Patents Represented by Attorney William J. Farrington
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Patent number: 5492948Abstract: A stabilizer system for the suppression of yellowing in styrenic polymers, consisting essentially of a benzotriazole such as 2-(2'-hydroxy-3',5'-di-tert-amylphenyl)benzotriazole, a hydroxybenzocyanurate such as tris-(3,5-di-tert-butyl-4-hydroxybenzyl)isocyanurate and a condensation product of a N,N'-(2,2,6,6-tetramethylpiperidyl)-alkylenediamine and a 6-amino-2,4-dichloro-1,3,5-s-triazine such as the condensation product of N,N'-(2,2,6,6-tetramethylpiperidyl)hexamethylenediamine and 6-morpholino-2,4-dichloro-1,3,5-s-triazine. Additionally a dialkyl thiodipropionate and a zinc dialkyldithiocarbamate may be included in the stabilizer system.Type: GrantFiled: January 9, 1995Date of Patent: February 20, 1996Assignee: Monsanto CompanyInventors: Moh C. O. Chang, Chuan-Ju Chen, Allen R. Padwa
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Patent number: 5492755Abstract: Disclosed herein are pultruded articles prepared from a reinforcing material and a polyamide matrix made by the process of impregnating a reinforcing material with a polyamide forming reaction mixture and then pultruding the impregnated reinforcing material through a die while polymerizing the polyamide forming reaction mixture to form a polyamide matrix, wherein the temperature of the material being pultruded is at least about at the lower end of the melting range of the polyamide.Type: GrantFiled: August 17, 1994Date of Patent: February 20, 1996Assignee: Monsanto CompanyInventors: Patrick Binse, Christian Campener, Philip Keating
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Patent number: 5409774Abstract: Disclosed herein is a composite structure comprising a layer of a gas filled cellular insulation material combined with a layer of impact resistant thermoplastic sheet material wherein an ABS sheet having a substantial number of rubber particles in range of from about 4 to about 10 microns (LR ABS) is interposed between the gas filled cellular material and the thermoplastic sheet.Type: GrantFiled: July 1, 1993Date of Patent: April 25, 1995Assignee: Monsanto CompanyInventors: Craig W. Pehlert, Paul J. Drenzek, Glenn B. Hilton
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Patent number: 5374385Abstract: A process for the reactive pultrusion of a reinforcing material and a polyamide matrix wherein a reinforcing material is impregnated with a polyamide forming reaction mixture and then pultruded through a die while the polyamide forming reaction mixture is polymerized to form a polyamide matrix, wherein the temperature of the material being pultruded is at least about at the lower end of the melting range of the polyamide.Type: GrantFiled: November 25, 1992Date of Patent: December 20, 1994Assignee: Monsanto Europe S.A.Inventors: Patrick Binse, Christian Campener, Philip Keating
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Patent number: 5334635Abstract: Antistatic thermoplastic styrenic compositions comprising high molecular weight polyethylene oxide and a lithium salt and ethylene glycol, diethylene glycol or triethylene glycol, characterized by their possession of a balance of mechanical properties, gloss and antistatic behavior.Type: GrantFiled: December 18, 1992Date of Patent: August 2, 1994Assignee: Monsanto CompanyInventor: Kishore Udipi
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Patent number: 5290849Abstract: The ammonium salt of a polymer of styrene and maleic anhydride includes 0.02 to 0.20 weight fraction copolymerized C.sub.1 -C.sub.3 alkyl methacrylate to improve paper signing properties.Type: GrantFiled: November 6, 1992Date of Patent: March 1, 1994Assignee: Monsanto CompanyInventor: Kang I. Lee
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Patent number: 5286792Abstract: Acrylonitrile-butadiene-styrene-ester compositions having a unique rubber phase morphology are prepared by a continuous mass polymerization process. The compositions have an improved balance between impact and tensile strengths and gloss.Type: GrantFiled: September 4, 1990Date of Patent: February 15, 1994Assignee: Monsanto CompanyInventors: Wan C. Wu, Vincent A. Aliberti
