Patents Represented by Attorney William H. Benz
  • Patent number: 4144252
    Abstract: Polymeric colorants comprising a hydrocarbon backbone and attached directly thereto through amine linkages, at least one water-solubilizing group and at least one optically chromophoric group are disclosed. In a preferred embodiment, the backbone is a saturated aliphatic hydrocarbon, the chromophore is an anthraquinone chromophore and the solubilizing group is a sulfonate or sulfamate residue.
    Type: Grant
    Filed: February 7, 1977
    Date of Patent: March 13, 1979
    Assignee: Dynapol
    Inventors: Patricia C. Wang, Robert E. Wingard
  • Patent number: 4138409
    Abstract: A new compound, denominated epoxysultone, having the structure ##STR1## is disclosed. The compound is an electrophilic addition agent of broad application which finds especial use in the preparation of new sweetener compounds. An intermediate to epoxysultone is also disclosed.
    Type: Grant
    Filed: July 31, 1978
    Date of Patent: February 6, 1979
    Assignee: Dynapol
    Inventors: Patricia C. Wang, Robert E. Wingard, Jr.
  • Patent number: 4127564
    Abstract: Diolefin-phenolic copolymeric antioxidants having solvent contents below 50 ppm and containing less than 0.3% of materials of molecular weight below 500 Daltons are recovered directly from a crude reaction product by removing catalyst and adjusting the reaction solvent content to 10-50% and thereafter subjecting the product to melt processing under volatilizing conditions at 200.degree.-425.degree. C, 0.1 to 10 mm Hg absolute, a surface area of at least 4 cm.sup.2 /g for from 0.5 to 7.5 minutes and then recovering the purified product.
    Type: Grant
    Filed: June 9, 1976
    Date of Patent: November 28, 1978
    Assignee: Dynapol
    Inventor: William L. Sanborn
  • Patent number: 4113505
    Abstract: Viscoelastic materials are differently colored in zones with polymric dyes. When a polymeric dye is added to a zone of a viscoelastic material it does not migrate from the zone; thus permitting an essentially permanently multizoned colored product.
    Type: Grant
    Filed: May 23, 1977
    Date of Patent: September 12, 1978
    Assignee: Dynapol
    Inventors: Nicolo Bellanca, Thomas Edward Furia
  • Patent number: 4107336
    Abstract: Edibles which contain water-soluble polymeric colorants having an ethylsulfonate-alkylamine co-polymer backbone.
    Type: Grant
    Filed: September 20, 1977
    Date of Patent: August 15, 1978
    Assignee: Dynapol
    Inventors: Kenneth Melvin Otteson, Daniel Joseph Dawson
  • Patent number: 4104196
    Abstract: Novel, nonabsorbable antioxidants of the general formula (An).sub.n R wherein An is a means for preventing oxidation of an oxidizable material, R is a means for essentially restricting the absorption of An in a biological environment, .about. is a means for covalently bonding An to R for a prolonged time, and n is at least one. The nonabsorbable antioxidants are useful as stabilizers in oxidizable materials without any substantial absorption of the antioxidant in the biological environment.
    Type: Grant
    Filed: March 15, 1976
    Date of Patent: August 1, 1978
    Assignee: Dynapol
    Inventor: Alejandro Zaffaroni
  • Patent number: 4098829
    Abstract: Polymeric hydroquinones of the structure ##STR1## WHEREIN N IS FROM 3 TO 10,000 INCLUSIVE AND R and R' independently are hydrogen or a lower alkyl, are disclosed, as is the preparation and the use of such materials, especially as nonabsorbable polymeric antioxidants for edible materials.
    Type: Grant
    Filed: May 19, 1977
    Date of Patent: July 4, 1978
    Assignee: Dynapol
    Inventors: Ned M. Weinshenker, James A. Dale
  • Patent number: 4096134
    Abstract: Ethylsulfonate-alkylamine copolymers are disclosed. These copolymers find special application as intermediates in the preparation of new water-soluble polymeric colorants which are also disclosed, especially water-soluble polymeric colorants for edibles.
    Type: Grant
    Filed: December 8, 1975
    Date of Patent: June 20, 1978
    Assignee: Dynapol
    Inventors: Kenneth Melvin Otteson, Daniel Joseph Dawson
  • Patent number: 4088572
    Abstract: The ultrafiltration purification of aqueous solutions of polymeric anthraquinone colorants, wherein low molecular weight impurities are removed in an ultrafiltrate leaving a purified anthraquinone colorant-bearing retentate, is carried out with improved efficiency when pyridine is present and maintained in the aqueous solutions at a level of from 1 to 20% by volume.
    Type: Grant
    Filed: November 18, 1976
    Date of Patent: May 9, 1978
    Assignee: Dynapol
    Inventors: Anthony R. Cooper, Robin G. Booth, David P. Matzinger
  • Patent number: 4078091
    Abstract: N-substituted maleimide polymers comprising the recurring structural units: ##STR1## wherein R and R' independently are lower alkyl groups of from 1 to 5 carbon atoms and n is an integer of from about 2 to about 2,000, are disclosed. Their preparation as well as the preparation of their monomer precursors and the preferred use of the polymers as antioxidants, particularly nonabsorbable food antioxidants, are also disclosed.
