:20 to 20:1, based on the hydroxyl and epoxy groups, in the presence of a metal complex of formula II as catalyst[M.sup.n+ (L.sub.1).sub.x (L.sub.2).sub.y (L.sub.3.sup.m-).sub.z ][X.sup.k- ].sub.(n-zm)/k (II),whereinM is a metal of the main groups or subgroups of the Periodic Table of the Elements,L.sub.1 and L.sub.2 are weakly bonded, neutral, unidentale or multidentate ligands,L.sub.3 is a strongly bonded, non-replaceable neutral or anionic unidentale or multidentate ligand,X is an anion of the following formulae BF.sub.4.sup.-, PF.sub.6.sup.-, AsF.sub.6.sup.-, SbF.sub.6.sup.-, ClO.sub.4.sup.-, IO.sub.4.sup.-, NO.sub.3.sup.
    Type: Grant
    Filed: April 30, 1993
    Date of Patent: August 30, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Heinz Wolleb, Andreas Hafner, William M. Rolfe
  • Patent number: 5342867
    Abstract: The present invention provides an adhesive composition comprising a polyurethane resin and, as adhesion promoter, a compound of formula I: ##STR1## in which Z is an organic radical which is derived from an aliphatic aromatic or heterocyclic polyisocyanate containing m+n isocyanate groups; m is a value greater than or equal to 1; n is a value greater than or equal to 0; m+n is a value greater than or equal to 2; Y is 0 or S; X is 0, S or N--C.sub.1 -C.sub.4 alkyl; R.sub.1 is C.sub.1 -C.sub.8 alkylene; R.sub.2 is C.sub.1 -C.sub.4 alkyl or two groups R.sub.2 together for m a C.sub.1 -C.sub.4 alkylene residue; R.sub.3 is C.sub.1 -C.sub.4 alkyl or phenyl; and q is a value from 0 to 2.
    Type: Grant
    Filed: September 30, 1993
    Date of Patent: August 30, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Glen R. Ryan, Steven A. Allen, David A. Taylor
  • Patent number: 5339537
    Abstract: A continuous drier for flat piece material, especially for liquid-coated printed circuit boards, and the like, comprises a heatable drier housing and a transport path that ascends in the housing and, after passing an upper turning point descends again. Secured to an endless chain that extends substantially vertically are carriers for the piece material to be transported, which carriers project outwards from the endless chain. The drier also comprises a supply duct for drying air for the piece material to be dried. The supply duct is so arranged that an airstream supplied by it flows over the piece material transversely to the direction in which the carriers project from the chain links.
    Type: Grant
    Filed: November 9, 1992
    Date of Patent: August 23, 1994
    Assignee: Ciba-Geigy Corporation
    Inventor: Kaspar Kuster
  • Patent number: 5340900
    Abstract: The invention relates to compositions comprising a) a polyol having on average 3 to 8 hydroxyl groups per molecule and an average molecular weight per hydroxyl group of up to 150; b) a polyether-polyol having on average 2 to 3 hydroxyl groups per molecule and an average molecular weight per hydroxyl group of 150 to 500 and c) a poly(oxyalkylene)polyamine having on average 2 to 4 amino groups per molecule and an average total molecular weight of between 1000 and 3000.The compositions described are distinguished by a low tendency to demix, even during prolonged storage.Reaction mixtures of the compositions described, as hardeners, and polyisocyanates of the diphenylmethane series cure fully without passing through a brittle phase. The shaped articles formed have good mechanical properties.
    Type: Grant
    Filed: July 22, 1993
    Date of Patent: August 23, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Martin Spitzer, Hans Freistadter