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Patent number: 5227428Abstract: A polyamide composition of improved impact comprising a blend of components (A) 5 to 79.5 weight percent of a graft rubber composition of a graft polymer of methyl (meth)acrylate and/or (meth)acrylonitrile and a vinylaromatic monomer grafted onto a substrate rubber, (B) 94.5 to 20 weight percent of a polyamide resin, and (C) 0.5 to 60 weight percent of a polymer compatibilizer which contains from about 0.05 to 4.0 mole percent of a comonomer containing a functional group which reacts with the polyamide resin is useful for molding and extrusion.Type: GrantFiled: January 15, 1992Date of Patent: July 13, 1993Assignee: Monsanto CompanyInventors: Richard E. Lavengood, Allen R. Padwa, Alva F. Harris
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Patent number: 5189098Abstract: Dispersions of core-shell polymers in caprolactam wherein the core-shell polymer comprises a crosslinked elastomer core and a hard thermoplastic shell prepared by adding an aqueous dispersion of core-shell polymer to an aqueous solution of caprolactam, stirring the mixture to provide a uniform dispersion and evaporating water from the mixture. Such dispersions can be combined with caprolactam polymerization initiator and caprolactam polymerization catalyst to provide rubber-modified nylon-6 polymers.Type: GrantFiled: October 1, 1990Date of Patent: February 23, 1993Assignee: Monsanto CompanyInventor: Kishore Udipi
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Patent number: 5189551Abstract: A solar screening film for a motor vehicle windshield comprises an interference filter having one or more heat reflecting metal layers and one or more coacting reflection-suppressing layers to minimize reflection and enhance visible transmission and a gradient band continuation of the interference filter above the direct line of forward vision through a windshield when the film is disposed therein in a motor vehicle, for reflective rejection of infra-red solar energy, such band including a light-reflecting metal layer gradually increasing in thickness toward an edge of the film.Type: GrantFiled: July 27, 1989Date of Patent: February 23, 1993Assignee: Monsanto CompanyInventor: Floyd E. Woodard
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Patent number: 5187230Abstract: Polymer blends useful as thermoplastic molding resins comprise PC, PETG and sufficient rubber, e.g. nitrile rubber or ethylene-acrylate copolymer rubber, to enhance the moldability of the blend. Preferred blends comprise at least 30% PC, 30% PETG and 5% rubber.Type: GrantFiled: August 7, 1991Date of Patent: February 16, 1993Assignee: Monsanto CompanyInventor: Kishore Udipi
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Patent number: 5183852Abstract: The invention pertains to blends of polymers containing a polyurethane, a polymer having reactive carboxyl moieties and a siloxane crosslinking agent. The polymer is most preferably represented by a terpolymer. The crosslinking agent contains reactive moieties such as hydroxy-, amine-, and epoxy-moieties and has a molecular weight which is preferably in the range of from about 1,500 to 60,000. The crosslinker can be used in relatively low molecular ratios vs. the polymerisable dicarboxylic acid in the polymer. Shaped articles made from the polyblends herein can be processed under high temperature conditions without suffering alterations; the articles so produced show desirable physical properties inclusive of reduced plasticiser migration, reduced fogging and enhanced low-temperature flexibility.Type: GrantFiled: May 22, 1991Date of Patent: February 2, 1993Assignee: Monsanto CompanyInventor: Peter M. Gomez
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Patent number: 5180777Abstract: A polyamide composition of improved impact resistance comprising a blend of components (A) a core/shell graft rubber composition having a thermoplastic copolymer shell comprising a polyamide-interactive monomer, (B) a polyamide and, (C) an acid-containing acrylate copolymer rubber.Type: GrantFiled: July 19, 1991Date of Patent: January 19, 1993Assignee: Monsanto CompanyInventors: Allen R. Padwa, Richard E. Lavengood, Raman Patel