    Type: Grant
    Filed: December 18, 1975
    Date of Patent: March 7, 1978
    Assignee: Dynapol
    Inventors: James A. Dale, Steve Y. W. Ng
  • Patent number: 4055604
    Abstract: Insoluble polymeric organotin hydrides of the formula: ##STR1## WHEREIN P represents an organic polymer backbone; R and R.sub.1 each represent a hydrogen atom, a lower alkyl group of 1 to 5 carbon atoms, an aryl group of 6 to 10 carbon atoms, or an alkaryl or aralkyl group of from 7 to 10 carbon atoms; and n is a positive number greater than 1 are disclosed. Such polymeric organotin hydrides are useful as reagents for reducing organic compounds such as organic halides, ketones, and aldehydes without the difficult problem of removing dissolved or dispersed tin impurities from the reduced compounds.
    Type: Grant
    Filed: January 28, 1976
    Date of Patent: October 25, 1977
    Assignee: Dynapol
    Inventor: Ned M. Weinshenker
  • Patent number: 4055678
    Abstract: Dihydrochalcones of the formula ##STR1## derivatizing group, Y is a polar group, X is hydrogen or hydroxyl and R is a lower alkyl, their preparation and their use as non-sugar sweeteners are disclosed.
    Type: Grant
    Filed: January 12, 1976
    Date of Patent: October 25, 1977
    Assignee: Dynapol
    Inventors: Guy A. Crosby, Grant E. DuBois
  • Patent number: 4054676
    Abstract: Polymeric hydroquinones of the structure ##STR1## , wherein n is from 3 to 10,000 inclusive and R and R' independently are hydrogen or a lower alkyl, are disclosed, as is the preparation and the use of such materials, especially as nonabsorbable polymeric antioxidants for edible materials.
    Type: Grant
    Filed: December 4, 1974
    Date of Patent: October 18, 1977
    Assignee: Dynapol
    Inventors: Ned M. Weinshenker, James A. Dale
  • Patent number: 4051138
    Abstract: Polymeric colorants comprising a hydrocarbon backbone and attached directly thereto through amine linkages, at least one water-solubilizing group and at least one optically chromophoric group are disclosed. In a preferred embodiment, the backbone is a saturated aliphatic hydrocarbon, the chromophore is an anthraquinone chromophore and the solubilizing group is a sulfonate or sulfamate residue.
    Type: Grant
    Filed: December 8, 1975
    Date of Patent: September 27, 1977
    Assignee: Dynapol
    Inventors: Patricia C. Wang, Robert E. Wingard
  • Patent number: 4029706
    Abstract: Complexes of boron trihydride with solid particulate insoluble cross-linked thiohydrocarbon polymers are used in organic reduction reactions.
    Type: Grant
    Filed: March 10, 1975
    Date of Patent: June 14, 1977
    Assignee: Dynapol
    Inventor: Guy A. Crosby
  • Patent number: 4028342
    Abstract: Polymeric phenols of the formula ##STR1## WHEREIN N IS AN INTEGER FROM 3 TO 2,000, R.sub.1 is a lower alkyl and R.sub.2 is hydrogen or a lower alkyl, are disclosed. Their preparation and preferred use as antioxidants, especially nonabsorbable food antioxidants, are also disclosed.
    Type: Grant
    Filed: May 29, 1975
    Date of Patent: June 7, 1977
    Assignee: Dynapol Corporation
    Inventors: James A. Dale, William J. Leonard
  • Patent number: 4025535
    Abstract: Flavanones represented by the formula ##STR1## wherein R is a lower alkyl of from one to three carbon atoms inclusive, n is an integer of from one to three inclusive and M is hydrogen or a physiologically acceptable metal cation, are disclosed. These materials are themselves useful as dietetic sweeteners as well as being direct intermediates for the preparation of useful dihydrochalcone sweeteners.
    Type: Grant
    Filed: February 13, 1976
    Date of Patent: May 24, 1977
    Assignee: Dynapol Corporation
    Inventors: Guy A. Crosby, Grant E. DuBois, Ned M. Weinshenker
  • Patent number: 4018826
    Abstract: Poly(vinylamine) salts of mineral acids are produced by reacting acetaldehyde and acetamide at a mole ratio of 1:2-4 with acid catalyst, cracking the ethylidene-bis-acetamide which results into vinylacetamide, polymerizing the vinylacetamide with a free radical polymerization catalyst, and hydrolyzing the poly(vinylacetamide) to the desired amine salts by contacting the polyvinylacetamide with an aqueous solution of the corresponding mineral acid. This product may be converted to the free amine, which in turn may function as a precursor in the manufacture of certain polymeric dyes and colorants.
    Type: Grant
    Filed: November 4, 1974
    Date of Patent: April 19, 1977
    Assignee: Dynapol Corporation
    Inventors: Richard D. Gless, Jr., Daniel J. Dawson, Robert E. Wingard
  • Patent number: 4013801
    Abstract: Edible materials including foods, beverages and oral pharmaceuticals are sweetened by the addition of a sweetening amount in the range of from about 0.002% to 1% by weight (basis edible material) of flavanone represented by the structural formula ##STR1## wherein R is a lower alkyl of from one to three carbon atoms inclusive, n is an integer of from one to three inclusive and M is hydrogen or a physiologically acceptable metal cation.
    Type: Grant
    Filed: February 13, 1976
    Date of Patent: March 22, 1977
    Assignee: Dynapol Corporation
    Inventors: Daniel J. Dawson, Kenneth M. Otteson, C. Thomas Seitz
  • Patent number: 4000201
    Abstract: Organic liquids subject to oxidative decomposition, such as ethers, are stabilized against such decomposition by the addition of particulate, insoluble solid polymer resin to which is covalently bonded a plurality of oxidation active groups.
    Type: Grant
    Filed: October 4, 1974
    Date of Patent: December 28, 1976
    Assignee: Dynapol Corporation
    Inventor: Ned M. Weinshenker