Abstract: A process for fluid catalytic cracking of residuum and other heavy oils comprising gas oil, petroleum residue, reduced and whole crudes and shale oil with high metals contents wherein contaminant metals comprising nickel, vanadium, copper and iron are deactivated, organic sulfur compounds deposited on the cracking catalyst are removed, wherein the said contaminant metals are deactivated by contact with a high temperature reducing atmosphere comprising carbon monoxide in a range of from about 4 to about 14 volume percent, the temperature being at least 900.degree. F. and preferably greater than 1200.degree. F., wherein the catalyst is modified with at least one inorganic sulfur oxide absorbent which reacts with sulfur oxides under regeneration conditions to form non-volatile inorganic sulfur compounds, the said sulfur oxide absorbent being present in sufficient amount to effect said reduction of said sulfur oxides.
Abstract: A process for fluid catalytic cracking of residuum and other heavy oils comprising gas oil, petroleum residue, reduced and whole crudes and shale oil to produce gasoline and other liquid products which are separated in various streams in a fractionator and associated vapor recovery equipment wherein heat from combustion of coke on the coked catalyst is removed by reacting sulfur-containing coke deposits with steam and oxygen in a separate stripper-gasifier to produce a low BTU gas stream comprising sulfur compounds, methane, carbon monoxide, hydrogen, and carbon dioxide at a temperature of from about 1,100.degree. F. to about 2,200.degree. F. The partially regenerated catalyst then undergoes complete carbon removal in a regeneration vessel. The regenerated catalyst is recycled for re-use in the cracking of heavy petroleum fractions. The liquid products are gasoline, distillates, heavy fuel oil, and light hydrocarbons.
Abstract: A composition suitable for warp sizing polyester and polyester/cotton yarns comprising water soluble polyester resin having (1) a backbone portion comprising the reaction product of dihydroxy compound having a maximum molecular weight of 250 and dicarboxylic acid compound wherein the acid number of said backbone portion is less than 3 and (2) internal and pendant carboxylic acid moieties comprising an aromatic polycarboxylic acid compound having at least 3 acyl moieties which provides from 5 to 75 equivalent percent of the acyl moieties in the polyester, the said polyester resin having a molecular weight within the range of from 5000 to 35000 and an acid number within the range of from 15 to 55.
Abstract: Polymerization process for the solution or bulk polymerization of chlorocyclophosphazenes using sulfamic acid compounds or derivatives of sulfamic acid as catalyst. Poly(aryloxyphosphazene) resulting therefrom can be controlled as to molecular weight, and molecular weight distribution.
Abstract: Isomerization process for petroleum light hydrocarbons with a boiling point within the range of from about 100.degree. F. (38.degree. C.) to about 210.degree. F. (99.degree. C.) wherein said process comprises contacting said hydrocarbons with a catalyst consisting essentially of an ultrastable, large pore crystalline zeolite aluminosilicate material containing less than 1 (wt)% alkali metal and characterized by well-defined hydroxyl infra-red bands and a maximum unit cubic cell dimension of 24.55 A and a metal component selected from the metals, oxides or sulfides of the Group VIII elements of the Periodic Table, under suitable isomerization conditions.
Type:
Grant
Filed:
April 23, 1979
Date of Patent:
December 9, 1980
Assignee:
Standard Oil Company (Indiana)
Inventors:
F. William Hauschildt, Ralph J. Bertolacini
Abstract: Ethylene-propylene-diene ionic polymer compositions useful in injection molding, extrusion and other plastic processing techniques for fabricated products comprising an ionic elastomeric polymer and poly(alpha-methylstyrene).
Abstract: 4-Peroxyester derivatives of trimellitic anhydride and polymers derived by use of these derivatives as dual function reagents for polymerization and introduction of the phthalic anhydride moiety.
Abstract: Alpha-olefin polymerization catalyst comprising (A) a solid component which is the reaction product of components comprising (1) an alkyl aluminum halide and (2) a reaction product prepared by reacting components comprising a magnesium compound and a Group IVB or VB amide compound of the general formula M(NR.sub.2).sub.n L.sub.4-n wherein M is a Group IVB or VB metal, R is an alkyl or aryl group, L is a non-amine ligand, and n is a number of from 1 to 4; and (B) an organo aluminum promoter.
Abstract: This invention relates to the intramolecular oxidation and reduction of aromatic hydrocarbons containing at least one methyl group and a nitro group ortho to the methyl group. Further, it relates to preparing methyl o-amino arylcarboxylates and aromatic amines. The process comprises reacting aromatic hydrocarbons having at least one methyl group and a nitro group ortho to the methyl group in a solvent at a temperature of about 450.degree. to 750.degree. C. When the solvent is methanol, methyl o-amino arylcarboxylates useful in anesthetics, printing inks for polyethylene, and useful in the manufacture of azo dyes are produced. Novel substituted methyl anthranilates have been produced which have the foregoing uses. When no solvent is used or the solvent is benzene, cyclohexane, toluene, hexafluorobenzene or any other non-reactive solvent, the compounds are demethylated and aromatic amines are produced.
Abstract: A method and composition for fracturing a subterranean formation which comprises (1) contacting a subterranean formation with an aqueous liquid comprising a propping agent and a composition containing water, acrylamide:methacrylate copolymer cross-linked with chromium (III) ion, in presence of carbonate ion, oxalate ion, and, optionally, persulfate ion, (2) applying pressure to said liquid, (3) maintaining said pressure to fracture said formation, (4) and said gel breaking within 24 hours of gel formation. The composition without the persulfate gel breaking is also useful for sand consolidation and fluid control.