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Patent number: 5166261Abstract: Disclosed herein is a continuous mass polymerization process for the preparation of acrylonitrile-butadiene-styrene-ester polymers (ABSE) having a balance of gloss, tensile strength, impact strength, processability and heat resistance properties.Type: GrantFiled: September 4, 1990Date of Patent: November 24, 1992Assignee: Monsanto CompanyInventors: Wan C. Wu, Vincent A. Aliberti
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Patent number: 5157080Abstract: A crosslinker composition comprising an etherified phenol-formaldehyde resin modified by addition of a styrene (meth)-allyl alcohol copolymer is used to provide epoxy and polyester-alkoxymethylmelamine coil coating compositions of enhanced gloss, hardness, chemical resistance, adhesion and flexibility.Type: GrantFiled: April 3, 1991Date of Patent: October 20, 1992Assignee: Monsanto CompanyInventors: Kenneth J. Gardner, Gary T. X. Mallalieu
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Patent number: 5149756Abstract: Hybrid curable compositions comprising components curable by condensation, and components curable by free-radical initiated polymerization, cure being catalyzed by a metal sulfonate. The components curable by condensation comprise amino resins and co-reactants. The components curable by free-radical initiated polymerization comprise acryloyl compounds.Type: GrantFiled: January 24, 1989Date of Patent: September 22, 1992Assignee: Monsanto CompanyInventor: David W. Demarey
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Patent number: 5145744Abstract: A wrinkle-free bilayer glazing panel comprising sequentially: a) a sheet of glass; b) a layer of plasticized partial polyvinyl butyral; c) a transparent polyester layer; and d) a layer of cross-linked, self-healing polyurethane.Type: GrantFiled: November 26, 1990Date of Patent: September 8, 1992Assignee: Monsanto CompanyInventors: George E. Cartier, Carl P. Piretti, Robert H. M. Simon
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Patent number: 5137954Abstract: Sheet for safety glazings made of: a) polyvinyl butyral internally plasticized by the presence in the polymer of C.sub.7 to C.sub.15 aliphatic aldehyde groups and b) an external plasticizer in amount sufficient to provide a sheet glass transition temperature of about 25.degree. to 30.degree. C.Type: GrantFiled: September 30, 1991Date of Patent: August 11, 1992Assignee: Monsanto CompanyInventors: Arijit M. DasGupta, Donald J. David, Roland J. Tetreault
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Patent number: 5137673Abstract: Plasticized polyvinyl butyral sheet optionally containing a gradient color band is formed by continuously extruding a sheet having a predetermined region across its width formed from melt issuing from a die at an increased mass flow rate in comparison with other portions of the melt forming the rest of the sheet and then forwardly distorting such sheet immediately after forming by preferentially stretching the side containing the predetermined region to form an arcuate shape of substantially uniform thickness. Arcuately shaped sections are then cut from the sheet to form discrete, shaped interlayer blanks having improved thickness uniformity and dimensional stability providing improved performance when used in laminated safety glass.Type: GrantFiled: November 17, 1987Date of Patent: August 11, 1992Assignee: Monsanto CompanyInventors: David P. Bourcier, Robert A. Esposito
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Patent number: 5130174Abstract: A shaped interlayer blank adapted for use with glass in a vehicle windshield, such blank formed of plasticized polyvinyl butyral and having a quadrilateral peripheral contour with two sides of arcuate shape and a wedge-shaped thickness profile. The blank preferably has an arcuate gradient color band substantially parallel to an arcuate edge of the blank in the greater thickness region of the blank. The wedge-shaped thickness gradually increases from about 30 mils to about 35 to 40 mils across the width of the blank. The blank is tailored for safety windshields featureing head-up displays where to function effectively the glass layes must be nonparallel and canted with respect to each other.Type: GrantFiled: October 12, 1989Date of Patent: July 14, 1992Assignee: Monsanto CompanyInventor: Robert A. Esposito