Abstract: A coal conversion process which produces an increased yield of distillable products through an efficient use of hydrogen. Coal is contacted with a liquefaction solvent comprised of a process derived light phase residuum and a process derived distillate under liquefaction conditions to form a coal conversion product effluent. The effluent is admixed with a process derived hydrogenation residuum to supply hydrogen-donors and to cool and stabilize the effluent against regressive reactions. Distillables boiling below about 1000.degree. F. then are separated from the combined stream. A portion of the distillables can be recycled for use as solvent or hydrogenated and then recycled. The remaining residuum is admixed with a deashing solvent and thereafter deashed and fractionated under elevated temperature and pressure conditions. The residuum is separated to form a light phase residuum which is recycled for use as solvent and a heavy phase residuum suitable for further up grading.

Abstract: A borehole survey method and apparatus for use in drilling substantially horizontal boreholes through a mineral deposit wherein a dip accelerometer, a roll accelerometer assembly and a fluxgate are disposed near the drill bit, which is mounted on a bent sub, and connected to a surface computation and display unit by a cable which extends through the drill string. The dip angle of the borehole near the drill bit, the azimuth of the borehole near the drill bit and the roll angle or orientation of the bent sub are measured and selectively displayed at the surface while the drill string is in the borehole for utilization in guiding the drill bit through the mineral deposit along a predetermined path.

Abstract: A method of stabilizing wet process phosphoric acid containing acid soluble impurities preparatory to solvent extraction for the recovery of valuable minerals. The acid is introduced into a vessel containing crystal seed bed of the impurities. A portion of the acid then is withdrawn and concentrated to effect supersaturation of the impurities contained therein. The supersaturated acid is returned to the vessel to mix with the remaining solution and cause additional impurities to precipitate. Thereafter, a portion of the solution, containing precipitated impurities, is withdrawn and introduced into a separator. In the separator, the solution is separated into an essentially solids-free stream containing unprecipitated soluble impurities and a solids-containing stream.

Abstract: An improved process for beneficiating titaniferous material whereby formation of fines during leaching of the titaniferous material is minimized. The titaniferous material and mineral acid reactants each are heated to an elevated temperature prior to admixing in the leaching operation. The heated reactants then are admixed in a leaching zone and further heated to a leaching temperature of from about 110.degree. C. to about 150.degree. C. The preheating causes at least a portion of the acid-soluble titanium values in the titaniferous material to be hydrolyzed upon dissolution and to form an acid-insoluble precipitate. At least a portion of the precipitate is caused to deposit upon the titaniferous material such that fines or slime formation in the leach liquor is minimized. The leaching is continued for a sufficient time to dissolve most of the acid-soluble impurities contained in the titaniferous material. The solid residue remaining in the leaching zone is recovered as the beneficiated product.

Abstract: A process and apparatus for separating a solvent from a bituminous material by pressure reduction and steam stripping without carry-over of entrained bituminous material. A fluid-like phase comprising bituminous material and solvent is reduced in pressure by passage through a pressure reduction valve to vaporize a portion of the solvent. The reduction in pressure also results in dispersing a mist of fine particle size bituminous material in the vaporized solvent. The stream of vaporized solvent, fine particle size bituminous material and fluid-like bituminous material then is introduced into a steam stripper through an inlet horn that imparts a centrifugal motion to the stream. The inlet horn contains a plurality of corrugated vanes which utilize the centrifugal motion to create turbulence in the stream within the inlet horn.

Abstract: In general, the present invention provides processes and apparatus for bending and straightening or otherwise installing marine pipelines at underwater installations, and includes systems in which marine pipelines are installed at water depths to 250 feet or more, utilizing an underwater chamber which may be operated with its interior wet, dry or combinations thereof. In one form, the system provides for interconnecting wellheads or other stations with manifolds or other stations and comprises running marine pipeline generally vertically downwardly from the water surface into the work chamber, mounted in operative association with an underwater wellhead or station, wherein the pipe is bent in the desired radius and through the desired angle and then straightened to exit from the chamber and wellhead in a substantially horizontal attitude such that it may then be pulled to a manifold or other underwater station with, for example, a wire line.

