Abstract: A melt blended thermoplastic molding composition consisting essentially of, on a weight basis: (A) 40 to 70 parts plasticized polyvinyl butyral; (B) 60 to 30 parts poly(methylmethacrylate); (C) 0 to 15 parts filler; (D) 0 to 30 parts elastomeric graft polymer; and 0 to 30 parts thermoplastic polyurethane; provided that at least 10 parts of (D) or (E) or mixtures of (D) and (E) is present; and the sum of (A)+(B)+(C)+(D)+(E) is always 100.
Abstract: Weatherable thermoplastic polymeric compositions are formed by blending weatherable grafted rubber composition with an aliphatic diester selected from the group consisting of dialkoxyalkoxyalkyl diesters and dialkoxydialkoxyalkyl diesters of aliphatic dicarboxylic acids containing 4 to 8 carbon atoms.
Abstract: High solids compositions are described comprising a glycidamide containing more than one glycidamide group per molecule, a (meth)-acryloyl compound containing more than one (meth)-acryloyl group per molecule and a non-aromatic amine containing more than 2 amine hydrogen atoms per molecule. The compositions can be applied in coating, adhesive and laminating applications. They cure rapidly at room temperature to provide smooth, glossy, weather resistant surfaces.
Abstract: Polymer blends useful as thermoplastic molding resins comprise polycarbonate, PETG and ABS or ASA exhibit enhanced moldability, heat resistance and thick section impact resistance not available in binary blends of the components.
Abstract: Ethylenically unsaturated carbamates are prepared by reaction of unsaturated isocyanates with the hydroxy groups of polyvinyl acetals. The ethylenically unsaturated carbamates either alone or formulated with unsaturated co-reactants such as (meth)-acryloyl monomers and oligomers, maleates and fumarates provide radiation curable coating compositions.
Abstract: Hydroxy functional epoxidized amino resins comprising glycidamide groups. The polyglycidamides are produced from alkoxymethyl amino resins by reaction with acrylamide, followed by reaction with a polyol to introduce hydroxy functionality and then the unsaturated groups of the hydroxyfunctional acrylamidomethyl amino resins are epoxidized with an epoxidation agent such as hydrogen peroxide. The polyglycidamides are formulated with epoxy reactants to provide curable epoxy systems.
Abstract: A laminate which is substantially free of distortion when used in a safety glazing comprising a transparent, thermoplastic substrate layer, optionally surface treated or coated to improve adhesion, bearing one or more functional performance layers, such as an infra-red radiation reflecting stack, and at least one layer of plasticized polyvinyl butyral bonded on one side to a functional performance layer or the substrate layer having a roughened deairing surface on its other side characterized by a roughness value, Rz, of at least 10 micrometers, such plasticized polyvinyl butyral layer, before bonding to the substrate layer or functional performance layer, possessing low surface waviness on each side characterized by a wave index value, WI, of less than 15,000 square micrometers.
Abstract: A process for forming intermediate sheeting for forming shaped interlayer blanks comprising extruding plasticized polyvinyl butyral melt into an endless straight-sided sheet having a gradient color band extending along one side, the melt forming the region of the sheet laterally of the color band extruding at a greater thickness than that forming the portion containing the color band, thereby providing a wedge-shaped thickness profile in the sheet, quenching the extruded sheet to set the polymer and winding the sheet in roll form. The intermediate sheet is at least about twenty inches wide and the wedge-shaped cross section gradually increases from about 28 to 32 mils at one edge to about 33 to 40 mils at the other edge.
Abstract: Hybrid curable compositions comprising components curable by condensation, and components curable by free-radical initiated polymerization, cure being catalyzed by a metal sulfonate. The components curable by condensation comprise amino resins and co-reactants. The components curable by free radical initiated polymerization comprise acryloyl compounds and allylic or vinylenearylenemethylidyne compounds.
Abstract: A method of forming a bilayer glazing panel by providing an optically clear prelaminate of stretched polyester film coated with a cross-linked, self-healing polyurethane layer; assembling the prelaminate with a layer of plasticized partial polyvinyl butyral with the side of the polyester film without the polyurethane layer in facing contact with a subjacent textured surface of the partial polyvinyl butyral layer; clamping the assembled layers in a perimeter anchoring system; sequentially carrying out the following steps i), ii), iii), and optionally the above clamping step within an air autoclave; i) deairing the interface between the polyester film and plasticized partial polyvinyl butyral; ii) forcing localized regions of the layers within the perimeter anchoring system against a sheet of glass; and iii) subjecting the assembly of step ii) to elevated temperature and pressure while the plastic layers remain clamped within the perimeter anchoring system to firmly bond the plastic layers and glass sheet toget
Type:
Grant
Filed:
November 26, 1990
Date of Patent:
January 21, 1992
Assignee:
Monsanto Company
Inventors:
George E. Cartier, Carl P. Piretti, Robert H. M. Simon
Abstract: Polymer blends useful as thermoplastic molding resins comprise polycarbonate, PCTG and ABS or ASA and exhibit enhanced moldability, heat resistance and thick section toughness not available in binary blends of the components.