Abstract: Beta-phosphosulfoxy alcohols and preparation thereof by reacting an olefinically unsaturated compound and a poly-thiophosphoric acid with oxygen using actinic radiation as an energy source at a temperature of from -10.degree. to 70.degree. C., preferably in the presence of a dye sensitizer.
Abstract: A decarboxylation process for coupling aromatic compounds wherein cyclic hydrocarbons and heterocyclic compounds having at least one labile ring hydrogen are reacted with the mono silver salts of aromatic carboxylic acids, or mono silver salts of unsaturated compounds such as .alpha.,.beta.-ethylenically unsaturated acid compounds, or silver trifluoroacetate, or the mono silver salts are reacted with themselves, by heating to temperatures of 100.degree. to 500.degree. C. at pressures of 0.1 to 10 atmospheres, or by irradiating the reactants with ultraviolet light of 200 to 400 nanometers at temperatures of -30.degree. to 100.degree. C. The resulting dimers, trimers, polysubstituted polyphenyls, polyheterocyclics and trifluoromethylated aromatics are useful as heat transfer media, as intermediates for high molecular weight polymers, pesticides and petroleum additives, and as scintillation counters.
Abstract: Process for increasing the concentration of normal cis olefins in a hydrocarbon composition with pre-treated molecular sieves which have been heated to a temperature of from 400.degree. to 500.degree. F. for a period of about 1 to 6 hours to reach the water-zeolite equilibrium at said temperature range in the presence of water.
Type:
Grant
Filed:
February 27, 1978
Date of Patent:
January 29, 1980
Assignee:
Standard Oil Company (Indiana)
Inventors:
Chi-Hung Lin, William F. Pansing, deceased
Abstract: Highly-purified monomers for poly(p-methylenebenzoate) polymers and poly(m-methylenebenzoate) polymers are prepared by purifying acetoxylated hydroxymethylbenzoic acid compounds derived by side-chain acetoxylation of toluic acid compounds. The purification process can be by recrystallation or by fractional distillation.
Type:
Grant
Filed:
June 16, 1978
Date of Patent:
January 8, 1980
Assignee:
Standard Oil Company (Indiana)
Inventors:
Ellis K. Fields, Steven A. Cerefice, Edward E. Paschke
Abstract: Ethyl aromatics contained in the C.sub.9 aromatic fraction from fractionated reformate are selectively converted to xylenes via ethyl scission in the presence of a catalyst comprising a carrier of highly purified gamma alumina containing essentially no silica and of a surface area of at least 100 m.sup.2 /g and a metal selected from the group consisting of a Group VIII metal and a Group VIII metal promoted with zinc.
Type:
Grant
Filed:
April 24, 1978
Date of Patent:
December 4, 1979
Assignee:
Standard Oil Company (Indiana)
Inventors:
Allen I. Feinstein, Ralph J. Bertolacini, Dae K. Kim
Abstract: A decarboxylation process for coupling aromatic compounds wherein cyclic hydrocarbons and heterocyclic compounds having at least one labile ring hydrogen are reacted with the mono silver salts of aromatic carboxylic acids, or mono silver salts of unsaturated compounds such as .alpha.,.beta.-ethylenically unsaturated acid compounds, or silver trifluoroacetate, or the mono silver salts are reacted with themselves, by heating to temperatures of 100.degree. to 500.degree. C. at pressures of 0.1 to 10 atmospheres, or by irradiating the reactants with ultraviolet light of 200 to 400 nanometers at temperatures of -30.degree. to 150.degree. C. The resulting dimers, trimers, polysubstituted polyphenyls, polyheterocyclics and trifluoromethylated aromatics are useful as heat transfer media, as intermediates for high molecular weight polymers, pesticides and petroleum additives, and as scintillation counters.
Abstract: Fractionated heavy reformate containing ethyltoluenes and propylbenzenes is selectively hydrodealkylated and transalkylated to produce ethylbenzene-lean xylenes, benzene and C.sub.2 -C.sub.4 paraffins in the presence of a catalyst comprising a tungsten/molybdenum component of WO.sub.3 and MoO.sub.3 and an acidic component of 60 (wt)% of mordenite and 40 (wt)% of catalytically active alumina.
Type:
Grant
Filed:
November 8, 1977
Date of Patent:
October 30, 1979
Assignee:
Standard Oil Company (Indiana)
Inventors:
Allen I. Feinstein, Ralph J. Bertolacini
Abstract: Catalyst composition comprising highly purified alumina containing essentially no silica with a surface area of at least 100 m.sup.2 /g and up to 5% rhodium and up to 10% zinc.
Abstract: Process for disproportionation of petroleum hydrocarbons which comprises containing in a reaction zone said petroleum hydrocarbon under suitable disproportionation conditions with a catalytic composition comprising a tungsten/molybdenum component, said tungsten/molybdenum component deposited upon an acidic cracking component comprising a mordenite large pore crystalline aluminosilicate material and a refractory inorganic oxide.
Type:
Grant
Filed:
November 8, 1977
Date of Patent:
September 11, 1979
Assignee:
Standard Oil Company (Indiana)
Inventors:
Ralph J. Bertolacini, Dae K. Kim, Gerald M. Lehmann