Abstract: A process for effecting deashing solvent recovery from insoluble coal products and preparing a slurry of the insoluble products. An elevated temperature and pressure stream comprising insoluble coal products and deashing solvent is admixed with a makeup liquid to dilute the stream. The diluted stream is reduced in pressure and introduced into a first treatment vessel containing sufficient slurry to provide a hydrostatic pressure to prevent boiling of the diluted stream upon entry therein. The solvent then is permitted to flash and cool the remainder of the slurry. A portion of the cooled slurry is recycled to provide the makeup liquid and a second portion is introduced into a second treatment vessel to permit diffusion of solvent infused into the insoluble coal products in the slurry. The slurry of insoluble coal products in the second vessel then is introduced into a thickener to concentrate the slurry and provide a feed suitable for a gasifier.

Abstract: An energy efficient process for separating a hydrocarbonaceous material into various fractions. The hydrocarbonaceous material is admixed with a solvent and the mixture is introduced into a first separation zone maintained at an elevated first temperature and pressure. The feed mixture separates into a first light phase comprising solvent and at least a portion of the lightest hydrocarbonaceous material and a first heavy phase comprising the remainder of the hydrocarbonaceous material and some solvent. The first heavy phase is introduced into a second separation zone maintained at a second temperature level above the first temperature level and at an elevated pressure. The first heavy phase separates into a second light phase comprising solvent and a second heavy phase comprising at least a portion of the hydrocarbonaceous material. The separated hydrocarbonaceous material fractions are recovered.

Abstract: A process for drilling spaced horizontal boreholes in a coal or other mineral deposit in excess of 1500 feet in length in a pattern determined to maximize gas removal. Directional guidance is provided by a continuous downhole survey tool connected to data display devices by an internal drill rod cable system. Directional drilling control is provided by a positive displacement motor positioned at the end of the drill string and operated by a flow of drilling fluid through the drill string from the drilling rig. The mineral strata surrounding the borehole is periodically hydrofractured to permit effective removal of the gas. The hydrofractionation is effected without removal of the drill string or survey instruments from the borehole. Upon completion of the borehole, the drill string is removed and gas which enters the borehole from the surrounding deposit is withdrawn.

Abstract: A process for the production of sodium carbonate wherein sodium bicarbonate is recovered from a brine containing sodium carbonate by carbonation of the brine under controlled conditions. The sodium bicarbonate is crystallized from the carbonated brine in a multi-stage carbonating, cooling and crystallization process after which it is filtered to produce wet cake. The wet cake is subjected to predrying to provide a predried wet cake of a specified free moisture content and mixed with recycle light ash to provide a dryer feed of specified moisture content to alleviate problems of product fouling or plugging of the dryer. The light ash from the dryer then is bleached and subjected to recrystallization, screening, centrifuging and drying to provide a dried sodium carbonate possessing, after evaporation of the water of hydration and free moisture, less than 0.10 percent moisture and chemical and physical properties meeting commercial dense ash specifications.

Abstract: An improved particulate material loading system for transferring particulate material from a storage assembly to a vehicle having a storage bin wherein the material is protected from the outside environment during the transfer. The storage assembly includes a temporary cover which is operatively engagable with the vehicle to protect the storage bin of the vehicle when a hatch door of the vehicle is moved from a closed position to an open position to enable transfer of the material thereto. The vehicle is constructed to slidably receive the temporary cover of the storage assembly.

Abstract: A process for effecting a deep cut in a heavy hydrocarbon material without a decrease in the quality of the extracted oil caused by the presence of undesirable entrained resinous bodies and organometallic compounds. The heavy hydrocarbon material is contacted with a solvent in a first separation zone maintained at an elevated temperature and pressure to effect a separation of the feed into a first light phase and a first heavy phase comprising asphaltenes and some solvent. The first light phase is introduced into a second separation zone maintained at an elevated temperature and pressure to effect a separation of the first light phase into a second light phase comprising oils and solvent and a second heavy phase comprising resins and some solvent. A portion of the second heavy phase is withdrawn and introduced into an upper portion of the second separation zone to countercurrently contact the second light phase.

Abstract: A mining apparatus for excavating material from an earth formation having a miner which is removably connectable to a carrier by a coupling assembly, the mining apparatus including other carriers which are interconnected by the coupling assembly of the present invention. The coupling assembly includes a male connector and a female connector, the male connector being disposable in a portion of the female connector in an insert position and the male connector being movable from the insert position to a connected position for interconnecting the male and the female connectors.