Abstract: Hybrid curable compositions comprising components curable by condensation and components curable by free radical initiated polymerization. The components curable by condensation reaction comprise amino resins and co-reactants, the condensation reaction being optionally catalyzed by acid catalysts. The components curable by free radical initiated polymerization comprise acryloyl compounds and allylic or vinylenearylenemethylidyne compounds.
Abstract: Ethylenically unsaturated carbamates prepared by addition of unsaturated isocyanates to the hydroxy groups of styrene allyl alcohol copolymers are formulated with allylic monomers and unsaturated co-reactants selected from (meth)-acryloyl monomers and oligomers, maleates and fumarates to provide air-dry-and heat-curable coating compositions.
Abstract: A method of dimensionally stabilizing a transparent, shrinkable thermoplastic layer, such as polyethylene terephthalate, in a draw-formed laminate with plasticized polyvinyl butyral which comprises heat setting the thermoplastic layer.
Abstract: Terpolymers of styrene, mono-iso-butyl maleate and mono-2-(n-butoxy)ethyl maleate wherein the ratio of styrene units to maleate units is in the range of about 1:1 to about 1.6:1 and the ratio of mono-iso-butyl maleate units to mono-2-(n-butoxy)ethyl maleate is in the range of about 3:2 to about 1:3. The terpolymers are useful as alkali soluble binders for photoresist compositions.
Abstract: A polycarbonate composition having present therein particles of rubber grafted with an ethylenically unsaturated aromatic monomer and either acrylonitrile or methacrylonitrile, characterized in that the particles have an average size of from 20 to 300 nm before being blended with the polycarbonate and agglomerate during blending to form aggregates of average size 500 to 10,000 nm, and in that the composition can be injection moulded to produce a moulding wherein the aggregates substantially retain their identity and the moulding has a surface of matt appearance.
Abstract: In a solar screening assembly optionally heatable for defrosting/defogging/deicing which includes a plasticized polyvinyl butyral layer and a metal/dielectric stack comprising one or more light-reflecting metal layers and two or more antireflective layers, a cap layer Ta.sub.2 O.sub.5 or SiOx where x.ltoreq.2, in face-adhering contact with the plasticized polyvinyl butyral layer, such assembly when laminated with glass exhibiting pummel adhesion of at least 3 after at least 1000 hours exposure to UV radiation in a Fadeometer, Weatherometer or equivalent system.
Abstract: Ethylenically unsaturated carbamates are prepared by reaction of unsaturated isocyanates with the hydroxy groups of polyvinyl acetals. The ethylenically unsaturated carbamates either alone or formulated with unsaturated co-reactants such as (meth)-acryloyl monomers and oligomers, maleates and fumarates provide radiation curable coating compositions.
Abstract: The invention relates to a polyblend comprising from 20 to 80% of a polymer A and from 80 to 20% of a polymer B, based on the total weight of polymers A and B in the polyblend, and wherein:Polymer A is a copolymer of 35 to 65% of methyl methacrylate and 35 to 65% of styrene grafted on butadienestyrene rubber, methyl methacrylate being partially replaceable by an acrylic ester, and either methyl methacrylate or grafting styrene being partially replaceable by acrylonitrile; andPolymer B is a copolymer of from 20 to 60% of a vinylaromatic hydrocarbon monomer, from 20 to 60% of a C.sub.1 -C.sub.4 -alkyl acrylate or a C.sub.1 -C.sub.4 -alkyl methacrylate ester, and from 12 to 30% of maleic anhydride or maleimide or a N-substituted maleimide or a mixture of such maleic acid derivatives.The polyblends have heat resistance, transparency and impact strength.
Abstract: Ethylenically unsaturated carbamates are prepared by reaction of unsaturated isocyanates with the hydroxy groups of styrene allyl alcohol copolymers. The ethylenically unsaturated carbamates either alone or formulated with unsaturated co-reactants such as (meth)-acryloyl monomers and oligomers, maleates and fumarates provide radiation curable coating compositions.