Abstract: A continuous process for recovering substantially pure aluminum chloride from chlorination products of aluminum ore. The chlorination products are contacted with a first selective solvent to dissolve a substantial portion of the aluminum chloride and some ferric chloride. The solvent is separated from the chlorides which then are treated to produce a ferric chloride-rich stream and an aluminum chloride-rich stream in which the aluminum chloride to ferric chloride ratio is higher than the ratio prior to solvent separation. The aluminum chloride-rich stream is contacted with a second solvent to dissolve any ferric chloride present and saturate the solution with aluminum chloride. Aluminum chloride in excess of that soluble in the second solvent separates as a substantially pure solid phase. The solution is separated from solid phase and recycled in process to recover additional aluminum chloride.

Abstract: A process for separating a solvent from a bituminous material by pressure reduction and steam stripping without carry-over of entrained bituminous material. The fluid-like phase of bituminous material and solvent is reduced in pressure and introduced into a steam stripper. The solvent vaporizes upon pressure reduction and a mist of fine bituminous material particles forms and becomes dispersed in the vaporized solvent. The vaporized solvent and associated mist is separated from the bituminous material in the stripper and is withdrawn from the steam stripper and introduced into a condenser. The solvent and steam from the stripper condense, a substantial portion of the mist of entrained particles solidifies and an emulsion of water and fluid-like bituminous material from the mist forms. The liquid stream is withdrawn from the condenser and introduced into a separator.

Abstract: A process for recovering concentrated, purified tungsten values, such as ammonium paratungstate, from a brine containing minor amounts of soluble tungsten and a substantial concentration of impurities, the brine having a pH in the range of from about 7.0 to about 8.5. In general, the process comprises: contacting the brine with a substantially water-insoluble ion exchange resin to adsorb the soluble tungsten; eluting the adsorbed tungsten values from the ion exchange resin; treating the eluate to convert the tungsten values to an extractable species; recovering the extractable species of tungsten values from the eluate to substantially concentrate the tungsten values; contacting the concentrated tungsten values with an extractant to substantially load the extractant with the concentrated tungsten values; and recovering from the extractant a product having concentrated, purified tungsten values.

Abstract: A process for oxidizing a metal of variable valence to a higher valence state by electrochemical means. More particularly, a process for oxidizing a metal of variable valence, such as, for example, uranium or vanadium contained in wet process phosphoric acid to a higher valence state for extraction by subsequent contact with complex organic extractants. The wet process phosphoric acid is oxidized in an electrolytic cell operated at a constant current density. The cell comprises a tank having at least one anode having a surface coating containing manganese dioxide and at least one cathode, said anode and cathode having a ratio of surface areas exposed to the electrolyte in said cell of from at least about 100:1.

Abstract: A process for separating a solvent from a bituminous material by pressure reduction without carry-over of bituminous material. The fluid-like phase comprising bituminous material and solvent is reduced in pressure by passage through a pressure reduction valve and introduced into a steam stripper. The pressure reduction vaporizes part of the solvent and also disperses a mist of fine bituminous particles in the solvent. The solvent and mist are withdrawn from the steam stripper and introduced into a separation zone wherein they are caused to flow countercurrently to another stream of fluid-like bituminous material. The fluid-like bituminous material contacts the solvent and scrubs the fine bituminous material particles therefrom. The solvent is withdrawn and recovered. The fluid-like stream containing the bituminous particles can be recycled until the concentration is such that additional particles are not separated from the solvent after which a portion is bled off and fresh fluid-like material is added.

Abstract: An improved system for automatically transferring particulate material, such as coal, is provided wherein the particulate material is transferred from a railroad car into an underground storage bunker while maintaining the material in a substantially covered or protected condition.

Abstract: A process for drilling spaced horizontal boreholes in a coal or other mineral deposit in excess of 1500 feet in length in a pattern determined to maximize gas removal. Directional guidance is provided by a continuous downhole survey tool connected to data display devices by an internal drill rod cable system. Apparatus is provided to permit the passage of said cable system through the interior of a rotatable drill chuck assembly comprising a part of a drilling apparatus for drilling said boreholes. The apparatus supports the cable such that the cable is maintained in a substantially nonrotating position within the drill chuck assembly. Directional drilling control is provided by a positive displacement motor positioned at the end of the drill string and operated by a flow of drilling fluid through the drill string from the drilling rig. Upon completion of the borehole, the drill string is removed and gas which enters the borehole from the surrounding deposit is withdrawn.